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41. 发明授权

US08637443B2 Cleaning compositions and methods comprising a hydrofluoro-olefin or hydrochlorofluoro-olefin solvent 有权
标题翻译：包括氢氟烯烃或氢氯氟烯烃溶剂的清洁组合物和方法
公开(公告)号：US08637443B2
公开(公告)日：2014-01-28
申请号：US13140176
申请日：2009-12-17
申请人： Rajat Basu , Gary Zyhowski , Kane Cook , David Nalewajek
发明人： Rajat Basu , Gary Zyhowski , Kane Cook , David Nalewajek
IPC分类号： C11D3/24
CPC分类号： C11D3/43 , C11D1/004 , C11D1/006 , C11D7/5018 , C23G5/02809 , C23G5/02825 , D06L1/04 , D06M13/453 , D06M23/10 , D06M2200/01
摘要： The invention provides solvent and cleaning compositions comprising an ionic surfactant, which preferably has a fluorinated portion thereof, and a solvent selected from hydrofluoro- and/or hydrochlorofluoro-olefins. Additionally, the invention provides drying, dry cleaning, and soil repellency compositions containing a hydrofluoro- or hydrochlorofluoro-olefin and said surfactant. Additionally, the invention provides drying compositions containing a hydrofluoro-olefin or hydrochlorofluoro-olefin and an alcohol such as methanol, ethanol or isopropanol.
摘要翻译：本发明提供溶剂和清洁组合物，其包含优选具有其氟化部分的离子表面活性剂和选自氢氟酸和/或氢氯氟烯烃的溶剂。此外，本发明提供了含有氢氟或氢氯氟烯烃和所述表面活性剂的干燥，干洗和疏水组合物。此外，本发明提供含有氢氟烯烃或氢氯氟代烯烃和醇如甲醇，乙醇或异丙醇的干燥组合物。

42. 发明申请

US20110252694A1 COMPOSITIONS FOR DRIP FUMIGATION 审中-公开
标题翻译： DRIP FUMIGATION的组成
公开(公告)号：US20110252694A1
公开(公告)日：2011-10-20
申请号：US12762801
申请日：2010-04-19
申请人： Andrew Joseph Poss , Rajiv Ratna Singh , David Nalewajek , Cheryl Cantlon
发明人： Andrew Joseph Poss , Rajiv Ratna Singh , David Nalewajek , Cheryl Cantlon
IPC分类号： A01M13/00 , A01P13/00 , A01P5/00 , A01N29/00 , A01P3/00
CPC分类号： A01N29/00 , A01N25/04 , A01N2300/00
摘要： Soil fumigation compositions are provided herein that include methyl iodide, at least one fluorocarbon or hydrofluorocarbon, at least one surfactant, and water. The fumigant can be produced by combining the water and surfactant with an initial mixture that is an azeotropic or azeotrope-like mixture of methyl iodide and at least one fluorocarbon or hydrofluorocarbon. The fumigant compositions can be utilized in drip fumigation processes, and have increased volatility as compared to methyl iodide alone, which can reduce the risk of water contamination when utilizing methyl iodide as a fumigant.
摘要翻译：本文提供了包括甲基碘，至少一种碳氟化合物或氢氟烃，至少一种表面活性剂和水的土壤熏蒸组合物。熏蒸剂可以通过将水和表面活性剂与初始混合物（其是甲基碘和至少一种碳氟化合物或氢氟烃的共沸或类共沸混合物）混合来制备。熏蒸剂组合物可用于滴水熏蒸方法，并且与单独的甲基碘相比具有增加的挥发性，当使用甲基碘作为熏蒸剂时，这可以降低水污染的风险。

