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31. 发明授权

US5889101A Preparation of emulsifier-free aqueous polymer emulsions 失效
标题翻译：制备无乳化剂的聚合物乳液
公开(公告)号：US5889101A
公开(公告)日：1999-03-30
申请号：US597134
申请日：1996-02-06
申请人： Bernhard Schlarb , Eberhard Schupp , Maria Gyopar Rau , Gunther Schulz , Harm Wiese
发明人： Bernhard Schlarb , Eberhard Schupp , Maria Gyopar Rau , Gunther Schulz , Harm Wiese
IPC分类号： C08F2/22 , C08F2/30 , C08F220/06 , C08F220/12 , C08F222/02 , C09D109/00 , C09D123/00 , C09D125/02 , C09D127/00 , C09D131/02 , C09D133/06 , C09D133/18 , D06M15/00
CPC分类号： C08F222/02 , C08F220/06
摘要： An aqueous polymer emulsion obtainable by free radical polymerization of monomers in aqueous emulsion in the presence of a polymeric protective colloid contains, as components,from 5 to 50% by weight of at least one ethylenically unsaturated monomer having at least one acid or acid anhydride group (monomers I),from 0.1 to 80% by weight of at least one (meth)acrylate of an aliphatic alcohol of at least 10 carbon atoms (monomers II),from 0 to 94.9% by weight of main monomers selected from the group consisting of C.sub.1 -C.sub.8 -alkyl (meth)acrylates, vinyl esters of carboxylic acids of up to 20 carbon atoms, vinyl aromatics of up to 20 carbon atoms, ethylenically unsaturated nitriles, vinyl halides and aliphatic hydrocarbons having 2 to 8 carbon atoms and 1 or 2 double bonds (monomers III) andfrom 0 to 60% by weight of further monomers (monomers IV),the stated weights being based on the polymeric protective colloid.
摘要翻译：通过在聚合物保护胶体存在下在水乳状液中单体的自由基聚合可获得的聚合物水乳液含有5至50重量％的至少一种具有至少一个酸或酸酐基团的烯属不饱和单体（单体I），0.1至80重量％的至少一种至少10个碳原子的脂族醇（单体II）的（甲基）丙烯酸酯，0至94.9重量％的主要单体，所述主要单体选自的（甲基）丙烯酸C 1 -C 8烷基酯，至多20个碳原子的羧酸的乙烯基酯，至多20个碳原子的乙烯基芳族化合物，烯键式不饱和腈，乙烯基卤化物和具有2至8个碳原子的脂族烃和1或 2双键（单体III）和0至60重量％的其它单体（单体IV），所述重量基于聚合物保护胶体。

32. 发明授权

US5739195A Process for preparing aqueous solutions of poly(N-vinyl-.epsilon.-caprolactam) and their use 失效
标题翻译：制备聚（N-乙烯基 - ε-己内酰胺）水溶液及其用途的方法
公开(公告)号：US5739195A
公开(公告)日：1998-04-14
申请号：US809363
申请日：1997-03-28
申请人： Jorg Kroker , Reinhard Schneider , Eberhard Schupp , Michael Kerber
发明人： Jorg Kroker , Reinhard Schneider , Eberhard Schupp , Michael Kerber
IPC分类号： A61K8/65 , A61K8/73 , A61K8/81 , A61K8/86 , A61K47/32 , A61Q5/00 , A61Q19/00 , C08F2/10 , C08F26/06 , C08F126/06 , C09J139/04 , C09K9/02 , C10M149/10 , C11D3/37 , D06M17/06 , C08F2/16
CPC分类号： D06M17/06 , A61K8/65 , A61K8/731 , A61K8/732 , A61K8/8147 , A61K8/817 , A61K8/8176 , A61K8/86 , A61Q19/00 , A61Q5/06 , C08F26/06 , C11D3/3776
摘要： An aqueous solution of poly(N-vinyl-.di-elect cons.-caprolactam) is prepared by polymerizing N-vinyl-.di-elect cons.-caprolactam in an aqueous medium in the presence of a polymerization initiator and from 0.1 to 20% by weight, based on the monomer used, of a water-soluble polymeric protective colloid and is useful as a textile printing adhesive, as a raw material for adhesives, as a lubricant additive, as a cosmetic formulation aid, as a detergent additive and as an opacifier in automatic shading systems.
摘要翻译： PCT No.PCT / EP95 / 03688第 371日期1997年3月28日 102（e）1997年3月28日PCT PCT 1995年9月19日PCT公布。公开号WO96 / 10593 日期1996年4月11日在聚（N-乙烯基 - + 531-己内酰胺）的水溶液中，通过在聚合引发剂的存在下，在水性介质中聚合N-乙烯基 - + 531-己内酰胺，并且将0.1〜20％重量，基于所使用的单体，水溶性聚合物保护胶体，并且可用作纺织品印花粘合剂，作为粘合剂的原料，作为润滑剂添加剂，作为化妆品助剂，作为洗涤剂添加剂和作为遮光剂在自动遮阳系统中。

