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31. 发明申请

WO2011073226A3 DEBOTTLENECKING OF A STEAM CRACKER UNIT TO ENHANCE PROPYLENE PRODUCTION 审中-公开
公开(公告)号：WO2011073226A3
公开(公告)日：2011-06-23
申请号：PCT/EP2010/069694
申请日：2010-12-15
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , VERMEIREN, Walter , BOUVART, François , CELIE, Ineke , GARCIA, Wolfgang
发明人： VERMEIREN, Walter , BOUVART, François , CELIE, Ineke , GARCIA, Wolfgang
IPC分类号： C10G9/00 , C10G51/04 , C10G69/06
摘要： The present invention is a method for debottlenecking an existing steam cracker unit of which the operation is modified from high severity to low severity operation, having a cracking zone and a fractionation zone, said fractionation zone comprising a gasoline stripper, a de-methaniser (I), a de-ethaniser (I), a de-propaniser (I) and a de-butaniser (I), said de-propaniser (I) receiving product from the bottom of the de-ethaniser (I) and optionally product from the bottom of the gasoline stripper (I), wherein said debottlenecking method comprises the steps of : a) adding a selective hydrogenation unit (II), b) adding a cracking reactor (II) comprising a catalyst selective towards light olefins in the outlet, c) adding a re-run column and a de-propaniser (II), d) sending a part or all of the bottoms stream of the gasoline stripper (I) to the selective hydrogenation unit (II) and subsequently to the cracking reactor (II) at conditions effective to produce an outlet with an olefin content of lower molecular weight than that of the inlet, e) sending a part of the bottoms stream of the de-ethaniser (I) to the de-propaniser (II), such as, not to overload the de-propaniser (I), f) optionally sending a part or all of the overhead raw C 4 fraction of the de-butaniser (I) to the selective hydrogenation unit (II), g) sending the cracking reactor (II) outlet to the re-run column to produce a C 6 + bottom stream and a C 1 -C 5 overhead, sending said overhead to the de-propaniser (II) to produce a C 1 -C 3 overhead and a C 4 + bottom stream recycled in whole or in part to the selective hydrogenation unit (II), optionally withdrawing a part of said C 4 + bottom stream.

32. 发明申请

WO2011012438A1 USE OF FREE FATTY ACIDS PRODUCED FROM BIO-SOURCED OILS&FATS AS THE FEEDSTOCK FOR A STEAMCRACKER 审中-公开
标题翻译：使用从生物来源的油和脂肪生产的免费脂肪酸作为蒸馏器的饲料
公开(公告)号：WO2011012438A1
公开(公告)日：2011-02-03
申请号：PCT/EP2010/060024
申请日：2010-07-13
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , VANRYSSELBERGHE, Valérie , VERMEIREN, Walter
发明人： VANRYSSELBERGHE, Valérie , VERMEIREN, Walter
IPC分类号： C10G3/00
CPC分类号： C10G3/00 , C10G2300/1007 , C10G2300/1014 , C10G2300/1018 , C10G2300/1044 , C10G2300/1059 , C10G2300/807 , C10G2400/02 , C10G2400/20 , C10G2400/22 , C10G2400/30 , Y02P30/20
摘要： Use of fatty acids produced from a complex mixture of natural occurring oils & fats and/or of triglycerides deriving from said complex mixture as the feedstock of a steamcracker, by mixing the fatty acids with steam in a steam/feedstock ratio of at least 0.2 kg per kg, a coil outlet temperature of at least 700 °C and a coil outlet pressure of at least 1.2 bara in order to obtain cracking products including bio-ethylene, bio-propylene, bio-butadiene,bio-isoprene, bio-cyclopentadiene and bio-piperylenes, bio-benzene, bio-toluene, bio-xylene and bio-gasoline.
摘要翻译：将由所述复合混合物衍生的天然存在的油脂和/或甘油三酯的复合混合物产生的脂肪酸用作蒸汽裂化器的原料，通过将蒸汽/原料比至少为0.2kg的脂肪酸与蒸汽混合每公斤，线圈出口温度至少为700℃，线圈出口压力为至少1.2巴，以获得包括生物乙烯，生物 - 丙烯，生物 - 丁二烯，生物异戊二烯，生物 - 环戊二烯的裂解产物和生物胡椒碱，生物苯，生物甲苯，生物二甲苯和生物汽油。