43. 发明申请

US20110198756A1 Organometallic Precursors and Related Intermediates for Deposition Processes, Their Production and Methods of Use 审中-公开
标题翻译：有机金属前体及相关中间体，用于沉积过程，其生产和使用方法
公开(公告)号：US20110198756A1
公开(公告)日：2011-08-18
申请号：US12067285
申请日：2006-08-25
申请人： ü Thenappan , Chien-Wei Li , David Nalewajek , Martin Cheney , Jingyu Lao , Eric Eisenbraun , Min Li , Nathaniel Berliner , Mikko Ritala , Markku Leskela , kaupo Kukli , Linda Cheney
发明人： ü Thenappan , Chien-Wei Li , David Nalewajek , Martin Cheney , Jingyu Lao , Eric Eisenbraun , Min Li , Nathaniel Berliner , Mikko Ritala , Markku Leskela , kaupo Kukli , Linda Cheney
IPC分类号： H01L21/3205 , H01L29/43 , H01L23/48
CPC分类号： C07F17/02 , C23C16/18
摘要： Vapor deposition precursors that can deposit conformal thin ruthenium films on substrates with a very high growth rate, low resistivity and low levels of carbon, oxygen and nitrogen impurities have been provided. The precursors described herein include a compound having the formula CMC′, wherein M comprises a metal or a metalloid; C comprises a substituted or unsubstituted acyclic alkene, cycloalkene or cycloalkene-like ring structure; and C′ comprises a substituted or unsubstituted acyclic alkene, cycloalkene or cycloalkene-like ring structure; wherein at least one of C and C′ further and individually is substituted with a ligand represented by the formula CH(X)R1, wherein X is a N, P, or S-substituted functional group or hydroxyl, and R1 is hydrogen or a hydrocarbon. Methods of production of the vapor deposition precursors and the resulting films, and uses and end uses of the vapor deposition precursors and resulting films are also described.
摘要翻译：已经提供了可以在非常高的生长速率，低电阻率和低水平的碳，氧和氮杂质的基底上沉积保形薄钌薄膜的气相沉积前体。本文所述的前体包括具有式CMC'的化合物，其中M包含金属或准金属; C包括取代或未取代的无环烯烃，环烯烃或环烯烃环结构; 和C'包括取代或未取代的无环烯烃，环烯烃或环烯烃环结构; 其中C和C'中的至少一个进一步和单独地被式CH（X）R 1表示的配体取代，其中X是N，P或S-取代的官能团或羟基，并且R 1是氢或烃。还描述了气相沉积前体和所得膜的生产方法，以及气相沉积前体和所得膜的用途和最终用途。

44. 发明申请

US20090269478A1 CARRIER SOLVENT FOR FINGERPRINT FORMULATIONS 失效
标题翻译：载体溶液用于指纹制剂
公开(公告)号：US20090269478A1
公开(公告)日：2009-10-29
申请号：US12422260
申请日：2009-04-11
申请人： David Nalewajek , Cheryl L. Cantlon , Andrew J. Poss , Rajiv Ratna Singh , Ian Shankland
发明人： David Nalewajek , Cheryl L. Cantlon , Andrew J. Poss , Rajiv Ratna Singh , Ian Shankland
IPC分类号： A61B5/117 , C09D11/00
CPC分类号： A61B5/1172
摘要： A method and composition for transforming a latent physiological biometric into a visible physiological biometric are provided, the method comprising: providing a latent biometric disposed on a surface of an article, wherein said biometric comprises at least one eccrine-derived compound; contacting said latent biometric with a developing solution, wherein said developing solution comprises at least one imaging reagent selected from ninhydrin and 1,8-diazafluoren-9-one and a carrier solvent comprising at least one C3-C4 hydrofluorocarbon; and reacting said imaging reagent with said eccrine-derived compound to produce a visible physiological biometric.
摘要翻译：提供了一种用于将潜在生理学生物转化为可见生理生物学的方法和组合物，所述方法包括：提供设置在制品表面上的潜伏生物测定，其中所述生物测定包含至少一种衍生化合物; 使所述潜在生物测定与显影溶液接触，其中所述显影溶液包含至少一种选自茚三酮和1,8-二氮杂芴-9-酮的成像试剂和包含至少一种C 3 -C 4氢氟烃的载体溶剂; 并使所述成像试剂与所述外分泌衍生的化合物反应以产生可见的生理学生物学特征。

