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41. 发明授权

EP1827673B1 PROCESS AND APPARATUS FOR THE POLYMERIZATION OF PROPYLENE 有权转让
标题翻译：方法和装置丙烯聚合，
公开(公告)号：EP1827673B1
公开(公告)日：2012-02-01
申请号：EP05816222.3
申请日：2005-12-09
申请人： Basell Poliolefine Italia S.r.l.
发明人： MEI, Gabriele , PATER, Joachim , BERTOLINI, Stefano
IPC分类号： B01J8/18
CPC分类号： B01J19/2435 , B01J8/1863 , B01J2219/00006 , B01J2219/0004 , C08F10/06 , C08F210/06 , C08F2/001 , C08F210/16 , C08F2500/12 , C08F2500/17
摘要： A process for preparing heterophasic propylene copolymers by polymerizing propylene in the presence of a polymerization catalyst and hydrogen as a molecular weight regulator, the process comprising the following steps: a) polymerizing in gas- or liquid-phase propylene to prepare a crystalline polymer fraction; b) copolymerizing ethylene with propylene and/or 1 -butene, and optionally one or more alpha-olefin comonomers Cs-C12, in a gas-phase reactor having interconnected polymerization zones, wherein the growing polymer particles flow upward through a first polymerization zone (riser) under fast fluidization or transport conditions, leave said riser and enter a second polymerization zone (downcomer) through which they flow downward under the action of gravity.

42. 发明授权

EP1377629B1 POLYOLEFIN SHEETS FOR THERMOFORMING 有权
标题翻译：聚烯烃热成型
公开(公告)号：EP1377629B1
公开(公告)日：2012-02-01
申请号：EP01994784.5
申请日：2001-12-13
申请人： Basell Poliolefine Italia S.r.l.
发明人： PELLICONI, Anteo , LONARDO, Angelo , MEI, Gabriele
IPC分类号： C08J5/18 , B29C51/00 , C08F10/06 , C08F210/06 , C08F297/08 , C08L23/14 , C08L23/16
CPC分类号： C08J5/18 , B29C51/00 , C08F210/06 , C08F210/16 , C08F297/08 , C08F297/083 , C08J2323/14 , C08L23/14 , C08L2203/30 , C08L2205/02 , C08L2666/04 , C08F210/14 , C08F2500/26 , C08F210/08 , C08F2500/20 , C08F2500/12
摘要： Polypropylene sheet for thermoforming wherein at least one layer comprises a propylene polymer containing at least 0.8 % by weight of ethylene and optionally one or more C4-C10 α-olefins, or a propylene polymer composition containing at least 0.8 % by weight of one or more comonomers selected from ethylene and C4-C10 α-olefins, and having the following features: 1) a melting temperature of 155 °C or higher; 2) a content of fraction soluble in xylene at room temperature lower than 4 % by weight, and a value of the ratio of the polymer fraction collected at the temperature range from 25 °C to 95 °C to the said xylene soluble fraction higher than 8.

43. 发明公开

EP2370201A1 PROCESS FOR FEEDING A CATALYST IN A POLYMERIZATION REACTOR 有权
标题翻译： EEREN POLYMERISATIONSREAKTOR的VERFAHREN ZUM EINTRAGEN EINES KATALYSATORS
公开(公告)号：EP2370201A1
公开(公告)日：2011-10-05
申请号：EP09796392.0
申请日：2009-12-23
申请人： Basell Poliolefine Italia S.r.l.
发明人： BAITA, Pietro , KARER, Rainer , MEIER, Gerhardus , FUNK, Guido , MEI, Gabriele
IPC分类号： B01J8/00 , B01J8/24 , C08F10/00
CPC分类号： B01J8/0015 , B01J8/1827 , B01J2208/00752 , B01J2208/00769 , C08F10/00 , C08F210/16 , C08F2/34 , C08F210/08 , C08F2500/12
摘要： A process for introducing a catalyst powder based on a titanium compound supported on magnesium halide into a gas-phase olefin polymerization reactor, characterized in that it comprises: (a) storing the catalyst powder under an atmosphere of a liquid C
3 -C
12 alkane; (b) withdrawing from step (a) a measured amount of said catalyst powder by means of a rotary valve; (c) transferring said metered amount of catalyst powder to a catalyst activation section by a continuous pick-up flow of a liquid C
3 -C
12 alkane; (d) contacting the catalyst powder with a liquid phase comprising an organo-aluminum compound and optionally an external donor compound, at a temperature ranging from -20 °C to 60 °C; (e) introducing the activated catalyst powder in one or more gas-phase olefin polymerization reactors, where a gaseous mixture comprising at least one alpha-olefin is subjected to polymerization.
摘要翻译：一种将负载在卤化镁上的钛化合物的催化剂粉末引入气相烯烃聚合反应器中的方法，其特征在于它包括：（a）将催化剂粉末储存在液体C 3 -C 12烷烃气氛下; （b）通过旋转阀从步骤（a）中取出测量量的所述催化剂粉末; （c）通过液体C 3 -C 12烷烃的连续吸入流将所述计量的催化剂粉末转移到催化剂活化部分; （d）在-20℃至60℃的温度下使催化剂粉末与包含有机铝化合物和任选的外部供体化合物的液相接触; （e）将活化的催化剂粉末引入一个或多个气相烯烃聚合反应器中，其中包含至少一种α-烯烃的气态混合物进行聚合。

