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    • 35. 发明授权
    • Continuous emulsification-aggregation process for the production of particles
    • 连续乳化聚集工艺生产颗粒
    • US08685612B2
    • 2014-04-01
    • US13008278
    • 2011-01-18
    • Santiago FaucherKimberly D. NosellaLai Chi So
    • Santiago FaucherKimberly D. NosellaLai Chi So
    • G03G9/08
    • B01J19/1862B01F13/1016G03G9/0804
    • A continuous emulsion aggregation process for the production of particles is presented including a plurality of continuous stirred-tank reactors (CSTR). The plurality of continuous stirred-tank reactors includes a first reactor and a second reactor for facilitating an aggregation process; a third reactor for facilitating a shell addition process; a fourth reactor for facilitating a freeze process; a fifth reactor for facilitating a chelating process; a sixth reactor for facilitating a ramp-up process; and a seventh reactor for facilitating a coalescence process. The reactors are sequentially assembled in a series configuration, each of the reactors cooperating with an overhead stirrer. In other embodiments, a CSTR system of the present disclosure possesses five reactors sequentially assembled in a series configuration to form toner particles.
    • 提出了用于生产颗粒的连续乳液聚集方法,包括多个连续搅拌釜反应器(CSTR)。 多个连续搅拌釜反应器包括用于促进聚集过程的第一反应器和第二反应器; 用于促进壳添加过程的第三反应器; 用于促进冷冻过程的第四反应器; 用于促进螯合过程的第五反应器; 用于促进加速过程的第六反应堆; 以及用于促进聚结过程的第七反应器。 反应器依次组装成串联构造,每个反应器与顶部搅拌器配合。 在其它实施方案中,本公开的CSTR系统具有顺序地以串联配置组装以形成调色剂颗粒的五个反应器。
    • 37. 发明授权
    • Reactive ink components and methods for forming images using reactive inks
    • 活性油墨组分和使用反应性油墨形成图像的方法
    • US08342669B2
    • 2013-01-01
    • US12562839
    • 2009-09-18
    • Santiago FaucherCheryl Lynn PearcePeter G. OdellDavid Allen MantellEmily L. Moore
    • Santiago FaucherCheryl Lynn PearcePeter G. OdellDavid Allen MantellEmily L. Moore
    • C09D11/00
    • C09D11/40C09D11/101C09D11/38
    • An ink set including at least two inks. A first ink includes an optional colorant, a first multi-functional monomer, a second multi-functional monomer that is different from the first multi-functional monomer, and a peroxide initiator comprising a thermal free radical initiator. A second ink includes an optional colorant, a first multi-functional monomer, a second multi-functional monomer that is different from the first multi-functional monomer, and an amine activator having a catalyst which catalyzes the homolytic cleavage of the thermal free-radical initiator at low temperatures into radicals. The first ink is free of the amine activator and the second ink is free of the peroxide initiator. The first multi-functional monomer and the second multi-functional monomer accelerate reaction kinetics through a Trommsdorff effect. The components are each present in an amount relative to the other that provides a) early onset of gelation that accelerates polymerization, and b) an ink viscosity that is suitable for jetting from an ink jet printer.
    • 一种包含至少两种油墨的油墨组。 第一油墨包括任选的着色剂,第一多官能单体,不同于第一多官能单体的第二多官能单体和包含热自由基引发剂的过氧化物引发剂。 第二油墨包括任选的着色剂,第一多官能单体,不同于第一多官能单体的第二多官能单体,以及具有催化剂的胺活化剂,其催化热自由基的均裂裂解 引发剂在低温进入自由基。 第一种油墨不含胺活化剂,第二种油墨不含过氧化物引发剂。 第一多官能单体和第二多功能单体通过Trommsdorff效应加速反应动力学。 组分各自以相对于另一种的量存在,其提供a)加速聚合的凝胶化的早期开始,和b)适合于从喷墨打印机喷射的油墨粘度。
    • 40. 发明授权
    • Production of polyesters in a continuous packed-bed reactor using immobilized enzyme catalysts
    • 在使用固定化酶催化剂的连续填充床反应器中生产聚酯
    • US08119763B2
    • 2012-02-21
    • US12240421
    • 2008-09-29
    • Jordan H. WosnickSantiago Faucher
    • Jordan H. WosnickSantiago Faucher
    • C08C19/20
    • C12P7/62C08G63/06C08G63/785C12P7/6436G03G9/08755
    • In accordance with various embodiments, there is a method of making a polyester. The method can include providing a monomer solution, the monomer solution including one or more cyclic esters in a concentration ranging from about 1 to about 100% and one or more solvents in a concentration ranging from about 99% to about 0%. The method of making a polyester can also include providing a packed-bed reactor including one or more immobilized enzymes, wherein the packed-bed reactor has an inlet and an outlet. The method can further include circulating the monomer solution through the packed-bed reactor to generate a solution enriched with polyester, such that the one or more immobilized enzymes convert the one or more cyclic esters to polyester in the packed-bed reactor during circulation and collecting the solution enriched with polyester exiting through the outlet.
    • 根据各种实施方案,有一种制备聚酯的方法。 该方法可以包括提供单体溶液,所述单体溶液包含浓度范围为约1至约100%的一种或多种环酯和浓度范围为约99%至约0%的一种或多种溶剂。 制备聚酯的方法还可以包括提供包含一种或多种固定化酶的填充床反应器,其中填充床反应器具有入口和出口。 该方法还可以包括使单体溶液循环通过填充床反应器以产生富含聚酯的溶液,使得一个或多个固定化酶在循环和收集期间将填料床反应器中的一种或多种环酯转化为聚酯 富含聚酯的溶液通过出口排出。