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31. 发明授权

US5728318A Liquid crystal composition, liquid crystal device and liquid crystal display apparatus 失效
标题翻译：液晶组合物，液晶装置和液晶显示装置
公开(公告)号：US5728318A
公开(公告)日：1998-03-17
申请号：US555063
申请日：1995-11-08
申请人： Masataka Yamashita , Kazuharu Katagiri , Masahiro Terada , Shosei Mori , Syuji Yamada , Hiroshi Mizuno
发明人： Masataka Yamashita , Kazuharu Katagiri , Masahiro Terada , Shosei Mori , Syuji Yamada , Hiroshi Mizuno
IPC分类号： C09K19/34 , C09K19/46 , C09K19/12 , C09K19/32 , G02F1/133
CPC分类号： C09K19/46 , C09K19/34
摘要： A liquid crystal composition is composed of at least three types of mesomorphic compounds. The liquid crystal composition may preferably contain a mesomorphic compound having an indan skeleton represented by the formula (1) or (3) and a mesomorphic compound having a terminal cyclic group represented by the formula (2) or (4). The liquid crystal composition may also preferably further contain an optically active compound to be formulated as a chiral smectic (or ferroelectric) liquid crystal composition. When the chiral smectic liquid crystal composition is disposed between a pair of electrode substrates provided with uniaxial alignment axes, the liquid crystal composition may preferably be placed in an alignment state in C1 uniform alignment, so that a resultant liquid crystal device provides a higher contrast ratio and a wider drive voltage margin.
摘要翻译：液晶组合物由至少三种类型的介晶化合物组成。液晶组合物可以优选含有具有由式（1）或（3）表示的茚满骨架的介晶化合物和具有由式（2）或（4）表示的末端环状基团的介晶化合物。液晶组合物还优选还含有配制成手性近晶（或铁电体）液晶组合物的光学活性化合物。当手性近晶液晶组合物配置在具有单轴取向轴的一对电极基板之间时，液晶组合物优选地可以以C1均匀取向放置在取向状态，使得所得到的液晶装置提供更高的对比度和更宽的驱动电压裕度。

32. 发明授权

US5582763A Liquid crystal composition, liquid crystal device and liquid crystal apparatus using same 失效
标题翻译：液晶组合物，液晶装置和使用其的液晶装置
公开(公告)号：US5582763A
公开(公告)日：1996-12-10
申请号：US314422
申请日：1994-09-28
申请人： Syuji Yamada , Masahiro Terada , Hiroshi Mizuno
发明人： Syuji Yamada , Masahiro Terada , Hiroshi Mizuno
IPC分类号： C09K19/02 , C09K19/32 , C09K19/34 , C09K19/52 , C09K19/30 , G02F1/13
CPC分类号： C09K19/3452 , C09K19/0225 , C09K19/32
摘要： A liquid crystal device with little temperature-dependence of drive characteristics, such as response speed, and with good storage stability, can be produced by using a liquid crystal composition, successively assuming SmA (smectic A) phase and SmC* (chiral smectic) phase on temperature decrease. The layer spacing composition has a temperature-dependence of layer spacing d in smectic phase such that the layer spacing d increases, is constant or decreases on temperature decrease in SmA phase temperature range, assumes a first transition point where the layer spacing d abruptly decreases on temperature decrease in vicinity of transition temperature from SmA phase to SmC* phase, and assumes a second transition point where the layer spacing d commences to increase on further temperature decrease below the first transition point in SmC* temperature range.
摘要翻译：可以通过使用液晶组合物，连续地假设SmA（近晶A）相和SmC *（手性近晶）相，可以产生对响应速度等驱动特性，具有良好的储存稳定性的驱动特性温度依赖性低的液晶装置温度下降。层间距组合物在层间相中具有层间距d的温度依赖性，使得层间距d增加，在SmA相温度范围内的温度降低时恒定或降低，假设层间距d突然降低的第一转变点在SmA相的转变温度附近温度降低到SmC *相，并且假定在SmC *温度范围内的第一转变点以后的温度降低的层间距d开始增加的第二转变点。

