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41. 发明授权

US5310714A Synthesis of zeolite films bonded to substrates, structures and uses thereof 失效
标题翻译：与底物结合的沸石膜的合成，结构及用途
公开(公告)号：US5310714A
公开(公告)日：1994-05-10
申请号：US910861
申请日：1992-07-08
申请人： Robert K. Grasselli , Rudolph M. Lago , Richard F. Socha , John G. Tsikoyiannis
发明人： Robert K. Grasselli , Rudolph M. Lago , Richard F. Socha , John G. Tsikoyiannis
IPC分类号： B01D53/02 , B01D53/86 , B01D53/94 , B01J37/02 , C07C5/32 , C07C5/333 , C07C7/13 , B01J29/06 , C01B33/26
CPC分类号： B01D53/9481 , B01D53/02 , B01D53/8668 , B01D53/9418 , B01J37/0246 , C07C5/325 , C07C5/3337 , C07C7/13 , B01D2251/202 , B01D2251/204 , B01D2251/2062 , B01D2251/208 , B01D2251/21 , B01D2255/504 , B01J2229/64
摘要： A method for synthesizing a zeolite bonded to a substrate utilizes a reaction mixture having a H.sub.2 O/YO.sub.2 molar ratio of at least 25 and Y is a tetravalent element, particularly silicon.A structure made according to this method includes a film of interconnected zeolite crystals bonded to a substrate and the structure is characterized by a value r representing the mg of zeolite/cm.sup.2 of substrate surface and a value e representing the coating efficiency as mg of bonded zeolite/mg of YO.sub.2 initially in the synthesis mixture; wherein r is at least 0.5 and e is at least 0.05.Processes are provided for separation, sorption, organic feedstock conversion and NO.sub.x conversion over the structure.
摘要翻译：合成与底物结合的沸石的方法利用H 2 O / YO 2摩尔比至少为25的反应混合物，Y为四价元素，特别是硅。根据该方法制造的结构包括结合到基底上的相互连接的沸石晶体的膜，该结构的特征在于表示基底表面的沸石/ cm 2的mg值，代表涂覆效率的值为mg的粘结的沸石 / mg的YO2最初在合成混合物中; 其中r为至少0.5，e为至少0.05。提供了在结构上进行分离，吸附，有机原料转化和NOx转化的方法。

42. 发明授权

US4886931A Upgrading low molecular weight hydrocarbons 失效
标题翻译：升级低分子量碳氢化合物
公开(公告)号：US4886931A
公开(公告)日：1989-12-12
申请号：US58016
申请日：1987-06-04
申请人： Joseph P. Bartek , James F. Brazdil, Jr. , John M. Hupp , Robert K. Grasselli
发明人： Joseph P. Bartek , James F. Brazdil, Jr. , John M. Hupp , Robert K. Grasselli
IPC分类号： C07C2/84
CPC分类号： C07C2/84 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2521/16 , C07C2523/04 , C07C2523/06 , C07C2527/224 , Y10S585/943
摘要： A multi-component oxide catalyst comprising zinc and an alkali metal is described which is useful particularly for converting methane and/or natural gas to higher molecular weight hydrocarbon products such as ethane and ethylene. The catalyst is characterized by the formulaZn.sub.a A.sub.b M.sub.c M'.sub.d O.sub.xwhereinA is Li, Na, K, or mixtures thereof;M is Al, Ga, Cr, La, Y, Sc, V, Nb, Ta, Cu or mixtures thereof;M' is Cs, Rb, Mg, Ca, Sr, Ba, Sm, Pb, Mn, Sb, P, Sn, Bi, Ti, Zr, Hf, or mixtures thereof;a is from about 1 to about 20;b is from about 0.1 to about 20;c is from about 0 to about 5;d is from about 0 to about 20; andx is a number needed to fulfill the valence requirements of the other elements; provided that(i) at least one of c and d is at least 0.1; and(ii) when M' is Sn, c must be at least 0.1. The process of the present invention involves contacting low molecular weight alkanes at elevated temperatures with oxygen and the catalyst of the invention for a period of time sufficient to provide the desired conversion.
摘要翻译：描述了包含锌和碱金属的多组分氧化物催化剂，其特别用于将甲烷和/或天然气转化为较高分子量烃产物如乙烷和乙烯。催化剂的特征在于式ZnaAbMcM'dOx，其中A为Li，Na，K或其混合物; M是Al，Ga，Cr，La，Y，Sc，V，Nb，Ta，Cu或其混合物; M'是Cs，Rb，Mg，Ca，Sr，Ba，Sm，Pb，Mn，Sb，P，Sn，Bi，Ti，Zr，Hf或它们的混合物; a为约1至约20; b为约0.1至约20; c为约0至约5; d为约0至约20; x是满足其他要素价格要求的数字; 条件是（i）c和d中的至少一个至少为0.1; 和（ii）当M'为Sn时，c必须至少为0.1。本发明的方法包括使低分子量烷烃在升高的温度下与氧和本发明的催化剂接触足以提供所需转化的时间。

