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31. 发明授权

US06268529B1 Method for the manufacture of acrylic acid 失效
标题翻译：使用碱金属，钙，铁，铋和钼的混合氧化物催化剂制造丙烯酸的方法
公开(公告)号：US06268529B1
公开(公告)日：2001-07-31
申请号：US09207837
申请日：1998-12-08
申请人： Dev Dhanaraj Suresh , Christos Paparizos , Patrick Eugene Mosier , Ying Wu , Maria Strada Friedrich , Michael J. Seely
发明人： Dev Dhanaraj Suresh , Christos Paparizos , Patrick Eugene Mosier , Ying Wu , Maria Strada Friedrich , Michael J. Seely
IPC分类号： C07C5116
CPC分类号： C07C51/252 , B01J2523/00 , C07C57/04 , B01J2523/13 , B01J2523/15 , B01J2523/22 , B01J2523/23 , B01J2523/3712 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/847 , B01J2523/845
摘要： A process for the manufacture of acrylic acid comprising reacting propylene and oxygen (preferably in the form of air) in a reaction zone having a catalyst characterized by the following formula: AaBbCcCadFeeBifMo12Ox where A=one or more of Li, Na, K, Rb and Cs B=one or more of Mg, Sr, Mn, Ni, Co and Zn C=one or more of Ce, Cr, Al, Sb, P, Ge, Sn, Cu, V and W and a=0.01 to 1.0; b and e =1.0-10 c=0 to 5.0, preferably 0.05 to 5.0, especially preferred being 0.05 to 4.0 d and f=0.05 to 5.0, and x is a number determined by the valence requirements of the other elements present; at an elevated temperature to produce acrylic acid and acrolein.
摘要翻译：一种制备丙烯酸的方法，其包括在具有催化剂的反应区中使丙烯和氧（优选空气形式）反应，其特征在于下式：其中A = Li，Na，K，Rb和CsB中的一种或多种= Ce，Cr，Al，Sb，P，Ge，Sn，Cu，V和Wanda中的一种或多种中的一种或多种Mg，Sr，Mn，Ni，Co和ZnC = 0.01至1.0; b和e = 1.0-10c = 0〜5.0，优选为0.05〜5.0，特别优选为0.05〜4.0d，f = 0.05〜5.0，x为通过存在的其他元素的化合价要求决定的数; 产生丙烯酸和丙烯醛的温度。

32. 发明授权

US5840648A Catalyst for the manufacture of acrylonitrile and hydrogen cyanide 失效
标题翻译：用于制造丙烯腈和氰化氢的催化剂
公开(公告)号：US5840648A
公开(公告)日：1998-11-24
申请号：US923878
申请日：1997-09-02
申请人： Dev Dhanaraj Suresh , Christos Paparizos , Michael J. Seely , Maria Strada Friedrich , Tama Lee Drenski
发明人： Dev Dhanaraj Suresh , Christos Paparizos , Michael J. Seely , Maria Strada Friedrich , Tama Lee Drenski
IPC分类号： B01J23/00 , B01J23/31 , B01J23/76 , B01J23/84 , B01J23/843 , B01J23/88 , B01J23/887 , B01J23/89 , B01J27/192 , B01J27/199 , B01J37/00 , B01J37/08 , C01C3/02 , C01G53/00 , C07B61/00 , C07C253/18 , C07C253/24 , C07C253/26 , C07C255/08 , B01J23/04 , B01J23/18
CPC分类号： C07C253/18 , B01J23/002 , B01J23/31 , B01J23/8876 , B01J37/08 , C01C3/0216 , C01G53/006 , B01J2523/00 , B01J37/0045 , Y02P20/52
摘要： A catalyst composition comprising a complex of catalytic oxides of iron, bismuth, molybdenum and calcium and characterized by the following empirical formula: A.sub.a B.sub.b C.sub.c D.sub.d Fe.sub.e Bi.sub.f MO.sub.12 O.sub.x where A=one or more of Li, Na, K, Rb and Cs or mixtures thereof B=one or more of Mg, Mn, Ni, Co, Ag, Pb, Re, Cd and Zn or mixtures thereof C=one or more of Ce, Cr, Al, Sb, P, Ge, La, Sn, V and W or mixtures thereofD=one or more of Ca, Sr, Ba or mixtures thereof and a=0.01 to 1.0; b and e=1.0-10; c, d, and f=0.1 to 5.0 and x is a number determined by the valence requirements of the other elements present.
摘要翻译：一种催化剂组合物，其包含铁，铋，钼和钙的催化氧化物的络合物，其特征在于以下经验式：AaBbCcDdFeeBifMO12Ox其中A = Li，Na，K，Rb和Cs中的一种或多种或其混合物B =一种或多种 Mg，Mn，Ni，Co，Ag，Pb，Re，Cd和Zn或其混合物C = Ce，Cr，Al，Sb，P，Ge，La，Sn，V和W中的一种或多种或其混合物D = Ca，Sr，Ba或其混合物中的一种或多种，a = 0.01至1.0; b和e = 1.0-10; c，d和f = 0.1〜5.0，x是由存在的其他元素的化合价要求决定的数。

