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31. 发明授权

US06677411B2 Component of catalyst for olefin polymerization 有权
标题翻译：用于烯烃聚合的催化剂组分
公开(公告)号：US06677411B2
公开(公告)日：2004-01-13
申请号：US10111408
申请日：2002-05-06
申请人： Hideshi Uchino , Hiroshi Nakano , Shuuichi Toriu , Takao Tayano , Hirotugu Niwa , Yoshiyuki Ishihama , Toshihiko Sugano
发明人： Hideshi Uchino , Hiroshi Nakano , Shuuichi Toriu , Takao Tayano , Hirotugu Niwa , Yoshiyuki Ishihama , Toshihiko Sugano
IPC分类号： C08F402
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65922 , C08F210/06 , C08F210/16 , Y10S526/943 , C08F4/02 , C08F4/65916 , C08F4/025 , C08F2500/12 , C08F2500/18 , C08F2500/24 , C08F210/08 , C08F210/14
摘要： A catalyst component for olefin polymerization, which comprises an ion-exchange layered silicate having the following features 1 and 2: feature 1: in a pore size distribution curve calculated from desorption isotherm by nitrogen adsorption-desorption method, a pore diameter Dm showing a maximum peak intensity DVM is from 60 to 200 Å; and feature 2: in a pore size distribution curve calculated from desorption isotherm by nitrogen adsorption-desorption method, a pore diameter Dm1/2 (Å) on the smaller pore size side corresponding to a ½ peak intensity of the maximum peak intensity DVM has a relation of Dm1/2/Dm of at least 0.65 and less than 1, provided that the largest value is employed when there are a plurality of Dm1/2 values.
摘要翻译：用于烯烃聚合的催化剂组分，其包含具有以下特征1和2的离子交换层状硅酸盐：特征1：通过氮吸附 - 解吸法由解吸等温线计算的孔径分布曲线中，孔径Dm表示最大值峰值强度DVM为60〜200; 特征2：在通过氮吸附 - 解吸法从解吸等温线计算的孔径分布曲线中，在与最大峰值强度DVM的1/2峰强度对应的较小孔径侧的孔径Dm1 / 2（）具有关系的Dm1 / 2 / Dm为0.65以上且小于1，条件是当存在多个Dm1 / 2值时采用最大值。

32. 发明授权

US06590045B2 Catalysts for polymerization of &agr;-olefins, process for producing &agr;-olefin polymers, novel transition metal compounds and catalyst components for polymerization of &agr;-olefin 有权
标题翻译：用于α-烯烃聚合的催化剂，用于生产α-烯烃聚合物的方法，用于α-烯烃聚合的新型过渡金属化合物和催化剂组分
公开(公告)号：US06590045B2
公开(公告)日：2003-07-08
申请号：US09966068
申请日：2001-10-01
申请人： Toshihiko Sugano , Naoshi Iwama , Eiji Isobe , Toru Suzuki , Yasuo Maruyama
发明人： Toshihiko Sugano , Naoshi Iwama , Eiji Isobe , Toru Suzuki , Yasuo Maruyama
IPC分类号： C08F442
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F110/06 , Y10S526/943 , C08F2500/03 , C08F2500/12 , C08F2500/15
摘要： Catalysts for polymerization of &agr;-olefin, composed of a transition metal compound, an inorganic silicate or an ion exchangeable layer compound other than silicate, and optionally an organoaluminum compound, are described. The transition metal compound is represented by formula (I): where A1 and A2 are each independently a conjugated 5-membered ring ligand provided that A1 and A2 may be the same or different in a molecule, and at least one of A1 and A2 forms a 7- to 10-membered condensed ring including two adjacent carbon atoms of the conjugated 5-membered ring, which condensed ring is formed by joining two adjacent substitutent groups on the conjugated 5-membered ring; Q is a bridging group of the two conjugated 5-membered rings of A1 and A2 at optional positions of the 5-membered rings; M is a metal atom selected from elements of Group 4-6 of the Periodic Table; and X and Z are each independently a hydrogen atom, a halogen atom, a hydrocarbon group, and amino group, a halogenated hydrocarbon group, an oxygen-containing hydrocarbon group, a nitrogen-containing hydrocarbon group, a phosphorus-containing hydrocarbon group or a silicon-containing hydrocarbon group.
摘要翻译：描述了由过渡金属化合物，无机硅酸盐或除了硅酸盐之外的可离子交换层化合物以及任选的有机铝化合物组成的α-烯烃聚合催化剂。过渡金属化合物由式（I）表示：其中A1和A2各自独立地为共轭五元环配体，条件是A1和A2在分子中可以相同或不同，并且A1和A2中的至少一个形成包含共轭五元环的两个相邻碳原子的7-至10-元稠环，所述稠合环通过连接共轭五元环上的两个相邻的取代基而形成; Q是在5元环的任选位置的A1和A2的两个共轭五元环的桥连基团; M是选自元素周期表第4-6组元素的金属原子; X和Z各自独立地为氢原子，卤素原子，烃基和氨基，卤代烃基，含氧烃基，含氮烃基，含磷烃基或含硅烃基。

