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    • 41. 发明授权
    • Dye releasing couplers for heat image separation systems
    • 用于热图像分离系统的脱色成色剂
    • US5356750A
    • 1994-10-18
    • US993580
    • 1992-12-21
    • John TexterThomas R. WelterDavid T. SouthbyJared B. Mooberry
    • John TexterThomas R. WelterDavid T. SouthbyJared B. Mooberry
    • G03C8/10G03C8/40G03C5/54
    • G03C8/4033G03C8/10G03C8/4066
    • An aqueous-developable photographic color diffusion transfer element comprising a single dimensionally stable support and one or more layers comprising radiation sensitive silver halide, thermal solvent for facilitating the thermal diffusion of dyes through a hydrophilic binder, a dye-releasing coupler, and hydrophilic binder, wherein said dye is heat diffusible in said binder and thermal solvent, and wherein said dye-releasing coupler is of the structureCp--L-DyewhereCp is a cyan dye forming radical, magenta dye forming radical, yellow dye forming radical, black dye forming radical, or colorless product forming radical, said Cp being substituted in the coupling position with a divalent linking group, L;Dye is a dye radical exhibiting selective absorption in the visible spectrum; and where said --L-Dye group couples off upon reaction of said coupler radical with the oxidation product of a primary amine developing agent is disclosed.
    • 含水显影照相色彩扩散转移元件包括单尺寸稳定的载体和一层或多层包含辐射敏感的卤化银,用于促进染料通过亲水性粘合剂的热扩散的热溶剂,染料释放成色剂和亲水性粘合剂, 其中所述染料在所述粘合剂和热溶剂中是热扩散的,并且其中所述染料释放成色剂具有结构Cp-L-Dye,其中Cp是形成自由基的青色染料,形成自由基的品红色染料,形成自由基的黄色染料,黑色染料 形成自由基或无色产物形成基团,所述Cp在偶联位置被二价连接基团L取代; 染料是在可见光谱中显示出选择性吸收的染料基团; 并且其中所述-L-染料基团在所述成色剂基团与伯胺显影剂的氧化产物反应时偶联。
    • 48. 发明授权
    • Photographic element containing cylacetamido yellow dye-forming couplers
    • 含有甲酰乙酰氨基黄染料成色剂的摄影元件
    • US5998106A
    • 1999-12-07
    • US069391
    • 1998-04-29
    • Paul B. MerkelDavid A. SteeleJerrold N. PoslusnyThomas R. Welter
    • Paul B. MerkelDavid A. SteeleJerrold N. PoslusnyThomas R. Welter
    • G03C7/36G03C1/005G03C7/30G03C7/305G03C7/46
    • G03C7/30535G03C1/0051G03C7/3022G03C7/30558G03C7/36
    • Disclosed is a photographic element comprising a silver halide emulsion layer having associated therewith a 3-indoloylacetanilide yellow dye-forming coupler of structure I, below: ##STR1## wherein: R.sub.1 is an alkyl or phenyl group;R.sub.2 is a phenyl, t-butyl, cyclohexyl or naphthyl group;X is a halogen atom or an alkoxy or alkyl group;each R.sub.3 is in the para position or either meta position relative to the anilino nitrogen and is individually selected from the group consisting of halogen atoms, and alkyl, phenyl, alkoxy, phenoxy, carbamoyl, sulfamoyl, carbonamido, sulfonamido, alkylsulfonyl, arylsulfonyl, alkoxycarbonyl, aryloxycarbonyl, acyloxy, sulfoxyl, sulfonyloxy, alkylthio, acyl and cyano groups; and n is 1, 2 or 3;R.sub.4 is a hydrogen atom or an alkyl group:R.sub.5 is a hydrogen atom or an alkyl group; andeach R.sub.6 is individually a halogen atom, an alkyl group or an alkoxy group and m is 0-4;provided that substituents may join to form a ring.
