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31. 发明专利

JP5854405B2 ハロゲン化触媒およびハロゲン化合物の製造方法有权
标题翻译：用于制造卤化催化剂和卤素化合物的方法
公开(公告)号：JP5854405B2
公开(公告)日：2016-02-09
申请号：JP2012549663
申请日：2011-08-17
申请人：国立大学法人岡山大学
发明人：仁科勇太 , 高井和彦 , 森田惇也
IPC分类号： C07C17/154 , C07C23/10 , C07C23/16 , C07C19/075 , C07C22/04 , C07C25/02 , C07C17/093 , C08F8/22 , B01J23/34
CPC分类号： C08F8/22 , B01J23/26 , B01J23/34 , B01J23/78 , C07C17/10 , C07C17/154 , C07C17/156 , C07D333/28 , C07C2101/14 , C07C2101/18

32. 发明专利

JP2012086159A Halogenation catalyst and method of manufacturing halogen compound 审中-公开
标题翻译：卤化催化剂和制备卤化物的方法
公开(公告)号：JP2012086159A
公开(公告)日：2012-05-10
申请号：JP2010235618
申请日：2010-10-20
申请人： Okayama Univ , 国立大学法人岡山大学
发明人： NISHINA YUTA , TAKAI KAZUHIKO , MORITA JUNYA
IPC分类号： B01J23/34 , B01J35/02 , C07B61/00 , C07C17/06 , C07C19/075 , C07C22/04 , C07C23/10 , C07C23/16 , C07C25/02 , C07D333/28 , C08F8/20 , C08G63/91 , C08G64/42 , C08G69/48
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To develop a highly-active catalyst which is used for efficient halogenation under a mild condition and can be easily recovered after reaction and be recycled with respect to reaction.SOLUTION: This halogenation catalyst includes an oxidized transition metal composite (a) indicated by a general formula (1) AMO(wherein, A represents alkali metal, M represents at least one transition metallic element selected from a group consisting of chromium, manganese, cobalt, nickel and iron, and x represents a number of 0
摘要翻译：要解决的问题：开发用于在温和条件下有效卤化的高活性催化剂，并且可以在反应后容易地回收并在反应中循环使用。解决方案：该卤化催化剂包括由通式（1）表示的氧化过渡金属复合材料（a）：A （2） + 0.5x）（其中，A表示碱金属，M表示选自铬，锰，钴，镍和铁中的至少一种过渡金属元素，x表示0

33. 发明专利

JPH06256224A HALOFLUORINATION OF ALKENES 失效
公开(公告)号：JPH06256224A
公开(公告)日：1994-09-13
申请号：JP4136393
申请日：1993-03-02
申请人： HOKKO CHEM IND CO , RIKAGAKU KENKYUSHO
发明人： UCHIBORI YUKITAKA , UMENO MASAYUKI , SETO HIDEHARU , YOSHIOKA HIROSUKE
IPC分类号： C07B39/00 , C07C17/02 , C07C17/04 , C07C19/08 , C07C19/10 , C07C19/12 , C07C19/14 , C07C19/16 , C07C22/08 , C07C23/10 , C07C23/16 , C07C23/34 , C07C29/62 , C07C31/34 , C07C67/307 , C07C69/63 , C07D301/00 , C07D303/08
摘要： PURPOSE:To obtain a halofluorinated product of various alkenes under relatively mild condition in high yield, stereoselectivity and site selectivity. CONSTITUTION:An alkene is made to react with a fluorination agent consisting of a tetrabutylphosphonium fluoride of formula ((m) is 1 or 2) and simultaneously a halogenation agent selected from an N-halosuccinimide (halogen is I, Br or Cl) and dibromodimethylhydantoin at 0-100 deg.C (preferably 0-60 deg.C). The amount of the fluorination agent and the halogenation agent is in slightly excess (preferably 1-3 equivalent) of the alkene. The compound of formula is preferably tetra-n-butylphosphonium hydrogen difluoride or tetra-n-butylphosphonium dihydrogen trifluoride.