33. 发明授权

US4340455A Polyadduct/polycondensate containing basic nitrogen groups, and its use 失效
标题翻译：含有碱性氮基团的多元/缩聚物及其用途
公开(公告)号：US4340455A
公开(公告)日：1982-07-20
申请号：US281920
申请日：1981-07-09
申请人： Fritz E. Kempter , Eberhard Schupp
发明人： Fritz E. Kempter , Eberhard Schupp
IPC分类号： C08C19/36 , C08G14/00 , C08G14/06 , C08G14/14 , C08G59/00 , C08G59/14 , C08G59/40 , C08G59/62 , C09D5/44 , C09D163/00 , C08G59/50 , C08G59/54 , C08L63/10
CPC分类号： C09D5/4419 , C08C19/36 , C08G14/06 , C08G14/14 , C08G59/4042 , C08G59/623 , C09D163/00 , Y10S524/901
摘要： A polyadduct/polycondensate, which is water-dilutable when protonated with an acid, and which contains basic nitrogen groups, is obtained by polyaddition reaction of(A) Mannich bases obtained from monophenols and/or polyphenols, one or more secondary amines which contain one or more hydroxyalkyl groups, or a mixture of such a secondary amine with another secondary amine, and formaldehyde or a formaldehyde donor, with(B) an epoxy resin, the polyadduct/polycondensate of (A) and (B) containing groups, bonded to aromatic rings, of the formula (I) ##STR1## with or without groups of the general formula II ##STR2## where R.sup.1 is a polydienyl radical, R.sup.2 and R.sup.3 are hydrogen or methyl and R.sup.4 and R.sup.5 are alkyl, hydroxyalkyl or alkoxyalkyl or are linked to one another to form a 5-membered or 6-membered ring.The polyadduct/polycondensate can be used, for example, as a surface-coating binder for the cathodic electrocoating of metal articles.
摘要翻译：通过（A）从单酚和/或多酚获得的曼尼希碱，一种或多种含有一个或多个仲胺的仲胺的加聚反应获得当用酸酸化并含有碱性氮基团时可水稀释的多缩合物/缩聚物或更多的羟基烷基，或这种仲胺与另一仲胺，甲醛或甲醛供体的混合物与（B）环氧树脂，（A）和（B）含有基团的聚加合物/缩聚物，键合到具有或不具有通式II（II）的基团的式（I）的化合物（I）的芳环：其中R 1是聚二烯基，R 2和R 3是氢或甲基，且R 4和R 5是烷基，羟基烷基或烷氧基烷基，或者彼此连接形成5元环或6元环。聚缩合物/缩聚物可以用作例如金属制品的阴极电涂层的表面涂层粘合剂。