45. 发明申请

US20050233932A1 Azeotrope-like compositions of tetrafluoropropene and pentafluoropropene 有权
标题翻译：四氟丙烯和五氟丙烯的类共沸组合物
公开(公告)号：US20050233932A1
公开(公告)日：2005-10-20
申请号：US10826597
申请日：2004-04-16
申请人： Rajiv Singh , Hang Pham , David Wilson , Raymond Thomas , David Nalewajek
发明人： Rajiv Singh , Hang Pham , David Wilson , Raymond Thomas , David Nalewajek
IPC分类号： C08J9/14 , C09K5/00 , C09K5/04 , C11D7/50 , C11D17/08
CPC分类号： C08J9/146 , C08J2207/04 , C09K5/045 , C09K2205/126 , C11D7/505
摘要： Provided are azeotrope-like compositions comprising tetrafluoropropene and pentafluoropropene and uses thereof, including use in refrigerant compositions, refrigeration systems, blowing agent compositions, and aerosol propellants.
摘要翻译：提供包含四氟丙烯和五氟丙烯的类共沸组合物及其用途，包括用于制冷剂组合物，制冷系统，发泡剂组合物和气溶胶推进剂中。

46. 发明授权

US06803441B2 Compositions and methods for thermosetting molecules in organic compositions 失效
标题翻译：有机组合物中热固性分子的组成和方法
公开(公告)号：US06803441B2
公开(公告)日：2004-10-12
申请号：US10267380
申请日：2002-10-08
申请人： Kreisler Lau , Feng Quan Liu , Boris Korolev , Emma Brouk , Ruslan Zherebin , David Nalewajek
发明人： Kreisler Lau , Feng Quan Liu , Boris Korolev , Emma Brouk , Ruslan Zherebin , David Nalewajek
IPC分类号： C08G6378
CPC分类号： C08G61/12 , C08G61/02 , C08G2650/60
摘要： In a method of producing a low dielectric constant polymer, a thermosetting monomer is provided, wherein the thermosetting monomer has a cage compound or aryl core structure, and a plurality of arms that are covalently bound to the cage compound or core structure. In a subsequent step, the thermosetting monomer is incorporated into a polymer to form the low dielectric constant polymer, wherein the incorporation into the polymer comprises a chemical reaction of a triple bond that is located in at least one of the arms. Contemplated cage compounds and core structures include adamantane, diamantane, silicon, a phenyl group and a sexiphenylene group, while preferred arms include an arylene, a branched arylene, and an arylene ether. The thermosetting monomers may advantageously be employed to produce low-k dielectric material in electronic devices, and the dielectric constant of the polymer can be controlled by varying the overall length of the arms.
摘要翻译：在制造低介电常数聚合物的方法中，提供了一种热固性单体，其中该热固性单体具有笼形化合物或芳基核心结构，以及共价结合笼形化合物或核心结构的多个臂。在随后的步骤中，将热固性单体引入聚合物中以形成低介电常数聚合物，其中掺入聚合物中包含位于至少一个臂中的三键的化学反应。考虑的笼状化合物和核心结构包括金刚烷，二金刚烷，硅，苯基和亚噻吩基，而优选的臂包括亚芳基，支链亚芳基和亚芳基醚。热固性单体可以有利地用于在电子器件中产生低k介电材料，并且聚合物的介电常数可以通过改变臂的整个长度来控制。