33. 发明授权

US3994972A Synthesis of N,N',N",N'"-tetra-salicylidene pentaerythrityl tetramine 失效
标题翻译：合成N，N {40，N {41，N {40 {41-四亚水杨基季戊四醇四嗪
公开(公告)号：US3994972A
公开(公告)日：1976-11-30
申请号：US591872
申请日：1975-06-30
申请人： Michael J. Seely , Thomas C. Peterson
发明人： Michael J. Seely , Thomas C. Peterson
IPC分类号： C07D205/04 , C07C143/78
CPC分类号： C07D205/04
摘要： An improved synthesis of N,N',N",N'"-tetra-salicylidene pentaerythrityl tetramine via pentaerythrityl benzene or toluene sulfonates.
摘要翻译：通过季戊四醇苯或甲苯磺酸改进N，N'，N“，N” - 四 - 亚水杨基季戊四醇四胺的合成。

34. 发明申请

US20110237753A1 Mixed metal oxide ammoxidation catalysts 有权
标题翻译：混合金属氧化物氨氧化催化剂
公开(公告)号：US20110237753A1
公开(公告)日：2011-09-29
申请号：US12661705
申请日：2010-03-23
申请人： James F. Brazdil , Mark A. Toft , Michael J. Seely , Charles J. Besecker , Robert A. Gustaferro
发明人： James F. Brazdil , Mark A. Toft , Michael J. Seely , Charles J. Besecker , Robert A. Gustaferro
IPC分类号： C08F8/30 , B01J23/10 , B01J21/08
CPC分类号： B01J23/8878 , B01J23/002 , B01J23/8871 , B01J23/8876 , B01J35/002 , B01J37/031 , B01J2523/00 , C07C253/26 , Y02P20/52 , B01J2523/12 , B01J2523/13 , B01J2523/15 , B01J2523/22 , B01J2523/3712 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/847 , B01J2523/14 , B01J2523/67 , C07C255/08
摘要： A catalytic composition useful for the conversion of an olefin selected from the group consisting of propylene, isobutylene or mixtures thereof, to acrylonitrile, methacrylonitrile, and mixtures thereof. The catalytic composition comprising a complex of metal oxides comprising bismuth, molybdenum, iron, cerium and other promoter elements, wherein the X-ray diffraction pattern of the catalytic composition has X-ray diffraction peaks at 2θ angle 28±0.3 degrees and 2θ angle 26.5±0.3 degrees, and wherein the ratio of the intensity of the most intense x-ray diffraction peak within 2θ angle 28±0.3 degrees to the intensity of most intense x-ray diffraction peak within 2θ angle 26.5±0.3 degrees is defined as X/Y, and wherein X/Y is greater than or equal to 0.7.
摘要翻译：用于将选自丙烯，异丁烯或其混合物的烯烃转化成丙烯腈，甲基丙烯腈及其混合物的催化组合物。所述催化剂组合物包含包含铋，钼，铁，铈和其它助催化剂元素的金属氧化物的复合物，其中所述催化剂组合物的X射线衍射图在2θ处具有X射线衍射峰; 角度28±0.3度和2度; 角度26.5±0.3度，并且其中最强烈的x射线衍射峰的强度在2θ范围内; 角度28±0.3度，最大强度x射线衍射峰值在2和之内; 角度26.5±0.3度被定义为X / Y，并且其中X / Y大于或等于0.7。