34. 发明授权

US4291147A Polyadducts of ammonia and epoxide compounds, processes for their modification, and their use 失效
标题翻译：氨和环氧化合物的加合物，其改性方法及其用途
公开(公告)号：US4291147A
公开(公告)日：1981-09-22
申请号：US137748
申请日：1980-04-07
申请人： Fritz E. Kempter , Eberhard Schupp , Hans-Uwe Schenck , Erich Gulbins
发明人： Fritz E. Kempter , Eberhard Schupp , Hans-Uwe Schenck , Erich Gulbins
IPC分类号： C08G12/00 , C08G12/02 , C08G12/46 , C08G59/00 , C08G59/14 , C08G59/40 , C08G65/26 , C08K5/29 , C09D5/44 , C09D163/00
CPC分类号： C08G12/46 , C08G12/00 , C08G12/02 , C08G59/1405 , C08G59/4014 , C08G65/2624 , C09D5/4438 , Y10S524/901 , Y10T428/2933
摘要： Polyadducts, free from epoxide groups, are obtained from ammonia and epoxide compounds by reacting 1 mole of ammonia with from 1.2 to 2.0 equivalents of epoxide, so that if diepoxide compounds are used products of the general formula (I) ##STR1## are obtained, while if triepoxides and/or tetraepoxide compounds are used, by themselves, or together with diepoxide compounds, products of the general formula II ##STR2## are produced; in these formulae, the E.sup.1 's are identical or different hydroxyl-containing divalent radicals and the E.sup.2 's are identical or different hydroxyl-containing trivalent or tetravalent radicals, resulting from the opening of the oxirane rings of epoxide compounds containing two, three or four epoxide groups in the molecule, n.sup.1, n.sup.3 and n.sup.5 are from 0 to 3, n.sup.2 and n.sup.4 are from 1 to 3 and X is 0 or 1, and one or more of the divalent radicals E.sup.1 in the general formula (II) may or may not be replaced by polyvalent radicals E.sup.2.The novel polyadducts can be modified by reaction with aldehydes, ketones, monoepoxide compounds, carboxylic acids, carboxylic acid esters or isocyanates, or by protonation with an acid, and may be used, for example, for the cathodic electrocoating of metallic articles.
摘要翻译：通过使1摩尔氨与1.2-2.0当量的环氧化物反应，从氨和环氧化合物得到不含环氧基的多元加成物，因此如果使用二环氧化合物，则得到通式（I）的产物而如果三环氧化物和/或四环氧化合物本身或与二环氧化合物一起使用，则制备通式II的产物（II）; 在这些式中，E1是相同或不同的含羟基的二价基团，并且E2是相同或不同的含羟基的三价或四价基团，其由环氧乙烷环的环氧化物环开放，所述环氧化物包含两个，三个或四个环氧基团分子n1，n3和n5为0〜3，n2和n4为1〜3，X为0或1，通式（II）中的一个或多个二价基团E1可以是也可以不是由多价基团E2代替。可以通过与醛，酮，单环化合物，羧酸，羧酸酯或异氰酸酯的反应或通过用酸质子化来改变新的多加合物，并且可以用于例如金属制品的阴极电泳涂层。

