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31. 发明授权

US06512040B1 Electropolymerization modified carbon black and articles including tires having at least one component containing such modified carbon black 失效
标题翻译：电聚合改性炭黑和包含具有至少一种含有这种改性炭黑的组分的轮胎的制品
公开(公告)号：US06512040B1
公开(公告)日：2003-01-28
申请号：US09667109
申请日：2000-09-21
申请人： Thierry Florent Edme Materne , Giorgio Agostini
发明人： Thierry Florent Edme Materne , Giorgio Agostini
IPC分类号： C08L304
CPC分类号： C09C1/565 , C01P2006/12 , C08K9/04 , C08K9/08 , C09C1/56 , C08L21/00
摘要： This invention relates to a carbon black modified by a two step process in which carbon black is initially treated with functional monomers by an electropolymerization process to form a functionalized carbon black having an initial polymer attached to, of grafted to, the carbon black following which (A) at least one diene monomer, or (B) living anionic catalysis prepared polymer, is introduced to the functionalized carbon black to continue the polymerization, starting from a living end of the initially formed polymer, and thereby form an extended diene-based polymer. By the addition of the diene monomer or the live anionic polymer to form the associated extended diene-based polymer, it is contemplated that the modified carbon black is rendered more compatible with diene-based elastomers. Such modified carbon black may be used, for example, as reinforcement for component(s) of various articles of manufacture, including tires. Accordingly, an article of manufacture is provided, such as for example a tire, having at least one component of a rubber composition which contains such modified carbon black.
摘要翻译：本发明涉及通过两步法改性的炭黑，其中炭黑最初通过电聚合方法用功能性单体处理，以形成具有连接到炭黑上的初始聚合物的官能化炭黑，随后将 A）将至少一种二烯单体或（B）活性阴离子催化制备的聚合物引入到官能化炭黑中以继续聚合，从最初形成的聚合物的活性端开始，从而形成延伸的二烯基聚合物。通过加入二烯单体或活性阴离子聚合物以形成相关的延长的二烯基聚合物，预期改性炭黑与二烯基弹性体更相容。这种改性炭黑可以用作例如包括轮胎在内的各种制品的组分的增强剂。因此，提供了具有至少一种含有这种改性炭黑的橡胶组合物组分的例如轮胎的制品。

32. 发明授权

US06225397B1 Rubber composition containing silica having first and second aggregates each containing different particle sizes 有权
标题翻译：含有二氧化硅的橡胶组合物，其具有各自含有不同粒径的第一和第二聚集体
公开(公告)号：US06225397B1
公开(公告)日：2001-05-01
申请号：US09255067
申请日：1999-02-22
申请人： Thierry Florent Edme Materne , Giorgio Agostini
发明人： Thierry Florent Edme Materne , Giorgio Agostini
IPC分类号： C08K336
CPC分类号： C08K3/36 , C08K2201/014 , Y10S977/773 , Y10S977/779 , C08L21/00
摘要： The present application relates to a rubber composition containing a precipitated silica filler having first and second aggregates. The first aggregates are from 10 to 90 weight percent of the overall weight of the silica having first and second aggregates. The second aggregates range from 90 to 10 weight percent of the overall weight of the silica having first and second aggregates. The first aggregates consist essentially of particles ranging in size of from 5 to 15 nanometers in diameter. The second aggregates consist essentially of particles ranging in size of from 17 to 30 nanometers in diameter. The pore size distribution of the silica, as measured by mercury porosimetry is monomodal.
摘要翻译：本申请涉及含有具有第一和第二聚集体的沉淀二氧化硅填料的橡胶组合物。第一聚集体是具有第一和第二聚集体的二氧化硅的总重量的10至90重量％。第二聚集体的范围为具有第一和第二聚集体的二氧化硅的总重量的90至10重量％。第一聚集体基本上由尺寸为5至15纳米直径的颗粒组成。第二聚集体基本上由直径范围为17至30纳米的颗粒组成。通过水银孔率法测量的二氧化硅的孔径分布是单峰的。

