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41. 发明授权

US4267380A Decomposition of cumene hydroperoxide using a Lewis acid catalyst 失效
标题翻译：使用路易斯酸催化剂分解氢过氧化枯烯
公开(公告)号：US4267380A
公开(公告)日：1981-05-12
申请号：US151090
申请日：1980-05-19
申请人： Richard G. Austin , Wayne R. Pretzer , Thaddeus P. Kobylinski
发明人： Richard G. Austin , Wayne R. Pretzer , Thaddeus P. Kobylinski
IPC分类号： C07C37/08 , C07C45/53
CPC分类号： C07C37/08 , C07C45/53
摘要： Cumene hydroperoxide is decomposed to phenol and acetone using a Lewis acid catalyst of the group tungsten hexafluoride, silicon tetrafluoride, stannous chloride, stannic fluoride, antimony pentachloride, sulfur monochloride and sulfur tetrafluoride.
摘要翻译：使用六氟化钨，四氟化硅，氯化亚锡，氟化锡，五氯化锑，一氯化硫和四氟化硫的路易斯酸催化剂将氢过氧化枯烯分解成苯酚和丙酮。

42. 发明授权

US4267379A Decomposition of cumene hydroperoxide and recovery of boron trifluoride catalyst 失效
标题翻译：氢过氧化枯烯的分解和三氟化硼催化剂的回收
公开(公告)号：US4267379A
公开(公告)日：1981-05-12
申请号：US66026
申请日：1979-08-13
申请人： Richard G. Austin , Wayne R. Pretzer , Thaddeus P. Kobylinski
发明人： Richard G. Austin , Wayne R. Pretzer , Thaddeus P. Kobylinski
IPC分类号： B01J27/12 , C07C37/08 , C07C45/53
CPC分类号： C07C37/08 , B01J27/12 , C07C45/53 , Y02P20/52
摘要： Cumene hydroperoxide is decomposed to phenol and acetone using boron trifluoride or boron trifluoride complexed with an oxygen-containing polar compound as the decomposition catalyst. The boron trifluoride in the reaction product is then complexed with an amine such as trimethyl amine for recovery and reuse in the process.
摘要翻译：使用三氟化硼或与含氧极性化合物配合的三氟化硼作为分解催化剂，将氢过氧化枯烯分解成苯酚和丙酮。然后将反应产物中的三氟化硼与胺如三甲胺络合，以在该过程中回收和再利用。

43. 发明授权

US4229601A Converting ethylene and propylene to the glycol using t.butyl hydroperoxide in a two-phase liquid reactant 失效
标题翻译：在二相液体反应物中使用叔丁基过氧化氢将乙烯和丙烯转化为二醇
公开(公告)号：US4229601A
公开(公告)日：1980-10-21
申请号：US972949
申请日：1978-12-26
申请人： Ching-Yong Wu , Thaddeus P. Kobylinski
发明人： Ching-Yong Wu , Thaddeus P. Kobylinski
IPC分类号： C07C29/03 , C07C31/20
CPC分类号： C07C29/03
摘要： Ethylene or propylene is converted to the corresponding glycol at high selectivity in a process in which t.butyl hydroperoxide is reacted with the olefin in a two-phase liquid, organic-aqueous reaction system in the presence of osmium tetroxide and cesium, rubidium or potassium hydroxide.
摘要翻译：在四氧化锇和铯，铷或钾的存在下，在二相液体有机 - 水反应体系中，叔丁基氢过氧化物与烯烃反应的方法中，乙烯或丙烯以高选择性转化为相应的二醇氢氧化物。

44. 发明授权

US4217291A Method of oxidizing osmium (III) and osmium (IV) to a higher valency state 失效
标题翻译：将锇（Ⅳ）和锇（Ⅳ）氧化成较高价态的方法
公开(公告)号：US4217291A
公开(公告)日：1980-08-12
申请号：US972929
申请日：1978-12-26
申请人： Ching-Yong Wu , Thaddeus P. Kobylinski
发明人： Ching-Yong Wu , Thaddeus P. Kobylinski
IPC分类号： C01G55/00 , C07C29/03 , C07C29/48 , C07F15/00 , B01J23/96 , B01J31/18
CPC分类号： C01G55/00 , C07C29/03 , C07C29/48 , Y02P20/52
摘要： Osmium (III) or (IV) in an anionic complex with oxygen and having an alkali metal, ammonium or tetra(lower)alkylammonium cation is oxidized to a valency state higher than 5 by reaction with an organic hydroperoxide, such as ethylbenzene hydroperoxide, at a temperature less than 30.degree. C.
摘要翻译：在具有氧并具有碱金属，铵或四（低级）烷基铵阳离子的阴离子络合物中的锇（III）或（IV）通过与有机氢过氧化物如乙苯氢过氧化物反应而被氧化成高于5的价态，温度低于30℃