33. 发明申请

WO2009156436A2 PROCESS TO MAKE OLEFINS FROM ORGANICS 审中-公开
标题翻译：从有机物制备烯烃的方法
公开(公告)号：WO2009156436A2
公开(公告)日：2009-12-30
申请号：PCT/EP2009/057890
申请日：2009-06-24
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , NESTERENKO, Nikolai , VERMEIREN, Walter , GRASSO, Giacomo , VAN DONK, Sander , GARCIA, Wolfgang
发明人： NESTERENKO, Nikolai , VERMEIREN, Walter , GRASSO, Giacomo , VAN DONK, Sander , GARCIA, Wolfgang
IPC分类号： C07C1/20 , C07C4/06 , B01J37/28 , B01J29/40
CPC分类号： C07C1/20 , B01J21/08 , B01J21/16 , B01J27/14 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/90 , B01J38/12 , B01J2229/16 , B01J2229/18 , B01J2229/36 , B01J2229/37 , C07C1/26 , C07C1/322 , C07C4/06 , C07C2529/40 , Y02P20/584 , Y02P30/42 , C07C11/02
摘要： The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : aθ) providing a first portion and a second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock, a) providing a catalyst comprising zeolitic molecular sieves containing at least 10 membered ring pore openings or larger in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, optionally at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting the first portion of said oxygen-containing, halogenide- containing or sulphur-containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; d) separating said light olefins from said heavy hydrocarbon fraction; e) contacting said heavy hydrocarbon fraction and the second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the OC reactor with the catalyst at conditions effective to convert at least a portion of said heavy hydrocarbon fraction and oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to light olefins.
摘要翻译：本发明涉及一种在组合的XTO-OC方法中由含氧的含卤化物或含硫有机原料制备轻质烯烃的方法，该方法包括：a）提供第一部分和第二部分所述含氧，含卤素或含硫有机原料，a）提供包含在其微孔结构中含有至少10元环孔或更大孔的沸石分子筛的催化剂，b）提供XTO反应区，OC反应区和催化剂再生区，所述催化剂在三个区域中循环，使得至少一部分再生催化剂通过OC反应区，任选地，将OC反应区中的至少一部分催化剂传递至XTO 反应区和XTO反应区中的至少一部分催化剂通入再生区; c）在有效地转化至少一部分原料以形成包含轻质烯烃的XTO反应器流出物的条件下，将XTO反应器中的含氧卤化物或含硫有机原料的第一部分与催化剂接触，重质烃馏分; d）从所述重质烃馏分中分离出所述轻质烯烃; e）在OC反应器中将所述重质烃部分和第二部分所述含氧卤化物或含硫有机原料与所述催化剂接触，所述条件有效地将至少一部分所述重质烃部分和氧 - 含卤素或含硫有机原料转化成轻质烯烃。

