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31. 发明申请

US20140303374A1 METHOD FOR PRODUCING COMPOUND WITH CARBONYL GROUP BY USING RUTHENIUM CARBONYL COMPLEX HAVING TRIDENTATE LIGAND AS DEHYDROGENATION OXIDATION CATALYST 有权
标题翻译：通过使用具有三氯甲烷配位体的碳酸氢钠复合物作为脱氢氧化催化剂生产碳化合物的方法
公开(公告)号：US20140303374A1
公开(公告)日：2014-10-09
申请号：US14113326
申请日：2012-04-18
申请人： Taichiro Touge , Kunimori Aoki , Hideki Nara , Wataru Kuriyama
发明人： Taichiro Touge , Kunimori Aoki , Hideki Nara , Wataru Kuriyama
IPC分类号： C07D453/02 , B01J31/22 , C07C51/265 , C07C51/29 , C07C51/235 , C07C51/255
CPC分类号： B01J31/2295 , B01J31/189 , B01J31/20 , B01J2231/763 , B01J2531/0238 , B01J2531/821 , C07B33/00 , C07C45/29 , C07C51/235 , C07C51/255 , C07C51/265 , C07C51/29 , C07C67/40 , C07D453/02 , C07F15/0046 , C07F17/02 , C07C69/24 , C07C69/78 , C07C47/02 , C07C47/228 , C07C47/238 , C07C47/54 , C07C49/403 , C07C49/413 , C07C49/603 , C07C49/78 , C07C49/786
摘要： Provided by the present invention is a method for efficient oxidation of alcohols by using, as a catalyst for dehydrogenation oxidation, a ruthenium complex which can be easily produced and easily handled and is obtainable at a relatively low cost. The invention relates to a method of producing a compound having a carbonyl group by dehydrogenation oxidation of alcohols by using as a catalyst the ruthenium carbonyl complex represented by the following general formula (1) RuXY(CO)(L) (1) (in the general formula (1), X and Y may be the same or different from each other and represent an anionic ligand, and L represents a tridentate aminodiphosphine ligand).
摘要翻译：通过本发明提供的是通过使用可以容易地制备和容易处理的钌络合物作为脱氢氧化催化剂来有效地氧化醇的方法，并且可以以相对低的成本获得。本发明涉及通过使用由以下通式（1）RuXY（CO）（L）（1）表示的钌羰基络合物作为催化剂，通过醇的脱氢氧化制备具有羰基的化合物的方法（在通式（1）中，X和Y可以相同或不同，表示阴离子配体，L表示三齿氨基二膦配体）。

32. 发明申请

US20130158276A1 RUTHENIUM-DIAMINE COMPLEXES AND METHOD FOR PRODUCING OPTICALLY ACTIVE COMPOUNDS 有权
标题翻译：十二烷基二胺复合物和生产光学活性化合物的方法
公开(公告)号：US20130158276A1
公开(公告)日：2013-06-20
申请号：US13819188
申请日：2011-06-17
申请人： Taichiro Touge , Hideki Nara , Tomohiko Hakamada
发明人： Taichiro Touge , Hideki Nara , Tomohiko Hakamada
IPC分类号： C07F15/00 , C07C29/143 , C07C209/52 , C07C253/30 , C07D311/22 , C07F19/00 , C07D307/42
CPC分类号： B01J31/1805 , B01J31/2295 , B01J2231/326 , B01J2231/643 , B01J2231/646 , B01J2531/0208 , B01J2531/821 , B01J2540/32 , C07C29/143 , C07C209/52 , C07C253/30 , C07D307/42 , C07D311/22 , C07F15/0046 , C07F19/00 , H01L2924/0002 , H01L2924/00
摘要： Provided is a catalyst for asymmetric reduction, which can be produced by a convenient and safe production method, has a strong catalytic activity, and has excellent stereoselectivity. The present invention relates to a ruthenium complex represented by the following formula (1): wherein R1 represents an alkyl group or the like; Y represents a hydrogen atom; X represents a halogen atom or the like; j and k each represent 0 or 1; R2 and R3 each represent an alkyl group or the like; R11 to R19 each represent a hydrogen atom, an alkyl group or the like; Z represents oxygen or sulfur; n1 represents 1 or 2; and n2 represents an integer from 1 to 3, a method for producing the ruthenium complex, a catalyst for asymmetric reduction formed from the ruthenium complex, and methods for selectively producing an optically active alcohol and an optically active amine using the catalyst for asymmetric reduction.
摘要翻译：提供了一种不对称还原的催化剂，其可以通过方便和安全的制备方法制备，具有很强的催化活性，并且具有优异的立体选择性。本发明涉及由下式（1）表示的钌络合物：其中R1表示烷基等; Y表示氢原子; X表示卤素原子等; j和k各自表示0或1; R2和R3各自表示烷基等; R 11〜R 19各自表示氢原子，烷基等; Z表示氧或硫; n1表示1或2; n2表示1〜3的整数，钌络合物的制造方法，由钌络合物形成的不对称还原用催化剂，以及使用不对称还原用催化剂选择性地制造光学活性醇和光学活性胺的方法。

