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41. 发明申请

WO2010024975A8 PROCESS FOR PRODUCING PHENOL 审中-公开
标题翻译：生产苯酚的方法
公开(公告)号：WO2010024975A8
公开(公告)日：2010-11-18
申请号：PCT/US2009050497
申请日：2009-07-14
申请人： EXXONMOBIL CHEM PATENTS INC , BUCHANAN JOHN SCOTT , STANAT JON E R , CHEN TAN-JEN , DAKKA JIHAD M , LATTNER JAMES R
发明人： BUCHANAN JOHN SCOTT , STANAT JON E R , CHEN TAN-JEN , DAKKA JIHAD M , LATTNER JAMES R
IPC分类号： C07C37/06 , C07C37/08 , C07C39/04 , C07C45/53 , C07C49/403 , C07C409/08 , C07C409/14
CPC分类号： C07C37/06 , C07C2/74 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2601/14 , C07C13/28 , C07C39/04 , C07C49/403 , C07C409/14
摘要： In a process for producing phenol, cyclohexylbenzene is oxidized to produce cyclohexylbenzene hydroperoxide and then the resultant cyclohexylbenzene hydroperoxide is cleaved to produce an effluent stream comprising phenol and cyclohexanone. At least a portion of the effluent stream is then fed to at least one dehydrogenation reaction zone, where the effluent stream portion is contacted with a dehydrogenation catalyst under conditions effective to convert at least part of the cyclohexanone in the effluent portion into phenol and hydrogen.
摘要翻译：在生产苯酚的方法中，将环己基苯氧化生产环己基苯氢过氧化物，然后将所得的环己基苯氢过氧化物切割以产生包含苯酚和环己酮的流出物流。然后将至少一部分流出物流送入至少一个脱氢反应区，其中流出物流部分与脱氢催化剂在有效地将流出物部分中的至少一部分环己酮转化为酚和氢的条件下接触。

42. 发明申请

WO2009131769A8 PROCESS FOR PRODUCING PHENOL AND/OR CYCLOHEXANONE 审中-公开
标题翻译：生产苯酚和/或环己酮的方法
公开(公告)号：WO2009131769A8
公开(公告)日：2010-10-28
申请号：PCT/US2009037223
申请日：2009-03-16
申请人： EXXONMOBIL CHEM PATENTS INC , DAKKA JIHAD M , BUCHANAN JOHN S , CHENG JANE C , CHEN TAN-JEN , DECAUL LORENZO C , HELTON TERRY E , STANAT JON E , BENITEZ FRANCISCO M
发明人： DAKKA JIHAD M , BUCHANAN JOHN S , CHENG JANE C , CHEN TAN-JEN , DECAUL LORENZO C , HELTON TERRY E , STANAT JON E , BENITEZ FRANCISCO M
IPC分类号： C07C2/74 , B01J29/72 , C07C5/367 , C07C13/28 , C07C15/04 , C07C37/08 , C07C45/53 , C07C49/403
CPC分类号： C07C37/08 , B01J29/064 , B01J29/7215 , B01J29/7276 , C07C2/74 , C07C37/07 , C07C45/53 , C07C407/00 , C07C409/14 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C49/403 , C07C39/04
摘要： In a process for producing phenol and/or cyclohexanone, benzene and hydrogen are contacted with a first catalyst in a hydroalkylation step to produce a first effluent stream comprising cyclohexylbenzene, cyclohexane, and unreacted benzene. At least part of the first effluent stream is supplied to a first separation system to divide the first effluent stream part into a cyclohexylbenzene-rich stream and a C6 product stream comprising unreacted benzene and cyclohexane.
摘要翻译：在制备苯酚和/或环己酮的方法中，苯和氢在加氢烷基化步骤中与第一催化剂接触以产生包含环己基苯，环己烷和未反应苯的第一流出料流。将第一流出物流的至少一部分供应到第一分离系统，以将第一流出物流部分分解成富含环己基苯的物流和包含未反应的苯和环己烷的C6产物流。