33. 发明授权

US06469100B2 Propylene block copolymer and resin composition 有权
标题翻译：丙烯嵌段共聚物和树脂组合物
公开(公告)号：US06469100B2
公开(公告)日：2002-10-22
申请号：US09325384
申请日：1999-06-04
申请人： Toru Suzuki , Toshihiko Sugano , Hironari Sano , Motohiro Seki , Takao Tayano , Hiroshi Nakano
发明人： Toru Suzuki , Toshihiko Sugano , Hironari Sano , Motohiro Seki , Takao Tayano , Hiroshi Nakano
IPC分类号： C08L5300
CPC分类号： C08F297/083 , C08L53/00 , Y10S526/943
摘要： A block copolymer is provided comprising one or more blocks of a propylene polymer (PP) and one or more blocks of an ethylene-propylene copolymer (EPR) having the properties: (1) the interface thickness of the PP block with EPR block is from 20-1000 nm; (2) the weight average molecular weight of the PP block is 10,000-1,000,000; (3) the proportion of mesopentad chain in the PP block is not less than 95%; (4) the particle diameter of the disperse phase in EPR block is 0.2-3 microns; (5) the weight average molecular weight of the EPR block is 50,000-1000,000; (6) the propylene content in the EPR block is 20-80 mole %; (7) the composition fluctuation in molecular weight in EPR block is within +/−5% from the average composition.
摘要翻译：提供一种包含一个或多个丙烯聚合物（PP）嵌段和一个或多个乙烯 - 丙烯共聚物嵌段（EPR）的嵌段共聚物，其具有以下性质：（1）PP嵌段与EPR嵌段的界面厚度为 20-1000nm;（2）PP块的重均分子量为10,000-1,000,000;（3）PP嵌段中的美链的比例不低于95％;（4）分散体的粒径 EPR嵌段的相为0.2-3微米;（5）EPR嵌段的重均分子量为50,000-1000,000;（6）EPR嵌段中的丙烯含量为20-80摩尔％;（7） EPR块中分子量的组成波动在平均组成的+/- 5％以内。