34. 发明申请

WO2009098268A1 DEHYDRATION OF ALCOHOLS IN THE PRESENCE OF AN INERT COMPONENT 审中-公开
标题翻译：酒精中存在异味组分时的脱水
公开(公告)号：WO2009098268A1
公开(公告)日：2009-08-13
申请号：PCT/EP2009/051341
申请日：2009-02-05
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , MINOUX, Delphine , NESTERENKO, Nikolai , VERMEIREN, Walter , VAN DONK, Sander
发明人： MINOUX, Delphine , NESTERENKO, Nikolai , VERMEIREN, Walter , VAN DONK, Sander
IPC分类号： C07C1/24 , C07C11/02 , C07C11/04
CPC分类号： C07C11/02 , C07C1/24 , C07C11/04
摘要： The present invention (first embodiment) relates to a process for the dehydration of at least an alcohol to make at least an olefin, comprising : a) introducing in a reactor a stream (A) comprising at least an alcohol optionally in aqueous solution and an inert component, b) contacting said stream with a catalyst in said reactor at conditions effective to dehydrate at least a portion of the alcohol to make an olefin, c) recovering from said reactor a stream (B) comprising : the inert component and at least an olefin, water and optionally unconverted alcohol, d) optionally fractionating the stream (B) to recover the unconverted alcohol and recycling said unconverted alcohol to the reactor of step a), e) optionally fractionating the stream (B) to recover the inert component and the olefin and recycling said inert component to the reactor of step a), Wherein, the inert component is selected among ethane, the hydrocarbons having from 3 to 10 carbon atoms, naphtenes and CO2, the proportion of the inert component is such as the reactor operates essentially adiabatically. The present invention also relates to a similar process as above but the catalyst is : • a crystalline silicate having a ratio Si/AI of at least 100, or • a dealuminated crystalline silicate, or • a phosphorus modified zeolite, the WHSV of the alcohol is at least 2 h -1 when the catalyst is a crystalline silicate having a ratio Si/AI of at least 100 or a dealuminated crystalline silicate. Advantageously the pressure of the dehydration reactor is high enough to help the recovery of the inert component and recycling thereof in the reactor of step a) without a gas compressor but only a pump.
摘要翻译：本发明（第一实施方案）涉及使至少一种醇脱水以制备至少一种烯烃的方法，其包括：a）在反应器中引入任选在水溶液中至少包含醇的流（A），和惰性组分，b）在有效使至少一部分醇脱水以制备烯烃的条件下使所述料流与催化剂在所述反应器中接触，c）从所述反应器回收包含惰性组分并且至少烯烃，水和任选未转化的醇，d）任选地将料流（B）分馏以回收未转化的醇并将所述未转化的醇再循环到步骤a）的反应器中，e）任选地将料流（B）分馏以回收惰性组分和烯烃，并将所述惰性组分再循环到步骤a）的反应器中，其中惰性组分选自乙烷，具有3至10个碳原子的烃，萘和CO 2，比例的惰性组分如反应器基本上绝热地进行操作。本发明还涉及上述类似的方法，但催化剂是：Si / Al比为至少100的结晶硅酸盐，或脱铝结晶硅酸盐或磷改性沸石，醇的WHSV至少为 2 h-1，当催化剂是Si / Al比为至少100的结晶硅酸盐或脱铝结晶硅酸盐时。有利地，脱水反应器的压力足够高以帮助惰性组分的回收和在步骤a）的反应器中的回收，而没有气体压缩机，而仅仅是泵。

35. 发明申请

WO2009016154A1 MIXTURES OF MOLECULAR SIEVES COMPRISING MEAPO, THEIR USE IN CONVERSION OF ORGANICS TO OLEFINS. 审中-公开
标题翻译：包含MEAPO的分子筛的混合物，它们在有机物转化成烯烃中的用途。
公开(公告)号：WO2009016154A1
公开(公告)日：2009-02-05
申请号：PCT/EP2008/059884
申请日：2008-07-28
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , VERMEIREN, Walter , NESTERENKO, Nikolai
发明人： VERMEIREN, Walter , NESTERENKO, Nikolai
IPC分类号： B01J29/00 , C07C1/20
CPC分类号： C07C1/20 , B01J29/005 , B01J29/035 , B01J29/84 , B01J29/85 , C07C1/322 , Y02P30/42 , C07C11/02
摘要： The present invention is a mixture comprising by weight 0.01 to 28% of at least one medium or large pore crystalline silicoaluminate, silicoaluminophosphate materials or silicoaluminate mesoporous molecular sieves (co-catalyst) (A) for respectively 99.99 to 72% of at least a MeAPO molecular sieve. Preferably the proportion of (A) is 1 to 15% for respectively 99 to 85% of MeAPO molecular sieves. MeAPO molecular sieves having CHA (SAPO-34) or AEI (SAPO-18) structure or mixture thereof are the most preferable. Si is the most desirable metal in MeAPO. The present invention also relates to catalysts consisting of the above mixture or comprising the above mixture. The present invention also relates to a process (hereunder referred as "XTO process") for making an olefin product from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock wherein said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock is contacted with the above catalyst (in the XTO reactor) under conditions effective to convert the oxygen- containing, halogenide-containing or sulphur-containing organic feedstock to olefin products (the XTO reactor effluent). The present invention also relates to a process (hereunder referred as "combined XTO and OCP process") to make light olefins from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : contacting said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with the above catalyst at conditions effective to convert at least a portion of the feedstock to form an XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; separating said light olefins from said heavy hydrocarbon fraction; contacting said heavy hydrocarbon fraction in the OCP reactor at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins.
摘要翻译：本发明是一种混合物，其包含0.01-28％的至少一种中孔或大孔结晶硅铝酸盐，硅铝磷酸盐物质或硅铝酸盐介孔分子筛（助催化剂）（A），分别为99.99至72％的至少MeAPO 分子筛。优选地，对于99〜85％的MeAPO分子筛，（A）的比例为1〜15％。具有CHA（SAPO-34）或AEI（SAPO-18）结构的MeAPO分子筛或其混合物是最优选的。 Si是MeAPO中最理想的金属。本发明还涉及由上述混合物组成或包含上述混合物的催化剂。本发明还涉及从含氧，含卤素或含硫有机原料制造烯烃产物的方法（以下称为“XTO法”），其中所述含氧卤化物或含硫的在有效地将含氧卤化物或含硫有机原料转化为烯烃产物（XTO反应器流出物）的条件下，有机原料与上述催化剂（在XTO反应器中）接触。本发明还涉及从含氧的含卤化物或含硫有机原料制备轻质烯烃的方法（以下称为“组合的XTO和OCP方法”），包括：使含有氧的含卤素的或含硫有机原料在具有上述催化剂的XTO反应器中，在有效地转化至少一部分原料以形成包含轻质烯烃和重质烃馏分的XTO反应器流出物的条件下; 将所述轻质烯烃与所述重质烃馏分分离; 在有效将至少一部分所述重质烃馏分转化为轻质烯烃的条件下使OCP反应器中的所述重质烃馏分接触。