43. 发明申请

WO2010074779A1 OXIDATION OF ALKYLAROMATIC COMPOUNDS 审中-公开
标题翻译：烷基化合物的氧化
公开(公告)号：WO2010074779A1
公开(公告)日：2010-07-01
申请号：PCT/US2009/057239
申请日：2009-09-17
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , DAKKA, Jihad, M. , ZUSHMA, Stephen , STANAT, Jon, E.
发明人： DAKKA, Jihad, M. , ZUSHMA, Stephen , STANAT, Jon, E.
IPC分类号： C07C407/00 , C07C409/02 , B01J31/02 , C07D209/48
CPC分类号： C07C407/00 , B01J31/006 , B01J31/0247 , B01J2231/70 , C07C37/08 , C07C45/53 , C07C409/08 , C07C409/10 , C07C409/14 , C07C2601/14 , C07D209/48 , Y02P20/52 , C07C39/04 , C07C49/08
摘要： In a process for oxidizing an alkylaromatic compound to the corresponding hydroperoxide, a feed comprising an alkylaromatic compound is contacted with an oxygen-containing gas in the presence of a catalyst comprising a cyclic imide. The contacting is conducted at a temperature of about 90°C to about 150°C, with the cyclic imide being present in an amount between about 0.05 wt% and about 5 wt% of the alkylarom in the feed and the catalyst being substantially free of alkali metal compounds. The contacting oxidizes at least part of the alkylaromatic compound in said feed to the corresponding hydroperoxide.
摘要翻译：在将烷基芳族化合物氧化成相应的氢过氧化物的方法中，包含烷基芳族化合物的进料在含有环状酰亚胺的催化剂存在下与含氧气体接触。接触在约90℃至约150℃的温度下进行，环状酰亚胺的存在量为进料中烷基溴的约0.05重量％至约5重量％，催化剂基本上不含碱金属化合物。接触将至少部分所述进料中的烷基芳族化合物氧化成相应的氢过氧化物。

44. 发明申请

WO2010074737A1 TRYGLYCERIDE PLASTICIZER AND PROCESS OF MAKING 审中-公开
标题翻译： TRYGLYCERIDE PLASTICIZER和制备方法
公开(公告)号：WO2010074737A1
公开(公告)日：2010-07-01
申请号：PCT/US2009/006642
申请日：2009-12-18
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY , DAKKA, Jihad, M. , MOZELESKI, Edmund, J. , BAUGH, Lisa, S. , BERLUCHE, Enock
发明人： DAKKA, Jihad, M. , MOZELESKI, Edmund, J. , BAUGH, Lisa, S. , BERLUCHE, Enock
IPC分类号： A61L2/08
CPC分类号： C08L91/00 , C08K5/103 , Y10T428/139 , Y10T442/20 , C08L27/06 , C08L67/00 , C08L75/04 , C08L31/04 , C08L33/00
摘要： Provided are compositions, processes for making, and processes for using triglycerides as plasticizers. Triglyceride plasticizers can be produced by recovery of linear or branched C4 to Cio aldehydes from a hydro formylation product, oxidation to the acid with oxygen and/or air, recovery of the resulting acid, and esterification with glycerol, wherein the total carbon number of the triester groups is from 20 to 25 for greater than or equal to 45 wt% of the plasticizer. Such plasticizers can be phthalate-free and provide outstanding properties including a suitable melting or glass transition or pour point, low volatility, increased compatibility, and excellent low temperature properties in a range of polymeric resins.
摘要翻译：提供组合物，制备方法和使用甘油三酯作为增塑剂的方法。甘油三酯增塑剂可以通过从加氢甲酰化产物中回收线性或分支的C 4至C 10醛，用氧和/或空气氧化成酸，回收所得酸并用甘油进行酯化来制备，其中总碳数对于大于或等于45重量％的增塑剂，三酯基团为20至25。这种增塑剂可以是无邻苯二甲酸酯，并提供突出的性能，包括合适的熔融或玻璃化转变或倾点，低挥发性，增加的相容性和在一系列聚合物树脂中的优异的低温性能。