34. 发明授权

US6084043A Catalyst component for polymerization of alpha-olefins and process for producing alpha-olefin polymers using the same 失效
标题翻译：用于α-烯烃聚合的催化剂组分和使用其制备α-烯烃聚合物的方法
公开(公告)号：US6084043A
公开(公告)日：2000-07-04
申请号：US975277
申请日：1997-11-20
申请人： Toshihiko Sugano , Hideshi Uchino , Kaori Imaeda , Eiji Taniyama , Naoshi Iwama
发明人： Toshihiko Sugano , Hideshi Uchino , Kaori Imaeda , Eiji Taniyama , Naoshi Iwama
IPC分类号： C08F4/642 , C08F4/44 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/646 , C08F4/6592 , C08F10/00
CPC分类号： C08F10/00 , C08F4/61908 , C08F4/61912 , C08F4/61927 , Y10S526/943
摘要： A catalyst component for the polymerization of alpha-olefins, represented by the following formula [I]: ##STR1## wherein R.sup.1 -R.sup.3 =H, a halogen, a C.sub.1-10 hydrocarbon radical, a Si-containing C.sub.1-18 hydrocarbon radical, or a halogen-containing C.sub.1-10, hydrocarbon radical (provided that R.sup.1 and R.sup.2 cannot be hydrogen at the same time); n=2 to 7; Q=a C.sub.1-20 hydrocarbon radical, a silylene or oligosilylene group having or not having a C.sub.1-20 hydrocarbon radical, a germylene group having or not having a C.sub.1-20 hydrocarbon radical; X and Y=H, a halogen, a C.sub.1-20 hydrocarbon radical, or an O- or N-containing C.sub.1-20 hydrocarbon radical; and M=a transition metal selected from the groups IVB-VIB; a catalyst for the polymerization of alpha-olefins, comprising the catalyst component; and a process for producing alpha-olefin polymers, where use is made of the catalyst. Use of the catalyst will produce alpha-olefin polymers having a high melting point and a high molecular weight in a high yield.
摘要翻译：由下式[I]表示的用于α-烯烃聚合的催化剂组分：其中R1-R3 = H，卤素，C1-10烃基，含Si的C1-18烃基或卤素含有C 1-10的烃基（条件是R1和R2不能同时为氢）; n = 2〜7; Q = C 1-20烃基，具有或不具有C 1-20烃基的亚甲硅烷基或低聚亚芳基，具有或不具有C 1-20烃基的亚乙烯基; X和Y = H，卤素，C 1-20烃基或含O-或N的C 1-20烃基; M =选自IVB-VIB族的过渡金属; 包含催化剂组分的α-烯烃聚合催化剂; 和使用催化剂的α-烯烃聚合物的制备方法。催化剂的使用将以高产率生产具有高熔点和高分子量的α-烯烃聚合物。

35. 发明授权

US5561093A Catalyst useful for the polymerization of olefins 失效
标题翻译：可用于烯烃聚合的催化剂
公开(公告)号：US5561093A
公开(公告)日：1996-10-01
申请号：US445556
申请日：1995-05-22
申请人： Takashi Fujita , Toshihiko Sugano , Hideshi Uchino
发明人： Takashi Fujita , Toshihiko Sugano , Hideshi Uchino
IPC分类号： C07F17/00 , C08F4/60 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F4/76 , C08F10/00 , C08F110/06 , C08F210/06 , B01J31/00
CPC分类号： C08F10/00 , C07F17/00 , C08F110/06 , C08F210/06 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： A catalyst useful for the polymerization of olefins, comprising the following components (A) and (B):Component (A):A transition metallic compound having the following formula [I]: ##STR1## wherein M:a transition metal selected from Ti, Zr and Hf; R.sup.1 :a monovalent C.sub.1-6 hydrocarbyl group, or a monovalent C.sub.1-6 hydrocarbyl group containing Si;R.sup.2 :a divalent C.sub.4-20 hydrocarbyl group, or a divalent C.sub.4-20 hydrocarbyl group containing Si;R.sup.3 :a divalent C.sub.1-30 hydrocarbyl group, or a divalent C.sub.1-30 hydrocarbyl group containing Si or Ge; andX and Y:H, halogen, a monovalent C.sub.1-20 hydrocarbyl group, or a monovalent C.sub.1-20 hydrocarbyl group containing N, O or Si.Component (B):Alumoxane having the following formula [II] or [III]: ##STR2## wherein m:4 to 30; and R.sup.4 :a monovalent hydrocarbyl group. A highly stereoregular polyolefin having a high molecular weight can be obtained by the above catalyst.
摘要翻译：用于烯烃聚合的催化剂，其包含以下组分（A）和（B）：组分（A）：具有下式[I]的过渡金属化合物：其中M：过渡金属选自Ti，Zr和Hf; R1：一价C 1-6烃基或含有Si的一价C 1-6烃基; R2：二价C 4-20烃基，或含有Si的二价C 4-20烃基; R3：二价C1-30烃基，或含有Si或Ge的二价C1-30烃基; 和X和Y：H，卤素，一价C 1-20烃基或含有N，O或Si的一价C 1-20烃基。组分（B）：具有下式[II]或[III]的铝氧烷：[II]价烃基。通过上述催化剂可以获得具有高分子量的高立体规则聚烯烃。