45. 发明授权

US4210606A Decomposition of cumene hydroperoxide with a halogen-substituted thiophenol catalyst 失效
标题翻译：用卤素取代的苯硫酚催化剂分解氢过氧化枯烯
公开(公告)号：US4210606A
公开(公告)日：1980-07-01
申请号：US48743
申请日：1979-06-15
申请人： Richard G. Austin , Wayne R. Pretzer , Thaddeus P. Kobylinski
发明人： Richard G. Austin , Wayne R. Pretzer , Thaddeus P. Kobylinski
IPC分类号： C07C37/08 , C07C45/53 , C07C45/00
CPC分类号： C07C45/53 , C07C37/08
摘要： Cumene hydroperoxide is decomposed to phenol and acetone using a halogen-substituted thiophenol as the catalyst.
摘要翻译：枯烯氢过氧化物用卤素取代的苯硫酚作为催化剂分解成苯酚和丙酮。

46. 发明授权

US4170606A Synthesis of ethylene glycol from carbon monoxide and hydrogen using an iridium complex catalyst and a pyridine base ligand 失效
标题翻译：使用铱配合物催化剂和吡啶碱配体从一氧化碳和氢气合成乙二醇
公开(公告)号：US4170606A
公开(公告)日：1979-10-09
申请号：US894173
申请日：1978-04-06
申请人： Roger C. Williamson , Thaddeus P. Kobylinski
发明人： Roger C. Williamson , Thaddeus P. Kobylinski
IPC分类号： C07C29/151 , C07C29/157 , C07C27/06 , C07C29/00
CPC分类号： C07C29/1514 , C07C29/1512 , C07C29/157
摘要： A process for selectively producing ethylene glycol which comprises contacting carbon monoxide and hydrogen with an iridium complex catalyst and a pyridine base ligand.
摘要翻译：选择性生产乙二醇的方法，其包括使一氧化碳和氢与铱配合物催化剂和吡啶碱配体接触。

47. 发明授权

US4151208A Process for the selective preparation of acetaldehyde from methanol and synthesis gas 失效
标题翻译：从甲醇和合成气中选择性制备乙醛的方法
公开(公告)号：US4151208A
公开(公告)日：1979-04-24
申请号：US863744
申请日：1977-12-23
申请人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
发明人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
IPC分类号： B01J31/16 , B01J31/18 , B01J31/26 , C07C45/49 , C07C47/06
CPC分类号： B01J31/183 , B01J31/26 , C07C45/49 , B01J2531/025 , B01J2531/845
摘要： A process for selectively producing acetaldehyde which comprises contacting methanol, hydrogen and carbon monoxide with cobalt (II) meso-tetraaromaticporphine and an iodine promoter.
摘要翻译：一种选择性生产乙醛的方法，包括使甲醇，氢气和一氧化碳与钴（Ⅱ）内消旋 - 四芳香卟吩和碘促进剂接触。

48. 发明授权

US3972831A Nitrogen oxide reduction system 失效
标题翻译：氮氧化物还原系统
公开(公告)号：US3972831A
公开(公告)日：1976-08-03
申请号：US409263
申请日：1973-10-24
申请人： Harold Beuther , Thaddeus P. Kobylinski , Harold E. Swift
发明人： Harold Beuther , Thaddeus P. Kobylinski , Harold E. Swift
IPC分类号： B01D53/92 , B01J23/46 , B01J21/02
CPC分类号： B01D53/927 , B01J23/462
摘要： A system is proposed for the purification of exhaust gases from internal combustion engines, preferably the reduction of nitrogen oxides in exhaust gases from internal combustion engines in which nitrogen is selectively formed as substantially the only nitrogen-containing product. The exhaust gas is contacted at an elevated temperature with a noble metal in a reducing atmosphere, wherein nitrogen oxides are selectively converted to nitrogen as substantially the only nitrogen containing product, and/or is contacted with a noble metal in an oxidizing atmosphere, wherein carbon monoxide and unburned hydrocarbons are converted to carbon dioxide and water, said noble metal being distended on a microporous glass body. In a preferred embodiment the exhaust gas is contacted at an elevated temperature in a reducing atmosphere with ruthenium supported on a microporous glass body comprising a leached, phase-separated alkali borosilicate.
摘要翻译：提出了一种用于净化来自内燃机的废气的系统，优选地将来自内部选择性地形成氮的内燃机的废气中的氮氧化物还原为基本上唯一的含氮产物。废气在升高的温度下与还原气氛中的贵金属接触，其中氮氧化物选择性地转化为氮气，基本上仅含有氮的产物，和/或在氧化气氛中与贵金属接触，其中碳一氧化碳和未燃碳氢化合物被转化为二氧化碳和水，所述贵金属膨胀在微孔玻璃体上。在优选的实施方案中，废气在还原气氛中在升高的温度下与负载在包含沥滤的相分离的碱金属硼硅酸盐的微孔玻璃体上的钌接触。