45. 发明申请

WO2010024975A1 PROCESS FOR PRODUCING PHENOL 审中-公开
标题翻译：生产苯酚的方法
公开(公告)号：WO2010024975A1
公开(公告)日：2010-03-04
申请号：PCT/US2009/050497
申请日：2009-07-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , BUCHANAN, John, Scott , STANAT, Jon, E., R. , CHEN, Tan-jen , DAKKA, Jihad, M. , LATTNER, James, R.
发明人： BUCHANAN, John, Scott , STANAT, Jon, E., R. , CHEN, Tan-jen , DAKKA, Jihad, M. , LATTNER, James, R.
IPC分类号： C07C37/06 , C07C37/08 , C07C39/04 , C07C45/53 , C07C409/08 , C07C409/14 , C07C49/403
CPC分类号： C07C37/06 , C07C2/74 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2601/14 , C07C13/28 , C07C39/04 , C07C49/403 , C07C409/14
摘要： In a process for producing phenol, cyclohexylbenzene is oxidized to produce cyclohexylbenzene hydroperoxide and then the resultant cyclohexylbenzene hydroperoxide is cleaved to produce an effluent stream comprising phenol and cyclohexanone. At least a portion of the effluent stream is then fed to at least one dehydrogenation reaction zone, where the effluent stream portion is contacted with a dehydrogenation catalyst under conditions effective to convert at least part of the cyclohexanone in the effluent portion into phenol and hydrogen.
摘要翻译：在生产苯酚的方法中，将环己基苯氧化以产生环己基苯氢过氧化物，然后将所得环己基苯氢过氧化物裂解以产生包含苯酚和环己酮的流出物料流。然后将至少一部分流出物流供入至少一个脱氢反应区，其中流出物流部分在有效将流出物部分中的至少部分环己酮转化为苯酚和氢气的条件下与脱氢催化剂接触。

46. 发明申请

WO2009134514A1 PROCESS FOR PRODUCING CYCLOHEXANONE 审中-公开
标题翻译：生产环己酮的方法
公开(公告)号：WO2009134514A1
公开(公告)日：2009-11-05
申请号：PCT/US2009/034514
申请日：2009-02-19
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , DAKKA, Jihad M. , BUCHANAN, John Scott , LATTNER, James R. , MIZRAHI, Sadi
发明人： DAKKA, Jihad M. , BUCHANAN, John Scott , LATTNER, James R. , MIZRAHI, Sadi
IPC分类号： C07C45/53 , C07C45/00 , C07C49/403
CPC分类号： C07C409/14 , C07C37/07 , C07C37/08 , C07C45/006 , C07C45/53 , C07C407/00 , C07C2601/14 , C07C49/403 , C07C39/04
摘要： In a process for producing cyclohexanone, cyclohexylbenzene is oxidized to produce cyclohexylbenzene hydroperoxide and then the resultant cyclohexylbenzene hydroperoxide is cleaved to produce an effluent stream comprising phenol and cyclohexanone. At least a portion of the effluent stream is then fed to at least one hydrogenation reaction zone, where the effluent stream portion is contacted with hydrogen in the presence of a hydrogenation catalyst under conditions effective to convert at least part of the phenol in the effluent portion into cyclohexanone.
摘要翻译：在制备环己酮的方法中，将环己基苯氧化生成环己基苯氢过氧化物，然后将所得的环己基苯氢过氧化物切割以产生包含苯酚和环己酮的流出物流。然后将至少一部分流出物流送入至少一个氢化反应区，在氢化反应区中，在氢化催化剂存在下，流出物流部分与氢接触，在有效地转化至少一部分在流出物部分中的苯酚的条件下加入环己酮。