36. 发明授权

US5510502A Catalyst component for use in the polymerization of .alpha.-olefins and process for producing .alpha.-olefin polymers using the same 失效
标题翻译：用于α-烯烃聚合的催化剂组分和使用其制备α-烯烃聚合物的方法
公开(公告)号：US5510502A
公开(公告)日：1996-04-23
申请号：US198257
申请日：1994-02-18
申请人： Toshihiko Sugano , Tomohiko Takahama
发明人： Toshihiko Sugano , Tomohiko Takahama
IPC分类号： C08F4/642 , C07F17/00 , C08F4/60 , C08F4/649 , C08F4/651 , C08F4/659 , C08F4/6592 , C08F10/00 , C07F7/28 , C07F9/00 , C07F11/00
CPC分类号： C07F17/00 , C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/65927
摘要： A catalyst component for use in the polymerization of .alpha.-olefins, comprising a compound represented by the following general formula I!: ##STR1## wherein R.sup.1 s represent a hydrogen atom, a C.sub.1-6 hydrocarbon group or a C.sub.1-12 hydrocarbon group containing silicon; each of R.sup.2 and R.sup.3 which forms the condensed ring represents a divalent C.sub.3-20 saturated or unsaturated hydrocarbon group, provided that at least one of R.sup.2 and R.sup.3 forms a ring condensed with the cyclopentadiene which is a seven- to twelve-membered ring having an unsaturated bond inherent in R.sup.2 or R.sup.3 ; Q represents a C.sub.1-20 divalent hydrocarbon group, a silylene group, a silylene group with a C.sub.1-20 hydrocarbon group, a germylene group, or a germylene group with a C.sub.1-20 hydrocarbon group; X and Y represent H, a halogen, a C.sub.1-20 hydrocarbon group, or a C.sub.1-20 hydrocarbon group containing oxygen, nitrogen or phosphorus; and M represents a Group IVB to VIB transition metal of the Periodic Table. Production of .alpha.-olefin polymers having a high melting point and a high molecular weight in a high yield and a process for producing .alpha.-olefin polymers is made possible upon the use of the catalyst.
摘要翻译：一种用于α-烯烃聚合的催化剂组分，其包含由以下通式[I]表示的化合物：其中R 1表示氢原子，C 1-6烃基或C 1-12 含烃基团; 形成稠环的R 2和R 3各自表示二价C 3-20饱和或不饱和烃基，条件是R 2和R 3中的至少一个与环戊二烯缩合形成环，该环是具有7至12元环， R2或R3固有的不饱和键; Q表示C 1-20二价烃基，亚甲硅烷基，具有C 1-20烃基的亚甲硅烷基，亚乙烯基或具有C 1-20烃基的亚
甲基; X和Y表示H，卤素，C 1-20烃基或含有氧，氮或磷的C 1-20烃基; 并且M表示周期表的IVB至VIB族过渡金属。在使用催化剂的情况下，可以生产具有高收率的高熔点和高分子量的α-烯烃聚合物和生产α-烯烃聚合物的方法。

37. 发明授权

US5449650A Catalyst components for polymerization of olefins and use thereof 失效
标题翻译：用于烯烃聚合的催化剂组分及其用途
公开(公告)号：US5449650A
公开(公告)日：1995-09-12
申请号：US161464
申请日：1993-12-06
申请人： Toshihiko Sugano , Tomohiko Takahama
发明人： Toshihiko Sugano , Tomohiko Takahama
IPC分类号： C07F5/06 , C08F4/623 , C08F4/639 , C08F4/6392 , C08F4/642 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , B01J31/14 , B01J21/02
CPC分类号： C08F10/00 , C07F5/068 , C08F110/02 , C08F110/06 , C08F210/16 , C08F4/63912 , C08F4/6392 , Y10S526/943
摘要： Disclosed is a catalyst component for the polymerization of olefins, which is a compound having the following structure: ##STR1## wherein R.sup.1 is a hydrocarbon radical having 1 to 10 carbon atoms or a halogen-containing hydrocarbon radical having 1 to 10 carbon atoms, and R.sup.2 s are each a hydrogen atom, a halogen atom, a siloxy group, a lower-alkyl-substituted siloxy group or a hydrocarbon radical having 1 to 10 carbon atoms, or which is a reaction product of the following sub-components (i) and (ii):sub-component (i) which is a compound having the formulaR.sup.1 -B-(OH).sub.2in which R.sup.1 is a hydrocarbon radical having 1 to 10 carbon atoms or a halogen-containing hydrocarbon radical having 1 to 10 carbon atoms; andsub-component (ii) which is an organoaluminum compound.
摘要翻译：公开了用于烯烃聚合的催化剂组分，其是具有以下结构的化合物：其中R1是具有1-10个碳原子的烃基或具有1-10个碳原子的含卤素烃基原子和R 2各自为氢原子，卤素原子，甲硅烷氧基，低级烷基取代的甲硅烷氧基或具有1-10个碳原子的烃基，或其是以下亚组分的反应产物（ i）和（ii）：具有式R1-B-（OH）2的化合物的其中R1是具有1-10个碳原子的烃基或含卤素的烃基的化合物的组分（i）至10个碳原子; 和作为有机铝化合物的副成分（ⅱ）。

