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    • 35. 发明申请
    • LOW TOXICITY SHALE HYDRATION INHIBITION AGENT AND METHOD OF USE
    • 低毒性SHALE HYDRIC抑制剂及其使用方法
    • US20110190171A1
    • 2011-08-04
    • US13082973
    • 2011-04-08
    • Arvind D. Patel
    • Arvind D. Patel
    • C09K8/06
    • C09K8/12C09K2208/12
    • A low toxicity composition and method of reducing the swelling of clay in well comprising circulating in the well a water-based fluid comprising a functionally effective concentration of the additive formed from the following reaction of a tertiary amine of the following general formula: wherein R1 and R2 are alkyl or hydroxyalkyl groups with one to three carbon atoms or combinations thereof, and R3 is a hydroxyalkyl group with one to three carbon atoms, with an alkylating agent of the following general formula: R-A wherein R is an alkyl radical with one to three carbon atoms, and A is an organic or inorganic anion selected from the group consisting of sulfate, phosphate, carbonate, and combinations thereof.
    • 一种低毒组合物和减少井中粘土膨胀的方法,包括在井中循环的水基流体,其包含由以下通式的叔胺的以下反应形成的功能有效浓度的添加剂:其中R1和 R2是具有1至3个碳原子的烷基或羟烷基或其组合,并且R 3是具有1至3个碳原子的羟烷基,具有以下通式的烷基化剂:其中R是具有1至3个 碳原子,A是选自硫酸盐,磷酸盐,碳酸盐及其组合的有机或无机阴离子。
    • 37. 发明授权
    • Shale hydration inhibition agent and method of use
    • 页岩水化抑制剂及其使用方法
    • US07312183B2
    • 2007-12-25
    • US10958635
    • 2004-10-05
    • Arvind D. PatelEmanuel Stamatakis
    • Arvind D. PatelEmanuel Stamatakis
    • C09K8/035
    • C09K8/22C09K8/20C09K8/24C09K8/68C09K2208/12
    • A water-base fluid for use in drilling, cementing, workover, fracturing and abandonment of subterranean wells through a formation containing shale which swells in the presence of water. In one illustrative embodiment, the drilling fluid is composed of an aqueous based continuous phase, a weighting agent, and a shale hydration inhibition agent. The shale hydration inhibition agent should have the general formula: in which R and R′ independently selected from hydrogen, methyl, ethyl or propyl, and X has a value from 1 to 6. The shale hydration inhibition agent is present in sufficient concentration to substantially reduce the swelling of shale drilling cuttings upon contact with the drilling fluid. The drilling fluid may be formulated to include a wide variety of components of aqueous based drilling fluids, such as weighting agents, fluid loss control agents, suspending agents, viscosifying agents, rheology control agents, as well as other compounds and materials known to one of skill in the art. The fluids may also be used in fracturing and the disposal by reinjection of drilling cutting into a selected subterranean disposal formation.
