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    • 47. 发明授权
    • FEINTEILIGE, AMPHOTERE, WÄSSRIGE POLYMERDISPERSIONEN, VERFAHREN ZU IHRER HERSTELLUNG UND IHRE VERWENDUNG
    • FEINTEILIGE,AMPHOTERE,WÄSSRIGEPOLYMERDISPERSIONEN,VERFAHREN ZU IHRER HERSTELLUNG UND IHRE VERWENDUNG
    • EP1756179B1
    • 2007-12-05
    • EP05750531.5
    • 2005-06-03
    • BASF Aktiengesellschaft
    • KUKULA, HildegardETTL, RolandDYLLICK-BRENZINGER, RainerSTURM, Bernhard
    • C08F212/08C08F220/34C08F220/36C08F220/60C08F2/06C08F257/02D21H21/16C14C11/00
    • D21H21/16C08F212/08C08F212/10C08F257/02C14C11/003D21H11/14D21H17/37D21H17/375D21H17/45C08F2/18C08F220/18
    • The invention relates to a fine-particled, amphoteric, aqueous polymer dispersion, obtained by means of a two-stage polymerisation, whereby, in the first polymerisation stage, a pre-polymer made from a monomer mixture of (a) 15 to 40 wt. % of at least one (meth)acrylate ester and/or (meth)acrylamide with a free, protonated and/or quaternised amino group, (b) 40 to 70 wt. % of at least one optionally substituted styrol, (c) 0 to 25 wt. % acrylonitrile and/or methacrylonitrile, (d) 0.5 to 5 wt. % of at least one ethylenically-unsaturated monomer comprising acid groups and (e) 0 to 30 wt. % of at least one non-ionic ethylenically-unsaturated monomer different from (b) or (c) and the sum of (a) + (b) + (c) + (d) + (e) = 100 wt. % is prepared by solution polymerisation in a solvent which is partly to completely miscible with water, the solution/dispersion of the pre-polymer is then added to water and then subjected to an emulsion polymerisation in a second polymerisation step with at least one non-ionic, ethylenically-unsaturated monomer. The invention further relates to the production of the polymer dispersion by a two-stage polymerisation and use of the polymer dispersion as sizing medium for paper, pulp and cardboard.
    • 本发明涉及通过两阶段聚合获得的细粒两性聚合物水分散体,其中在第一聚合阶段中,由(a)15-40重量%的单体混合物制备的预聚物 。 (b)40-70重量%的至少一种(甲基)丙烯酸酯和/或(甲基)丙烯酰胺与游离的,质子化的和/或季铵化的氨基。 %的至少一种任选取代的苯乙烯,(c)0-25wt。 %丙烯腈和/或甲基丙烯腈,(d)0.5-5wt。 至少一种含酸基的烯键式不饱和单体和(e)0-30wt。 (a)+(b)+(c)+(d)+(e)= 100wt%的至少一种与(b)或(c)不同的非离子烯键式不饱和单体。 %是通过溶液聚合在部分与水完全混溶的溶剂中制备的,然后将预聚物的溶液/分散体加入水中,然后在第二聚合步骤中与至少一种非离子表面活性剂进行乳液聚合, 离子型烯属不饱和单体。 本发明进一步涉及通过两阶段聚合生产聚合物分散体并使用聚合物分散体作为用于造纸,纸浆和纸板的施胶介质。
    • 50. 发明授权
    • VERFAHREN ZUR HERSTELLUNG VON PAPIER, PAPPE UND KARTON
    • VERFAHREN ZUR HERSTELLUNG VON PAPIER,PAPPE UND KARTON
    • EP0980450B1
    • 2002-10-02
    • EP98924201.1
    • 1998-04-24
    • BASF AKTIENGESELLSCHAFT
    • ETTL, RolandMEIXNER, HubertESSER, AntonSCHOLZ, RainerMAHR, NorbertSTEUERLE, UlrichHÖNE, MatthiasLORENZ, Klaus
    • D21H21/02D21H17/45D21H17/54
    • C08G73/0206C08F8/32C08F8/44C08G73/028D21H17/08D21H17/14D21H17/17D21H17/37D21H17/38D21H17/49D21H17/55D21H17/56D21H21/10D21H21/16
    • The invention relates to a method for producing paper, paperboard and cardboard by dehydrating paper material containing interfering substances in the presence of fixing agents. Reaction products are used as fixing agents. Said products are obtained by reacting polymers, containing amino and/or ammonium groups, from the group of: polymers containing vinyl amino units, polyalkylene polyamines, polyamidoamines, polyamidoamines grafted with ethylene imine and optionally cross-linked, polydiallydldimethylammoniumchlorides; polymers containing dialkylaminoalkylacrylamide-units or dialkylaminoalkylmethacrylamide units and polyallylamines and dicyandiamide-formaldehyde-condensates, with reactive sizing agents for paper with a polymer/reactive sizing agent weight ratio of 15,000 : 1 to 1 : 1. The invention also relates to reaction products thus obtained and to their use as fixing agents for water soluble and water insoluble interfering substances in the production of paper, paperboard and cardboard from paper materials containing interfering substances.
    • 本发明涉及一种通过在固定剂存在下使含有干扰物质的纸材料脱水来生产纸,纸板和纸板的方法。 反应产物用作固定剂。 所述产品通过使含有氨基和/或铵基团的聚合物与以下物质反应而获得:含乙烯基氨基单元,聚亚烷基多胺,聚酰胺胺,用乙烯亚胺接枝的聚酰胺胺和任选交联的聚二烯丙基二甲基氯化铵; 含有二烷基氨基烷基丙烯酰胺单元或二烷基氨基烷基甲基丙烯酰胺单元和聚烯丙基胺和双氰胺 - 甲醛 - 缩合物的聚合物,以及聚合物/活性施胶剂重量比为15,000:1至1:1的用于纸张的反应性施胶剂。本发明还涉及如此获得的反应产物 并且涉及它们在由含有干扰物质的纸材料生产造纸,纸板和纸板中作为水溶性和水不溶性干扰物质的固定剂的用途。