36. 发明申请

WO2009010407A1 PROCESS FOR THE SELECTIVE OXIDATION OF METHANE 审中-公开
标题翻译：甲烷选择性氧化方法
公开(公告)号：WO2009010407A1
公开(公告)日：2009-01-22
申请号：PCT/EP2008/058690
申请日：2008-07-04
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , DE WINNE, Hendrik , JACOBS, Pierre , SELS, Bert , VERMEIREN, Walter
发明人： DE WINNE, Hendrik , JACOBS, Pierre , SELS, Bert , VERMEIREN, Walter
IPC分类号： C07C29/50 , C07C31/04 , B01J19/00 , B01J19/24
CPC分类号： C07C29/50 , B01J19/0093 , B01J19/02 , B01J19/242 , B01J19/249 , B01J2219/00085 , B01J2219/00159 , B01J2219/00826 , B01J2219/00873 , B01J2219/024 , B01J2219/0281 , B01J2219/2461 , B01J2219/2487 , C07C31/04
摘要： The present invention is a process for converting methane to methanol, comprising: feeding methane and gaseous air or oxygen or gaseous air enriched with oxygen to a reactor under an elevated pressure; said reactor having an internal surface, made of silica or coated with silica, surrounding a zone in which said gases react; and reacting said gases in said reaction zone at an elevated temperature at conditions effective to produce methanol and /or valuable oxygenates. Advantageously the internal surface is made of quartz or coated with quartz Advantageously the internal surface, made of silica (advantageously quartz) or coated with silica (advantageously quartz), is treated with HF before the conversion of methane to methanol. Advantageously the reaction is carried out in the absence in said reaction zone of any added material which measurably affects the rate of the reaction or the yield of the product. Advantageously the reactor is operated under a pressure from 1 to 7.5 MPa. Advantageously the reactor is operated at a temperature from 300°C to 600°C. Advantageously the reactor is operated at a residence time from 0.1 to 100s. Advantageously the reactor is operated at a methane to oxygen molar ratio from 1 to 50. The present invention also relates to a reactor having an internal surface made of silica (advantageously quartz) or coated with silica (advantageously quartz)
摘要翻译：本发明是一种将甲烷转化成甲醇的方法，包括：在升高的压力下将甲烷和气态空气或富含氧气的氧气或气态空气送入反应器; 所述反应器具有由二氧化硅制成或涂覆有二氧化硅的内表面，所述内表面围绕所述气体反应的区域; 并在有效产生甲醇和/或有价值的含氧化合物的条件下，在升高的温度下使所述反应区中的所述气体反应。有利地，内表面由石英制成或用石英涂覆。有利的是，在将甲烷转化成甲醇之前，用HF处理由二氧化硅（有利的是石英）或用二氧化硅（有利的是石英）制成的内表面。有利地，反应在所述反应区中不存在可测量地影响反应速率或产物收率的任何添加物质。有利地，反应器在1至7.5MPa的压力下操作。有利地，反应器在300℃至600℃的温度下操作。有利地，反应器在0.1至100s的停留时间下运行。有利地，反应器以甲烷与氧的摩尔比为1至50进行操作。本发明还涉及具有由二氧化硅（有利地为石英）或用二氧化硅（有利地为石英）涂覆的内表面的反应器，