47. 发明授权

US5811604A Continuous production of 1,1,1,3,3,3-hexafluoropropane and 1-chloro-1,1,3,3,3-pentafluoropropane 失效
标题翻译：连续生产1,1,1,3,3,3-六氟丙烷和1-氯-1,1,3,3,3-五氟丙烷
公开(公告)号：US5811604A
公开(公告)日：1998-09-22
申请号：US796002
申请日：1997-02-05
申请人： Kevin Robert Benson , David Elliott Bradley , David Nalewajek
发明人： Kevin Robert Benson , David Elliott Bradley , David Nalewajek
IPC分类号： C07C17/20 , C07C17/00
CPC分类号： C07C17/206
摘要： A process for the continuous production of 1,1,1,3,3,3-hexafluoropropane (HFC-236fa) and/or 1-chloro-1,1,3,3,3-pentafluoropropane (HCFC-235fa) in the liquid phase wherein the HFC-235fa and/or HFC-236fa serve as solvents for the reaction. When the reaction is conducted in the presence of a catalyst of SbF.sub.3, SbF.sub.5 or a mixture of SbF.sub.5 and HSO.sub.3 F, the reaction mass is unexpectedly less corrosive to the reaction vessel used.
摘要翻译：一种连续制备1,1,1,3,3,3-六氟丙烷（HFC-236fa）和/或1-氯-1,1,3,3,3-五氟丙烷（HCFC-235fa）的方法液相，其中HFC-235fa和/或HFC-236fa用作反应的溶剂。当反应在SbF 3，SbF 5或SbF 5和HSO 3 F的混合物存在下进行时，反应物料对所用反应容器的腐蚀性意外地较少。

48. 发明授权

US5154846A Fluorinated butylene oxide based refrigerant lubricants 失效
标题翻译：氟化环氧丁烷基制冷剂润滑剂
公开(公告)号：US5154846A
公开(公告)日：1992-10-13
申请号：US614549
申请日：1990-11-16
申请人： Raymond H. P. Thomas , David Nalewajek , Hang T. Pham , David P. Wilson
发明人： Raymond H. P. Thomas , David Nalewajek , Hang T. Pham , David P. Wilson
IPC分类号： C09K5/04 , C10M107/38 , C10M111/04 , C10M171/00
CPC分类号： C09K5/041 , C10M107/38 , C10M111/04 , C10M171/008 , C10M2203/06 , C10M2203/065 , C10M2203/10 , C10M2203/1006 , C10M2203/102 , C10M2203/1025 , C10M2203/104 , C10M2203/1045 , C10M2203/106 , C10M2203/1065 , C10M2203/108 , C10M2203/1085 , C10M2205/00 , C10M2205/026 , C10M2205/04 , C10M2207/021 , C10M2207/026 , C10M2207/027 , C10M2207/028 , C10M2207/125 , C10M2207/129 , C10M2207/144 , C10M2207/146 , C10M2207/262 , C10M2207/28 , C10M2207/2805 , C10M2207/283 , C10M2207/345 , C10M2209/084 , C10M2209/086 , C10M2209/102 , C10M2209/1033 , C10M2209/1045 , C10M2209/105 , C10M2209/1055 , C10M2209/1065 , C10M2209/1075 , C10M2209/1085 , C10M2209/1095 , C10M2211/003 , C10M2211/022 , C10M2211/042 , C10M2211/06 , C10M2211/08 , C10M2213/00 , C10M2213/02 , C10M2213/023 , C10M2213/04 , C10M2213/043 , C10M2213/06 , C10M2213/0606 , C10M2213/062 , C10M2213/0623 , C10M2215/06 , C10M2215/065 , C10M2215/086 , C10M2215/28 , C10M2217/023 , C10M2217/028 , C10M2217/06 , C10M2219/02 , C10M2219/022 , C10M2219/024 , C10M2219/044 , C10M2219/046 , C10M2219/082 , C10M2223/04 , C10M2223/042 , C10M2223/045 , C10M2223/047 , C10M2223/065 , C10M2225/00 , C10M2225/02 , C10M2227/09 , C10M2229/02 , C10M2229/05 , C10M2229/051 , C10N2210/06 , C10N2220/02 , C10N2240/00 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66
摘要： The present invention provides a novel lubricating composition comprising polybutylene glycol having a cap of a fluorinated alkyl group on at least one end thereof. The composition has a molecular weight between about 300 and about 4,000, and a viscosity of about 5 to about 150 centistokes at 37.degree. C. The composition is miscible in combination with refrigerant.As such, the present invention provides a composition for use in compression refrigeration and air-conditioning comprising: (a) a refrigerant selected from the group consisting of hydrofluorocarbon, hydrochlorofluorocarbon, fluorocarbon, and chlorofluorocarbon; and (b) a sufficient amount to provide lubrication of at least one polybutylene glycol having a cap of a fluorinated alkyl group on at least one end thereof.
摘要翻译：本发明提供一种新型的润滑组合物，其包含在其至少一端具有氟化烷基的帽的聚丁二醇。该组合物的分子量在约300至约4000之间，并且在37℃下的粘度为约5至约150厘沲。该组合物可与制冷剂混合。因此，本发明提供了一种用于压缩制冷和空调的组合物，包括：（a）选自氢氟烃，氢氯氟烃，氟碳化合物和氯氟烃的制冷剂; 和（b）足够的量以在其至少一端上提供具有氟化烷基的帽的至少一种聚丁二醇的润滑。