35. 发明申请

US20080125554A1 METHODS OF PRODUCING WATER-SOLUBLE, NON-TURBID COPOLYMERS OF AT LEAST ONE WATER-SOLUBLE N-VINYLLACTAM AND AT LEAST ONE HYDROPHOBIC COMONOMER 有权
标题翻译：生产水溶性方法，至少一种水溶性N-乙烯基甲酰胺和至少一种疏水性共聚物的非涡轮共聚物
公开(公告)号：US20080125554A1
公开(公告)日：2008-05-29
申请号：US11947223
申请日：2007-11-29
申请人： Rainer Dobrawa , Ralf Widmaier , Klaus Schnell , Karl-Hermann Strube , Jurgen Nieberle , Reinhold Dieing , Bernd de Potzolli , Andreas Gruber , Ulrich Filges , Martin Meister , Josef Neutzner , Wolfgang Bouquet , Eberhard Schupp
发明人： Rainer Dobrawa , Ralf Widmaier , Klaus Schnell , Karl-Hermann Strube , Jurgen Nieberle , Reinhold Dieing , Bernd de Potzolli , Andreas Gruber , Ulrich Filges , Martin Meister , Josef Neutzner , Wolfgang Bouquet , Eberhard Schupp
IPC分类号： C08F4/36
CPC分类号： C08F2/06
摘要： Methods of producing vinyllactam copolymers which include: providing at least one water-soluble N-vinyllactam; providing at least one hydrophobic comonomer; and subjecting the at least one water-soluble N-vinyllactam and the at least one hydrophobic comonomer to free-radical polymerization in an organic solvent in the presence of an initiator, under a combination of process measures selected from the group consisting of A and B; wherein:(A) comprises (i) polymerization under reflux, and at least two of (ii), (iii), (iv), (v), (vi), and (vii), wherein (ii) comprises an addition of at least 5 mol % of N-vinyllactam to the polymerization mixture if at least 70 mol % of the total amount of hydrophobic monomer used have completely reacted, (iii) comprises return of condensate formed in the reflux from below to the polymerization mixture, (iv) comprises introduction of the initiator in the form of a solution in an organic solvent from below into the polymerization mixture, (v) comprises addition of N-vinyllactam to the reflux, (vi) comprises distilling off a portion of the organic solvent and continuing the polymerization following conversion of 70 to 99% by weight of the N-vinyllactam used, and (vii) comprises introduction of at least one monomer from below into the polymerization mixture; and wherein(B) comprises (viii) polymerization under a superatmospheric pressure such that vaporization of the polymerization components is avoided, and at least one of (i), (ii), (iii), (iv), (v), (vi), and (vii), with the proviso that a combination of (viii) with any of (i), (iii) or (v) is carried out sequentially.
摘要翻译：制备乙烯基内酰胺共聚物的方法包括：提供至少一种水溶性N-乙烯基内酰胺; 提供至少一种疏水性共聚单体; 以及在引发剂存在下，使所述至少一种水溶性N-乙烯基内酰胺和所述至少一种疏水性共聚单体在有机溶剂中进行自由基聚合，所述方法选自A和B ; 其中：（A）包括（i）在回流下聚合，和（ii），（iii），（iv），（v），（vi）和（vii）中的至少两个，其中（ii）的至少5摩尔％的N-乙烯基内酰胺加入到聚合混合物中，如果使用的疏水性单体总量的至少70摩尔％已经完全反应，（iii）包括将从回流中形成的缩合物返回到聚合混合物中，（iv）包括将引发剂以有机溶剂形式从有机溶剂中引入聚合混合物中，（v）包括向回流物中加入N-乙烯基内酰胺，（vi）包括蒸馏除去一部分有机溶剂并且在所使用的N-乙烯基内酰胺的70至99重量％的转化后继续聚合，和（vii）包括将下述至少一种单体引入聚合混合物中; （ⅰ），（ⅱ），（ⅲ），（ⅳ），（ⅴ），（Ⅴ），（Ⅴ），（Ⅳ），（Ⅳ）， vi）和（vii），条件是（viii）与（i），（iii）或（v）中任何一个的组合依次进行。

36. 发明申请

US20070149740A1 Method of producing water-soluble nonturbid copolymers of at least one water-soluble N-vinyllactam and at least one hydrophobic comonomer 有权
标题翻译：制备至少一种水溶性N-乙烯基内酰胺和至少一种疏水性共聚单体的水溶性非混浊共聚物的方法
公开(公告)号：US20070149740A1
公开(公告)日：2007-06-28
申请号：US11644681
申请日：2006-12-22
申请人： Rainer Dobrawa , Ralf Widmaier , Eberhard Schupp , Klaus Schnell , Karl-Hermann Strube
发明人： Rainer Dobrawa , Ralf Widmaier , Eberhard Schupp , Klaus Schnell , Karl-Hermann Strube
IPC分类号： C08F26/10
CPC分类号： C08F226/10 , C08F216/10
摘要： Method of producing vinyllactam copolymers by free-radical polymerization of at least one water-soluble N-vinyllactam and at least one hydrophobic comonomer in an organic solvent in the presence of an initiator under reflux conditions, where N-vinyllactam is added to the reflux.
摘要翻译：通过在回流条件下在引发剂的存在下，在有机溶剂中，将至少一种水溶性N-乙烯基内酰胺和至少一种疏水性共聚单体自由基聚合制备乙烯基内酰胺共聚物的方法，其中将N-乙烯基内酰胺加入到回流中。