47. 发明申请

WO2009025939A2 OXIDATION OF HYDROCARBONS 审中-公开
标题翻译：烃的氧化
公开(公告)号：WO2009025939A2
公开(公告)日：2009-02-26
申请号：PCT/US2008/069779
申请日：2008-07-11
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , DAKKA, Jihad, M. , VARTULI, James, C. , ZUSHMA, Stephen
发明人： DAKKA, Jihad, M. , VARTULI, James, C. , ZUSHMA, Stephen
IPC分类号： C07C407/00 , C07C409/08
CPC分类号： C07C409/08 , C07C29/50 , C07C37/08 , C07C37/20 , C07C45/53 , C07C51/313 , C07C407/00 , C07C407/003 , C07C409/04 , C07C409/10 , C07C2601/14 , Y02P20/52 , C07C55/14 , C07C35/08 , C07C39/04 , C07C39/16 , C07C409/14
摘要： In a process for oxidizing a hydrocarbon to a corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, the hydrocarbon is contacted with an oxygen- containing gas in the presence of a catalyst comprising a cyclic imide of the general formula (I), wherein each of R 1 and R 2 is independently selected from hydrocarbyl and substituted hydrocarbyl radicals having 1 to 20 carbon atoms, or from the groups SO 3 H, NH 2 , OH and NO2, or from the atoms H, F, Cl, Br and I provided that R 1 and R 2 can be linked to one another via a covalent bond; each of Q 1 and Q 2 is independently selected from C, CH, N and CR 3 ; each of X and Z is independently selected from C, S, CH 2 , N, P and an element of Group 4 of the Periodic Table; Y is O or OH; k is 0, 1, or 2; 1 is 0, 1, or 2; m is 1 to 3, and R 3 can be any of the entities listed for R 1 . The contacting produces an effluent comprising an oxidized hydrocarbon product and unreacted imide catalyst of formula (I) and the effluent is treated with an aqueous solution of a base to produce an aqueous phase comprising at least part of the unreacted imide catalyst of formula (I) and an organic phase comprising oxidized hydrocarbon product. The organic phase can then be recovered.
摘要翻译：在将烃氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，在含有环状酰亚胺的催化剂存在下使烃与含氧气体接触其中R 1和R 2各自独立地选自具有1至20个碳原子的烃基和取代的烃基，或来自基团 SO 3 H，NH 2，OH和NO 2，或者来自原子H，F，Cl，Br和I，条件是R 1和 R 2可以通过共价键相互连接; Q 1和Q 2中的每一个独立地选自C，CH，N和CR 3; X和Z中的每一个独立地选自C，S，CH 2，N，P和元素周期表第4族的元素; Y是O或OH; k是0,1或2; 1是0,1或2; m是1至3，并且R 3可以是针对R 1所列出的任何实体。该接触产生包含氧化的烃产物和式（I）的未反应的酰亚胺催化剂的流出物，并将该流出物用碱的水溶液处理以产生包含至少部分式（I）的未反应的酰亚胺催化剂的水相，和包含氧化烃产物的有机相。然后可以回收有机相。

48. 发明申请

WO2008147596A1 ISOPROPYL ALCOHOL FROM PROPYLENE USING ZIRCONIUM BASED MIXED METAL OXIDES 审中-公开
标题翻译：使用基于ZIRCONIUM的混合金属氧化物的丙烯的异丙醇
公开(公告)号：WO2008147596A1
公开(公告)日：2008-12-04
申请号：PCT/US2008/059881
申请日：2008-04-10
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , DAKKA, Jihad, M. , LEVIN, Dorin , MCCARTHY, Stephen, J. , REINE, Travis, A. , SCHNEIDER, Mary, Jo , VARTULI, James, C. , YARBROUGH, Charles, M.
发明人： DAKKA, Jihad, M. , LEVIN, Dorin , MCCARTHY, Stephen, J. , REINE, Travis, A. , SCHNEIDER, Mary, Jo , VARTULI, James, C. , YARBROUGH, Charles, M.
IPC分类号： B01J21/06 , B01J23/10 , B01J23/24 , B01J23/34 , B01J23/888 , B01J37/03 , B01J37/10 , C07C29/04 , B01J23/72 , B01J23/745 , B01J23/85
CPC分类号： B01J37/03 , B01J21/066 , B01J23/002 , B01J23/10 , B01J23/24 , B01J23/34 , B01J23/72 , B01J23/745 , B01J23/85 , B01J23/888 , B01J27/053 , B01J37/10 , B01J2523/00 , C07C29/04 , B01J2523/3712 , B01J2523/48 , B01J2523/69 , B01J2523/72 , B01J2523/17 , C07C31/10
摘要： The invention relates to the production of isopropyl alcohol (IPA) by direct hydration of propylene over mixed transition metal oxides co-precipitated with ZrO 2 . In embodiments the mixed metal oxides have improved hydrolytic stability and are active over a wider temperature range than existing direct hydration catalysts.
摘要翻译：本发明涉及通过在与ZrO 2共沉淀的混合过渡金属氧化物上直接水合丙烯来生产异丙醇（IPA）。在实施方案中，混合金属氧化物具有改善的水解稳定性，并且在比现有直接水合催化剂更宽的温度范围内具有活性。