35. 发明专利

DE10351643A1 未知
公开(公告)号：DE10351643A1
公开(公告)日：2005-06-09
申请号：DE10351643
申请日：2003-11-05
申请人： BASF AG , UNIV MUENCHEN L MAXIMILIANS
发明人： MIJOLOVIC DARIJO , HERRLICH-LOOS MIRJAM , LANG GABRIELE , MAYR HERBERT
IPC分类号： C07C17/08 , C07C23/16 , C07C43/184 , C07C69/013 , C07C69/14 , C08F10/10 , C08F110/10 , C07C23/02 , C07C67/04 , C07C41/06
摘要： Substituted 7- to 12-membered cycloalkanes which have leaving groups, in particular chlorine atoms, on tertiary ring carbons, a process for preparing them and their use as initiators for cationic polymerization, in particular the cationic polymerization of isobutene are described. Preferred compounds are 1,4-dichloro-1,4-dimethylcyclooctane, 1,5-dichloro-1,5-dimethylcyclooctane and mixtures thereof. They are prepared by addition of hydrogen chloride onto appropriately substituted cycloalkapolyenes.

36. 发明专利

CA2260277C IMIDAZOLATE SULFURYL DIFLUORIDES 未知
公开(公告)号：CA2260277C
公开(公告)日：2003-07-08
申请号：CA2260277
申请日：1999-01-25
申请人： AIR PROD & CHEM
发明人： SYVRET ROBERT GEORGE
IPC分类号： C07B39/00 , C07C17/16 , C07C17/18 , C07C23/10 , C07C23/16 , C07D233/54 , C07D233/56 , C07D233/60 , C07D521/00 , C07D301/00 , C07C23/02 , C07F7/12 , C07D403/14 , C07F9/38 , C07F9/50 , C07D233/64 , C07D233/68
摘要： A compound having the structure: (see Formula I) wherein R1-3 are the same or different and are selected from the group consisting of hydrogen, halogen, C1-8 alkyl, C1-8 haloalkyl, alkoxyalkyl where the alkoxy portion is C1-3 and the alkyl portion is C1-8, haloalkoxyalkyl where the haloalkoxy portion is C1-3 and the alkyl portion is C1-8, haloalkoxyhaloalkyl where the haloalkoxy portion is C1-3 and the haloalkyl portion is C1-8, C4-10 aryl, C4-10 haloaryl, alkylaryl where the alkyl portion is C1-8 and the aryl portion is C4-10, alkoxyaryl where the alkoxy portion is C1-3 and the aryl portion is C4-10, alkoxyalkylaryl where the alkoxy and alkyl portions each are C1-3 and the aryl portion is C4-10, C4-10 heteroaryl in which the heteroatom is oxygen, nitrogen or sulfur, cyano, nitro, amino, sulfonic acid, sulfonic methyl ester, a C4-8 saturated cyclic hydrocarbon having 1-3 heteroatoms selected from the group consisting of oxygen, nitrogen, sulfur, and mixtures thereof; and further R2-3 together form: (a) a cyclic ring having 2-10 carbon ring members and 1 heteroatom selected from the group consisting of oxygen, sulfur, nitrogen, C1-3 alkylated nitrogen, protonated nitrogen, and halogenated nitrogen; or (b) an unsaturated cyclic ring with 2 to 4 carbon atoms and 0-3 heteroatoms selected from the group consisting of oxygen, sulfur, nitrogen, C1-3 alkylated nitrogen, protonated nitrogen, and halogenated nitrogen; or (c) a fused C4-10 aryl, alkylaryl where the alkyl portion is C1-3 and the aryl portion is C4-10, haloalkylaryl where the haloalkyl portion is C1-3, and the aryl portion is C4-10, or C4-10 haloaryl radical; wherein R' and R" are the same or different and are selected from the group consisting of hydrogen, halogen, C1-8 alkyl, C1-8 haloalkyl, alkoxyalkyl where the alkoxy portion is C1-3 and the alkyl portion is C1-8, haloalkoxyalkyl where the haloalkoxy portion is C1-3 and the alkyl portion is C1-8, haloalkoxyhaloalkyl where the haloalkoxy portion is C1-3 and the haloalkyl portion is C1-8, C4-10 aryl, C4-10 haloaryl, alkylaryl where the alkyl portion is C1-8 and the aryl portion is C4-10, alkoxyaryl where the alkoxy portion is C1-3 and the aryl portion is C4-10, alkoxyalkylaryl where the alkoxy and alkyl portions each are C1-3 and the aryl portion is C4-10, C4-10 heteroaryl in which the heteroatom is oxygen, nitrogen or sulfur or taken together with the nitrogen group form a saturated cyclic ring having 2-10 carbon ring members and 0-2 heteroatoms selected from the group consisting of oxygen, nitrogen, sulfur, and mixtures thereof; and further R' and R" together form an imidazole ring of the formula: having R4-6 which are the same or different than R1-3 on the other ring and are selected from the group consisting of hydrogen, halogen, C1-8 alkyl, C1-8 haloalkyl, alkoxyalkyl where the alkoxy portion is C1-3 and the alkyl portion is C1-8, haloalkoxyalkyl where the haloalkoxy portion is C1-3 and the alkyl portion is C1-8, haloalkoxyhaloalkyl where the haloalkoxy portion is C1-3 and the haloalkyl portion is C1-8, C4-10 aryl, C4-10 haloaryl, alkylaryl where the alkyl portion is C1-8 and the aryl portion is C4-10, alkoxyaryl where the alkoxy portion is C1-3 and the aryl portion is C4-10, alkoxyalkylaryl where the alkoxy and alkyl portions each are C1-3 and the aryl portion is C4-10, C4-10 heteroaryl in which the heteroatom is oxygen, nitrogen or sulfur, cyano, nitro, amino, sulfonic acid, sulfonic methyl ester, a C4-8 saturated cyclic hydrocarbon having 1-3 heteroatoms selected from the group consisting of oxygen, nitrogen, sulfur, and mixtures thereof; and further R5-6 together form: (a) a cyclic ring having 2-10 carbon ring members and 1 heteroatom selected from the group consisting of oxygen, sulfur, nitrogen, C1-3 alkylated nitrogen, protonated nitrogen, and halogenated nitrogen; or (b) an unsaturated cyclic ring with 2 to 4 carbon atoms and 0-3 heteroatoms selected from the group consisting of oxygen, sulfur, nitrogen, C1-3 alkylated nitrogen, protonated nitrogen, and halogenated nitrogen; or (c) a f