44. 发明公开

EP2281010A1 PROCESS FOR THE GAS-PHASE POLYMERIZATION OF OLEFINS 有权转让
标题翻译：烯烃气相聚合的方法
公开(公告)号：EP2281010A1
公开(公告)日：2011-02-09
申请号：EP09753799.7
申请日：2009-05-15
申请人： Basell Poliolefine Italia S.r.l.
发明人： RINALDI, Riccardo , MAZZUCCO, Antonio , BALESTRA, Enrico , PENZO, Giuseppe , DORINI, Maurizio , MEI, Gabriele
IPC分类号： C08F10/00 , C08F2/34 , C08F2/01
CPC分类号： B01J19/2435 , B01J19/2465 , B01J2219/00087 , C08F10/00 , C08F110/02 , C08F110/06 , Y10S526/901 , C08F2/34 , C08F2/001 , C08F2/01 , C08F2500/05 , C08F2500/15
摘要： A process for the polymerisation of olefins carried out in a gas-phase reactor having interconnected polymerization zones, where the growing polymer particles flow upward through a first polymerization zone (riser) under fast fluidization or transport conditions, leave said riser and enter a second polymerization zone (downcomer) through which they flow downward under the action of gravity, leave said downcomer and are reintroduced into the riser, a gas recycle stream being withdrawn from said first polymerisation zone, subjected to cooling below its dew point and then returned to said first polymerisation zone, the process being characterised in that said gas recycle stream is cooled at a temperature Tc ranging from 0.05°C to 3°C below its dew point.
摘要翻译：在具有互连聚合区的气相反应器中进行烯烃聚合的方法，其中生长的聚合物颗粒在快速流化或运输条件下向上流过第一聚合区（提升管），离开所述提升管并进入第二聚合（降液管），在重力作用下它们向下流动，离开所述降液管并被再次引入提升管，从所述第一聚合区排出气体再循环流，经受冷却到其露点以下，然后返回到所述第一该方法的特征在于所述气体再循环流在低于其露点0.05℃至3℃的温度Tc下冷却。

45. 发明公开

EP3601383A1 PROPYLENE ETHYLENE RANDOM COPOLYMER 有权
公开(公告)号：EP3601383A1
公开(公告)日：2020-02-05
申请号：EP18711593.6
申请日：2018-03-23
申请人： Basell Poliolefine Italia S.r.l.
发明人： MEI, Gabriele , MAZZUCCO, Antonio , CAPUTO, Tiziana , BALESTRA, Enrico , TARTARI, Davide , MOSCARDI, Gilberto
IPC分类号： C08F210/06 , C08L23/10

46. 发明授权

EP2370201B1 PROCESS FOR FEEDING A CATALYST IN A POLYMERIZATION REACTOR 有权
标题翻译：在聚合反应器中加入催化剂的方法
公开(公告)号：EP2370201B1
公开(公告)日：2017-10-04
申请号：EP09796392.0
申请日：2009-12-23
申请人： Basell Poliolefine Italia S.r.l.
发明人： BAITA, Pietro , KARER, Rainer , MEIER, Gerhardus , FUNK, Guido , MEI, Gabriele
IPC分类号： B01J8/00 , B01J8/24 , C08F10/00
CPC分类号： B01J8/0015 , B01J8/1827 , B01J2208/00752 , B01J2208/00769 , C08F10/00 , C08F210/16 , C08F2/34 , C08F210/08 , C08F2500/12

47. 发明授权

EP2281010B1 PROCESS FOR THE GAS-PHASE POLYMERIZATION OF OLEFINS 有权转让
公开(公告)号：EP2281010B1
公开(公告)日：2013-03-20
申请号：EP09753799.7
申请日：2009-05-15
申请人： Basell Poliolefine Italia S.r.l.
发明人： RINALDI, Riccardo , MAZZUCCO, Antonio , BALESTRA, Enrico , PENZO, Giuseppe , DORINI, Maurizio , MEI, Gabriele
IPC分类号： C08F10/00 , C08F2/34 , C08F2/01
CPC分类号： B01J19/2435 , B01J19/2465 , B01J2219/00087 , C08F10/00 , C08F110/02 , C08F110/06 , Y10S526/901 , C08F2/34 , C08F2/001 , C08F2/01 , C08F2500/05 , C08F2500/15

