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41. 发明专利

MXPA05012229A PRODUCCION DE ALDEHIDOS, ACIDOS CARBOXILICOS, Y/O ANIHIDRIDOS DE ACIDO CARBOXILICO POR MEDIO DE CATALIZADORES QUE CONTIENEN OXIDO DE VANADIO, DIOXIDO DE TITANIO Y OXIDO DE ANTIMONIO. 未知
公开(公告)号：MXPA05012229A
公开(公告)日：2006-02-10
申请号：MXPA05012229
申请日：2004-05-21
申请人： BASF AG
发明人： NETO SAMUEL
IPC分类号： C07C51/265 , C07C51/31 , C07C63/16
摘要： Se describe un metodo para producir aldehidos, acidos carboxilicos, y/o anhidridos de acido carboxilico, especialmente anhidrido ftalico. De acuerdo con dicho metodo de una corriente gaseosa que comprende un hidrocarburo aromatico y oxigeno molecular es dirigida por menos a traves de un lecho de un primer catalizador y un lecho de un segundo catalizador a temperatura elevada, el segundo catalizador que esta ubicado corriente abajo desde el primer catalizador en la direccion de flujo de la corriente gaseosa y que tiene una mayor actividad que el primer catalizador, El material cataliticamente activo del primer catalizador contiene por lo menos oxido de vanadio, oxido de titanio, y oxido de antimonio, la relacion entre el vanadio, el cual es clasificado como V2O5, y el antimonio, el cual es clasificado como Sb2O3, en el primer catalizador varia entre 3.5: y 5:1. De manera preferible, el trioxido de antimionio, en particulas que tiene un tamano de particular promedio 0.5 hasta 5 ??m es utilizado como la fuente de oxido de antimonio. En el primer catalizador. El metodo de la invencion permite que se obtengan los productos de oxidacion deseados en un gran rendimiento a traves de periodos prolongados.

42. 发明专利

DE10344846A1 未知
公开(公告)号：DE10344846A1
公开(公告)日：2005-04-14
申请号：DE10344846
申请日：2003-09-26
申请人： BASF AG
发明人： STORCK SEBASTIAN , ZUEHLKE JUERGEN , NETO SAMUEL , ROSOWSKI FRANK , RUMMEL WOLFGANG
IPC分类号： B01J23/00 , B01J23/22 , B01J27/198 , B01J35/02 , B01J37/02 , C07C51/265 , C07C51/31 , B01J35/10
摘要： A process is described for producing a catalyst for gas-phase oxidations, in which a suspension of TiO2 and V2O5 particles is applied to a fluidized inert support, wherein at least 90% by volume of the V2O5 particles have a diameter of 20 mum or less and at least 95% by volume of the V2O5 particles have a diameter of 30 mum or less. The defined particle size distribution of the V2O5 allows a high coating efficiency.

43. 发明专利

MX2007016471A METODO PARA PONER EN FUNCIONAMIENTO CATALIZADORES DE OXIDACION. 未知
公开(公告)号：MX2007016471A
公开(公告)日：2008-03-04
申请号：MX2007016471
申请日：2006-06-30
申请人： BASF AG
发明人： ROSOWSKI FRANK , STORCK SEBASTIAN , NETO SAMUEL , ZUHLKE JURGEN , ALLMANN HANS-MARTIN , LAUTENSACK THOMAS , STEEG RAINER
IPC分类号： B01J23/00 , C07C51/21 , C07C51/265 , C07C51/31 , C07D307/89
摘要： La invencion se relaciona con un metodo para poner en funcionamiento catalizadores de oxidacion, caracterizado en que el catalizador se pone en funcionamiento a una temperatura de 360 degree C a 400 degree C, con un suministro de aire de 1.0 a 3.5 Nm3/h y una carga de hidrocarburos de 20 a 65 g/Nm3 con formacion de una zona activa en el primer 7 a 20 % del lecho del catalizador a una temperatura de 390 degree C a menos de 450 degree C.

44. 发明专利

BRPI0511970A 未知
公开(公告)号：BRPI0511970A
公开(公告)日：2008-01-22
申请号：BRPI0511970
申请日：2005-06-14
申请人： BASF AG
发明人： NETO SAMUEL , HIBST HARTMUT , ROSOWSKI FRANK , STORCK SEBASTIAN , ZUEHLKE JUERGEN
IPC分类号： C01G31/00 , B01J23/00 , B01J23/68 , B01J27/198
摘要： Multimetal oxides corresponding to the general formula (I), processes for their preparation, precatalysts containing such oxides and catalysts made therefrom for gas phase partial oxidation of hydrocarbons: Ag a-c Q b M c V 12 O d .eH 2 O (I) wherein a represents a number having a value of 5 to 9; Q represents an element selected from the group consisting of P, As, Sb, Bi and mixtures thereof; b represents a number having a value of 0.2 to 3; M represents a metal selected from the group consisting of Li, Na, K, Rb, Cs, Tl, Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pb, Cr, Au, Al, Fe, Co, Ni, Ce, Mn, Nb, W, Ta, Mo and mixtures thereof; c represents a number having a value of less than 1; d represents a number having a value of which is determined by the valency and frequency of Ag, Q, M and V in the formula (I); and e represents a number having a value of 0 to 20; wherein the multimetal oxide has a crystal structure wherein its powder X-ray diffractogram includes reflections at at least 5 interplanar spacings selected from the group of 7.13 Å, 5.52 Å, 5.14 Å, 3.57 Å, 3.25 Å, 2.83 Å, 2.79 Å, 2.73 Å, 2.23 Å and 1.71 Å, each interplanar spacing value±0.04 Å.