35. 发明申请

US20110218352A1 METHOD OF MAKING MIXED METAL OXIDE CATALYSTS FOR AMMOXIDATION AND/OR OXIDATION OF LOWER ALKANE HYDROCARBONS 失效
标题翻译：制备混合的金属氧化物催化剂用于氧化和/或氧化低碱性烃的方法
公开(公告)号：US20110218352A1
公开(公告)日：2011-09-08
申请号：US12737604
申请日：2009-07-28
申请人： Charles J. Besecker , Bhagya Chandra Sutradhar , Mark A. Toft , James F. Brazdil , Muin S. Haddad , Christos Paparizos , Michael J. Seely
发明人： Charles J. Besecker , Bhagya Chandra Sutradhar , Mark A. Toft , James F. Brazdil , Muin S. Haddad , Christos Paparizos , Michael J. Seely
IPC分类号： C07C253/24 , B01J27/057 , B01J21/08 , B01J37/04 , B01J37/08
CPC分类号： C07C253/24 , B01J23/002 , B01J23/28 , B01J27/0576 , B01J27/132 , B01J37/0045 , B01J2523/00 , Y02P20/52 , C07C255/08 , B01J2523/11 , B01J2523/53 , B01J2523/55 , B01J2523/56 , B01J2523/68 , B01J2523/23 , B01J2523/3712 , B01J2523/3725 , B01J2523/64
摘要： The present invention comprises a method for preparing a mixed oxide catalyst for use in producing acrylonitrile or methacrylonitrile from propane or isobutane by ammoxidation in a gaseous phase via methods of contacting any one of the antimony compound, the molybdenum compound, and the vanadium compound with hydrogen peroxide prior to combining with source compounds for the remaining elements in the catalyst.
摘要翻译：本发明包括通过使任何一种锑化合物，钼化合物和钒化合物与氢气接触的方法，通过气相通过氨氧化制备用于由丙烷或异丁烷生产丙烯腈或甲基丙烯腈的混合氧化物催化剂的方法在与源化合物组合之前用于催化剂中的剩余元素。

36. 发明授权

US07576232B2 In situ modification of molybdenum-based catalysts 有权
标题翻译：钼基催化剂的原位改性
公开(公告)号：US07576232B2
公开(公告)日：2009-08-18
申请号：US11415565
申请日：2006-05-02
申请人： Michael J. Seely , Christos Paparizos
发明人： Michael J. Seely , Christos Paparizos
IPC分类号： C07C253/00
CPC分类号： C07C253/26 , B01J23/002 , B01J23/28 , B01J23/8876 , B01J35/0006 , B01J2523/00 , Y02P20/52 , B01J2523/11 , B01J2523/68 , B01J2523/13 , B01J2523/15 , B01J2523/14 , B01J2523/12 , C07C255/08
摘要： A process for the conversion of a hydrocarbon selected from the group consisting of propylene, isobutylene, propane, isobutane or mixtures thereof, to acrylonitrile, methacrylonitrile, or mixtures thereof, the process comprising the step of reacting in the vapor phase at an elevated temperature and pressure said hydrocarbon with a molecular oxygen-containing gas and ammonia, in the presence of a molybdenum-based ammoxidation catalyst and a catalyst modifier, wherein said catalyst modifier comprises a molybdate or a polymolybdate of at least one element M selected from the group consisting of cesium, rubidium, potassium, sodium, thallium, lithium, nickel, cobalt, iron, chromium, copper, magnesium, manganese, cerium and phosporus, and wherein the ratio of the M elements to Mo in the molybdate or polymolybdate is greater than the ratio for these M elements to Mo in the molybdenum-based catalyst. The catalyst modifier is useful in modifying the performance of molybdenum-based catalyst and inhibiting molybdenum oxide loss for such catalysts.
摘要翻译：一种将选自丙烯，异丁烯，丙烷，异丁烷或其混合物的烃转化为丙烯腈，甲基丙烯腈或其混合物的方法，该方法包括在升高的温度下在气相中反应和在钼基氨氧化催化剂和催化剂改性剂的存在下，用含分子氧的气体和氨压力所述烃，其中所述催化剂改性剂包含选自以下的至少一种元素M的钼酸盐或多钼酸盐：铯，铷，钾，钠，铊，锂，镍，钴，铁，铬，铜，镁，锰，铈和磷，并且其中钼酸盐或多钼酸盐中的M元素与Mo的比例大于对于这些M元素在钼基催化剂中的Mo。催化剂改性剂可用于改性钼基催化剂的性能并抑制这种催化剂的氧化钼损失。

