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    • 38. 发明授权
    • Coating compositions containing isocyanate-functional non-aqueous dispersed polymers
    • 含有异氰酸酯官能的非水分散聚合物的涂料组合物
    • US06632880B2
    • 2003-10-14
    • US09901394
    • 2001-07-09
    • Robert J. BarsottiLaura Ann LewinChristopher Scopazzi
    • Robert J. BarsottiLaura Ann LewinChristopher Scopazzi
    • C08L5100
    • C08G18/0871C08G18/6254C08G18/633C08G18/728C09D175/04
    • A coating composition containing about 40-90% by weight of film forming binder and 10-60% by weight of an organic liquid carrier; wherein the binder contains about (a) 10-70% by weight, based on the weight of the binder, of a dispersed gelled acrylic polymer having (i) a core of gelled polymerized ethylenically unsaturated monomers which is not soluble in the organic liquid carrier and having chemically grafted thereto (ii) substantially linear stabilizer polymeric components that are soluble in the organic liquid carrier and comprise polymerized ethylenically unsaturated monomers and have a weight average molecular weight of about 500-20,000 determined by GPC (gel permeation chromatography) using polystyrene as the standard; wherein the core, the stabilizer polymeric component, or both contain at least 3% by weight of polymerized ethylenically unsaturated monomers having isocyanate groups attached thereto that are capable of reacting with component (b); (b) 30-90% by weight, based on the weight of the binder, of an oligomer or polymer or both having functional groups capable of reacting with the isocyanate groups of component (a); and (c) 0-60% by weight, based on the weight of the binder, of an organic polyisocyanate crosslinking agent.
    • 一种涂料组合物,其含有约40-90重量%的成膜粘合剂和10-60重量%的有机液体载体; 其中所述粘合剂含有基于粘合剂重量10-70重量%的分散的凝胶状丙烯酸类聚合物,其具有(i)胶凝聚合的烯属不饱和单体的核心, (ii)可溶于有机液体载体并且包含聚合的烯键式不饱和单体并且重均分子量为约500-1000μm的基本上线性的稳定剂聚合物组分, 20,000,通过使用聚苯乙烯作为标准的GPC(凝胶渗透色谱法)测定;其中核心,稳定剂聚合物组分或两者含有至少3重量%的具有连接到其上的具有异氰酸酯基团的聚合的烯键式不饱和单体, 与组分(b)反应;(b)30-90重量%,基于粘合剂的重量,低聚物或聚合物或具有官能团能够 与组分(a)的异氰酸酯基团反应; 和(c)基于粘合剂的重量,为有机多异氰酸酯交联剂的0-60重量%。
    • 39. 发明授权
    • Two-stage cure coating compositions
    • 两阶段固化涂料组合物
    • US06326059B1
    • 2001-12-04
    • US09633765
    • 2000-08-07
    • Laura Ann LewinChristopher ScopazziDouglas Matt Lamb
    • Laura Ann LewinChristopher ScopazziDouglas Matt Lamb
    • B05D302
    • This invention provides for a two-pack solvent based coating composition that cures in two stages when applied over substrates. The first stage of the cure takes place rapidly under ambient conditions to produce a coating surface that can be readily sanded or buffed. Thereafter, over a period of days a second stage cure takes place to produce a coating having excellent coating properties. Thus, a coated component, such as automotive body, can be speedily moved out from a spray booth without affecting the surface quality of the coated surface. As a result, coating operation productivity can be increased. The aforedescribed dual cure properties of the coating composition result from including in a binder component of the coating composition an acrylic polymer having secondary amine and hydroxyl functionalities. The composition is most suited for use in automotive refinish applications.
    • 本发明提供了一种双组分溶剂型涂料组合物,其在施加在基材上时分两个阶段固化。 固化的第一阶段在环境条件下快速发生,以产生可以容易地打磨或抛光的涂层表面。 此后,在一段时间内,进行第二阶段固化以产生具有优异涂层性能的涂层。 因此,诸如汽车车身的涂覆部件可以从喷涂室中快速地移出,而不影响涂覆表面的表面质量。 结果,可以提高涂布操作生产率。 涂料组合物的上述双重固化性质是由涂料组合物的粘合剂组分中含有具有仲胺和羟基官能团的丙烯酸聚合物构成的。 该组合物最适用于汽车修补漆应用。