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31. 发明授权

US4864030A Preparation of 1-alkylimidazoles 失效
标题翻译： 1-烷基咪唑的制备
公开(公告)号：US4864030A
公开(公告)日：1989-09-05
申请号：US238121
申请日：1988-08-30
申请人： Hermann Koehler , Toni Dockner , Helmut Karn
发明人： Hermann Koehler , Toni Dockner , Helmut Karn
IPC分类号： C07D233/90
CPC分类号： C07D233/90
摘要： Process for the preparation of 1-alkylimidazoles of the general formula (I) ##STR1## where R.sup.1 is alkyl, R.sup.2 and R.sup.3 are hydrogen, alkyl, aryl, arylalkyl, or alkylaryl, R.sup.4 is carboxy, alkoxycarbonyl R.sup.5 OCC--, carbamoyl, or cyano, and R.sup.5 is an alkyl of from 1 to 8 carbon atoms--by the reaction of imidazoles of the general formula (II) ##STR2## with dialkyl sulfates of the general formula (III)(R.sup.1 O).sub.2 SO.sub.2 (III)at elevated temperatures in the presence of a carboxylic acid or anhydride or of both acid and anhydride.
摘要翻译：制备通式（I）的1-烷基咪唑的方法其中R 1是烷基，R 2和R 3是氢，烷基，芳基，芳基烷基或烷基芳基，R 4是羧基，烷氧基羰基，R 5 OCC - ，氨基甲酰基，或氰基，R 5是1至8个碳原子的烷基 - 通式（II）的咪唑与（II）的二烷基硫酸盐（R 1 O）2 SO 2（ III）在羧酸或酸酐或酸和酸酐的存在下在升高的温度下进行。

32. 发明授权

US4845247A 3,4,-dihydro-2H-pyrans 失效
标题翻译： 3,4， - 二氢-2H-吡喃
公开(公告)号：US4845247A
公开(公告)日：1989-07-04
申请号：US76612
申请日：1987-07-23
申请人： Wolfgang Spiegler , Norbert Goetz , Manfred Sauerwald , Toni Dockner , Rolf Fischer
发明人： Wolfgang Spiegler , Norbert Goetz , Manfred Sauerwald , Toni Dockner , Rolf Fischer
IPC分类号： C07D309/22 , C07D309/28 , C07D309/32
CPC分类号： C07D309/32 , C07D309/22 , C07D309/28
摘要： 3,4-dihydro-2H-pyrans I ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each H or C.sub.1 -C.sub.6 -alkyl and R.sup.3 is not C.sub.2 -C.sub.4 -alkyl when A is COOR.sup.5 and A is COOR.sup.5, .dbd.CHOR.sup.5, in which R.sup.5 is C.sub.1 -C.sub.4 -alkyl, or CH.sub.2 OR.sup.6, in which R.sup.6 is C.sub.1 -C.sub.4 -alkyl or is benzyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkyl, alkoxy or halogen, or is formyl, C.sub.2 -C.sub.4 -alkylcarbonyl or benzoyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkyl, alkoxy or halogen, are prepared by eliminating an alcohol from a 2-alkoxytetrahydropyran II ##STR2## where R.sup.7 is C.sub.1 -C.sub.18 -alkyl and A' is COOR.sup.5, CH(OR.sup.5).sub.2 or CH.sub.2 OR.sup.6, in which R.sup.5 and R.sup.6 have the meanings stated for I, the elimination being carried out by passing II, in the liquid or gaseous state, into a high boiling mineral oil at above the boiling point of the resulting dihydropyran I, removing I in gaseous form, replenishisng the high boiling mineral oil when it becomes enriched with byproducts, and removing the said mineral oil enriched with byproducts.
摘要翻译： 3,4-二氢-2H-吡喃酮其中R 1，R 2，R 3和R 4各自是H或C 1 -C 6烷基，当A是COOR 5 + L时，R 3不是C 2 -C 4 - 烷基，A是 COOR 5 = CHOR 5，其中R 5是C 1 -C 4 - 烷基或CH 2 OR 6，其中R 6是C 1 -C 4烷基或是未被取代或被C 1 -C 4 - 烷基，烷氧基或卤素取代的苄基，或是甲酰基，未取代或被C 1 -C 4 - 烷基，烷氧基或卤素取代的C 2 -C 4 - 烷基羰基或苯甲酰基通过从2-烷氧基四氢吡喃II中除去醇来制备，其中R 7是C 1 -C 18烷基和A' 是COOR 5，CH（OR 5）2或CH 2 OR 6，其中R 5和R 6具有I所述的含义，通过使II在液体或气态下进行的消除在高于沸点的高沸点矿物油中进行的所得二氢吡喃I，除去气体形式的I，当富含副产物时补充高沸点矿物油，并除去富含副产物的所述矿物油。