49. 发明申请

WO2008101617A1 OXIDATION OF SEC-BUTYLBENZENE AND PRODUCTON OF PHENOL AND METHYL ETHYL KETONE 审中-公开
标题翻译：苯乙烯和甲基乙基酮的甲苯磺酸氧化
公开(公告)号：WO2008101617A1
公开(公告)日：2008-08-28
申请号：PCT/EP2008/001044
申请日：2008-02-07
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , EXXONMOBIL CHEMICAL LIMITED , DAKKA, Jihad, M. , ZUSHMA, Stephen , STANAT, Jon, E.
发明人： DAKKA, Jihad, M. , ZUSHMA, Stephen , STANAT, Jon, E.
IPC分类号： C07C2/66 , C07C37/08 , C07C39/04 , C07C45/53 , C07C409/08 , C07C49/10
CPC分类号： C07C409/08 , C07C2/66 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2529/70 , C07C15/02 , C07C49/10 , C07C39/04
摘要： In a process for oxidizing sec-butylbenzene to the corresponding hydroperoxide, a feed containing sec-butylbenzene is contacted with an oxygen- containing gas in a reactor comprising a gas inlet and a gas outlet for said oxygen- containing gas. The contacting is conducted at a temperature, T, in degrees Centigrade, between about 90°C and about 140°C and an oxygen partial pressure at the gas outlet of the reactor, Opp, in kPa determined by the formula (I) (1527.33 - 10.83T) > O pp > (1320.48 - 10.83T) (I), provided that Opp is always greater than zero. The resulting hydroperoxide can be cleaved, optionally in the presence of a catalyst, to co-produce phenol and methyl ethyl ketone.
摘要翻译：在将仲丁基苯氧化成相应的氢过氧化物的过程中，含有仲丁基苯的进料在含有气体入口的反应器和含氧气体的气体出口的反应器中与含氧气体接触。接触在T，以摄氏度，约90℃至约140℃之间的温度和反应器气体出口处的氧分压Opp（以公式（I）确定的kPa）（1527.33） - 1083T）>（1320.48-10.83T）（I），条件是Opp总是大于零。所得氢过氧化物可以任选在催化剂存在下裂解，共同生产苯酚和甲基乙基酮。

50. 发明申请

WO2008101616A1 PRODUCTION OF ALKYLAROMATIC COMPOUNDS 审中-公开
标题翻译：生产烷基化合物
公开(公告)号：WO2008101616A1
公开(公告)日：2008-08-28
申请号：PCT/EP2008/001043
申请日：2008-02-07
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , EXXONMOBIL CHEMICAL LIMITED , DAKKA, Jihad, M. , MOZELESKI, Edmund, J. , BENITEZ, Frank, M. , BUCHANAN, John S.
发明人： DAKKA, Jihad, M. , MOZELESKI, Edmund, J. , BENITEZ, Frank, M. , BUCHANAN, John S.
IPC分类号： C10G69/12 , B01J23/46
CPC分类号： C10G69/123 , B01J23/44 , B01J23/464 , B01J27/10 , B01J29/70 , B01J31/0235 , C07C2/66 , C07C7/163 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/08 , C07C409/10 , C07C2529/70 , Y02P20/52 , C07C15/02 , C07C49/08 , C07C49/10 , C07C39/04
摘要： In a process for producing an alkylaromatic compound, an aromatic compound is contacted with an olefin under alkylation conditions and in the presence of an alkylation catalyst to produce an alkylation effluent comprising an alkylaromatic compound and at least one oligomer of said olefin. The alkylation effluent is then treated with hydrogen under hydrogenation conditions in the presence of a rhodium-containing catalyst to selectively hydrogenate said at least one oligomer.
摘要翻译：在制备烷基芳族化合物的方法中，芳族化合物在烷基化条件下和在烷基化催化剂存在下与烯烃接触以产生包含烷基芳族化合物和所述烯烃的至少一种低聚物的烷基化流出物。然后在氢化条件下，在含铑催化剂的存在下，用氢气处理烷基化流出物，以选择性氢化所述至少一种低聚物。

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