38. 发明授权

US5385877A Production of alpha-olefin polymers 失效
标题翻译：生产α-烯烃聚合物
公开(公告)号：US5385877A
公开(公告)日：1995-01-31
申请号：US832322
申请日：1992-02-07
申请人： Takashi Fujita , Toshihiko Sugano , Hideshi Uchino
发明人： Takashi Fujita , Toshihiko Sugano , Hideshi Uchino
IPC分类号： C08F4/642 , C07F17/00 , C08F4/60 , C08F4/602 , C08F4/639 , C08F4/6392 , C08F4/6592 , C08F10/00
CPC分类号： C08F10/00 , C07F17/00 , C08F4/63912 , C08F4/63927
摘要： A catalyst for .alpha.-olefin polymerization which comprises the following components (A) and (B):component (A), which is a transition metal compound represented by the formulaQ(C.sub.5 H.sub.4-m R.sup.1.sub.m)(C.sub.5 H.sub.4-n R.sup.2.sub.n)MeXYwherein (C.sub.5 H.sub.4-m R.sup.1.sub.m) and (C.sub.5 H.sub.4-n R.sup.2.sub.n) respectively represent a conjugated five-membered ring ligand coordinating to a metal Me; R.sup.1 and R.sup.2 which may be the same or different and a plurality of each of which can be bonded together, respectively represent a hydrocarbyl group having 1 to 20 carbon atoms, a halogen atom, an alkoxy group, a silicon-containing hydrocarbyl group, a phosphorus-containing hydrocarbyl group, a nitrogen-containing hydrocarbyl group or a boron-containing hydrocarbyl group; Q represents a bonding group which crosslinks the two conjugated five-membered ring ligand; Me represents a transition metal of the IVB-VIB group in the Periodic Table; X and Y, which may be the same or different, respectively represent hydrogen, a halogen atoms, a hydrocarbyl group, an alkoxy group, an amino group, a phosphorus-containing hydrocarbyl group or a silicon-containing hydrocarbyl group; m denotes an integer of 0.ltoreq.m.ltoreq.4 and n denotes an integer of 0.ltoreq.n.ltoreq.4; component (B), which is a methylisobutylalumoxane which satisfies the following conditions (a), (b) and (c): (a) the molar ratio of a methyl group to an isobutyl group being in the range of 4:1 to 1:4, (b) the chemical shift of .sup.27 Al-NMR being in the range of 160 ppm to 250 ppm and the peak having a half-height width of no smaller than 3000 Hz, and (c) it has a repeating unit of Al--O in an amount of 2 to 100. The methylisobutylalumoxane is assumed to be novel.
摘要翻译：用于α-烯烃聚合的催化剂，其包含以下组分（A）和（B）：组分（A），其为由式Q（C5H4-mR1m）（C5H4-nR2n）MeXY表示的过渡金属化合物，其中（C5H4 -mR1m）和（C5H4-nR2n）分别表示与金属Me配位的共轭五元环配体; R 1和R 2可以相同或不同，并且多个可以键合在一起，分别表示具有1至20个碳原子的烃基，卤素原子，烷氧基，含硅烃基，含磷烃基，含氮烃基或含硼烃基; Q表示交联两个共轭五元环配体的键合基团; Me表示周期表中IVB-VIB基团的过渡金属; X和Y可以相同或不同，分别表示氢，卤素原子，烃基，烷氧基，氨基，含磷烃基或含硅烃基; m表示0≤n≤4的整数，n表示0