49. 发明授权

US4935519A N-fluoropyridinium pyridine heptafluorodiborate 失效
标题翻译： N-氟吡啶鎓吡啶七氟二硼酸酯
公开(公告)号：US4935519A
公开(公告)日：1990-06-19
申请号：US406659
申请日：1989-09-13
申请人： Michael Van Der Puy , David Nalewajek , George A. Shia , William J. Wagner
发明人： Michael Van Der Puy , David Nalewajek , George A. Shia , William J. Wagner
IPC分类号： C07D213/89 , C07F5/02
CPC分类号： C07D213/89 , C07F5/022
摘要： The present invention provides a novel compound represented as ##STR1## The present novel compound is prepared by reacting fluorine with pyridine-boron trifluoride and is useful as a fluorinating agent in the fluorination of organic compounds.
摘要翻译：本发明提供了一种新化合物，其表示为本发明的新化合物，其通过氟与吡啶 - 三氟化硼反应制备，并且可用作有机化合物的氟化中的氟化剂。

50. 发明授权

US4886921A Synthesis of carbon fluoride and carbon fluoride chloride 失效
标题翻译：氟化碳和氟化碳氯化物的合成
公开(公告)号：US4886921A
公开(公告)日：1989-12-12
申请号：US182637
申请日：1988-04-18
申请人： David Nalewajek
发明人： David Nalewajek
IPC分类号： C01B9/02 , C01B9/08 , C01B31/00 , C01B31/30 , H01M4/58 , H01M4/583
CPC分类号： H01M4/583 , C01B31/005 , H01M4/5835
摘要： An improved synthesis of carbon fluoride CF.sub.x, and carbon fluoride chloride, (C.sub.y F.sub.x Cl.sub.z).sub.n, is described. Direct fluorination of the intermediate (C.sub.y F.sub.x Cl.sub.z).sub.n (x.ltoreq.0.7, y.ltoreq.1 and z.ltoreq.0.1) in the absence of chlorine produces, either CF.sub.x (x.gtoreq.1) or (C.sub.y F.sub.x Cl.sub.z).sub.n (x.gtoreq.0.9, y=1, z.ltoreq.0.01) in as brief a period as 1 hour. The final CF.sub.x product is novel and exhibits improved properties compared to CF.sub.x made via conventional methods. The novel process for producing carbon fluoride chloride is more economical than prior art methods.
摘要翻译：描述了氟化碳CF x和氟化碳氯化物（CyFxClz）n的改进合成。在不存在氯的情况下，中间体（CyFxClz）n（x <= 0.7，y = 1和z / = 1）或（CyFxClz）n x> = 0.9，y = 1，z <0.01）。与通过常规方法制备的CFx相比，最终的CFx产品是新颖的并且表现出改进的性能。生产氟化碳氯化物的新方法比现有技术方法更经济。

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