43. 发明授权

US4721789A Oxidative cyclization of 2-methylglutaronitrile to 3-cyanopyridine 失效
标题翻译： 2-甲基戊二烯氧化环化为3-氰基吡啶
公开(公告)号：US4721789A
公开(公告)日：1988-01-26
申请号：US678433
申请日：1984-12-05
申请人： Robert DiCosimo , James D. Burrington , Robert K. Grasselli
发明人： Robert DiCosimo , James D. Burrington , Robert K. Grasselli
IPC分类号： C07D213/84 , C07D213/85
CPC分类号： C07D213/84
摘要： A process for making 3-cyanopyridine by the vapor phase catalytic reaction of 2-methylglutaronitrile with molecular oxygen.
摘要翻译：通过2-甲基戊二腈与分子氧的气相催化反应制备3-氰基吡啶的方法。

44. 发明授权

US4615967A Optical information storage material 失效
标题翻译：光学信息存储材料
公开(公告)号：US4615967A
公开(公告)日：1986-10-07
申请号：US700428
申请日：1985-02-11
申请人： Michael A. Tenhover , Robert K. Grasselli
发明人： Michael A. Tenhover , Robert K. Grasselli
IPC分类号： G11B7/243 , G11B7/257 , G03F7/02 , G03C1/00
CPC分类号： G11B7/243 , G11B2007/24312 , G11B2007/24316 , G11B2007/24324 , G11B7/2531 , G11B7/257
摘要： A thin film device for recording information in readable form that decreases its light absorbancy in response to increased temperature. The film includes two elements from column IVa of the Periodic Table, such as silicon, germanium, tin and lead, bound with one of or a mixture of sulfur and selenium.The as-deposited inventive materials contain tetrahedral units, some ethane-like units and some rings and chains. Upon heating the ethane-like units are converted to rings and chains and tetrahedral units producing a dramatically decreased light absorbancy. The materials are stable at relatively high operating temperatures.
摘要翻译：用于记录可读形式的信息的薄膜装置，其响应于升高的温度降低其光吸收。该膜包括周期表列IVa中的两个元素，例如硅，锗，锡和铅，与硫和硒中的一种或其混合物结合。沉积的本发明材料包含四面体单元，一些乙烷样单元和一些环和链。在加热时，乙烷样单元转化成环和链和四面体单元，产生显着降低的光吸收。材料在较高的工作温度下是稳定的。