49. 发明授权

US3965040A Process for preparing catalyst 失效
标题翻译：制备催化剂的方法
公开(公告)号：US3965040A
公开(公告)日：1976-06-22
申请号：US509073
申请日：1974-09-25
申请人： Thaddeus P. Kobylinski , Brian W. Taylor , Roger F. Vogel
发明人： Thaddeus P. Kobylinski , Brian W. Taylor , Roger F. Vogel
IPC分类号： B01D53/94 , B01J23/40 , B01J27/185 , B01J27/14 , B01J29/12
CPC分类号： B01D53/945 , B01J23/40 , B01J27/1856 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/1026 , Y02T10/22
摘要： A process for preparing a catalyst which involves coating a support with a platinum or palladium salt, calcining, further coating the calcined support with a solution containing a ruthenium or rhodium salt and an oxide, salt or acid of phosphorus and then further calcining.
摘要翻译：一种制备催化剂的方法，其包括用铂或钯盐涂覆载体，煅烧，用含有钌或铑盐的溶液和磷的氧化物，盐或酸进一步包覆煅烧的载体，然后进一步煅烧。

50. 发明授权

US5980840A Autothermic reactor and process using oxygen ion--conducting dense ceramic membrane 失效
标题翻译：自热反应器和工艺采用氧离子导电致密陶瓷膜
公开(公告)号：US5980840A
公开(公告)日：1999-11-09
申请号：US845310
申请日：1997-04-25
申请人： Mark S. Kleefisch , Carl A. Udovich , Alakananda Bhattacharyya , Thaddeus P. Kobylinski
发明人： Mark S. Kleefisch , Carl A. Udovich , Alakananda Bhattacharyya , Thaddeus P. Kobylinski
IPC分类号： B01D53/22 , B01D53/88 , B01D71/02 , B01J8/00 , B01J19/24 , C01B3/38 , C01B3/40 , C01G49/00 , C01G51/00 , C04B35/00 , B01J8/02 , C10J1/28 , F28D21/00
CPC分类号： C01B3/382 , B01D53/885 , B01J19/2475 , B01J8/009 , C01B3/40 , B01J2219/00117 , B01J2219/00135 , B01J2219/00164 , B01J2219/00166 , C01B2203/1052 , C01B2203/1082 , C01B2203/142 , C01B2203/82
摘要： The present invention relates to devices for conducting, simultaneously, exothermic and endothermic chemical conversions with transfer of heat therebetween. More particularly, this invention relates to autothermic modules using oxygen ion-conducting dense ceramic membranes to separate, selectively, oxygen from an oxygen-containing gas and supply it directly to partial combustion of gaseous organic compounds. Processes using autothermic modules in accordance with this invention are, advantageously, used for production of synthesis gas comprising carbon monoxide and molecular hydrogen which synthesis gas is substantially free of deleterious and/or inert gaseous diluents such as nitrogen. In particular, for conversions, within the integral autothermic module, of natural gas or other forms of gaseous lower alkanes to synthesis gas by means of partial combustion followed by reforming.
摘要翻译：本发明涉及用于同时传导放热和吸热化学转化的装置，其间传递热量。更具体地说，本发明涉及使用氧离子传导致密陶瓷膜从含氧气体中选择性分离氧并将其直接供应到气态有机化合物的部分燃烧的自热模块。使用根据本发明的自热模块的方法有利地用于生产包含一氧化碳和分子氢的合成气，该合成气基本上不含有害和/或惰性的气态稀释剂如氮气。特别地，在整体自热模块内，通过部分燃烧，随后重整，将天然气或其它形式的气态低级烷烃转化成合成气。

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