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    • 31. 发明授权
    • Alkylaromatics production
    • 烷基芳烃生产
    • US07649122B2
    • 2010-01-19
    • US11599864
    • 2006-11-15
    • Michael C. ClarkVijay Nanda
    • Michael C. ClarkVijay Nanda
    • C07C2/58
    • C07C2/66C07C2529/06C10G2400/30C07C15/073C07C15/085
    • A process for alkylation of an alkylatable aromatic compound to produce a monoalkylated aromatic compound, comprising the steps of (a) contacting at least one the alkylatable aromatic compound and at least one the alkylating agent with at least one molecular sieve catalyst under suitable alkylation or transalkylation conditions in at least one reaction zone, to produce at least one effluent which comprises the monoalkylated aromatic compound, wherein the suitable alkylation or transalkylation conditions comprise a water content being in a range from about 1 wppm to about 10 wt. % based on the combined weight of the alkylatable aromatic compound and the alkylating agent; and (b) maintaining the water content in the reaction zone; wherein the cycle length of the molecular sieve catalyst operated inside the range of the water content is greater than the cycle length of the molecular sieve catalyst operated outside the range of the water content.
    • 烷基化芳族化合物以制备单烷基化芳族化合物的方法,包括以下步骤:(a)在合适的烷基化或烷基转移下使至少一种可烷基化芳族化合物与至少一种烷基化剂与至少一种分子筛催化剂接触 在至少一个反应区中的条件,以产生至少一种包含单烷基化芳族化合物的流出物,其中合适的烷基化或烷基转移条件包括水含量在约1wppm至约10wt。 基于可烷基化芳族化合物和烷基化剂的总重量的%; 和(b)保持反应区中的水分含量; 其中在水含量范围内操作的分子筛催化剂的循环长度大于在水含量范围之外运行的分子筛催化剂的循环长度。