39. 发明授权

US5346925A Method for producing .alpha.-olefin polymers 失效
标题翻译： α-烯烃聚合物的制备方法
公开(公告)号：US5346925A
公开(公告)日：1994-09-13
申请号：US149911
申请日：1993-11-10
申请人： Toshihiko Sugano , Takashi Fujita , Kazuyo Kuwaba
发明人： Toshihiko Sugano , Takashi Fujita , Kazuyo Kuwaba
IPC分类号： C08F4/02 , C08F4/615 , C08F4/639 , C08F4/6392 , C08F10/00 , C08F10/06 , C08F110/06 , C08F210/06 , C08J9/40
CPC分类号： C08F10/06 , C08F10/00 , C08F110/06 , C08F210/06 , C08F4/63912 , C08F4/63916 , C08F4/6392 , Y10S526/904 , Y10S526/943
摘要： A method for preparing an .alpha.-olefin polymer in which an .alpha.-olefin is polymerized in the presence of a catalyst, characterized in that the catalyst is a solid obtained by making the following components (ii) and (iii) be supported in the component (i):Component (i): an organic porous polymer having an average particle diameter of 5 to 1,000 .mu.m, in which the total pore volume of all pores whose diameter is 0.006 to 10 .mu.m is 0.3 cc/g or more, and the total pore volume of all pores whose diameter is 0.05 to 2 .mu.m is 50% or more of the total pore volume of all pores whose diameter is 0.006 to 10 .mu.m;Component (ii) a compound having the structure ##STR1## in which R is a hydrocarbon group having 1 to 10 carbon atoms; and Component (iii) a compound of a transition metal which belongs to one of the Groups IVB to VIB in the Periodic Table, having at least one conjugated 5-membered cyclic ligand.
摘要翻译：一种制备其中α-烯烃在催化剂存在下聚合的α-烯烃聚合物的方法，其特征在于催化剂是通过使以下组分（ii）和（iii）支持在组分（i）成分（i）：成分（i）：平均粒径为5〜1000μm的有机多孔质聚合物，其直径为0.006〜10μm的全部孔的总细孔容积为0.3cc / g以上，直径为0.05〜2μm的所有孔的总细孔容积为直径为0.006〜10μm的全部孔的总孔体积的50％以上; 组分（ii）具有结构的化合物，其中R是具有1-10个碳原子的烃基; 和组分（ⅲ）属于元素周期表IVB至VIB族之一的过渡金属的化合物，其具有至少一个共轭的5元环配体。

40. 发明授权

US5032563A Production of alpha-olefin polymers 失效
标题翻译：生产α-烯烃聚合物
公开(公告)号：US5032563A
公开(公告)日：1991-07-16
申请号：US437661
申请日：1989-11-17
申请人： Mitsuyuki Matsuura , Toshihiko Sugano , Kazuo Nakamura
发明人： Mitsuyuki Matsuura , Toshihiko Sugano , Kazuo Nakamura
IPC分类号： C08F4/658 , C08F4/60 , C08F4/646 , C08F4/69 , C08F10/00
CPC分类号： C08F10/00 , C08F2410/04
摘要： Ziegler polymerization of .alpha.-olefins is disclosed which is characterized by a solid catalyst component used in the Ziegler-type catalyst. The solid catalyst component, Component (A), comprises Component (i) which is a solid catalyst component for a Ziegler-type catalyst comprising Ti, Mg and a halogen; Component (ii) a silicon compound of a formula:R.sup.1 R.sup.2.sub.3-n Si(OR.sup.3).sub.nwherein R.sup.1 -R.sup.3 are each hydrocarbyl group characterized by R.sup.1 which has a branched hydrocarbyl group;Component (iii) a halogen compound of W or Mo; and Component (iv) an organometal compound of a metal of Groups I to IV of the Periodic Table.

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