37. 发明授权

US07071140B2 Catalyst for the manufacture of acrylonitrile 有权
标题翻译：用于制造丙烯腈的催化剂
公开(公告)号：US07071140B2
公开(公告)日：2006-07-04
申请号：US10717130
申请日：2003-11-18
申请人： Christos Paparizos , Stephen C. Jevne , Michael J. Seely
发明人： Christos Paparizos , Stephen C. Jevne , Michael J. Seely
IPC分类号： B01J27/057 , C07C253/24
CPC分类号： C07C253/26 , B01J23/002 , B01J23/8876 , B01J23/8878 , B01J27/1853 , B01J27/192 , B01J35/023 , B01J37/0045 , B01J37/0081 , B01J2523/00 , Y02P20/52 , B01J2523/11 , B01J2523/14 , B01J2523/22 , B01J2523/3712 , B01J2523/54 , B01J2523/67 , B01J2523/68 , B01J2523/842 , B01J2523/845 , B01J2523/847 , B01J2523/12 , B01J2523/51 , C07C255/08
摘要： A catalyst comprising a complex of catalytic oxides comprising rubidium, cerium, chromium, iron, bismuth, molybdenum, and at least one of nickel or nickel and cobalt, optionally magnesium, and optionally one of phosphorus, antimony, tellurium, sodium, lithium, potassium, cesium, thallium, boron, germanium, tungsten calcium, wherein the relative ratios of these elements are represented by the following general formula: RbaCebCrcMgdAeFefBigYhMo12Ox wherein A is Ni or the combination of Ni and Co, Y is at least one of P, Sb, Te, Li, Na, K, Cs, Tl, B, Ge, W, Ca, Zn, a rare earth element, or mixtures thereof, a is about 0.01 to about 1, b is about 0.01 to about 3, c is about 0.01 to about 2, d is 0 to about 7, e is about 0.01 to about 10, f is about 0.01 to about 4, g is about 0.05 to about 4, h is 0 to about 3, x is a number determined by the valence requirements of the other elements present, wherein “b”+“c” is greater than “g” and wherein the catalyst is substantially free of manganese, a noble metal and vanadium. The catalyst is useful in processes for the ammoxidation of an olefin selected from the group consisting of propylene, isobutylene or mixtures thereof, to acrylonitrile, methacrylonitrile and mixtures thereof, respectively.
摘要翻译：一种催化剂，其包含包含铷，铈，铬，铁，铋，钼以及镍或镍和钴，任选的镁中的至少一种的催化氧化物的复合物，以及任选的磷，锑，碲，钠，锂，钾，铯，铊，硼，锗，钨钙，其中这些元素的相对比例由以下通式表示：<？in-line-formula description =“In-line formula”end =“lead”？> Rb 另一方面，C C C ＆lt;＆lt;＆lt;＆lt;＆lt;＆lt;＆lt;＆lt;＆lt;＆lt; 其中A为Ni或Ni和Co的组合，Y为P，Sb，Te，Li，Na，K，Cs，Tl，B，Ge，W中的至少一种，Ca，Zn，稀土元素或其混合物，a为约0.01至约1，b为约0.01至约3，c为约0.01至约2，d为0至约7，e为约0.01至约10，f约为0.01 4，g为约0.05至约4，h为0至约3，x为由其它存在的元素的化合价要求确定的数，其中“b”+“c”大于“g”，其中催化剂基本上不含锰，贵金属和钒。该催化剂可用于分别选自丙烯，异丁烯或其混合物的烯烃与丙烯腈，甲基丙烯腈及其混合物的氨氧化反应的方法。

38. 发明授权

US06413485B2 Ammoxidation of a mixture of ketones to acetonitrile and HCN 失效
标题翻译：酮与乙腈和HCN的混合物的氨氧化
公开(公告)号：US06413485B2
公开(公告)日：2002-07-02
申请号：US09320937
申请日：1999-05-27
申请人： Michael J. Seely , Sanjay Purushottam Godbole , Dev Dhanaraj Suresh
发明人： Michael J. Seely , Sanjay Purushottam Godbole , Dev Dhanaraj Suresh
IPC分类号： C01C302
CPC分类号： C07C253/26 , C01C3/0212 , C01C3/0225 , C07C253/24 , Y02P20/52 , C07C255/08
摘要： A process increasing the yield of both HCN and acetonitrile produced during the manufacture of acrylonitrile comprising introducing a hydrocarbon selected from the group consisting of propylene and propane, a crude ketone and/or a mixture of at least two ketones, ammonia and air, into a reaction zone containing an ammoxidation catalyst, reacting the hydrocarbon, the ketone, ammonia and oxygen over said catalyst at an elevated temperature to produce acrylonitrile, hydrogen cyanide and acetonitrile, and recovering the acrylonitrile, hydrogen cyanide and acetonitrile from the reactor.
摘要翻译：包括将选自丙烯和丙烷，粗酮和/或至少两种酮，氨和空气的混合物的烃引入到丙烯和丙烯的制备过程中产生的HCN和乙腈的产率的方法，含有氨氧化催化剂的反应区，在升高的温度下使所述催化剂上的烃，酮，氨和氧反应生成丙烯腈，氰化氢和乙腈，并从反应器回收丙烯腈，氰化氢和乙腈。