33. 发明授权

US5573703A Ferroelectric liquid crystal device and liquid crystal apparatus using it 失效
标题翻译：铁电液晶装置及其使用的液晶装置
公开(公告)号：US5573703A
公开(公告)日：1996-11-12
申请号：US320525
申请日：1994-10-11
申请人： Masahiro Terada , Shosei Mori , Masataka Yamashita
发明人： Masahiro Terada , Shosei Mori , Masataka Yamashita
IPC分类号： G02F1/1337 , C09K19/02 , C09K19/34 , G02F1/141 , C09K19/52 , C09K19/20 , G02F1/15
CPC分类号： C09K19/0225 , C09K19/34 , G02F1/1416
摘要： A ferroelectric liquid crystal device comprises:a pair of substrates comprising electrodes for applying a voltage, the pair of substrates having been subjected to a uniaxial orientation treatment, and being oriented at a distance opposite to each other such that the uniaxial orientation axes cross each other at a predetermined angle; the display device further comprising a liquid crystal material disposed between the exhibiting at least two stable states and pair of substrates, the liquid crystal material having a cone angle, a pretilt angle, a tilt angle and an apparent tilt angle, wherein:the liquid crystal material having an orientation state which satisfies the conditions represented by.THETA. .THETA..sub..alpha. >.THETA./2 in which .THETA. denotes the cone angle, .alpha. denotes the pretilt angle, .delta. denotes the tilt angle and .THETA..sub..alpha. denotes the apparent tilt angle,wherein the phase of the liquid crystal changes from isotropic phase via cholesteric phase and smectic A phase to chiral smectic C phase as the liquid crystal cools from a high temperature and the liquid crystal has a temperature range in which the cholesteric phase and the smectic A phase exist at the same time.
摘要翻译：铁电液晶装置包括：一对基板，包括用于施加电压的电极，所述一对基板经过单轴取向处理，并且以彼此相对的距离取向，使得单轴取向轴彼此交叉以预定角度; 所述显示装置还包括设置在显示至少两个稳定状态和一对基板之间的液晶材料，所述液晶材料具有锥角，预倾角，倾斜角和视在倾斜角，其中：所述液晶具有满足由THETA表示锥形角度的THETA <α+δ，Δα和THETA> THETAα> THETA / 2表示的条件的取向状态的材料α表示预倾角，delta表示倾斜角， THETAα表示视在倾斜角，其中当液晶从高温冷却时，液晶的相位从各向同性相通过胆甾醇相和近晶A相变为手性近晶C相，液晶的温度范围为胆甾醇相和近晶A相同时存在。

34. 发明授权

US5542982A Method of removing coating films 失效
标题翻译：去除涂膜的方法
公开(公告)号：US5542982A
公开(公告)日：1996-08-06
申请号：US383675
申请日：1995-02-01
申请人： Masahiro Terada , Hirosuke Kamae , Motoyasu Yusawa , Kazuyuki Watanabe , Mitsuo Saito
发明人： Masahiro Terada , Hirosuke Kamae , Motoyasu Yusawa , Kazuyuki Watanabe , Mitsuo Saito
IPC分类号： C08J7/00 , B29B17/02 , C08J7/02 , C08J11/06 , C09D9/00 , B08B3/08 , B08B3/10 , B08B7/00
CPC分类号： C08J11/06 , B29B17/02 , B29B2017/0296 , B29B2017/0492 , B29K2023/00 , B29K2033/04 , B29K2075/00 , B29L2009/005 , B29L2031/3044 , B29L2031/3055 , Y02P20/582 , Y02W30/622 , Y02W30/625 , Y02W30/701
摘要： Improved methods of removing coating films from resin substrates includes first treating the resin substrates in an aqueous alkali solution with a concentration of 0.1 wt % or more at a temperature of 110.degree. C. or more, which temperature is lower than the melting point of the substrates and then polishing the surfaces of the substrates by either bringing them into contact with each other in suitable equipment such as a screw feeder, or using an abrasive in suitable equipment such as a high-speed vessel type stirrer, or subjecting the substrates to a liquid honing process.
摘要翻译：从树脂基板上除去涂膜的改进方法包括首先在110℃或更高的温度下在浓度为0.1重量％或更高的碱性水溶液中处理树脂基材，该温度低于然后通过在合适的设备例如螺旋进料器中使它们彼此接触，或者在合适的设备例如高速容器式搅拌器中使用研磨剂，或者使基板进行液体珩磨过程。