37. 发明申请

US20070149737A1 Method of producing water-soluble nonturbid copolymers of at least one water-soluble n-vinyllactam and at least one hydrophobic comonomer 审中-公开
标题翻译：制备至少一种水溶性n-乙烯基内酰胺和至少一种疏水性共聚单体的水溶性非混浊共聚物的方法
公开(公告)号：US20070149737A1
公开(公告)日：2007-06-28
申请号：US11643395
申请日：2006-12-21
申请人： Rainer Dobrawa , Ralf Widmaier , Eberhard Schupp , Klaus Schnell , Karl-Hermann Strube , Jurgen Nieberle , Bernd de Potzolli , Andreas Gruber , Reinhold Dieing
发明人： Rainer Dobrawa , Ralf Widmaier , Eberhard Schupp , Klaus Schnell , Karl-Hermann Strube , Jurgen Nieberle , Bernd de Potzolli , Andreas Gruber , Reinhold Dieing
IPC分类号： C08F26/10
CPC分类号： C08F226/10 , C08F216/10
摘要： Method of producing vinyllactam copolymers by free-radical polymerization of at least one water-soluble N-vinyllactam and at least one hydrophobic comonomer in an organic solvent in the presence of an initiator under reflux conditions, where at least 10 mol % of the N-vinyllactam are added to the polymerization mixture when at least 90 mol % of the hydrophobic monomer have completely reacted.
摘要翻译：通过至少一种水溶性N-乙烯基内酰胺和至少一种疏水性共聚单体在有机溶剂中在引发剂存在下，在回流条件下进行自由基聚合制备乙烯基内酰胺共聚物的方法，其中至少10mol％当至少90mol％的疏水单体完全反应时，将乙烯基内酰胺加入到聚合混合物中。

38. 发明申请

US20070149735A1 Method of producing water-soluble nonturbid copolymers of at least one water-soluble n-vinyllactam and at least one hydrophobic comonomer by polymerization under increased pressure 有权
标题翻译：通过在增加的压力下聚合制备至少一种水溶性n-乙烯基内酰胺和至少一种疏水性共聚单体的水溶性非混浊共聚物的方法
公开(公告)号：US20070149735A1
公开(公告)日：2007-06-28
申请号：US11643222
申请日：2006-12-21
申请人： Rainer Dobrawa , Ralf Widmaier , Eberhard Schupp , Klaus Schnell , Karl-Hermann Strube , Ulrich Filges , Jurgen Neiberle , Josef Neutzner , Reinhold Dieing , Andreas Gruber , Wolfgang Bouquet
发明人： Rainer Dobrawa , Ralf Widmaier , Eberhard Schupp , Klaus Schnell , Karl-Hermann Strube , Ulrich Filges , Jurgen Neiberle , Josef Neutzner , Reinhold Dieing , Andreas Gruber , Wolfgang Bouquet
IPC分类号： C08F26/10
CPC分类号： C08F226/10 , C08F218/08
摘要： Method of producing copolymers by free-radical polymerization of at least one water-soluble N-vinyllactam and at least one hydrophobic comonomer in an organic solvent in the presence of an initiator, where the polymerization is carried out under a gauge pressure such that evaporation of the components is avoided.
摘要翻译：在引发剂的存在下，在有机溶剂中，通过至少一种水溶性N-乙烯基内酰胺和至少一种疏水性共聚单体的自由基聚合制备共聚物的方法，其中聚合在表压下进行，使得蒸发避免了组件。