48. 发明授权

EP1515998B1 LIQUID PHASE PROCESS FOR THE POLYMERIZATION OF ALPHA-OLEFINS 有权
标题翻译：液相方法α-烯烃聚合
公开(公告)号：EP1515998B1
公开(公告)日：2011-05-11
申请号：EP03760626.6
申请日：2003-06-17
申请人： Basell Poliolefine Italia S.r.l.
发明人： BIGIAVI, Daniele , MEI, Gabriele , ARICH DE FINETTI, Nicolò , PENZO, Giuseppe , VITALE, Gianni , COVEZZI, Massimo
IPC分类号： C08F10/08 , C08F2/06 , C08F2/42
CPC分类号： C08F110/08 , Y10S526/903 , C08F2/001 , C08F2/06 , C08F2/42 , C08F2500/12 , C08F2/01 , C08F2/00
摘要： A liquid-phase process for polymerizing α-olefins of the formula CH2=CHR, where R is H or an alkyl radical C1-C6, to produce a polymer that is soluble in the reaction medium, comprising the steps of: a) continuously polymerizing in liquid phase the α- olefin in the presence of a catalyst system based on a transition metal compound; b) continuously withdrawing from step a) a solution of polymer in the liquid reaction medium; c) mixing in one or more mixing stages said solution of polymer in the reaction medium with an organic deactivator having: at least a hydroxy group, a boiling point higher than 150°C, and a ratio between the molecular weight (MW) and the number of hydroxy groups (OH) comprised between 20 and 100.

49. 发明授权

EP1549687B1 POLYMERIZATION PROCESS 有权
标题翻译：烯烃的气相催化聚合
公开(公告)号：EP1549687B1
公开(公告)日：2011-04-20
申请号：EP03753465.8
申请日：2003-09-25
申请人： Basell Poliolefine Italia S.r.l.
发明人： COVEZZI, Massimo , MEIER, Gerhardus , MEI, Gabriele
IPC分类号： C08F10/00 , C08F2/34 , C08F2/00 , B01J8/18 , B01J8/24 , B01J8/26 , B01J19/24
CPC分类号： B01J8/388 , B01J8/1827 , B01J8/1872 , B01J2208/00176 , B01J2208/00212 , B01J2208/00256 , B01J2208/00274 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , C08F210/18 , Y10S526/901 , Y10S526/918 , C08F2/34 , C08F2/01 , C08F2/001 , C08F2500/07 , C08F2500/15 , C08F210/08 , C08F2500/08 , C08F236/00 , C08F2500/21
摘要： Process for the gas-phase catalytic polymerization of olefins carried out in a plurality of interconnected polymerization zones, the process comprising feeding one or more monomers to said polymerization zones in the presence of a catalyst under reaction conditions and collecting the polymer product from said polymerization zones, in which process the polymer particles grow within a first polymerization zone where a fluidized bed is formed, at least a part of said polymer particles leave said first polymerization zone to enter a second polymerization zone through which they flow downward, leave said second polymerization zone and enter a third polymerization zone through which they flow upward under fast fluidization or transport conditions, leave said third polymerization zone and are reintroduced into the first polymerization zone, thus establishing a circulation of polymer between the different polymerization zones.

50. 发明公开

EP1926755A1 GAS-PHASE PROCESS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：气相工艺的烯烃聚合
公开(公告)号：EP1926755A1
公开(公告)日：2008-06-04
申请号：EP06793567.6
申请日：2006-09-15
申请人： BASELL POLIOLEFINE ITALIA S.R.L.
发明人： PATER, Jochem , BAITA, Pietro , MEI, Gabriele , MAZZUCCO, Antonio
IPC分类号： C08F2/34 , C08F10/00 , C08F2/01 , B01J8/06
CPC分类号： B01J8/1827 , B01J8/002 , B01J8/0035 , B01J8/1872 , B01J19/2415 , B01J2208/00256 , B01J2208/00274 , B01J2208/0053 , B01J2208/00752 , B01J2219/00006 , B01J2219/00033 , B01J2219/0004 , C08F10/00 , C08F110/02 , C08F2/34 , C08F2/01 , C08F2500/05 , C08F2500/12 , C08F2500/24
摘要： A process for the gas-phase polymerization of one or more alpha-olefins in the presence of a polymerization catalyst system, the process comprising: a) contacting in a continuous way a gas comprising one or more of said alpha-olefins with said catalyst system in a gas-phase tubular reactor at a temperature from 30°C to 130°C in order to obtain a polymerization degree up to 500 grams per gram of catalyst system; b) feeding in continuous the prepolymer from step a) to a successive gas-phase polymerization reactor; wherein said gas-phase tubular reactor has a length/diameter ratio higher than 100.

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