37. 发明专利

GB1256085A POLYHALOALCOHOLS AND THEIR USE AS FLAME RETARDANTS IN POLYMER COMPOSITIONS 未知
公开(公告)号：GB1256085A
公开(公告)日：1971-12-08
申请号：GB5443268
申请日：1968-11-15
申请人： COLUMBIAN CARBON
IPC分类号： C07C23/16 , C07C31/34 , C07C35/02 , C08K5/05 , C08L77/00
摘要： 1,256,085. Lubricants. COLUMBIAN CARBON CO. 15 Nov., 1968 [29 Dec., 1967], No. 54432/68. Heading C5F. [Also in Divisions C2 and C3] Flame-retardant liquid polyester extreme pressure lubricants are obtained from alcohols of the formula Br a R(OH) b and alkylene oxide addition products thereof, R being a saturated cycloaliphatic hydrocarbon group containing a 5-16 membered carbocyclic ring, a is an integer of 2-6, b is an integer of 2-4, the ratio a :b is at least 1:1 and the sum a + b is 4, 6 or 8, no carbon atom bears more than one hetero substituent, each hydroxy group is on a carbon atom adjacent a brominated carbon atom, and each brominated carbon atom is adjacent a brominated or hydroxy substituted carbon atom.

38. 发明专利

DE1804804A1 未知
公开(公告)号：DE1804804A1
公开(公告)日：1969-07-10
申请号：DE1804804
申请日：1968-10-24
申请人： COLUMBIAN CARBON
发明人： M KERSCHNER PAUL
IPC分类号： C07C23/16 , C07C31/34 , C07C35/02 , C08K5/05 , C08L77/00

39. 发明授权

US2784240A Cyclooctatetraene derivatives 失效
标题翻译：环辛四烯衍生物
公开(公告)号：US2784240A
公开(公告)日：1957-03-05
申请号：US32825552
申请日：1952-12-27
申请人： MERCK & CO INC
发明人： COPE ARTHUR C , MARION BURG
IPC分类号： C07C17/23 , C07C23/16
CPC分类号： C07C23/16 , C07C17/23

40. 发明授权

US2626961A 1, 2, 5, 6-tetrachloro-1, 5-cyclooctadiene 失效
标题翻译： 1，2，5，6-四氯-1,5-环辛二烯
公开(公告)号：US2626961A
公开(公告)日：1953-01-27
申请号：US8438849
申请日：1949-03-30
申请人： FIRESTONE TIRE & RUBBER CO
发明人： EBERLY KENNETH C , REID ROBERT J
IPC分类号： C07C1/26 , C07C13/54 , C07C17/25 , C07C17/281 , C07C17/30 , C07C23/10 , C07C23/16 , C07C23/38 , C07C25/28
CPC分类号： C07C1/26 , C07C13/54 , C07C17/25 , C07C17/281 , C07C17/30 , C07C23/10 , C07C23/16 , C07C23/38 , C07C25/28 , C07C2601/14 , C07C2601/18 , C07C2603/00 , C07C13/00

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