39. 发明授权

US06803405B1 Thickeners for aqueous dispersions 失效
标题翻译：增稠剂用于水性分散体
公开(公告)号：US06803405B1
公开(公告)日：2004-10-12
申请号：US10088521
申请日：2002-03-29
申请人： Klaus Schnell , Michael Kerber , Eberhard Schupp , Eckehardt Wistuba
发明人： Klaus Schnell , Michael Kerber , Eberhard Schupp , Eckehardt Wistuba
IPC分类号： C08L3104
CPC分类号： C08F226/10 , C08F218/08
摘要： The invention relates to the aqueous preparation of a polymer. Said preparation contains a copolymer consisting of a) 30 to 79.5 wt. % N-vinylpyrrolidone, b) 20 to 69.5 wt. % vinylacetate, c) 0.5 to 25 wt % of a monovinyl ester of a C4 to C20 monocarboxylic acid and d) 0 to 40 wt. % of an additional, copolymerisable, ethylenically unsaturated compound.
摘要翻译：本发明涉及聚合物的水性制剂。所述制备物包含由以下组分组成的共聚物：a）30〜79.5重量％％N-乙烯基吡咯烷酮，b）20〜69.5重量％％乙酸乙烯酯，c）0.5〜25重量％的C4〜C20一元羧酸的单乙烯基酯，以及d）0〜40重量％％的另外的可共聚的烯属不饱和化合物。

40. 发明授权

US4517343A Cathodically electrodepositable surface coating binder 失效
标题翻译：阴极电沉积表面涂层粘合剂
公开(公告)号：US4517343A
公开(公告)日：1985-05-14
申请号：US441806
申请日：1982-11-15
申请人： Eberhard Schupp , Fritz E. Kempter
发明人： Eberhard Schupp , Fritz E. Kempter
IPC分类号： C08G14/06 , C08G59/62 , C09D5/44 , C25D13/06 , C08L61/12 , C08L63/02
CPC分类号： C08G59/623 , C08G14/06 , C09D5/4488 , Y10S525/901
摘要： A cathodic electrocoating binder comprises a mixture of(A) from 50 to 95 percent by weight of one or more polyadducts, polymers and/or polycondensates which possess basic nitrogen groups and(B) from 50 to 5 percent by weight of one or more amide-amines obtained by reacting monocarboxylic and/or dicarboxylic acids, or their esters, with diamines which possess one primary and one secondary amino group per molecule, the secondary amino group carrying a .beta.-hydroxyalkyl group,and the component (A) consists of one or more phenolic Mannich bases, which are obtained from(a) monophenols and/or polyphenols,(b) one or more primary or secondary amines and(c) formaldehyde or a formaldehyde donor, and which may or may not have been reacted with epoxy resins, and/orone or more polyadducts, polymers and/or polycondensates which have activated C-C double bonds, some or all of which may be blocked by adduct formation with secondary amines,and, instead of a mixture of (A) and (B), it is also possible to use reaction products of component (B) with component (A) or with intermediates of component (A). These binders are useful for the cathodic electrocoating of metal articles.
摘要翻译：阴极电涂层粘合剂包含（A）50至95重量％的一种或多种具有碱性氮基团的聚加合物，聚合物和/或缩聚物和（B）50至5重量％的一种或多种酰胺的混合物通过使单羧酸和/或二羧酸或其酯与每分子具有一个伯和仲氨基的二胺反应而获得的胺，具有β-羟烷基的仲氨基，组分（A）由一个（a）单酚和/或多酚，（b）一种或多种伯胺或仲胺和（c）甲醛或甲醛供体获得的酚基曼尼希碱或更多酚基曼尼希碱，其可以或可以不与环氧树脂和/或一种或多种具有活化的CC双键的聚加成物，聚合物和/或缩聚物，其中一些或全部可能被仲胺形成的加合物阻断，而不是（A）和（B ），它也是p 可以使用组分（B）与组分（A）或组分（A）的中间体的反应产物。这些粘合剂可用于金属制品的阴极电涂层。

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