    • 一种用于钻井,固井,修井,压裂和放弃地下井的水基流体,通过含有在水存在下膨胀的页岩的地层。 在一个说明性实施例中,钻井流体由基于水的连续相,加重剂和页岩水化抑制剂组成。 页岩水化抑制剂应具有以下通式:其中R和R'独立地选自氢,甲基,乙基或丙基,X具有1至6的值。页岩水化抑制剂以足够的浓度存在于基本上 与钻井液接触时减少页岩钻屑的膨胀。 钻井液可以被配制成包括水基钻井液的各种各样的组分,例如加重剂,流体损失控制剂,悬浮剂,增粘剂,流变控制剂,以及其它化合物和材料 艺术技能 流体也可以用于压裂和通过将钻削切割注入到选定的地下处理层中来进行处理。
    • 38. 发明授权
    • Shale hydration inhibition agent and method of use
    • 页岩水化抑制剂及其使用方法
    • US07084092B2
    • 2006-08-01
    • US10647830
    • 2003-08-25
    • Arvind D. PatelEmanuel StamatakisEric DavisJim Friedheim
    • Arvind D. PatelEmanuel StamatakisEric DavisJim Friedheim
    • C09K8/12
    • C09K8/06C09K8/22C09K2208/12Y10S507/922
    • A water-base fluid for use in drilling, cementing, workover, fracturing and abandonment of subterranean wells through a formation containing a shale which swells in the presence of water. In one illustrative embodiment, the drilling fluid includes, an aqueous based continuous phase, a weighting agent, and a shale hydration inhibition agent. The shale hydration inhibition agent should have the general formula: in which A is independently selected from H and CH2CH2CH2NH2; and in which B is independently selected from H, CH2CH2OH, CH2CH2OCH2CH2CH2NH2 and CH2CH2CH2NH2. The shale hydration inhibition agent is present in sufficient concentration to substantially reduce the swelling of shale drilling cuttings upon contact with the drilling fluid. The drilling fluid may be formulated to include a wide variety of components of aqueous based drilling fluids, such as weighting agents, fluid loss control agents, suspending agents, viscosifying agents, rheology control agents, as well as other compounds and materials known to one of skill in the art. The fluids may also be used in the disposal by reinjection of drilling cutting into a selected subterranean disposal formation.
    • 一种用于通过含有在水存在下膨胀的页岩的地层的钻井,固井,修井,压裂和放弃地下井的水基流体。 在一个说明性实施例中,钻井流体包括水基连续相,加重剂和页岩水合抑制剂。 页岩水化抑制剂应具有以下通式:其中A独立地选自H和CH 2 CH 2 CH 2 H 2 N 2 并且其中B独立地选自H,CH 2 CH 2 OH,CH 2 CH 2 OCH 2, 2> 2 CH 2 2 CH 2 NH 2和CH 2 CH 2 2 < / 2 NH 2。 页岩水化抑制剂以足够的浓度存在,以在与钻井液接触时基本上减少页岩钻屑的膨胀。 钻井液可以被配制成包括水基钻井液的各种各样的组分,例如加重剂,流体损失控制剂,悬浮剂,增粘剂,流变控制剂,以及其它化合物和材料 艺术技能 流体还可以通过将钻削切割注入到选定的地下处理层中而用于处理。
    • 39. 发明授权
    • High performance water based drilling mud and method of use
    • 高性能水基钻井泥浆及其使用方法
    • US06831043B2
    • 2004-12-14
    • US10062071
    • 2002-01-31
    • Arvind D. PatelEmanuel StamatakisEric DavisJim Friedheim
    • Arvind D. PatelEmanuel StamatakisEric DavisJim Friedheim
    • C09K702
    • C09K8/22C09K8/24C09K2208/12
    • A water-base fluid for use in drilling wells and other drilling operation includes a shale clay which swells in the presence of water. The fluid preferably includes: an aqueous based continuous phase, and a shale hydration inhibition agent having the formula: wherein R and R′ are independently selectable alkylene groups having 2 to 4 carbon atoms, and wherein x and y have independently selected values such that the sum of x and y is at least 1. The shale hydration inhibition agent should be present in sufficient concentration to reduce the swelling of the shale clay. The fluid may be used for formulating drilling fluids such as water-base drilling muds or clear brine drilling fluids. The fluid may also be used in the slurrification and disposal of drill cuttings that contain water swellable clays or shale clays.
    • 用于钻井和其他钻井操作的水基流体包括在水存在下膨胀的页岩粘土。 流体优选包括:基于水性的连续相和具有下式的页岩水化抑制剂:其中R和R'独立地是可选择的具有2至4个碳原子的亚烷基,并且其中x和y具有独立选择的值,使得 x和y之和至少为1.页岩水化抑制剂应以足够的浓度存在,以减少页岩粘土的溶胀。 流体可以用于配制钻井液,例如水基钻井泥浆或透明盐水钻井液。 该流体也可用于含有可溶胀的粘土或页岩粘土的钻屑的脱气和处理。