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    • 33. 发明授权
    • Method of performing sugar dehydration and catalyst treatment
    • 糖脱水和催化剂处理方法
    • US07728156B2
    • 2010-06-01
    • US11342146
    • 2006-01-26
    • Jianli HuJohnathan E. HolladayXinjie ZhangYong Wang
    • Jianli HuJohnathan E. HolladayXinjie ZhangYong Wang
    • C07C29/00C07D315/00C07D493/00C07H1/00C07H17/00C07H5/04C07H1/06C13K5/00
    • C07H1/00
    • The invention includes a method of treating a solid acid catalyst. After exposing the catalyst to a mixture containing a sugar alcohol, the catalyst is washed with an organic solvent and is then exposed to a second reaction mixture. The invention includes a process for production of anhydrosugar alcohol. A solid acid catalyst is provided to convert sugar alcohol in a first sample to an anhydrosugar alcohol. The catalyst is then washed with an organic solvent and is subsequently utilized to expose a second sample. The invention includes a method for selective production of an anhydrosugar. A solid acid catalyst is provided within a reactor and anhydrosugar alcohol is formed by flowing a starting sugar alcohol into the reactor. The acid catalyst is then exposed to an organic solvent which allows a greater amount of additional anhydrosugar to be produced than would occur without exposing the acid catalyst to the organic solvent.
    • 本发明包括一种处理固体酸催化剂的方法。 在将催化剂暴露于含有糖醇的混合物之后,用有机溶剂洗涤催化剂,然后暴露于第二反应混合物。 本发明包括生产脱水葡萄糖醇的方法。 提供固体酸催化剂以将第一样品中的糖醇转化为脱水葡萄糖醇。 然后将催化剂用有机溶剂洗涤,随后用于暴露第二个样品。 本发明包括选择性生产脱水糖的方法。 在反应器内提供固体酸催化剂,通过将起始糖醇流入反应器而形成脱水葡萄糖醇。 然后将酸催化剂暴露于有机溶剂,其允许比不会将酸催化剂暴露于有机溶剂而产生更多量的额外的脱水糖。
    • 34. 发明授权
    • Method of forming a dianhydrosugar alcohol
    • 形成二脱水糖醇的方法
    • US07649099B2
    • 2010-01-19
    • US11341961
    • 2006-01-26
    • Johnathan E. HolladayJianli HuYong WangTodd A. WerpyXinjie Zhang
    • Johnathan E. HolladayJianli HuYong WangTodd A. WerpyXinjie Zhang
    • C07C29/00C07D315/00C07D493/00C07H1/00C07H17/00C07H5/04C07H1/06C13K5/00
    • C07D307/20C07D493/04Y02P20/127
    • The invention includes methods of producing dianhydrosugars. A polyol is reacted in the presence of a first catalyst to form a monocyclic sugar. The monocyclic sugar is transferred to a second reactor where it is converted to a dianhydrosugar alcohol in the presence of a second catalyst. The invention includes a process of forming isosorbide. An initial reaction is conducted at a first temperature in the presence of a solid acid catalyst. The initial reaction involves reacting sorbitol to produce 1,4-sorbitan, 3,6-sorbitan, 2,5-mannitan and 2,5-iditan. Utilizing a second temperature, the 1,4-sorbitan and 3,6-sorbitan are converted to isosorbide. The invention includes a method of purifying isosorbide from a mixture containing isosorbide and at least one additional component. A first distillation removes a first portion of the isosorbide from the mixture. A second distillation is then conducted at a higher temperature to remove a second portion of isosorbide from the mixture.
    • 本发明包括生产二脱水甘油糖的方法。 多元醇在第一催化剂存在下反应形成单环糖。 将单环糖转移到第二反应器中,在第二反应器中,在第二催化剂的存在下将其转化为二脱水甘油醇。 本发明包括形成异山梨醇的方法。 在固体酸催化剂存在下,在第一温度下进行初始反应。 初始反应包括使山梨醇反应生成1,4-脱水山梨糖醇,3,6-脱水山梨糖醇,2,5-甘露聚糖和2,5-己烷。 利用第二温度,将1,4-脱水山梨醇和3,6-脱水山梨醇转化为异山梨醇。 本发明包括从含有异山梨醇和至少一种另外的组分的混合物中纯化异山梨醇的方法。 第一蒸馏从混合物中除去第一部分的异山梨醇。 然后在较高温度下进行第二次蒸馏以从混合物中除去第二部分的异山梨醇。