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    • 41. 发明授权
    • Flexible, scratch resistant radiation curable inkjet inks
    • 灵活,耐划伤的可辐射固化喷墨油墨
    • US08998398B2
    • 2015-04-07
    • US13695096
    • 2011-06-09
    • Ivan Hoogmartens
    • Ivan Hoogmartens
    • B41J2/01C09D11/101B41J2/21C09D11/32
    • C09D11/101B41J2/2107C09D11/32
    • A free radical radiation curable inkjet ink containing a photoinitiator and polymerizable compounds includes a) no more than 15 wt % of one or more monofunctional acrylates wherein the homopolymer thereof has a Tg smaller than 20° C.; and b) at least 45 wt % of a mixture of monomers consisting of b1) 10 to 45 wt % of a N-vinyl lactam and/or a vinylether acrylate; and b2) 10 to 45 wt % of an ethoxylated and/or propoxylated polyacrylate having a molecular weight of at least 450; wherein all wt % are based on the total weight of the inkjet ink; and wherein the Tg is determined by the DSC method in ISO 11357-2:1999.
    • 含有光引发剂和可聚合化合物的自由基可辐射固化喷墨油墨包括:a)不超过15重量%的一种或多种单官能丙烯酸酯,其中其均聚物的Tg小于20℃; 和b)至少45重量%的由b1)10至45重量%的N-乙烯基内酰胺和/或乙烯基醚丙烯酸酯组成的单体混合物; 和b2)10至45重量%的分子量为至少450的乙氧基化和/或丙氧基化聚丙烯酸酯; 其中所有wt%都是基于喷墨油墨的总重量; 并且其中Tg通过ISO 11357-2:1999中的DSC方法测定。
    • 44. 发明申请
    • NON-AQUEOUS PIGMENTED INKJET INKS
    • 不含水的墨水INKJET墨水
    • US20090270537A1
    • 2009-10-29
    • US12441719
    • 2007-10-02
    • Ivan HoogmartensKatrien BernaertsGeert Deroover
    • Ivan HoogmartensKatrien BernaertsGeert Deroover
    • C09D11/10C08K5/3492
    • C09D11/101
    • A non-aqueous inkjet ink includes C.I. Pigment Yellow 150 and a polymeric dispersant according to Formula (I): wherein, T represents hydrogen or a polymerization terminating group; Z represents the residue of polyethyleneimine having a number-average molecular weight of at least 100; A represents an oxyalkylene carbonyl group; T-C(O)An- represents a TPOAC-chain which is bound to Z through an amide bond; and n and m are integers wherein m is at least 2 and n is from 2 to 100; the polymeric dispersant fulfills the conditions of: WTPOAC>57 and NAmide≧65 mol % wherein WTPOAC represents the ratio of the weight percentage of TPOAC-chains over the weight percentage of amide bonds in the polymeric dispersant; NAmide represents the mol % of amide bonds based on the total nitrogen content of the polymeric dispersant; and the values of WTPOAC and NAmide are calculated from the total nitrogen content determined by dry combustion of the polymeric dispersant and from the amine content determined through potentiometric titration in a mixture of CH3COOH:THF (14.5:0.5) with 0.1N aqueous perchloric acid.
    • 非水性喷墨油墨包括C.I. 颜料黄150和根据式(I)的聚合物分散剂:其中,T表示氢或聚合终止基团; Z表示数均分子量为100以上的聚乙烯亚胺的残基; A表示氧化烯羰基; T-C(O)An-表示通过酰胺键与Z结合的TPOAC-链; 并且n和m是其中m为至少2且n为2至100的整数; 聚合物分散剂满足以下条件:WTPOAC> 57和NAmide> = 65mol%,其中WTPOAC表示TPOAC链的重量百分比与聚合物分散剂中酰胺键的重量百分比的比率; 基于聚合物分散剂的总氮含量,NAmide表示酰胺键的摩尔%; 并且从通过聚合物分散剂的干燃烧确定的总氮含量和通过在CH 3 COOH:THF(14.5:0.5)与0.1N高氯酸的混合物中的电位滴定测定的胺含量计算WTPOAC和NAmide的值。
    • 47. 发明授权
    • Thermographic recording material with improved print archivability without loss in printability
    • 具有改进的打印可归档性而不损失可打印性的热成像记录材料
    • US06759367B2
    • 2004-07-06
    • US10107378
    • 2002-03-27
    • Johan LoccufierGeert DefieuwIvan Hoogmartens
    • Johan LoccufierGeert DefieuwIvan Hoogmartens
    • B41M530
    • G03C1/4989G03C1/49827
    • A monosheet black and white substantially light-insensitive thermographic recording material comprising a thermosensitive element and a support, the thermosensitive element containing a substantially light-insensitive organic silver salt, a 3,4-dihydroxybenzene compound in thermal working relationship therewith and a binder, wherein the 3,4-dihydroxybenzene compound is an aryloxo-3,4-dihydroxybenzene compound in which the aryl-group is substituted with at least one substituent having a &sgr;m-value greater than 0; or a heteroaryloxo-3,4-dihydroxybenzene compound in which the heteroaryl group has a unified aromaticity index IA greater than 53 and is optionally substituted with at least one group selected from the group consisting of aryl, hydroxy, carboxy, sulfo, sulfoalkyl, sulfoaryl, sulfonylalkyl, sulfonylaryl, annulated aryl, annulated heteroaryl, carboxyalkyl, carboxyaryl, oxoalkyl, oxoaryl, halogen, nitro, cyano and mercapto-alkyl groups; and a thermographic recording process therefor.