39. 发明授权

US5877108A Performance of used molybdenum based catalysts by the addition of ammonium dimolybdate 失效
标题翻译：通过加入二钼酸铵的二氧化钼基催化剂的性能
公开(公告)号：US5877108A
公开(公告)日：1999-03-02
申请号：US988589
申请日：1997-12-11
申请人： Dev Dhanaraj Suresh , Christos Paparizos , Michael J. Seely , Tama Lee Drenski , Maria Strada Friedrich
发明人： Dev Dhanaraj Suresh , Christos Paparizos , Michael J. Seely , Tama Lee Drenski , Maria Strada Friedrich
IPC分类号： B01J23/28 , B01J23/30 , B01J23/34 , B01J23/64 , B01J23/88 , B01J23/92 , B01J27/057 , B01J27/192 , B01J38/00 , B01J38/68 , B01J20/34 , B01J23/90
CPC分类号： B01J23/92 , B01J38/68
摘要： A process for regenerating molybdenum containing ammoxidation catalyst comprising replacing the molybdenum loss from the catalyst during the ammoxidation reaction wherein ammonium dimolybdenum is utilized as the source for replacement of the molybdenum loss from the original catalyst.
摘要翻译：一种用于再生含钼氨氧化催化剂的方法，其包括在氨氧化反应期间代替钼催化剂的损失，其中使用铵二钼作为替代原始催化剂的钼损失的来源。

40. 发明申请

US20110237820A1 Process for preparing improved mixed metal oxide ammoxidation catalysts 有权
标题翻译：改进的混合金属氧化物氨氧化催化剂的制备方法
公开(公告)号：US20110237820A1
公开(公告)日：2011-09-29
申请号：US12661716
申请日：2010-03-23
申请人： Charles J. Besecker , James Frank Brazdil, JR. , Mark A. Toft , Michael J. Seely , Robert A. Gustaferro
发明人： Charles J. Besecker , James Frank Brazdil, JR. , Mark A. Toft , Michael J. Seely , Robert A. Gustaferro
IPC分类号： C07C253/18 , B01J21/08 , B01J23/04 , B01J23/887
CPC分类号： B01J23/002 , B01J23/8871 , B01J23/8876 , B01J23/8878 , B01J35/002 , B01J37/031 , B01J2523/00 , C07C253/26 , Y02P20/52 , B01J2523/14 , B01J2523/22 , B01J2523/3712 , B01J2523/54 , B01J2523/67 , B01J2523/68 , B01J2523/842 , B01J2523/847 , B01J2523/12 , B01J2523/13 , B01J2523/15 , C07C255/08
摘要： A process for the preparation of a catalyst comprising bismuth, molybdenum, iron, cerium and other promoter elements, wherein the elements in said catalyst are combined together in an aqueous catalyst precursor slurry, the aqueous precursor slurry so obtained is dried to form a catalyst precursor, and the catalyst precursor is calcined to form said catalyst, the process comprising: (i) combining, in an aqueous solution, source compounds of Bi and Ce, and optionally one or more of Na, K, Rb, Cs, Ca, a rare earth element, Pb, W and Y, to form a mixture, (ii) adding a source compound of molybdenum to the mixture to react with the mixture and form a precipitate slurry, and (iii) combining the precipitate slurry with source compounds of the remaining elements and of the remaining molybdenum in the catalyst to form the aqueous catalyst precursor slurry.
摘要翻译：一种制备包含铋，钼，铁，铈和其它助催化剂元素的催化剂的方法，其中所述催化剂中的元素在水性催化剂前体浆液中混合在一起，将如此得到的水性前体浆液干燥以形成催化剂前体，并且催化剂前体被煅烧以形成所述催化剂，所述方法包括：（i）在水溶液中将Bi和Ce的源化合物，以及任选的一种或多种Na，K，Rb，Cs，Ca，稀土元素Pb，W和Y形成混合物，（ii）向混合物中加入钼化合物与混合物反应并形成沉淀物浆料，和（iii）将沉淀物浆料与剩余元素和剩余的钼在催化剂中形成含水催化剂前体浆料。

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