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    • 33. 发明申请
    • PHOTOREACTIVE EXO-RICH NORBORNENE POLYMER AND METHOD FOR PREPARING THE SAME
    • 光催化超高斯诺酮聚合物及其制备方法
    • US20100121005A1
    • 2010-05-13
    • US12450303
    • 2008-03-21
    • Heon KimSung-Ho ChunHye-Young JungDai-Seung ChoiKyoung-Hoon KimJong-Chan Kim
    • Heon KimSung-Ho ChunHye-Young JungDai-Seung ChoiKyoung-Hoon KimJong-Chan Kim
    • C08F132/08C08F4/00
    • C08F32/08C08F8/00
    • The present invention relates to a norbornene polymer that comprises a norbornene monomer having a photoreactive functional group, and a method of manufacturing the same. The norbornene polymer comprises at least 50 mol % of exo isomers among the norbornene monomers having the photoreactive functional group. Since the norbornene polymer according to the present invention comprises at least 50 mol % of exo isomers among the norbornene monomers having the photoreactive functional group, a molecular weight is significantly increased while the yield is not reduced during the manufacturing of the polymer. In views of the three dimensional structure, stability is ensured because the polymer has a planar structure in which the photoreactive groups between the molecules are close to each other. Therefore, the distance between the photoreactive groups is reduced, thus increasing the photoreaction rate.
    • 本发明涉及包含具有光反应性官能团的降冰片烯单体的降冰片烯聚合物及其制造方法。 降冰片烯聚合物包含具有光反应性官能团的降冰片烯单体中的至少50摩尔%的外来异构体。 由于根据本发明的降冰片烯聚合物在具有光反应性官能团的降冰片烯单体中包含至少50mol%的外部异构体,所以在聚合物的制造过程中分子量显着增加,而收率没有降低。 从三维结构的观点来看,确保了稳定性,因为聚合物具有其中分子之间的光反应基团彼此接近的平面结构。 因此,光反应基团之间的距离减小,从而增加光反应速率。