33. 发明授权

US4803283A Preparation of 4(5)-nitroimidazole-5(4)-carboxylic acids 失效
标题翻译： 4（5） - 硝基咪唑-5（4） - 羧酸的制备
公开(公告)号：US4803283A
公开(公告)日：1989-02-07
申请号：US126867
申请日：1987-11-30
申请人： Toni Dockner , Uwe Kempe , Hermann Koehler
发明人： Toni Dockner , Uwe Kempe , Hermann Koehler
IPC分类号： C07D233/92 , C07D233/91
CPC分类号： C07D233/92
摘要： 4(5)-nitroimidazole-5(4)-carboxylic acids are prepared by reacting an imidazole-4(5)-carboxylic acid with a mixture of sulfuric acid and nitric acid at not less than 80.degree. C., the water content of the reaction mixture at the beginning of the reaction being no higher than 5% by weight, based on the reaction mixture.
摘要翻译：通过使咪唑-4（5） - 羧酸与硫酸和硝酸的混合物在不低于80℃下反应制备4（5） - 硝基咪唑-5（4） - 羧酸，基于反应混合物，反应开始时的反应混合物不高于5重量％。

34. 发明授权

US4670567A Process for the preparation of 5,6-dihydro-2H-thiopyran-3-carboxaldehyde derivatives wherein the reactions are conducted in a high boiling mineral oil without a catalyst 失效
标题翻译：制备5,6-二氢-2H-噻喃-3-甲醛衍生物的方法，其中反应在不含催化剂的高沸点矿物油中进行
公开(公告)号：US4670567A
公开(公告)日：1987-06-02
申请号：US758812
申请日：1985-07-25
申请人： Manfred Sauerwald , Toni Dockner , Wolfgang Rohr , Gernot Reissenweber
发明人： Manfred Sauerwald , Toni Dockner , Wolfgang Rohr , Gernot Reissenweber
IPC分类号： C07D335/02
CPC分类号： C07D335/02
摘要： 5,6-Dihydro-2H-thiopyran-3-carboxaldehydes of the formula ##STR1## where R denotes hydrogen or methyl, are prepared by a method in which acrolein or crotonaldehyde is reacted with hydrogen sulfide in a mineral oil whose boiling point is higher than those of the starting materials and of the end product, and the 5,6-dihydro-2H-thiopyran-3-carboxaldehyde is obtained by distillation. These aldehydes are important intermediates for the preparation of some crop protection agents.
摘要翻译：其中R表示氢或甲基的式“IMAGE”的5,6-二氢-2H-噻喃-3-甲醛通过以下方法制备：其中丙烯醛或巴豆醛与沸点较高的矿物油中的硫化氢反应比原料和最终产物的原料和5,6-二氢-2H-噻喃-3-甲醛通过蒸馏得到。这些醛是制备一些作物保护剂的重要中间体。

