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41. 发明专利

DE19922038A1 Multistage oligomerization of 2-8C olefins uses a nickel-containing catalyst distributed over the zones to make maximum use of its activity 未知
公开(公告)号：DE19922038A1
公开(公告)日：2000-11-16
申请号：DE19922038
申请日：1999-05-12
申请人： BASF AG
发明人： SCHULZ RALF , WALTER MARC , NEUMANN HANS-PETER , BROX WOLFGANG
IPC分类号： C07B61/00 , C07C2/08 , C07C2/10 , C07C11/02
摘要： Oligomerization of 2-8C olefins in a sequence of \- 2 reaction zones is such that the volume of Ni-containing catalyst in each zone is set so that the difference between the temperature rises experienced by the feed in two zones is no more than 20 deg C. Oligomerization of 2-8C olefins comprises passing an olefin-containing hydrocarbon stream through a sequence of \- 2 adiabatically-operated reaction zones over a heterogeneous Ni-containing catalyst so that the stream experiences a temperature increase delta Treact in each zone and such that the stream enters the first zone at Tin and, prior to entering each subsequent zone, is cooled to Tin +/- 20 deg C. The relative catalyst volume in each zone is such that the difference in delta Treact between two zones is at most 20 deg C. An Independent claim is also included for a process comprising: (i) passing the olefin-containing hydrocarbon stream over a first zone over a heterogeneous Ni-containing catalyst; (ii) separating off the oligomers formed and dividing the hydrocarbon stream into two sub-streams (Ia) and (Ib); (iii) recycling sub-stream (Ia) to the first zone and passing (Ib) to a second zone containing the catalyst; (iv) separating off the oligomers from the product of the second zone and dividing the stream into sub-streams (IIa) and (IIb); and (v) recycling (IIa) to the second zone and taking (IIb) out of the process, the ratios (Ia)/(Ib) and (IIa)/(IIb) being such that the oligomer concentration in the reaction mixture does not exceed 30 wt.% in any zone.

42. 发明专利

AU3813000A Method for producing alcohol surfactants and alcohol ether surfactants, the products obtained and their use 未知
公开(公告)号：AU3813000A
公开(公告)日：2000-10-09
申请号：AU3813000
申请日：2000-03-17
申请人： BASF AG
发明人： MAAS HEIKO , ROPER MICHAEL , WALTER MARC , SCHULZ RALF , TROPSCH JURGEN , JAGER HANS-ULRICH
IPC分类号： C07H15/04 , C07B61/00 , C07C2/06 , C07C2/08 , C07C2/10 , C07C11/00 , C07C11/02 , C07C27/22 , C07C29/132 , C07C29/16 , C07C29/36 , C07C29/38 , C07C29/40 , C07C29/44 , C07C29/46 , C07C31/02 , C07C31/125 , C07C41/03 , C07C43/13 , C07C45/50 , C07C303/24 , C07C305/06 , C07C305/10 , C07F9/09 , C07F9/11 , C07H1/00 , C07H13/04 , C08B1/00 , C08B37/00 , C11D1/72
摘要： The invention describes a process for the preparation of surfactant alcohols and surfactant alcohol ethers which are, inter alia, highly suitable as surfactants or for the preparation of surfactants. The process, starting from olefin mixtures having a defined minimum content of linear hexenes, gives mixtures having a predominant fraction of branched dodecenes, which are subsequently derivatized to give surfactant alcohols and then optionally alkoxylated. The surfactant alcohol mixture obtained in the process has a degree of branching of from 2.0 to 3.0 and in particular exhibits advantageous properties as regards ecotoxicity and biodegradability. A description is also given of the use of the surfactant alcohols and surfactant alcohol ethers as surfactants by glycosidation or polyglycosidation, sulfation or phosphation.