45. 发明专利

UA80765C2 METHOD FOR PRODUCING PHTHALIC ANHYDRIDE 未知
公开(公告)号：UA80765C2
公开(公告)日：2007-10-25
申请号：UAA200512406
申请日：2004-05-15
申请人： BASF AG
发明人： NETO SAMUEL , ZUEHLKE JUERGEN , STORCK SEBASTIAN , ROSOWSKI FRANK
IPC分类号： C07C51/21 , C07C51/265 , C07C51/31 , C07D307/89
摘要： The invention relates to a method for producing phthalic anhydride during which the catalytic gas phase oxidation of o-xylol and/or naphthalene is carried out over at least three layers of catalysts of increasing activity, whereby only the last layer of the catalyst system contains phosphorous, and the last layer contains at least 10% by weight of vanadium (expressed as V2O5) with regard to the active mass of the catalyst and has a ratio of vanadium (expressed as V2O5) to phosphorous of greater than 35.

46. 发明专利

DE502004004958D1 未知
公开(公告)号：DE502004004958D1
公开(公告)日：2007-10-25
申请号：DE502004004958
申请日：2004-05-15
申请人： BASF AG
发明人： STORCK SEBASTIAN , ZUEHLKE JUERGEN , NETO SAMUEL , ROSOWSKI FRANK
IPC分类号： B01J35/02 , B01J23/00 , B01J23/22 , B01J27/198 , B01J35/00 , B01J35/10 , C07C51/265 , C07C51/31
摘要： Catalyst systems for preparing phthalic anhydride by means of gas-phase oxidation of o-xylene and/or naphthalene, and a process for preparing phthalic anhydride using the catalyst systems.

47. 发明专利

AT372827T 未知
公开(公告)号：AT372827T
公开(公告)日：2007-09-15
申请号：AT04733250
申请日：2004-05-15
申请人： BASF AG
发明人： STORCK SEBASTIAN , ZUEHLKE JUERGEN , NETO SAMUEL , ROSOWSKI FRANK
IPC分类号： B01J35/02 , B01J23/00 , B01J23/22 , B01J27/198 , B01J35/00 , B01J35/10 , C07C51/265 , C07C51/31
摘要： Catalyst systems for preparing phthalic anhydride by means of gas-phase oxidation of o-xylene and/or naphthalene, and a process for preparing phthalic anhydride using the catalyst systems.

48. 发明专利

DE502004003631D1 未知
公开(公告)号：DE502004003631D1
公开(公告)日：2007-06-06
申请号：DE502004003631
申请日：2004-07-30
申请人： BASF AG
发明人： NETO SAMUEL , ZUEHLKE JUERGEN , STORCK SEBASTIAN , ROSOWSKI FRANK
IPC分类号： B01J31/06 , B01J21/06 , B01J23/22 , B01J27/198 , B01J37/02 , C07C51/215 , C07C51/265
摘要： A catalyst for gas-phase oxidations which comprises an inert support and a catalytically active composition comprising transition metal oxides applied thereto, or a precatalyst, is described. The (pre)catalyst is obtained by treating the inert support with an aqueous suspension or solution of the transition metal oxides or their precursor compounds, where the suspension contains a binder dispersion and the binder is a copolymer of an alpha-olefin and a vinyl-C 2 -C 4 -carboxylate whose vinyl C 2 -C 4 -carboxylate content is at least 62 mol %.

49. 发明专利

DE502004003563D1 未知
公开(公告)号：DE502004003563D1
公开(公告)日：2007-05-31
申请号：DE502004003563
申请日：2004-09-24
申请人： BASF AG
发明人： NETO SAMUEL , RUMMEL WOLFGANG , STORCK SEBASTIAN , ZUEHLKE JUERGEN , ROSOWSKI FRANK
IPC分类号： B01J2/00 , B01J2/16 , B01J8/18 , B01J23/00 , B01J23/22 , B01J27/199 , B01J35/02 , B01J37/02 , F26B3/08 , F26B3/092

50. 发明专利

DE502004002687D1 未知
公开(公告)号：DE502004002687D1
公开(公告)日：2007-03-08
申请号：DE502004002687
申请日：2004-05-21
申请人： BASF AG
发明人： STORCK SEBASTIAN , ZUEHLKE JUERGEN , NETO SAMUEL , ROSOWSKI FRANK
IPC分类号： C07C51/265 , C07C51/31 , C07C63/16
摘要： A description is given of a process for preparing aldehydes, carboxylic acids and/or carboxylic anhydrides, in particular phthalic anhydride, in which a gaseous stream comprising an aromatic hydrocarbon and molecular oxygen is passed at elevated temperature over a bed of a first catalyst and a bed which is made up of a second catalyst having a higher activity than the first catalyst and is located downstream of the first catalyst in the flow direction of the gaseous stream, wherein the catalytically active composition of the first catalyst comprises at least vanadium oxide, titanium dioxide and antimony oxide and the ratio of vanadium, calculated as V 2 O 5 , to antimony, calculated as Sb 2 O 3 , in the first catalyst is from 3.5:1 to 5:1. The source of antimony oxide used for the first catalyst is preferably particulate antimony trioxide having a mean particle size of from 0.5 to 5 mum. The process allows the desired oxidation products to be obtained in high yield over longer periods of time.

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