    • 包含热敏元件和载体的单片黑色和白色基本上不光敏感的热敏成像记录材料,所述热敏元件含有基本上不光敏的有机银盐,与其热处理的3,4-二羟基苯化合物和粘合剂,其中 3,4-二羟基苯化合物是芳氧基-3,4-二羟基苯化合物,其中芳基被至少一个Sigmam值大于0的取代基取代; 或杂芳基氧-3,4-二羟基苯化合物,其中杂芳基具有大于53的统一芳香族指数IA,并且任选被至少一个选自芳基,羟基,羧基,磺基,磺基烷基,磺基芳基 磺酰基烷基,磺酰基芳基,环状芳基,环状杂芳基,羧基烷基,羧基芳基,氧代烷基,氧代芳基,卤素,硝基,氰基和巯基 - 烷基; 及其热成像记录方法。
    • 48. 发明授权
    • Thermographic recording material with improved image tone
    • 具有改善图像色调的热成像记录材料
    • US06686313B2
    • 2004-02-03
    • US09996272
    • 2001-11-28
    • Carlo UyttendaeleRene De KeyzerJohan LoccufierIvan Hoogmartens
    • Carlo UyttendaeleRene De KeyzerJohan LoccufierIvan Hoogmartens
    • B41M530
    • G03C1/4989
    • A monosheet black and white substantially light-insensitive thermographic recording material comprising a thermosensitive element and a support, the thermosensitive element containing a substantially light-insensitive organic silver salt and an organic reducing agent therefor in thermal working relationship therewith and a binder, wherein the thermographic recording material comprises a reaction product of an amino-group containing polymer and a compound according to formula (I): wherein each of R1, R2, R3 and R4 is independently hydrogen or an optionally substituted alkyl, aryl, heteroaryl, alkoxy or aryloxy group; L is a divalent linking group selected from the group consisting of oxygen and optionally substituted alkyl, aryl, heteroaryl, alkenyl and alkynyl groups; and m is either 0 or 1; and n is either 0 or 1; and a preparation process therefor.
    • 包含热敏元件和载体的单片黑色和白色基本上不光敏感的热敏成像记录材料,热敏元件含有基本上不光敏的有机银盐和与其进行热加工关系的有机还原剂和粘合剂,其中热敏成像 记录材料包含含氨基聚合物和根据式(I)的化合物的反应产物:其中R 1,R 2,R 3和R 4各自独立地为氢或 任选取代的烷基,芳基,杂芳基,烷氧基或芳氧基; L是选自氧和任选取代的烷基,芳基,杂芳基,烯基和炔基的二价连接基团; m为0或1; 且n为0或1; 及其制备工艺。
    • 49. 发明授权
    • Thermographic recording material with improved image tone
    • 具有改善图像色调的热成像记录材料
    • US06586363B2
    • 2003-07-01
    • US09995281
    • 2001-11-27
    • Johan LoccufierIvan Hoogmartens
    • Johan LoccufierIvan Hoogmartens
    • B41M530
    • B41M5/3375B41M5/30G03C1/49845G03C1/4989
    • A substantially light-insensitive black and white thermographic recording material comprising a thermosensitive element and a support, the thermosensitive element containing at least one substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, an image tone stabilizer and a binder, wherein the image tone stabilizer is a compound according to formula (I): wherein R1 is hydrogen, an alkali metal ion, an ammonium ion, a phosphonium ion, a sulphonium ion, an alkaline earth ion or an optionally substituted alkyl, cycloalkyl, heterocyclic, alkaryl, aralkyl, heteroaryl or aryl group; R2 is an optionally substituted alkyl, cycloalkyl, heterocyclic, alkaryl, aralkyl, heteroaryl or aryl group; or R1 and R2 together represent the atoms necessary to form a ring structure; and X is hydrogen, an alkali metal ion, an ammonium ion, a phosphonium ion, a sulphonium ion or an alkaline earth ion; and a recording process therefor.
    • 包含热敏元件和支持体的基本上不透光的黑白热成像记录材料,所述热敏元件含有至少一种基本上不光敏的有机银盐,与其热加工关系的有机还原剂,图像色调稳定剂和 粘合剂,其中所述图像稳定剂是根据式(I)的化合物:其中R1是氢,碱金属离子,铵离子,鏻离子,锍离子,碱土金属离子或任选取代的烷基, 环烷基,杂环,烷芳基,芳烷基,杂芳基或芳基; R2是任选取代的烷基,环烷基,杂环,烷芳基,芳烷基,杂芳基或芳基; 或者R1和R2一起表示形成环结构所必需的原子; X为氢,碱金属离子,铵离子,鏻离子,锍离子或碱土金属离子; 及其记录过程。