43. 发明专利

AU3164200A Method of preparing surface-active alcohols and surface-active alcoholic ethers,products obtained by said method and their use 未知
公开(公告)号：AU3164200A
公开(公告)日：2000-09-28
申请号：AU3164200
申请日：2000-03-06
申请人： BASF AG
发明人： MAAS HEIKO , ROPER MICHAEL , WALTER MARC , SCHULZ RALF , TROPSCH JURGEN , JAGER HANS-ULRICH
IPC分类号： C07H15/04 , A61K31/454 , A61K31/498 , A61P25/28 , C07B61/00 , C07C2/08 , C07C2/10 , C07C11/02 , C07C29/141 , C07C29/16 , C07C29/48 , C07C31/125 , C07C41/03 , C07C43/11 , C07C43/13 , C07C303/24 , C07C305/06 , C07C305/10 , C07D235/06 , C07D241/42 , C07D263/56 , C07D317/68 , C07D319/18 , C07D405/06 , C07F9/09 , C07F9/11 , C09K23/02 , C09K23/14 , C09K23/42 , C09K23/56 , C11D1/29 , C11D1/34 , C11D1/72
摘要： The invention describes a process for the preparation of surfactant alcohols and surfactant alcohol ethers which are, inter alia, highly suitable as surfactants or for the preparation of surfactants. The process, starting from olefin mixtures which comprise less than 30% by weight of linear hexene isomers and utilizing a catalyst which contains nickel, prepares olefin mixtures having a predominant fraction of branched dodecenes, which are subsequently derivatized to give surfactant alcohols and then optionally alkoxylated.The invention further relates to the use of the surfactant alcohols and surfactant alcohol ethers for the preparation of surfactants by glycosidation or polyglycosidation, sulfation or phosphation.

44. 发明专利

DE19912418A1 未知
公开(公告)号：DE19912418A1
公开(公告)日：2000-09-21
申请号：DE19912418
申请日：1999-03-19
申请人： BASF AG
发明人： MAAS HEIKO , ROEPER MICHAEL , WALTER MARC , SCHULZ RALF , TROPSCH JUERGEN , JAEGER HANS-ULRICH
IPC分类号： C07H15/04 , C07B61/00 , C07C2/06 , C07C2/08 , C07C2/10 , C07C11/00 , C07C11/02 , C07C27/22 , C07C29/132 , C07C29/16 , C07C29/36 , C07C29/38 , C07C29/40 , C07C29/44 , C07C29/46 , C07C31/02 , C07C31/125 , C07C41/03 , C07C43/13 , C07C45/50 , C07C303/24 , C07C305/06 , C07C305/10 , C07F9/09 , C07F9/11 , C07H1/00 , C07H13/04 , C08B1/00 , C08B37/00 , C11D1/72
摘要： The invention relates to a method for producing alcohol surfactants and alcohol ether surfactants which are inter alia suitable as surfactants or for producing surfactants. According to the inventive method, olefinic mixtures with a defined minimum content of linear hexene mixtures with a prevailing amount of branched dodecenes are produced which are converted to alcohol surfactants and are then optionally alkoxylated. The alcohol surfactant mixture obtained by the inventive method is characterized by a branching degree of 2.0 to 3.0 and has specifically advantageous properties in terms of its ecotoxicity and biodegradability. The invention further relates to the use of the alcohol surfactants and alcohol ether surfactants as surfactants by glycosidation or polyglycosidation, sulfation or phosphatization.