    • 公开了一种照相元件,其包含卤化银乳剂层,其具有下文结构I的3-吲哚基乙酰替苯胺黄色染料形成成色剂:其中:R1是烷基或苯基; R2是苯基,叔丁基,环己基或萘基; X是卤素原子或烷氧基或烷基; 苯基,烷氧基,苯氧基,氨基甲酰基,氨磺酰基,碳酰氨基,亚磺酰氨基,烷基磺酰基,芳基磺酰基,烷氧基羰基,烷氧基羰基, ,芳氧基羰基,酰氧基,磺酰氧基,磺酰氧基,烷硫基,酰基和氰基; n为1,2或3; R4是氢原子或烷基:R5是氢原子或烷基; 并且各个R6分别为卤素原子,烷基或烷氧基,m为0-4; 条件是取代基可以连接形成环。
    • 49. 发明授权
    • Heat image separation with phenolic thermal solvents and dye releasing
couplers
    • 用酚类热溶剂和染料释放成色剂进行热图像分离
    • US5512410A
    • 1996-04-30
    • US323967
    • 1994-10-17
    • John TexterThomas R. WelterDavid T. SouthbyJared B. MooberryDavid S. Bailey
    • John TexterThomas R. WelterDavid T. SouthbyJared B. MooberryDavid S. Bailey
    • G03C8/10G03C8/40G03C8/50
    • G03C8/4033G03C8/10G03C8/4066
    • An aqueous-developable photographic color diffusion transfer element comprising one and only one dimensionally stable support and one or more layers comprising radiation sensitive silver halide, thermal solvent for facilitating the thermal diffusion of dyes through a hydrophilic binder, a dye-releasing coupler, a dye-receiving layer intermediate said support and dye-releasing coupler containing layers, a stripping layer intermediate said dye-receiving layer and any layers containing silver halide or dye-releasing coupler, and hydrophilic binder, wherein said dye is heat diffusible in said binder and thermal solvent, wherein said dye-releasing coupler is of the structureCp--L--DyewhereCp is a coupler radical substituted in the coupling position with a divalent linking group, L;Dye is a dye radical exhibiting selective absorption in the visible spectrum; and where said --L--Dye group couples off upon reaction of said coupler radical with the oxidation product of a primary amine developing agent, and such that said Dye radical is subsequently released from the --L--Dye group;where said stripping layer contains a stripping agent; andwherein said thermal solvent has the structure I: ##STR1## wherein (a) Z.sub.1, Z.sub.2, Z.sub.3, Z.sub.4, and Z.sub.5 are substituents, the Hammet sigma parameters of Z.sub.2, Z.sub.3, and Z.sub.4 sum to give a total, .SIGMA., of at least -0.28 and less than 1.53;(b) the calculated logP for I is greater than 3 and less than 10, is disclosed.
    • 一种含水显影照相色彩扩散转移元件,包括一个且仅一维稳定的载体和一个或多个包含辐射敏感卤化银的层,用于促进染料通过亲水性粘合剂的热扩散的热溶剂,染料释放成色剂,染料 接收层介于所述支持和释放染料的成色剂层之间,所述染料接收层和包含卤化银或染料释放成色剂的任何层的剥离层和亲水性粘合剂,其中所述染料在所述粘合剂中热扩散,并且热 溶剂,其中所述染料释放成色剂具有结构Cp-L-Dye,其中Cp是在与二价连接基团L的偶联位置取代的成色剂基团; 染料是在可见光谱中显示出选择性吸收的染料基团; 并且其中所述-L-染料基团在所述成色剂基团与伯胺显影剂的氧化产物反应时脱离,并且使得所述染料自由基随后从-L-染料基团中释放; 其中所述剥离层包含剥离剂; 并且其中所述热溶剂具有以下结构I:其中(a)Z 1,Z 2,Z 3,Z 4和Z 5为取代基,Z 2,Z 3和Z 4的Hammetσ参数相加, SIGMA至少为-0.28且小于1.53; (b)公开了I的计算logP大于3并小于10。