35. 发明授权

US5514297A Ferroelectric chiral smectic liquid crystal composition and liquid crystal device using same 失效
标题翻译：铁电手性近晶液晶组合物和使用其的液晶装置
公开(公告)号：US5514297A
公开(公告)日：1996-05-07
申请号：US76927
申请日：1993-06-16
申请人： Kenji Shinjo , Takao Takiguchi , Hiroyuki Kitayama , Kazuharu Katagiri , Masahiro Terada , Takeshi Togano , Masataka Yamashita , Masanobu Asaoka
发明人： Kenji Shinjo , Takao Takiguchi , Hiroyuki Kitayama , Kazuharu Katagiri , Masahiro Terada , Takeshi Togano , Masataka Yamashita , Masanobu Asaoka
IPC分类号： C07D271/10 , C07D285/12 , C09K19/34 , C09K19/42 , C09K19/46 , C09K19/06 , C09K19/12 , G02F1/13
CPC分类号： C07D271/10 , C07D285/12 , C09K19/345 , C09K19/3455 , C09K19/3463 , C09K19/348 , C09K19/3497 , C09K19/42 , C09K19/46
摘要： A ferroelectric chiral smectic liquid crystal composition, comprising at least one compound represented by the following formula (I): ##STR1## wherein R.sub.1 and R.sub.2 respectively denote a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent; X.sub.1 and X.sub.2 respectively denote a single bond, ##STR2## Y.sub.1 denotes --CH.sub.2 O-- or --OCH.sub.2 ; and m and n are respectively 1 or 2; and at least one compound represented by the following formula (II): ##STR3## wherein R.sub.3 and R.sub.4 respectively denote a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent, at least one of R.sub.3 and R.sub.4 being optically active; and; X.sub.3 and X.sub.4 respectively denote a single bond, ##STR4##
摘要翻译：一种铁电手性近晶液晶组合物，其包含至少一种由下式（I）表示的化合物：其中R 1和R 2分别表示具有1-18个碳原子的直链或支链烷基，其能够具有取代基; X1和X2分别表示单键，Y1表示-CH2O-或-OCH2; m和n分别为1或2; 和由下式（II）表示的至少一种化合物：其中R 3和R 4分别表示可具有取代基的具有1-18个碳原子的直链或支链烷基，R 3和 R4是光学活性的; 和; X3和X4分别表示单键，

36. 发明授权

US5413735A Liquid crystal composition, liquid crystal device using the liquid crystal composition, and display method and apparatus using the liquid crystal composition and device 失效
标题翻译：液晶组合物，使用液晶组合物的液晶装置以及使用该液晶组合物和装置的显示方法和装置
公开(公告)号：US5413735A
公开(公告)日：1995-05-09
申请号：US130427
申请日：1993-10-01
申请人： Masataka Yamashita , Masahiro Terada , Shousei Mori , Kazuharu Katagiri
发明人： Masataka Yamashita , Masahiro Terada , Shousei Mori , Kazuharu Katagiri
IPC分类号： C09K19/34 , C09K19/42 , C09K19/44 , C09K19/46 , G02F1/13 , C09K19/12
CPC分类号： C09K19/34 , C09K19/42 , C09K19/44 , C09K19/46
摘要： A liquid crystal composition comprises at least one type of liquid crystal compound having the following general formula (I) and at least one type of liquid crystal compound having the following general formula (II): ##STR1## wherein R.sub.1 and R.sub.2 each is a straight-chain or branched-chain alkyl group having 1 to 18 carbon atoms. These alkyl groups may have alkoxy groups having 1 to 12 carbon atoms as substituents. Both R.sub.1 and R.sub.2 are optically inactive. Z.sub.1 is a single bond, --O--, ##STR2## wherein R.sub.3 and R.sub.4 each is a straight-chain or branched-chain alkyl group having 1 to 18 carbon atoms. Z.sub.2 and Z.sub.3 each is single bond, ##STR3## A.sub.1 is --A.sub.2 -- or --A.sub.2 --A.sub.3 --, wherein A.sub.2 and A.sub.3 are ##STR4##
摘要翻译：液晶组合物包含至少一种具有以下通式（I）的液晶化合物和至少一种具有以下通式（II）的液晶化合物：其中R 1和R 2各自是具有1至18个碳原子的直链或支链烷基。这些烷基可以具有1〜12个碳原子的烷氧基作为取代基。 R1和R2都是光学无活性的。 Z1是具有1至18个碳原子的单键，-O-，高链或支链烷基。 Z2和Z3各自是单键，A3是

