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    • 41. 发明专利
    • Removal apparatus of trace harmful substance in exhaust gas and its operation method
    • 排气中痕量有害物质的去除装置及其操作方法
    • JP2006205128A
    • 2006-08-10
    • JP2005023859
    • 2005-01-31
    • Babcock Hitachi Kkバブコック日立株式会社
    • NAGAI YOSHINORIKATSUBE TOSHIOMORITA ISATOYOSHIKAWA HIROBUMIKATO YASUYOSHI
    • B01D53/86B01D53/50B01D53/64B01D53/77B01D53/94B01J23/28B01J23/30
    • PROBLEM TO BE SOLVED: To provide a long-term stable and highly reliable removal apparatus of trace harmful substances in exhaust gas, and its operation method. SOLUTION: The removal apparatus of trace harmful substances in exhaust gas is disposed with; a denitration device equipped with a denitration catalyst layer having a function of removing nitrogen oxide in exhaust gas in order from the upstream side to oxidize metallic mercury, in an exhaust gas flow channel discharged from a combustion facility; an air preheater for heat-exchanging air for combustion of the combustion facility to exhaust gas; a dust removal device having a bag filter containing oxidation catalysts for metallic mercury; and a desulfurization device for removing sulfur oxide in exhaust gas. The bag filter may be disposed in front of the desulfurization device. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供废气中痕量有害物质的长期稳定,高可靠的去除装置及其操作方法。

      解决方案:废气中痕量有害物质的去除装置与; 脱硝装置,在从燃烧设备排出的排气流路中配备有脱硝催化剂层,所述脱硝催化剂层具有从上游侧依次除去废气中的氮氧化物以氧化金属汞的功能; 空气预热器,用于将燃烧设备的燃烧空气进行热交换至排气; 具有袋式过滤器的除尘装置,该袋式过滤器含有用于金属汞的氧化催化剂; 以及用于除去废气中的硫氧化物的脱硫装置。 袋式过滤器可以设置在脱硫装置的前面。 版权所有(C)2006,JPO&NCIPI

    • 42. 发明专利
    • Glass melting furnace-exhaust gas treatment method and treatment apparatus
    • 玻璃熔炼炉 - 排气处理方法和处理装置
    • JP2006075764A
    • 2006-03-23
    • JP2004263874
    • 2004-09-10
    • Babcock Hitachi Kkバブコック日立株式会社
    • NAGAI YOSHINORIKATSUBE TOSHIOINATSUNE YOSHIROUMORITA ISATO
    • B01D53/56B01D53/34B01D53/50B01D53/77
    • PROBLEM TO BE SOLVED: To provide a glass melting furnace-exhaust gas treatment method enabling the treatment of the exhaust gas generated from a glass melting furnace with a high reliability and a high efficiency, and its treatment apparatus. SOLUTION: (1) The glass melting furnace-exhaust gas treatment method comprises steps of adding an alkali neutralizer to the exhaust gas generated from the glass melting furnace to make the sulfur oxide in the exhaust gas to a sulfate compound, removing the produced product by a dust removing operation, thereafter, maintaining the exhaust gas temperature in the range of 200-300°C, and in supplying the exhaust gas into an exhaust gas denitrization equipment provided with a catalyst layer to remove nitrogen oxides in the exhaust gas under a reducer, injecting the reducer when the exhaust gas temperature at an outlet of the catalyst layer reaches not less than 130°C. (2) The exhaust gas treatment method comprises heating the catalyst layer of the exhaust gas denitrization equipment to not less than 100°C before the exhaust gas denitrization equipment is started up. COPYRIGHT: (C)2006,JPO&NCIPI
    • 解决的问题:提供一种能够以高可靠性和高效率处理从玻璃熔炉产生的废气的玻璃熔融炉废气处理方法及其处理装置。 (1)玻璃熔融炉废气处理方法包括以下步骤:向由玻璃熔炉产生的废气中加入碱中和剂,使废气中的硫氧化物形成硫酸盐化合物,除去 然后将废气温度维持在200-300℃的范围内,并将排气供给到具有催化剂层的排气脱硝装置中以除去排气中的氮氧化物 在减速机下方,当催化剂层出口处的排气温度达到130℃以上时,注入还原剂。 (2)废气处理方法包括在排气脱硝装置起动之前将废气脱硝装置的催化剂层加热至不低于100℃。 版权所有(C)2006,JPO&NCIPI
    • 43. 发明专利
    • WET FLUE-GAS DESULFURIZATION APPARATUS
    • JP2002172312A
    • 2002-06-18
    • JP2000369791
    • 2000-12-05
    • BABCOCK HITACHI KK
    • SHIMAZU HIROMICHIKATSUBE TOSHIO
    • B01D53/50B01D53/34B01D53/77
    • PROBLEM TO BE SOLVED: To prevent the deposition of solid substances at the outlet of an absorption tower without increasing the height of the absorption tower. SOLUTION: At the bottom of an outlet section 50 of an absorption tower for absorbing and removing soot and dust or sulfur oxides contained in a combustion flue gas of a boiler, etc., with an absorbent liquid comprising an absorbent slurry containing limestone, lime, or the like, a downward inclined part is formed along a gas flow 51 in the outlet section 50. When a mist 60 containing solid substances falling down on the bottom becomes an absorption tower outlet drain 52 and returns to the absorption tower 4, the direction of the gas flow 51 and that of the absorption tower outlet drain flow 53 are the same, facilitating the flow of the drain 52 and thus making the deposition of solid substances on the bottom of the outlet section 50 difficult. Since the inclined part of the bottom of the outlet section 50 is downward inclined along the gas flow 51, the absorption tower 4 is not required to be high in height.