45. 发明授权

US4526884A Ruthenium containing catalyst composition useful for process for the demerization of acrylic compounds 失效
标题翻译：含有钌的催化剂组合物，用于丙烯酸类化合物的脱色方法
公开(公告)号：US4526884A
公开(公告)日：1985-07-02
申请号：US453410
申请日：1982-12-27
申请人： Dean T. Tsou , James D. Burrington , Elizabeth A. Maher , Robert K. Grasselli
发明人： Dean T. Tsou , James D. Burrington , Elizabeth A. Maher , Robert K. Grasselli
IPC分类号： B01J31/06 , B01J31/16 , B01J31/18 , B01J31/22 , B01J31/24 , C07C45/73 , C07C51/353
CPC分类号： B01J31/2291 , B01J31/1658 , B01J31/1805 , B01J31/2234 , B01J31/24 , C07C255/00 , C07C45/73 , C07C51/353 , B01J2531/0216 , B01J2531/44 , B01J2531/821 , B01J2531/842 , B01J2531/845 , B01J2531/847
摘要： Catalyst composition and process are provided for the dimerization of acrylic compounds. An acrylic compound may be dimerized in the liquid phase by contacting an acrylic compound with a catalyst in the presence of hydrogen, at a pressure of least about 1 psi and a temperature of at least about 50.degree. C., wherein the catalyst comprises an organic polymer catalyst support, trivalent pendant atoms covalently bonded to the support, ruthenium complexed with said trivalent pendant atoms, and a second metal which is at least one of Pb and the Group VIII metals other than Ru and Pd and is disposed on the organic polymer catalyst support.
摘要翻译：为丙烯酸类化合物的二聚提供催化剂组合物和方法。丙烯酸化合物可以通过在氢气存在下，在至少约1psi的压力和至少约50℃的温度下使丙烯酸化合物与催化剂接触而在液相中二聚，其中催化剂包含有机聚合物催化剂载体，与支持体共价结合的三价侧链原子，与所述三价侧基原子配位的钌，以及除Ru和Pd以外的Pb和Ⅷ族金属中的至少一种的第二金属，并且设置在有机聚合物催化剂上支持。

46. 发明授权

US4485079A Ammoxidation of methanol to produce hydrogen cyanide 失效
标题翻译：甲醇的甲氧基化产生氰化氢
公开(公告)号：US4485079A
公开(公告)日：1984-11-27
申请号：US501671
申请日：1983-06-06
申请人： James F. Brazdil, Jr. , Thomas G. Attig , Robert K. Grasselli
发明人： James F. Brazdil, Jr. , Thomas G. Attig , Robert K. Grasselli
IPC分类号： B01J23/31 , B01J23/68 , B01J23/88 , C01C3/02 , C07C120/14
CPC分类号： B01J23/8872 , B01J23/31 , B01J23/683 , B01J23/8871 , B01J23/8874 , B01J23/8876 , B01J23/8878 , C01C3/0241
摘要： Promoted bismuth rare earth molybdenum oxide complexes are excellent catalysts for the ammoxidation of methanol to HCN especially at high methanol throughputs at contact times appropriate for fluid-bed operation.
摘要翻译：促进的铋稀土钼氧化物配合物是用于甲醇氨化至HCN的优异催化剂，特别是在适用于流化床操作的接触时间的高甲醇生产量下。

47. 再颁专利

USRE31088E Process for the manufacture of unsaturated aldehydes and acids from the corresponding olefins 失效
标题翻译：从相应的烯烃制造不饱和醛和酸的方法
公开(公告)号：USRE31088E
公开(公告)日：1982-11-23
申请号：US904941
申请日：1978-05-11
申请人： Robert K. Grasselli , Dev D. Suresh , Ernest C. Milberger
发明人： Robert K. Grasselli , Dev D. Suresh , Ernest C. Milberger
IPC分类号： B01J23/28 , B01J23/30 , B01J23/31 , B01J23/32 , B01J23/88 , B01J23/887 , B01J27/00 , B01J27/057 , C07C45/35 , C07C51/25 , C07D307/79 , C07D307/80 , C07D307/82 , C07D307/83 , C07D307/92 , C07D333/60 , C07D333/68 , D06L3/12
CPC分类号： B01J23/8875 , B01J23/28 , B01J23/30 , B01J23/31 , B01J23/32 , B01J23/8876 , B01J23/8878 , B01J27/00 , B01J27/0576 , C07C253/26 , C07C45/34 , C07C45/35 , C07C51/252 , C07D307/79 , C07D307/80 , C07D307/82 , C07D307/83 , C07D307/92 , C07D333/60 , C07D333/68 , D06L3/1228 , B01J2523/00 , Y02P20/52
摘要： A process for the catalytic oxidation of olefins to unsaturated aldehydes and acids and the ammoxidation of olefins to unsaturated nitriles in which the catalyst comprises a promoted, reduced, antimony oxidemolybdenum oxide-containing catalyst.