45. 发明专利

DE19859911A1 未知
公开(公告)号：DE19859911A1
公开(公告)日：2000-06-29
申请号：DE19859911
申请日：1998-12-23
申请人： BASF AG
发明人： MAAS HEIKO , ROEPER MICHAEL , WALTER MARC , SCHULZ RALF , TROPSCH JUERGEN , JAEGER HANS-ULRICH , SCHWAB PETER , SCHULZ MICHAEL
IPC分类号： C07B61/00 , C07C2/10 , C07C6/04 , C07C11/02 , C07C11/107 , C07C29/16 , C07C31/125 , C07C41/03 , C07C43/13 , C07C45/50 , C07F9/09 , C07F9/11 , C07C11/00 , C07C2/06 , C07H15/04 , C07C305/06 , C11D1/825
摘要： The invention relates to a method for producing novel surfactant alcohols and surfactant alcohol ethers by derivatising olefins with approximately 10 to 20 C-atoms or mixtures of such olefins to produce alkanols and optionally, subsequently alkoxylating them. The method is characterised in that a C4-olefin-mixture is subjected to metathesis, the resulting olefins are dimerised and then derivatised to produce surfactant alcohols, and these are optionally alkoxylated. The olefin mixture obtained from dimerisation contains a large proportion of branched components and less than 10 wt. % of compounds containing a vinylidene group. The invention also relates to the use of surfactant alcohols and surfactant alcohol ethers for producing surfactants by glycosylation or polyglycosylation, sulphation or phosphation.

46. 发明专利

ES2219097T3 未知
公开(公告)号：ES2219097T3
公开(公告)日：2004-11-16
申请号：ES99962263
申请日：1999-12-21
申请人： BASF AG
发明人： MAAS HEIKO , ROPER MICHAEL , WALTER MARC , SCHULZ RALF , TROPSCH JURGEN , JAGER HANS-ULRICH
IPC分类号： C07B61/00 , C07C2/10 , C07C6/04 , C07C11/02 , C07C11/107 , C07C29/16 , C07C31/125 , C07C41/03 , C07C43/13 , C07C45/50 , C07F9/09 , C07F9/11
摘要： The invention describes a process for the preparation of novel surfactant alcohols and surfactant alcohol ethers by derivatization of olefins having from about 10 to 20 carbon atoms or of mixtures of such olefins to give alkanols, and optional subsequent alkoxylation, which comprises subjecting a C 4 -olefin mixture to metathesis, dimerizing the resulting olefins, and then derivatizing them to give surfactant alcohols, and optionally alkoxylating said alcohols. The olefin mixture obtained in the dimerization has a high proportion of branched components and less than 10% by weight of compounds which contain a vinylidene group. invention further describes the use of the surfactant alcohols and surfactant alcohol ethers to give surfactants by glycosylation or polyglycosylation, sulfation or phosphation.

47. 发明专利

ES2207489T3 未知
公开(公告)号：ES2207489T3
公开(公告)日：2004-06-01
申请号：ES00909324
申请日：2000-03-06
申请人： BASF AG
发明人： MAAS HEIKO , ROPER MICHAEL , WALTER MARC , SCHULZ RALF , TROPSCH JURGEN , JAGER HANS-ULRICH
IPC分类号： A61K31/454 , A61K31/498 , A61P25/28 , C07B61/00 , C07C2/08 , C07C2/10 , C07C11/02 , C07C29/141 , C07H15/04 , C07C29/16 , C07C29/48 , C07C31/125 , C07C41/03 , C07C43/11 , C07C43/13 , C07C303/24 , C07C305/06 , C07C305/10 , C07D235/06 , C07D241/42 , C07D263/56 , C07D317/68 , C07D319/18 , C07D405/06 , C07F9/09 , C07F9/11 , C09K23/02 , C09K23/14 , C09K23/42 , C09K23/56 , C11D1/29 , C11D1/34 , C11D1/72
摘要： The invention describes a process for the preparation of surfactant alcohols and surfactant alcohol ethers which are, inter alia, highly suitable as surfactants or for the preparation of surfactants. The process, starting from olefin mixtures which comprise less than 30% by weight of linear hexene isomers and utilizing a catalyst which contains nickel, prepares olefin mixtures having a predominant fraction of branched dodecenes, which are subsequently derivatized to give surfactant alcohols and then optionally alkoxylated.The invention further relates to the use of the surfactant alcohols and surfactant alcohol ethers for the preparation of surfactants by glycosidation or polyglycosidation, sulfation or phosphation.