37. 发明申请

WO2008110526A1 METALLOALUMINOPHOSPHATE MOLECULAR SIEVES WITH LAMELLAR CRYSTAL MORPHOLOGY AND THEIR PREPARATION 审中-公开
标题翻译：金刚石磷酸酯分子筛与晶体晶体形态及其制备
公开(公告)号：WO2008110526A1
公开(公告)日：2008-09-18
申请号：PCT/EP2008/052807
申请日：2008-03-10
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) , VERMEIREN, Walter , NESTERENKO, Nikolai , PETITTO, Carolina , DI RENZO, Francesco , FAJULA, François
发明人： VERMEIREN, Walter , NESTERENKO, Nikolai , PETITTO, Carolina , DI RENZO, Francesco , FAJULA, François
IPC分类号： C01B37/08 , C07C1/32 , C07C1/26 , C07C1/20 , B01J29/85
CPC分类号： B01J29/85 , B01J29/005 , B01J29/84 , B01J35/026 , B01J2029/062 , C01B37/06 , C01B37/08 , C01B39/54 , C07C1/20 , C07C1/26 , C07C1/322 , C07C2529/85 , Y02P20/52 , Y02P30/42 , C07C11/04 , C07C11/06
摘要： The present invention relates to metalloaluminophosphate (MeAPO) molecular sieve with lamellar crystal morphology having an empirical chemical composition on an anhydrous basis, after synthesis and calcination, expressed by the formula H x Me y Al z P k O 2 wherein, y+z+k=1 x = 10 and advantageously ranges from 10 to 100. In a preferred embodiment T is 2 insoluble in the TIA, reactive sources of Al 2 O 3 and P 2 O 5 , b) crystallizing the above reaction mixture thus formed until crystals of the metalloaluminophosphate are formed, c) recovering a solid reaction product, d) washing it with water to remove the TIA and e) calcinating it to remove the organic template. In an advantageous embodiment the MeAPO of the invention have essentially a structure CHA or AEI or a mixture thereof. Preferably they have essentially the structure SAPO 18 or SAPO 34 or a mixture thereof. The present invention also relates to catalysts consisting of the above MeAPO molecular sieves or comprising the above MeAPO molecular sieves. The present invention also relates to a process for making an olefin product from an oxygen-containing, halogenide-containing or sulphur-containing feedstock wherein said oxygen-containing, halogenide-containing or sulphur-containing feedstock is contacted with the above catalyst under conditions effective to convert the oxygen-containing, halogenide-containing or sulphur-containing feedstock to olefin products.
摘要翻译：本发明涉及具有层状晶体形态的金属铝磷酸盐（MeAPO）分子筛，其具有无水基础上的经验化学组成，在合成和煅烧之后，由式H x表示，其中，y + z + k = 1 x <= y表示主要是平板晶体的分子筛宽度（W）和厚度（T）的形态如下：W / T> 10，有利地在10至100的范围内。在优选实施例中，T <0.15μm，更优选<=0.10μm 更优选<=0.08μm，有利地在0.01〜0.07μm的范围内，优选为0.04〜0.07μm。上述金属铝磷酸盐（MeAPO）分子筛可以通过以下方法制备：a）形成含有纹理影响剂（TIA），有机模板剂（TEMP），至少一种反应性无机的MeO _{2 不溶于TIA的Al 2 N 3 O 3和P 2 O 5的反应性源 b）使如此形成的上述反应混合物结晶直到形成金属磷酸铝的晶体，c）回收固体反应产物，d）用水洗涤以除去TIA，和e）煅烧以除去有机模板。在有利的实施方案中，本发明的MeAPO基本上具有结构CHA或AEI或其混合物。优选地，它们基本上具有结构SAPO 18或SAPO 34或其混合物。本发明还涉及由上述MeAPO分子筛组成或包含上述MeAPO分子筛的催化剂。本发明还涉及一种由含氧卤化物或含硫原料制备烯烃产物的方法，其中所述含氧卤化物或含硫原料在有效的条件下与上述催化剂接触以将含氧的含卤化物或含硫原料转化为烯烃产物。}

