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    • 38. 发明授权
    • Polymetallic reforming catalysts and their preparation
    • 多金属重整催化剂及其制备
    • US4812435A
    • 1989-03-14
    • US157605
    • 1988-02-19
    • William C. Baird, Jr.
    • William C. Baird, Jr.
    • B01J23/46B01J23/656C10G35/09B01J21/04B01J27/13B01J27/132B01J27/135
    • B01J23/6567B01J23/468C10G35/09
    • A catalyst useful for reforming a naphtha feed at reforming conditions which comprises an iridium component dispersed throughout and bound within an alumina support matrix, a platinum component dispersed upon said iridium-containing alumina support, and halogen. In all of its aspects, the iridium component will remain in its dispersed state, without significant agglomeration, when subjected to temperature in the presence of oxygen for extended periods sufficient to agglomerate presently known halogenated platinum-iridium catalysts. This catalyst is prepared in an initial step by dispersing the iridium within the alumina matrix, and then calcining the iridium-containing alumina at high temperature to bind the iridium within the alumina support matrix. The platinum, or platinum and additional metal promoters, especially rhenium, is then impregnated upon the iridium-alumina support. This catalyst can be used in reforming at reforming conditions to provide high activity, high activity maintenance, high sulfur tolerance, low coke make and high C.sub.5 + liquid volume yield.
    • 一种可用于在重整条件下重整石脑油进料的催化剂,其包含分散在氧化铝载体基质内的结合的铱组分,分散在所述含铱氧化铝载体上的铂组分和卤素。 在其所有方面中,当在氧气存在下经受长时间的温度以足够聚集目前已知的卤化铂 - 铱催化剂时,铱组分将保持分散状态而没有显着的团聚。 该催化剂在初始步骤中通过将铱分散在氧化铝基体内,然后在高温下煅烧含铱氧化铝以将铱在氧化铝载体基质内结合来制备。 然后将铂或铂和另外的金属促进剂,特别是铼浸渍在铱 - 氧化铝载体上。 该催化剂可用于重整条件下的重整,以提供高活性,高活性维持性,高硫耐受性,低焦炭成分和高C5 +液体体积产率。