37. 发明授权

US5409636A Ferroelectric chiral smectic liquid crystal composition and liquid crystal device using same 失效
标题翻译：铁电手性近晶液晶组合物和使用其的液晶装置
公开(公告)号：US5409636A
公开(公告)日：1995-04-25
申请号：US130428
申请日：1993-10-01
申请人： Kenji Shinjo , Takao Takiguchi , Hiroyuki Kitayama , Kazuharu Katagiri , Masataka Yamashita , Takeshi Togano , Masahiro Terada , Junko Sato
发明人： Kenji Shinjo , Takao Takiguchi , Hiroyuki Kitayama , Kazuharu Katagiri , Masataka Yamashita , Takeshi Togano , Masahiro Terada , Junko Sato
IPC分类号： C07D271/10 , C07D285/12 , C09K19/34 , C09K19/42 , C09K19/46 , G02F1/13
CPC分类号： C07D271/10 , C07D285/12 , C09K19/345 , C09K19/3455 , C09K19/3463 , C09K19/348 , C09K19/3497 , C09K19/42 , C09K19/46
摘要： A ferroelectric chiral smectic liquid crystal composition, comprising at least one compound represented by the following formula (I): ##STR1## wherein R.sub.1 denotes a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent, R.sub.2 denotes a linear or branched alkyl group having 1-14 carbon atoms capable of having a substituent; X.sub.1 and X.sub.2 respectively denote a single bond, --O--, ##STR2## m is 0-7; and n is 0 or 1; and at least one compound represented by the following formula (II): ##STR3## wherein R.sub.3 denotes a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent; R.sub.4 denotes a linear alkyl group having 1-10 carbon atoms; X.sub.3 denotes a single bond, --O--, ##STR4## Y denotes ##STR5## --CH.sub.2 O-- or --OCH.sub.2 --; and ##STR6## respectively denote ##STR7##
摘要翻译：一种铁电手性近晶液晶组合物，其包含至少一种由下式（I）表示的化合物：其中R 1表示具有1-18个能够具有取代基的碳原子的直链或支链烷基，R2 表示具有能够具有取代基的具有1-14个碳原子的直链或支链烷基; X1和X2分别表示单键-O-，M为0-7; 并且n为0或1; 和由下式（II）表示的至少一种化合物：其中R 3表示可具有取代基的具有1-18个碳原子的直链或支链烷基; R4表示具有1-10个碳原子的直链烷基; X 3表示单键-O-，Y表示-CH 2 O-或-OCH 2 - ; 和分别表示

38. 发明授权

US5186858A Ferroelectric chiral smectic liquid crystal composition and liquid crystal device using same 失效
标题翻译：铁电手性近晶液晶组合物和使用其的液晶装置
公开(公告)号：US5186858A
公开(公告)日：1993-02-16
申请号：US378922
申请日：1989-07-12
申请人： Masahiro Terada , Takeshi Togano , Masataka Yamashita , Kazuharu Katagiri , Takao Takiguchi , Kenji Shinjo , Hiroyuki Kitayama , Shinichi Nakamura
发明人： Masahiro Terada , Takeshi Togano , Masataka Yamashita , Kazuharu Katagiri , Takao Takiguchi , Kenji Shinjo , Hiroyuki Kitayama , Shinichi Nakamura
IPC分类号： C09K19/30 , C09K19/34 , C09K19/42
CPC分类号： C09K19/3066 , C09K19/3458 , C09K19/42
摘要： A ferroelectric chiral smectic liquid crystal composition, comprising at least one compound represented by the following formula (I): ##STR1## wherein, R.sub.1 denotes a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent; R.sub.2 denotes a linear alkyl group having 1-12 carbon atoms; X.sub.1 denote a single bond, --O--, ##STR2## respectively denote ##STR3## and at least one compound represented by the following formula (II): ##STR4## wherein R.sub.3 and R.sub.4 respectively denote a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent; X.sub.2 and X.sub.3 respectively denote a single bond, --O--, ##STR5## and m and n are respectively 0, 1 or 2 with proviso that m+n is 2 or above.
摘要翻译：一种铁电手性近晶液晶组合物，其包含至少一种由下式（I）表示的化合物：其中，R 1表示可具有取代基的具有1-18个碳原子的直链或支链烷基; R2表示具有1-12个碳原子的直链烷基; X1表示单键，-O-，分别表示和至少一种由下式（II）表示的化合物：其中R 3和R 4分别表示直链或具有1-18个能够具有取代基的碳原子的支链烷基; X2和X3分别表示单键，-O-，，m和n分别为0,1或2，条件是m + n为2或更高。

