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    • 50. 发明授权
    • Multifunctional 3,4-alkylenedioxythiophene derivatives and electrically conductive polymers containing them
    • 多功能3,4-亚烷基二氧噻吩衍生物和含有它们的导电聚合物
    • US07358326B2
    • 2008-04-15
    • US11005211
    • 2004-12-06
    • Helmut-Werner HeuerRolf Wehrmann
    • Helmut-Werner HeuerRolf Wehrmann
    • C08G75/32C08G75/00C08G61/00C08G61/12
    • C07D519/00C08G61/126
    • Multifunctional 3,4-alkylenedioxythiophene derivatives represented by formula (I) are described, In formula (I), n and m each independently of each other, and independently for each o, are an integer from 1 to 5, and o is 3 or 4. The groups R1, R2, R3 and R4 are independently of each other and independently for each o, selected from, for example, hydrogen, halogen and optionally substituted linear or branched C1-C20-alkyl. The group R— of formula (I) may be, independently for each o, hydrogen or a thiophene represented by the following formula (II), in which m, n, R1, R2, R3 and R4 are as described in formula (I). The group X— of formula (I) is a polyvalent linking unit (e.g., a triphenylamine radical). Also described are electrically conductive oligomers and polymers comprising the multifunctional 3,4-alkylenedioxythiophene derivatives of the present invention as a repeating or crosslinking unit.
    • 式(I)表示的多功能3,4-亚烷基二氧噻吩衍生物在式(I)中描述,n和m各自独立地相互独立地表示,各个o独立地为1〜5的整数,o为3或 基团R 1,R 2,R 3和R 4彼此独立地彼此独立地独立地 对于每个o,选自例如氢,卤素和任选取代的直链或支链C 1 -C 20 - 烷基。 式(I)的基团R-可以独立地为每个o是氢或由下式(II)表示的噻吩,其中m,n,R 1,R 2, 2,R 3和R 4如式(I)所述。 式(I)的基团X是多价连接单元(例如三苯基胺基)。 还描述了包含本发明的多官能3,4-亚烷基二氧噻吩衍生物作为重复或交联单元的导电低聚物和聚合物。