38. 发明申请

WO2008012219A1 CATALYTIC CONVERSION OF ALKYLAROMATIC COMPOUNDS 审中-公开
标题翻译：烷基化合物的催化转化
公开(公告)号：WO2008012219A1
公开(公告)日：2008-01-31
申请号：PCT/EP2007/057261
申请日：2007-07-13
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , DATH, Jean-Pierre , VERMEIREN, Walter
发明人： DATH, Jean-Pierre , VERMEIREN, Walter
IPC分类号： C07C4/18 , C07C11/04 , C07C11/06 , C07C15/04 , B01J29/06
CPC分类号： C07C4/18 , B01J29/035 , B01J29/06 , B01J29/70 , Y02P20/52 , C07C11/06 , C07C11/04
摘要： A process for catalytically converting alkylaromatic compounds in a hydrocarbon feedstock, the process comprising passing a hydrocarbon feedstock including at least one alkylaromatic compound, wherein the alkyl group comprises at least two carbon atoms, through a reactor containing a crystalline silicate catalyst to produce an effluent including at least one aromatic compound and at least one light olefin selected from C 2 and C 3 olefins.
摘要翻译：一种用于在烃原料中催化转化烷基芳族化合物的方法，该方法包括使包含至少一种烷基芳族化合物的烃原料（其中烷基包含至少两个碳原子）通过含有结晶硅酸盐催化剂的反应器，以产生流出物，其包括至少一种芳族化合物和至少一种选自C 2和C 3 O 3烯烃的轻质烯烃。

39. 发明申请

WO2007068734A1 CATALYTIC CRACKING 审中-公开
标题翻译：催化裂化
公开(公告)号：WO2007068734A1
公开(公告)日：2007-06-21
申请号：PCT/EP2006/069697
申请日：2006-12-14
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , DATH, Jean-Pierre , VERMEIREN, Walter , NOIRET, André
发明人： DATH, Jean-Pierre , VERMEIREN, Walter , NOIRET, André
IPC分类号： B01J29/40 , B01J29/08 , C10G11/05 , B01J37/00
CPC分类号： B01J29/40 , B01J29/084 , B01J29/80 , B01J37/0045 , B01J2229/16 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C10G11/05
摘要： A process for producing a catalyst additive for an FCC catalytic cracking process, the process comprising the steps of providing an MFI or MEL aluminosilicate having a silicon/aluminium atomic ratio of from 10 to 250; de-aluminating the MFI or MEL aluminosilicate by extracting from 20 to 40 wt% of the alumina therefrom; combining the de-aluminated MFI or MEL aluminosilicate with a binder; and calcining the combination of the de-aluminated MFI or MEL aluminosilicate and the binder at elevated temperature to produce the catalyst additive.
摘要翻译：一种生产用于FCC催化裂化过程的催化剂添加剂的方法，该方法包括以下步骤：提供硅/铝原子比为10至250的MFI或MEL硅铝酸盐; 通过从其中提取20至40重量％的氧化铝，使MFI或MEL硅铝酸盐脱铝; 将脱铝的MFI或MEL硅铝酸盐与粘合剂组合; 并在升高的温度下煅烧脱铝的MFI或MEL硅铝酸盐和粘合剂的组合以制备催化剂添加剂。

40. 发明公开

EP2459680A1 USE OF FREE FATTY ACIDS PRODUCED FROM BIO-SOURCED OILS&FATS AS THE FEEDSTOCK FOR A STEAMCRACKER 审中-公开
标题翻译：和油脂从生理的使用而生产的自由脂肪酸作为起始原料蒸汽裂解
公开(公告)号：EP2459680A1
公开(公告)日：2012-06-06
申请号：EP10742105.9
申请日：2010-07-13
申请人： Total Petrochemicals Research Feluy
发明人： VANRYSSELBERGHE, Valérie , VERMEIREN, Walter
IPC分类号： C10G3/00
CPC分类号： C10G3/00 , C10G2300/1007 , C10G2300/1014 , C10G2300/1018 , C10G2300/1044 , C10G2300/1059 , C10G2300/807 , C10G2400/02 , C10G2400/20 , C10G2400/22 , C10G2400/30 , Y02P30/20
摘要： Use of fatty acids produced from a complex mixture of natural occurring oils & fats and/or of triglycerides deriving from said complex mixture as the feedstock of a steamcracker, by mixing the fatty acids with steam in a steam/feedstock ratio of at least 0.2 kg per kg, a coil outlet temperature of at least 700 °C and a coil outlet pressure of at least 1.2 bara in order to obtain cracking products including bio-ethylene, bio-propylene, bio-butadiene,bio-isoprene, bio-cyclopentadiene and bio-piperylenes, bio-benzene, bio-toluene, bio-xylene and bio-gasoline.

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