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    • 36. 发明授权
    • Heterogeneous polymerization catalyst, process for producing acrylic polymer, and acrylic polymer
    • 非均相聚合催化剂,丙烯酸聚合物的制备方法和丙烯酸聚合物
    • US06683146B2
    • 2004-01-27
    • US10293326
    • 2002-11-14
    • Yoshihiro InabaSatoshi Hiraoka
    • Yoshihiro InabaSatoshi Hiraoka
    • C08F11802
    • C08F20/12C08F4/40
    • A process for producing an acrylic polymer capable of providing a polymer controlled in molecular weight and free of colorization, and a heterogeneous polymerization catalyst used in the process for producing an acrylic polymer are provided. The heterogeneous polymerization catalyst contains (A) a radical generating substance, (B) a metallic halide containing a metallic element selected from the group consisting of the Group 4 to Group 12 elements and a halogen element selected from the group consisting of chlorine, bromine and iodine, and (C) a carrier carrying a ligand capable of forming a coordination bond with the metallic halide (B). The process for producing an acrylic polymer contains a step of polymerizing a monomer containing at least an acrylate and/or a methacrylate in the presence of the heterogeneous polymerization catalyst.
    • 提供了能够提供控制分子量且不着色的聚合物的丙烯酸类聚合物的制备方法,以及用于制备丙烯酸类聚合物的方法中使用的非均相聚合催化剂。 非均相聚合催化剂含有(A)自由基产生物质,(B)含有选自第4族至第12族元素的金属元素的金属卤化物和选自氯,溴和 碘,和(C)携带能够与金属卤化物(B)形成配位键的配体的载体。 制备丙烯酸类聚合物的方法包括在非均相聚合催化剂的存在下聚合至少含有丙烯酸酯和/或甲基丙烯酸酯的单体的步骤。
    • 37. 发明授权
    • Capsule toner
    • 胶囊墨粉
    • US5334480A
    • 1994-08-02
    • US991360
    • 1992-12-15
    • Yoshihiro InabaKoichi TakashimaIzuru MatsuiTsutomu Kubo
    • Yoshihiro InabaKoichi TakashimaIzuru MatsuiTsutomu Kubo
    • G03G9/08G03G9/093
    • G03G9/09321G03G9/09342G03G9/09328
    • A capsule toner comprising a core covered with an outer shell, the outer shell comprising a substance capable of forming a radical, a polymer comprising at least a unit derived from a quaternary ammonium salt-containing vinyl monomer represented by formula (I) being deposited on the surface of the outer shell, and basic carbon black being externally added to the capsule toner: ##STR1## wherein R.sub.1 represents a hydrogen atom or a methyl group; R.sub.2, R.sub.3, and R.sub.4 each represents a hydrogen atom, an alkyl group having 1 to 5 carbon atoms or a benzyl group; Y represents --COO--, --CONH-- or a phenylene group; n represents an integer of from 1 to 7; and X.sup.- represents a halogen ion or an anion having a --COO.sup.- group or an --SO.sub.3.sup.- group.
    • 一种胶囊调色剂,其包含覆盖有外壳的芯,所述外壳包含能够形成自由基的物质,至少包含衍生自由式(I)表示的含季铵盐的乙烯基单体的单元的聚合物,其沉积在 外壳的表面和外部添加到胶囊调色剂中的碱性炭黑:其中R1表示氢原子或甲基;(I)其中R1表示氢原子或甲基; R 2,R 3和R 4各自表示氢原子,碳原子数1〜5的烷基或苄基。 Y表示-COO - , - CONH-或亚苯基; n表示1〜7的整数, X表示卤素离子或具有-COO-基团或-SO 3 - 基团的阴离子。