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    • 32. 发明授权
    • Vinyl aromatic-(vinyl aromatic-co-acrylic) block copolymers prepared by stabilized free radical polymerization
    • 通过稳定的自由基聚合制备的乙烯基芳族 - (乙烯基芳族 - 共 - 丙烯酸)嵌段共聚物
    • US06531547B1
    • 2003-03-11
    • US09717751
    • 2000-11-21
    • Daniel C. VisgerRichard M. Lange
    • Daniel C. VisgerRichard M. Lange
    • C08F29300
    • C10M145/14C08F293/005C10M143/10C10M2205/04C10M2209/084
    • A process for preparing a block copolymer. In one embodiment, the block copolymers comprise (A) a poly (vinyl aromatic) block and (B) a poly (vinyl aromatic-co-acrylic) block, said process comprising the steps, (a) polymerizing at an elevated temperature from about 5 to about 95 mole % of a charge comprising at least one vinyl aromatic monomer to prepare a stabilized active polymer block (A), using a free radical polymerization process, wherein a stable free radical agent is employed during the polymerization, thereby preserving the stabilized active polymerization site at the terminus of the poly (vinyl aromatic) block (A); (b) adding at least one acrylic monomer and optionally, additional vinyl aromatic monomer, to the mixture of vinyl aromatic monomer and stabilized active polymer block of (a); and (c) further reacting the mixture of (b) using a free radical process to effect copolymerization of said monomers, thereby preparing a (vinyl aromatic-co-acrylate) block (B). The present invention also relates to block copolymers prepared by the above process, additive concentrates for preparing lubricating oil compositions and lubricating oil compositions. In other embodiments, the present invention relates to block copolymers having more than two blocks.
    • 一种制备嵌段共聚物的方法。 在一个实施方案中,嵌段共聚物包含(A)聚(乙烯基芳族)嵌段和(B)聚(乙烯基芳族 - 共 - 丙烯酸)嵌段,所述方法包括以下步骤:(a)在高温从约 5至约95摩尔%的包含至少一种乙烯基芳族单体的电荷以制备稳定的活性聚合物嵌段(A),使用自由基聚合方法,其中在聚合期间使用稳定的自由基试剂,从而保持稳定的 在聚(乙烯基芳族)嵌段(A)的末端的活性聚合位点;(b)将至少一种丙烯酸单体和任选的另外的乙烯基芳族单体加入乙烯基芳族单体和稳定的活性聚合物嵌段 ); (c)使(b)使用自由基方法的混合物进一步反应以实现所述单体的共聚,从而制备(乙烯基芳族 - 共 - 丙烯酸酯)嵌段(B)。本发明还涉及由 上述方法,用于制备润滑油组合物和润滑油组合物的添加剂浓缩物。 在其它实施方案中,本发明涉及具有多于两个嵌段的嵌段共聚物。
    • 34. 发明授权
    • Metal containing dispersant polymers from condensation of polymers containing acidic group with overbased compositions containing reactive nucleophilic group
    • 含有酸性基团的聚合物与包含反应性亲核基团的高碱性组合物的含金属的分散剂聚合物
    • US06403725B1
    • 2002-06-11
    • US09378587
    • 1999-08-20
    • Nai Z. HuangRichard M. Lange
    • Nai Z. HuangRichard M. Lange
    • C08F842
    • C08F8/44
    • Disclosed is a metal containing polymer composition comprising; a metal overbased imide or ester functionalized polymer prepared by reacting (A) a polymer comprising (A1) an acidic functionalized polymer or ester functionalized polymer; (A2) an acidic mixed ester-acid of a carboxy containing interpolymer; or (A3) an ester functionalized polymer comprising a lactone and (B) a metal overbased composition that contains a reactive basic functionality comprising (B1) a metal overbased amine wherein the reactive basic functionality is a primary or secondary amino group; (B2) a metal overbased hydroxy substituted carboxylic acid wherein the reactive basic functionality is a hydroxy group; or (B3) a metal overbased dispersant wherein the reactive basic functionality is a primary or secondary amino group.
    • 公开了含金属的聚合物组合物,其包含:通过使(A)包含(A1)酸性官能化聚合物或酯官能化聚合物的聚合物反应制备的金属高碱性酰亚胺或酯官能化聚合物;(A2)羧基的酸性混合酯酸 含有互聚物; 或(A3)包含内酯的酯官能化聚合物和(B)含有活性碱性官能团的金属高碱性组合物,其包含(B1)金属高碱性胺,其中反应性碱性官能团是伯或仲氨基;(B2) 金属高碱性羟基取代的羧酸,其中反应性碱性官能团是羟基; 或(B3)金属高碱性分散剂,其中反应性碱性官能团是伯或仲氨基。
    • 38. 发明授权
    • Thermal oxidatively stable synthetic fluid composition
    • 热氧化稳定的合成液组成
    • US5164122A
    • 1992-11-17
    • US622300
    • 1990-12-05
    • Richard M. LangeMary F. Salomon
    • Richard M. LangeMary F. Salomon
    • C10M105/36C10M105/38C10M129/72C10M171/00
    • C10M171/008C10M105/36C10M105/38C10M129/72
    • A thermal oxidatively stable synthetic fluid composition is disclosed. The composition is essentially comprised of an aromatic carboxylic acid ester of the general formula ##STR1## wherein Ar is an aromatic moiety, R is a neo hydrocarbyl group containing from about 5 to about 18 carbon atoms, with the proviso that R is not a cycloalkyl substituted neo hydrocarbyl group, R.sub.1 is a mono, di, tri or tetra functional hydrocarbyl group containing from 1 to about 18 carbon atoms, n is an integer from about 2 to about 4 and represents the total number of carboxylic acid ester groups on the aromatic moiety, a is an integer from about 1 to about 4, when a is 1 R.sub.1 is monovalent, when a is 2 R.sub.1 is divalent, when a is 3 R.sub.1 is trivalent and when a is 4 R.sub.1 is tetravalent, R.sub.2 is a hydrocarbyl group derived from a diol containing from about 2 to about 18 carbon atoms and x is an integer from 0 to about 4.
    • 公开了一种热氧化稳定的合成流体组合物。 组合物基本上由通式为(I)的芳族羧酸酯组成,其中Ar是芳族部分,R是含约5至约18个碳原子的新烃基,条件是R是 不是环烷基取代的新烃基,R1是含有1至约18个碳原子的单,二,三或四官能烃基,n是约2至约4的整数,并且表示羧酸酯基的总数 在芳族部分,a为约1至约4的整数,当a为1时,R1为单价,当a为2时,R1为二价,当a为3时,R1为三价,当a为4时,R2为四价,R2为 衍生自含有约2至约18个碳原子的二醇的烃基,x是0至约4的整数。