    • 44. 发明专利
    • WET STACK GAS DESURFURIZING DEVICE
    • JP2001149745A
    • 2001-06-05
    • JP33983399
    • 1999-11-30
    • BABCOCK HITACHI KK
    • ODA NAOKIKATSUBE TOSHIONAKAMOTO TAKANORIYOSHIKAWA HIROBUMIISHIZAKA HIROSHI
    • B01D53/50B01D53/18B01D53/34B01D53/77
    • PROBLEM TO BE SOLVED: To obtain the stable operation of a desulturizing device by accelerating the oxidation and neutralization reaction of an absorbent solution and preventing the settling of the solid such as gypsum by eliminating the dead space of slurry agitation at a rectangular liquid reservoir. SOLUTION: The flow for sweeping the absorbent solution to the direction from a slurry agitator 11 to a discharge piping 12 of a circulation pump 6 is generated and moreover the solution is made to flow to the circulation pump 6 direction by the draw-in force resulted from the suction of the solution by the circulation pump 6 by arranging the slurry agitator 11 at the position at which the sweeping direction of the absorbent solution from the agitator 11 is placed oppositly to a discharge piping 12 of the circulation pump at the liquid reservoir 7 provided at the lower part of a absorption tower body 1 having a rectangular horizontal section. Therefore, a dwelling part of the solution is hardly caused at the liquid reservoir 7, especially bottom part, and the solid matter such as gypsum is hardly caused. In such a way, the pH of the absorbent solution becomes liable to recover since the retention time of the limestone supplied to the liquid reservoir 7 at the liquid reservoir 7 is increased.
    • 45. 发明专利
    • FLUE GAS PROCESSOR AND METHOD OF OPERATING THE SAME
    • JP2001074229A
    • 2001-03-23
    • JP25071999
    • 1999-09-03
    • BABCOCK HITACHI KK
    • ISHIZAKI MASANORIKATSUBE TOSHIOSAITO TAKAYUKIYAMAMOTO MASAYUKI
    • B01D53/34B01D53/50B01D53/77F23J15/08
    • PROBLEM TO BE SOLVED: To provide an economical flue gas treating equipment by using only one drain tank with a heat exchanger. SOLUTION: This processor comprises a GGH heat recovery unit 4 for recovering the heat of exhaust gas discharged from a burner, a desulphurization unit for removing SOx in the exhaust gas at the outlet of the GGH heat recovery unit 4, an SGH 50 for heating the exhaust gas at the outlet of the desulphurization unit with steam and a GGH reheating unit 8 for reheating the exhaust gas at the outlet of the desulphurization unit, wherein these components are sequentially arranged on an exhaust gas channel. The processor further comprises heat transfer tubes 11 and 12 respectively provided in the GGH heat recovery unit 4 and the GGH reheating unit 8 which tubes are communicated with each other, and heating medium circulation lines 13-1 and 13-2 provided with a heating-medium heater 17 for heating the heating medium therein with steam. In this case, drain from the heating-medium heater 17 is pressurized by a heating-medium heater drain recovery pump 57 and is led to an SGH drain tank 54 provided with a heat exchanger through a heating-medium heater drain recovery tank 56. As a result, it is possible to omit the installation of the heating- medium heater drain recovery tank with an expensive heat exchanger.
    • 46. 发明专利
    • METHOD FOR REMOVING STEEL BALL SCATTERING DUST AND FUEL GAS TREATING APPARATUS APPLIED THEREBY
    • JPH10197197A
    • 1998-07-31
    • JP123097
    • 1997-01-08
    • BABCOCK HITACHI KK
    • TANIGUCHI KENSHOKATSUBE TOSHIOSAITO TAKAYUKI
    • F28G1/12
    • PROBLEM TO BE SOLVED: To establish a method for removing dust by maintaining heat transfer performance of a gas-gas heater(GGH) heat transfer tube group constant at the time of starting steel ball scattering and suppressing rise of smoke soot concentration in primary GGH. SOLUTION: A heat transfer tube group 5 of a gas-gas heater(GGH) heat recovering unit is divided into a plurality of blocks, a steel ball scattering time per one block is formed in an A pattern of a short time and the other pattern is formed in a B pattern of a long time to sequentially control to scatter the balls in one block of the divided blocks. The balls are scattered from above the group 5 disposed at an exhaust gas channel of a combustion equipment outlet of a boiler by this combination to remove smoke soots. The soots adhered to all areas of the group 5 are roughly removed in the A pattern, and the balls are scattered in an important manner in each block by the B pattern to remove the dusts, thereby suppressing rise of the soot concentration in the gas of a GGH rear stream side at the time of starting scattering of the balls. Since the soot amount adhered to the entire area of the group 5 can be reduced by the roughly removing by the A pattern scattering, pressure loss can be decreased, and heat transfer performance can be stabilized.