48. 发明授权

US4324908A Preparation of unsaturated acids and esters from saturated carboxylic acid derivatives and carbonyl compounds over phosphate catalysts 失效
标题翻译：由饱和羧酸衍生物和羰基化合物在磷酸盐催化剂上制备不饱和酸和酯
公开(公告)号：US4324908A
公开(公告)日：1982-04-13
申请号：US221583
申请日：1980-12-31
申请人： Robert K. Grasselli , Andrew T. Guttmann
发明人： Robert K. Grasselli , Andrew T. Guttmann
IPC分类号： C07C69/52 , B01J27/00 , C07B61/00 , C07C51/00 , C07C51/353 , C07C57/04 , C07C67/00 , C07C69/54 , C07C67/343
CPC分类号： C07C51/353
摘要： Promoted phosphate catalysts have been found to be effective for the vapor phase condensation of saturated monocarboxylic acids or esters with formaldehyde, to produce unsaturated carboxylic acids or esters.
摘要翻译：已经发现促进磷酸盐催化剂对饱和一元羧酸或酯与甲醛的气相缩合有效，以产生不饱和羧酸或酯。

49. 发明授权

US4323520A Preparation of methacrylic derivatives from tertiary-butyl-containing compounds 失效
标题翻译：由含叔丁基的化合物制备甲基丙烯酸衍生物
公开(公告)号：US4323520A
公开(公告)日：1982-04-06
申请号：US794875
申请日：1977-05-09
申请人： Harley F. Hardman , James L. Callahan , Robert K. Grasselli
发明人： Harley F. Hardman , James L. Callahan , Robert K. Grasselli
IPC分类号： B01J23/88 , C07C45/32 , C07C45/34 , C07C45/37 , C07C51/235 , C07C51/25 , C07C120/00 , C07C120/14
CPC分类号： B01J23/8876 , B01J23/887 , C07C253/24 , C07C45/32 , C07C45/34 , C07C45/37 , C07C51/235 , C07C51/252 , B01J2523/00 , Y02P20/52
摘要： The present invention relates to a process for the conversion of tertiary-butyl-containing compounds to methacrylic derivatives, and more particularly to a process for the conversion of tertiary-butyl-containing compounds selected from the group consisting of alkyl tertiary-butyl ethers, tertiary-butyl alcohol, isobutylene dimer (2,2,4-trimethylpentene) and isobutylene trimer, to methacrolein, methacrylic acid or methacrylonitrile.
摘要翻译：本发明涉及将叔丁基化合物转化为甲基丙烯酸衍生物的方法，更具体地涉及一种将叔丁基化合物转化为选自烷基叔丁基醚，叔丁基醚，丁基醇，异丁烯二聚体（2,2,4-三甲基戊烯）和异丁烯三聚物，甲基丙烯醛，甲基丙烯酸或甲基丙烯腈。

50. 发明授权

US4290920A Sb-containing catalysts by Sb-oxide impregnation 失效
标题翻译：含Sb催化剂通过Sb-氧化物浸渍
公开(公告)号：US4290920A
公开(公告)日：1981-09-22
申请号：US107942
申请日：1979-12-28
申请人： Dev D. Suresh , James F. Brazdil , Robert K. Grasselli
发明人： Dev D. Suresh , James F. Brazdil , Robert K. Grasselli
IPC分类号： C07C45/34 , B01J23/18 , B01J23/22 , B01J23/24 , B01J23/34 , B01J23/84 , B01J23/88 , B01J27/057 , B01J38/48 , C07C45/00 , C07C67/00 , C07C253/00 , C07C255/08 , B01J27/02 , B01J23/10 , B01J23/64
CPC分类号： B01J23/8876 , B01J23/002 , B01J23/24 , B01J23/887 , B01J37/0201 , C07C253/26 , B01J2523/00 , Y02P20/52
摘要： Antimony-based oxide complex catalysts are improved by adding to these catalysts an antimony-containing compound such as Sb.sub.2 O.sub.3.
摘要翻译：通过向这些催化剂中加入含锑化合物如Sb 2 O 3来改进锑基氧化物络合物催化剂。

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