33. 发明申请

US20100113814A1 METHOD FOR PRODUCING RUTHENIUM COMPLEX 有权
标题翻译：生产金属复合材料的方法
公开(公告)号：US20100113814A1
公开(公告)日：2010-05-06
申请号：US12609163
申请日：2009-10-30
申请人： Taichiro Touge , Hideki Nara
发明人： Taichiro Touge , Hideki Nara
IPC分类号： C07F17/02
CPC分类号： C07F15/0046
摘要： The present invention provides a novel method for simply and efficiently producing a ruthenium aromatic complex which is suitable also as an industrial production method.The production method includes reacting a ruthenium aromatic complex with an aromatic compound, whose boiling point is lower than that of an aromatic compound as a ligand of the ruthenium aromatic complex, in a sealed reaction container at a reaction temperature higher than the boiling point of the aromatic compound to produce a ruthenium aromatic complex having, as a ligand, an aromatic compound having a lower boiling point.
摘要翻译：本发明提供了一种简单有效地制备钌芳香族络合物的新方法，其也适合工业生产方法。该制造方法包括使钌芳香族络合物与芳香族化合物的沸点低于作为钌芳香族配合物的配体的芳香族化合物的反应温度在密闭的反应容器中反应，反应温度高于芳族化合物以制备具有低沸点芳族化合物作为配体的钌芳香族络合物。

34. 发明申请

US20100036149A1 METHOD FOR PRODUCING AN OPTICALLY ACTIVE TETRAHYDROQUINOLINE 有权
标题翻译：生产光学活性四氢喹啉的方法
公开(公告)号：US20100036149A1
公开(公告)日：2010-02-11
申请号：US12550948
申请日：2009-08-31
申请人： Takashi Moroi , Tsukasa Sotoguchi , Kazuhiko Matsumura , Motonobu Takenaka , Wataru Kuriyama , Toshiyuki Murayama , Hideki Nara , Tohru Yokozawa , Kenji Yagi
发明人： Takashi Moroi , Tsukasa Sotoguchi , Kazuhiko Matsumura , Motonobu Takenaka , Wataru Kuriyama , Toshiyuki Murayama , Hideki Nara , Tohru Yokozawa , Kenji Yagi
IPC分类号： C07C227/16
CPC分类号： C07C229/18 , C07C211/49 , C07C229/30 , C07D215/42
摘要： The present invention provides an industrially advantageous production method of optically active tetrahydroquinolines of formula (1), which comprises: 1) a step of reacting a β-ketoester of formula (2) with an amine of formula (3) to produce an enaminoester of formula (4); 2) a step of subjecting the enaminoester of formula (4) above obtained in 1) to asymmetric hydrogenation to produce an optically active β-amino acid derivative of formula (5); 3) a step of amidating the optically active β-amino acid derivative (5) above obtained in 2) to produce an amide of formula (6); 4) a step of alkoxycarbonylating the amide of formula (6) above obtained in 3) to produce a compound of formula (7); and 5) a step of subjecting the compound of formula (7) above to cyclization to produce the optically active tetrahydroquinoline of formula (1).
摘要翻译：本发明提供了一种工业上有利的式（1）的光学活性四氢喹啉的制备方法，其包括：1）使式（2）的β-酮酯与式（3）的胺反应以产生一种公式（4）; 2）使在1）中获得的上述式（4）的烯氨基酯进行不对称氢化以产生式（5）的光学活性β-氨基酸衍生物的步骤; 3）将2）中得到的光学活性β-氨基酸衍生物（5）酰胺化以制备式（6）的酰胺的步骤; 4）在3）中得到的上述式（6）的酰胺进行烷氧基羰基化以制备式（7）化合物的步骤; 和5）使上述式（7）化合物环化以制备式（1）的光学活性四氢喹啉的步骤。

35. 发明授权

US06365755B1 Ammonium 3,5,6-trihydroxyhexanoate derivatives and preparation process thereof 有权
标题翻译：铵3,5,6-三羟基己酸铵衍生物及其制备方法
公开(公告)号：US06365755B1
公开(公告)日：2002-04-02
申请号：US09930263
申请日：2001-08-16
申请人： Kenzo Sumi , Toshiyuki Murayama , Yoshiharu Gonda , Hideki Nara , Takashi Moroi
发明人： Kenzo Sumi , Toshiyuki Murayama , Yoshiharu Gonda , Hideki Nara , Takashi Moroi
IPC分类号： C07D31906
CPC分类号： C07D319/06
摘要： Provided are a novel ammonium (3R,5S)-3,5,6-trihydroxyhexanoate derivative represented by the following formula (I): wherein R1 represents a benzyl group which may have a substituent, a triphenylmethyl group which may have a substituent, an organosilyl group or a C1-5 acyl group; and A means a specific amine; and a preparation process of the derivative.
摘要翻译：提供由下式（I）表示的新型铵（3R，5S）-3,5,6-三羟基己酸衍生物：其中R1表示可具有取代基的苄基，可具有取代基的三苯基甲基，有机甲硅烷基或C 1-5酰基; A表示特定的胺; 和衍生物的制备过程。

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