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    • 44. 发明授权
    • Metallocene complex and polymerization catalyst composition containing the same
    • 茂金属络合物和聚合催化剂组合物含有它
    • US08653290B2
    • 2014-02-18
    • US12227058
    • 2007-05-02
    • Shojiro KaitaOlivier Tardif
    • Shojiro KaitaOlivier Tardif
    • C07F17/00C08F4/52
    • C07F17/00C08F10/00C08F36/04C08F112/08C08F212/08C08F4/52C08F4/54C08F236/06C08F4/545
    • Disclosed are a metallocene complex represented by the general formula (I), (II) or (III), and a polymerization catalyst composition containing such a metallocene complex. In the formulae (I), (II) and (III), M represents a lanthanoid element, scandium or yttrium; CpR independently represents an unsubstituted or substituted indenyl; CpR′ represents an unsubstituted or substituted cyclopentadienyl, indenyl or fluorenyl; Ra-Rf independently represents a hydrogen or an alkyl group having 1-3 carbon atoms; X and X′ respectively represent a hydrogen atom, a halogen atom, an alkoxide group, a thiolate group, an amide group, a silyl group or a hydrocarbon group having 1-20 carbon atoms; L represents a neutral Lewis base; w represents an integer of 0-3; and [B]− represents a non-coordinating anion.
    • 公开了由通式(I),(II)或(III)表示的茂金属络合物和含有这种茂金属络合物的聚合催化剂组合物。 在式(I),(II)和(III)中,M表示镧系元素,钪或钇; CpR独立地表示未取代或取代的茚基; CpR'表示未取代或取代的环戊二烯基,茚基或芴基; Ra-Rf独立地表示氢或具有1-3个碳原子的烷基; X和X'分别表示氢原子,卤素原子,醇盐基,硫醇基,酰胺基,甲硅烷基或具有1-20个碳原子的烃基; L代表中性路易斯碱; w表示0-3的整数; 和[B] - 表示非配位阴离子。