35. 发明授权

US4550176A Preparation of imidazole-4,5-dicarboxylic acid 失效
标题翻译：咪唑-4,5-二羧酸的制备
公开(公告)号：US4550176A
公开(公告)日：1985-10-29
申请号：US569965
申请日：1984-01-11
申请人： Toni Dockner , Uwe Kempe , Anton Frank
发明人： Toni Dockner , Uwe Kempe , Anton Frank
IPC分类号： C07D233/90
CPC分类号： C07D233/90
摘要： Imidazole-4,5-dicarboxylic acid is prepared by a process in which imidazole is reacted with formaldehyde, and the reaction mixture is treated with nitric acid.
摘要翻译：咪唑-4,5-二羧酸通过咪唑与甲醛反应的方法制备，反应混合物用硝酸处理。

36. 发明授权

US4339448A Imidazole-copper complex compounds and fungicides containing them 失效
标题翻译：咪唑铜络合物和含有它们的杀真菌剂
公开(公告)号：US4339448A
公开(公告)日：1982-07-13
申请号：US87556
申请日：1979-10-22
申请人： Toni Dockner , Anton Frank , Ernst-Heinrich Pommer
发明人： Toni Dockner , Anton Frank , Ernst-Heinrich Pommer
IPC分类号： A01N43/50 , C07D233/54 , C07D233/92 , C07D233/94 , C07D233/95 , C07D521/00 , A01N55/02 , C07F1/08
CPC分类号： C07D233/54 , A01N43/50 , C07D231/12 , C07D233/56 , C07D233/64 , C07D233/92 , C07D233/94 , C07D233/95 , C07D249/08
摘要： New imidazole-copper complex compounds having a good fungicidal action, fungicides containing these compounds as active ingredients, processes for their manufacture, and their use for combating fungi.
摘要翻译：具有良好杀真菌作用的新咪唑铜络合物，含有这些化合物作为活性成分的杀真菌剂，其制造方法及其对抗真菌的用途。

37. 发明授权

US4298748A Preparation of 2-imidazolines 失效
标题翻译： 2-咪唑啉的制备
公开(公告)号：US4298748A
公开(公告)日：1981-11-03
申请号：US97814
申请日：1979-11-27
申请人： Toni Dockner , Uwe Kempe , Herbert Krug , Peter Magnussen , Werner Praetorius , Hans J. Szymanski
发明人： Toni Dockner , Uwe Kempe , Herbert Krug , Peter Magnussen , Werner Praetorius , Hans J. Szymanski
IPC分类号： C07D233/06 , C07D233/08 , C07D233/10
CPC分类号： C07D233/10 , C07D233/06
摘要： A novel process for the preparation of 2-imidazolines by reacting 1,2-diamines with nitriles or carbonyl compounds in the gas phase at from 200.degree. to 450.degree. C. in the presence of an oxide or phosphate of a metal of group 3 or 4 of the periodic table and/or in the presence of silicon dioxide.The 2-imidazolines obtainable by the process of the invention are valuable starting materials for the preparation of dyes, crop protection agents and drugs.
摘要翻译：一种新型的制备2-咪唑啉的方法，该方法是在200-350℃的气相中，在二氧化碳或磷酸三烷基酯存在下，使1,2-二胺与腈或羰基化合物反应， 4和/或在二氧化硅存在下。通过本发明的方法可获得的2-咪唑啉是制备染料，作物保护剂和药物的有价值的起始原料。

