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    • 44. 发明授权
    • Apparatus for removing selenium from refinery process water and waste
water streams
    • 从炼油厂工艺用水和废水流中除去硒的设备
    • US6156191A
    • 2000-12-05
    • US412677
    • 1999-10-05
    • Steven D. Overman
    • Steven D. Overman
    • C02F1/28C02F1/38C02F1/52C02F1/58C02F1/66C02F1/72C02F9/00C02F1/62
    • C02F9/00C02F1/5236C02F1/72C02F1/38C02F1/66C02F2101/20C02F2103/36Y10S210/911
    • The present invention provides an efficient and highly effective method of removing dissolved selenium from a variety of refinery process water and wastewater streams. The present invention also provides a new and effective method of oxidizing selenium and organo-selenium compounds to the selenite [+IV] oxidation state in order to be adsorbed by a metal oxide or metal hydroxide precipitate. The invention includes two continuous stirred-tank reactors (CSTR) operated in series. The stream to be treated and one of several iron salts (ferric sulfate, ferric chloride, etc.) are introduced into the first CSTR, forming ferric hydroxide and ferric oxyhydroxide precipitates. The pH of the first CSTR is automatically controlled by adjusting the injection rate of the ferric salt. The effluent stream from the first CSTR is directed into a second CSTR into which potassium permanganate is introduced. The selenium in the original stream to be treated is oxidized to selenite [+IV]; manganese dioxide precipitates as a byproduct of the oxidation reactions. The selenite is then adsorbed by the various precipitates, which are removed by centrifugation. The pH of the centrifuged water is automatically adjusted by the controlled addition of sodium hydroxide. The effectiveness of this continuous process has been demonstrated for streams with a wide range of selenium concentrations, including refinery wastewater and refinery stripped sour water. The process is also effective for treating secondary waste water streams, such as reverse osmosis reject water and ion exchange regeneration wastewater, which result from the pretreatment of refinery wastewater or refinery stripped sour water.
    • 本发明提供从各种炼油工艺水和废水流中除去溶解的硒的有效和高效的方法。 本发明还提供了将硒和有机硒化合物氧化成亚硒酸盐[+ IV]氧化态以便被金属氧化物或金属氢氧化物沉淀物吸附的新的和有效的方法。 本发明包括串联操作的两个连续搅拌釜式反应器(CSTR)。 要处理的物流和几种铁盐(硫酸铁,氯化铁等)之一被引入到第一CSTR中,形成氢氧化铁和氢氧化三铁沉淀。 通过调节铁盐的注入速率自动控制第一个CSTR的pH值。 来自第一CSTR的流出物流被引导到引入高锰酸钾的第二CSTR中。 待处理的原始流中的硒被氧化成亚硒酸盐[+ IV]; 二氧化锰沉淀作为氧化反应的副产物。 然后亚硒酸盐被各种沉淀物吸附,通过离心除去。 通过控制加入氢氧化钠自动调节离心水的pH。 已经证明了这种连续过程的有效性,其具有范围广泛的硒浓度的流,包括炼厂废水和炼油厂剥离的酸性水。 该方法对于处理炼油厂废水或炼厂脱水酸水所产生的二次废水流,如反渗透排放水和离子交换再生废水也是有效的。
    • 46. 发明授权
    • Gas handling for plastics liquefaction
    • 气体处理塑料液化
    • US6121334A
    • 2000-09-19
    • US230133
    • 1999-05-13
    • John D. Winter
    • John D. Winter
    • C10G1/00C10G1/10C08J11/10B01D53/14C08J11/14
    • C10G1/002C10G1/10
    • The present invention relates to a method for removing high molecular weight high melting point hydrocarbon vapors from a hydrocarbon vapor offgas stream produced during the liquefaction of a solid waste plastic material to produce an oil that serves as a liquid feedstock for a partial oxidation reaction. The hydrocarbon vapor offgas stream (2) is directly contacted with a water spray (4) at a condensation temperature above the melting point of the high molecular weight hydrocarbons contained in the offgas. This results in the condensation and convenient removal of the high melting point hydrocarbons, referred to as "waxes." One or more subsequent condensation steps can be conducted at lower condensation temperatures to remove the lower temperature condensable hydrocarbons. The remaining uncondensed vapors are then recycled to serve as a heater fuel for the liquefaction of the waste plastic material.
    • PCT No.PCT / US97 / 12481 Sec。 371日期1999年5月13日 102(e)1999年5月13日PCT PCT 1997年7月14日PCT公布。 出版物WO98 / 02504 日期1998年1月22日本发明涉及一种从在固体废塑料材料液化期间产生的烃蒸汽废气流中除去高分子量高熔点烃蒸汽的方法,以产生用作液体原料的油 部分氧化反应。 烃蒸汽废气流(2)在高于废气中所含的高分子量烃的熔点的冷凝温度下与水喷雾(4)直接接触。 这导致冷凝和方便地去除被称为“蜡”的高熔点烃。 一个或多个随后的冷凝步骤可以在较低的冷凝温度下进行以除去较低温度的可冷凝烃。 然后将剩余的未冷凝的蒸气再循环用作用于液化废塑料的加热器燃料。