48. 发明专利

DK1159237T3 未知
公开(公告)号：DK1159237T3
公开(公告)日：2004-01-19
申请号：DK00909324
申请日：2000-03-06
申请人： BASF AG
发明人： MAAS HEIKO , ROEPER MICHAEL , WALTER MARC , SCHULZ RALF , TROPSCH JUERGEN , JAEGER HANS-ULRICH
IPC分类号： A61K31/454 , A61K31/498 , A61P25/28 , C07B61/00 , C07C2/08 , C07C2/10 , C07C11/02 , C07C29/141 , C07H15/04 , C07C29/16 , C07C29/48 , C07C31/125 , C07C41/03 , C07C43/11 , C07C43/13 , C07C303/24 , C07C305/06 , C07C305/10 , C07D235/06 , C07D241/42 , C07D263/56 , C07D317/68 , C07D319/18 , C07D405/06 , C07F9/09 , C07F9/11 , C09K23/02 , C09K23/14 , C09K23/42 , C09K23/56 , C11D1/29 , C11D1/34 , C11D1/72
摘要： The invention describes a process for the preparation of surfactant alcohols and surfactant alcohol ethers which are, inter alia, highly suitable as surfactants or for the preparation of surfactants. The process, starting from olefin mixtures which comprise less than 30% by weight of linear hexene isomers and utilizing a catalyst which contains nickel, prepares olefin mixtures having a predominant fraction of branched dodecenes, which are subsequently derivatized to give surfactant alcohols and then optionally alkoxylated.The invention further relates to the use of the surfactant alcohols and surfactant alcohol ethers for the preparation of surfactants by glycosidation or polyglycosidation, sulfation or phosphation.

49. 发明专利

DE50004250D1 未知
公开(公告)号：DE50004250D1
公开(公告)日：2003-12-04
申请号：DE50004250
申请日：2000-02-25
申请人： BASF AG
发明人： MAAS HEIKO , SCHWAB PETER , SCHULZ RALF , WALTER MARC , BROX WOLFGANG
IPC分类号： B01J23/755 , C07B61/00 , C07C2/10 , C07C11/02 , C08F4/06 , C08F10/00
摘要： In a process for oligomerizing C6-olefins by reactin of a C6-olefin-containing reaction mixture over a nickel-containing fixed-bed catalyst, the reaction over the fixed-bed catalyst is run at a conversion to oligomerized C6-olefins of not more than 30% by weight, based on the reaction mixture.

50. 发明专利

DE50003643D1 未知
公开(公告)号：DE50003643D1
公开(公告)日：2003-10-16
申请号：DE50003643
申请日：2000-03-06
申请人： BASF AG
发明人： MAAS HEIKO , ROEPER MICHAEL , WALTER MARC , SCHULZ RALF , TROPSCH JUERGEN , JAEGER HANS-ULRICH
IPC分类号： A61K31/454 , A61K31/498 , A61P25/28 , C07B61/00 , C07C2/08 , C07C2/10 , C07C11/02 , C07C29/141 , C07H15/04 , C07C29/16 , C07C29/48 , C07C31/125 , C07C41/03 , C07C43/11 , C07C43/13 , C07C303/24 , C07C305/06 , C07C305/10 , C07D235/06 , C07D241/42 , C07D263/56 , C07D317/68 , C07D319/18 , C07D405/06 , C07F9/09 , C07F9/11 , C09K23/02 , C09K23/14 , C09K23/42 , C09K23/56 , C11D1/29 , C11D1/34 , C11D1/72
摘要： The invention describes a process for the preparation of surfactant alcohols and surfactant alcohol ethers which are, inter alia, highly suitable as surfactants or for the preparation of surfactants. The process, starting from olefin mixtures which comprise less than 30% by weight of linear hexene isomers and utilizing a catalyst which contains nickel, prepares olefin mixtures having a predominant fraction of branched dodecenes, which are subsequently derivatized to give surfactant alcohols and then optionally alkoxylated.The invention further relates to the use of the surfactant alcohols and surfactant alcohol ethers for the preparation of surfactants by glycosidation or polyglycosidation, sulfation or phosphation.

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