38. 发明授权

US4242517A Process for preparing 4-methyl-5[(2-aminoethyl)thiomethyl)]-imidazole 失效
标题翻译：制备4-甲基-5 [（2-氨基乙基）硫代甲基）] - 咪唑的方法
公开(公告)号：US4242517A
公开(公告)日：1980-12-30
申请号：US64909
申请日：1979-08-08
申请人： Toni Dockner , Anton Frank , Uwe Kempe , Matthias Wetzler , Helmut Karn
发明人： Toni Dockner , Anton Frank , Uwe Kempe , Matthias Wetzler , Helmut Karn
IPC分类号： C07D233/64 , C07D233/54 , C07D233/60 , C07D521/00 , C08G12/26 , C08G59/40 , C08G59/50 , C10L1/32
CPC分类号： C07D233/64 , C07D231/12 , C07D233/56 , C07D249/08 , C08G12/26 , C10L1/328
摘要： 1-Hydroxymethylimidazoles which are unsubstituted or alkyl-substituted in the 2-position, their manufacture and their use as chemical intermediates, e.g. for other imidazole derivatives or for the drug cimetidine.
摘要翻译：在2-位未被取代或被烷基取代的1-羟基甲基咪唑，它们的制备及其作为化学中间体的用途。用于其他咪唑衍生物或药物西咪替丁。

39. 发明授权

US3956387A Manufacture of concentrated aqueous (meth)acrylamide solutions by catalytic addition of water to (meth)acrylonitrile 失效
标题翻译：通过向（甲基）丙烯腈催化加水，制备浓缩的（甲基）丙烯酰胺水溶液
公开(公告)号：US3956387A
公开(公告)日：1976-05-11
申请号：US459457
申请日：1974-04-10
申请人： Toni Dockner , Rolf Platz
发明人： Toni Dockner , Rolf Platz
IPC分类号： C07C231/06 , C07C20060101 , C07C67/00 , C07C213/06 , C07C231/00 , C07C231/24 , C07C233/09 , C07C103/08
CPC分类号： B01J23/72
摘要： By adding water to (meth)acrylonitrile there is formed a concentrated aqueous (meth)acrylamide solution, the addition being effected in the presence of a heterogeneous catalyst at elevated temperature and in aqueous (meth)acrylamide/(meth)acrylonitrile solution at an initial ratio of amide to nitrile of from 1:1 to 1:7.
摘要翻译：通过向（甲基）丙烯腈中加入水形成浓缩的（甲基）丙烯酰胺水溶液，加入在高温下在非均相催化剂存在下和在（甲基）丙烯酰胺/（甲基）丙烯酸水溶液中初始化酰胺与腈的比例为1:1至1:7。

40. 发明授权

US06827858B2 Method for separating alkali metal ions from alkoxylates 有权
标题翻译：从烷氧基化物中分离碱金属离子的方法
公开(公告)号：US06827858B2
公开(公告)日：2004-12-07
申请号：US10275942
申请日：2002-11-14
申请人： Joachim Bader , Hans-Heinrich Bechtolsheimer , Armin Brucker , Toni Dockner , Gabriele Iffland , Hans Klink , Stefan Martin , Jürgen Mohr , Hans-Martin Mugrauer
发明人： Joachim Bader , Hans-Heinrich Bechtolsheimer , Armin Brucker , Toni Dockner , Gabriele Iffland , Hans Klink , Stefan Martin , Jürgen Mohr , Hans-Martin Mugrauer
IPC分类号： C02F142
CPC分类号： C08G65/30 , B01J39/04 , B01J49/06 , B01J49/53
摘要： Alkali metal ions are separated off from alkoxylates containing alkali metal ions by a process comprising: a) dilution of the alkali metal-containing alkoxylate with an inert solvent, b) treatment of the alkali metal-containing solution of the alkoxylate with a cationic exchanger in order to obtain a substantially alkali metal-free solution of the alkoxylate, and c) removal of the solvent from the substantially alkali metal-free solution of the alkoxylate in order to obtain a substantially alkali metal-free and substantially solvent-free alkoxylate.
摘要翻译：碱金属离子与含有碱金属离子的烷氧基离子分离，其方法包括：a）用惰性溶剂稀释含碱金属的烷氧基化物，b）用阳离子交换剂处理含烷氧基化物的碱金属的溶液以获得基本上不含碱金属的烷氧基化物溶液，和c）从基本上不含碱金属的烷氧基化物溶液中除去溶剂，以获得基本上无碱金属和基本上无溶剂的烷氧基化物。

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