39. 发明授权

US5139697A Liquid crystal composition and liquid crystal device using same 失效
标题翻译：液晶组合物和使用其的液晶装置
公开(公告)号：US5139697A
公开(公告)日：1992-08-18
申请号：US711566
申请日：1991-05-30
申请人： Takeshi Togano , Masahiro Terada , Masataka Yamashita , Shosei Mori , Takashi Iwaki
发明人： Takeshi Togano , Masahiro Terada , Masataka Yamashita , Shosei Mori , Takashi Iwaki
IPC分类号： C09K19/46
CPC分类号： C09K19/46
摘要： A liquid crystal composition comprises at least one compound represented by the formula [I] below and at least one compound represented by the formula [II] below: ##STR1## wherein R.sub.1 denotes an alkyl group having 1-16 carbon atoms capable of having a substituent; R.sub.2 denotes any one of alkyl group, alkoxy group, alkoxycarbonyl group, acyloxy group and alkoxycarbonyloxy group, each having 1-16 carbon atoms and being capable of having a substituent; and A denotes any one of ##STR2## each capable of having a substituent; and ##STR3## wherein R.sub.3 denotes a linear alkyl group having 1-16 carbon atoms; R.sub.4 denotes a linear alkyl group having 1-12 carbon atoms; X.sub.1 is a single bond, --O--, ##STR4## X.sub.2 is --OCH.sub.2 --, ##STR5## or --CH.sub.2 --; and Z is ##STR6##
摘要翻译：液晶组合物包含至少一种由下式[I]表示的化合物和至少一种由下式[II]表示的化合物：其中R 1表示具有1-16个碳原子的烷基具有取代基; R2表示具有1-16个碳原子并能够具有取代基的烷基，烷氧基，烷氧基羰基，酰氧基和烷氧基羰基氧基中的任一个; A表示能够具有取代基的中的任一个; 和[II]其中R3表示具有1-16个碳原子的直链烷基; R4表示具有1-12个碳原子的直链烷基; X 1是单键，-O-，X 2是-OCH 2 - ，或-CH 2 - ; 而Z是

40. 发明申请

US20120330038A1 BIS-PHOSPHATE COMPOUND AND ASYMMETRIC REACTION USING THE SAME 失效
标题翻译：使用相同的双磷酸盐化合物和不对称反应
公开(公告)号：US20120330038A1
公开(公告)日：2012-12-27
申请号：US13583875
申请日：2011-03-08
申请人： Masahiro Terada , Norie Momiyama , Tohru Konno
发明人： Masahiro Terada , Norie Momiyama , Tohru Konno
IPC分类号： C07F9/6574 , C07D307/58 , C07C269/06
CPC分类号： C07B53/00 , C07C231/18 , C07C269/06 , C07C2601/16 , C07D307/58 , C07F9/65746 , C07C271/24 , C07C271/16 , C07C233/76
摘要： A novel bis-phosphate compound is provided which can be applied to a wide range of reactive substrates and reactions as an asymmetric reaction catalyst and can realize an asymmetric reaction affording a high yield and a high enantiomeric excess. The bis-phosphate compound has a tetraaryl skeleton represented by General Formula (1). In an asymmetric reaction, an amidodiene and an unsaturated aldehyde compound are reacted with each other in the presence of the optically active bis-phosphate compound to give an optically active amidoaldehyde. The invention allows a reaction such as an asymmetric Diels-Alder reaction to proceed efficiently, which has been difficult with conventional mono-phosphate compounds. Thus, the invention enables an industrially feasible method for the production of optically active amidoaldehydes, optically active β-amino acid derivatives, optically active diamine compounds, optically active pyrrolidine derivatives and optically active dihydropyran derivatives which are useful as products such as medicines, agricultural chemicals and chemical products as well as synthesis intermediates for such products.
摘要翻译：提供了一种新型的双磷酸化合物，其可以应用于广泛的反应性底物和作为不对称反应催化剂的反应，并且可以实现提供高产率和高对映异构体过量的不对称反应。双磷酸化合物具有由通式（1）表示的四芳基骨架。在不对称反应中，酰胺二烯和不饱和醛化合物在光学活性双磷酸酯化合物的存在下彼此反应，得到光学活性的酰胺醛。本发明允许诸如不对称Diels-Alder反应的反应有效地进行，这对于常规的单磷酸酯化合物是困难的。因此，本发明使得工业上可行的方法可用于生产光学活性酰胺醛，光学活性和聚氨基酸衍生物，光学活性二胺化合物，光学活性吡咯烷衍生物和光学活性二氢吡喃衍生物，其可用作药物，农业化学品和化学产品以及此类产品的合成中间体。

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