33. 发明授权

US6160047A Rubber composition and tire having tread thereof 失效
标题翻译：橡胶组合物和具有胎面的轮胎
公开(公告)号：US6160047A
公开(公告)日：2000-12-12
申请号：US938990
申请日：1997-09-26
申请人： Giorgio Agostini , Thierry Florent Edme Materne
发明人： Giorgio Agostini , Thierry Florent Edme Materne
IPC分类号： B60C1/00 , C08K3/04 , C08K3/36 , C08K9/02 , C08K9/04 , B60C11/00 , C08K3/06
CPC分类号： C08K9/02 , B60C1/0016 , C08K3/04 , C08K3/36 , C08K9/04 , C08L21/00
摘要： A rubber composition as a blend comprised of an elastomer(s), and particulate reinforcement provided as an intimate blend of carbon black particles and fumed silica particles, together with a coupling agent.A tire having a component of such rubber composition such as, for example, a tread, is specifically contemplated.
摘要翻译：橡胶组合物作为混合物，由弹性体和作为炭黑颗粒和热解法二氧化硅颗粒的紧密共混物提供的颗粒增强剂与偶联剂一起提供。特别考虑了具有这种橡胶组合物的成分例如胎面的轮胎。

34. 发明申请

US20080132647A1 Polymeric composition for seals and gaskets 失效
标题翻译：用于密封和垫圈的聚合物组合物
公开(公告)号：US20080132647A1
公开(公告)日：2008-06-05
申请号：US12012811
申请日：2008-02-06
申请人： Manoj Ajbani , Christopher Kiehl , Thierry Florent Edme Materne
发明人： Manoj Ajbani , Christopher Kiehl , Thierry Florent Edme Materne
IPC分类号： C08F8/00
CPC分类号： C08L23/16 , C08L9/02 , C08L9/06 , C08L15/00 , C08L15/005 , C08L21/00 , C08L23/10 , C08L23/12 , C08L23/14 , C08L25/00 , C08L53/005 , C08L53/02 , C08L53/025 , C08L71/12 , C08L91/00 , C08L2205/02 , C08L2205/03 , C08L2205/035 , C08L2312/00 , Y10T428/31826 , Y10T428/31931 , Y10T428/31935 , C08L2666/24 , C08L2666/06 , C08L2666/02 , C08L2666/08 , C08L2666/04
摘要： The present invention relates to a polymeric composition which has an excellent combination of properties for use in making seals and gaskets for utilization in appliances, automotive applications, and building applications, such as window glazing gaskets. These polymeric compositions offer excellent dimensional stability, low compression set, outstanding sealing characteristics, low temperature flexibility, heat resistance and ultra-violet light resistance. The present invention more specifically discloses a polymeric composition having excellent characteristics for utilization in manufacturing seals and gaskets including dimensional stability, low compression set and outstanding sealing characteristics, said polymeric composition being comprised of a blend of (A) a thermoplastic resin selected from the group consisting of polypropylene, polyethylene, poly phenylene ether, polystyrene, and styrene containing copolymer resins, (B) an elastomeric polymer selected from the group consisting of block copolymer comprising a first polymeric block that is comprised of repeat units that are derived from a vinyl aromatic monomer and a second block that is comprised of repeat units that are derived from a conjugated diolefin monomer, wherein the repeat units in the second block are hydrogenated, and wherein the repeat units in the second block are elastomeric in nature, and a crosslinked olefinic elastomer, (C) a high molecular weight crosslinked diene elastomer comprised of repeat units that are derived from conjugated diene monomer selected from the group consisting of 1,3-butadiene and isoprene, wherein the high molecular weight diene elastomer has a weight average molecular weight of at least about 200,000, and (D) an oil.
摘要翻译：本发明涉及一种聚合物组合物，其具有用于制造用于制造密封件的特性和用于家用电器，汽车应用以及建筑应用（例如窗玻璃垫片）的垫圈的优异组合。这些聚合物组合物具有优异的尺寸稳定性，低压缩永久变形，优异的密封特性，低温柔韧性，耐热性和耐紫外光性。本发明更具体地公开了一种聚合物组合物，其具有用于制造密封件和垫片的优异特性，包括尺寸稳定性，低压缩永久变形和优异的密封特性，所述聚合物组合物由（A）选自组由聚丙烯，聚乙烯，聚苯醚，聚苯乙烯和含苯乙烯的共聚物树脂组成的弹性体聚合物，（B）弹性体聚合物，其选自由包含衍生自乙烯基芳族化合物的重复单元组成的第一聚合物嵌段的嵌段共聚物单体和由衍生自共轭二烯烃单体的重复单元组成的第二嵌段，其中第二嵌段中的重复单元被氢化，并且其中第二嵌段中的重复单元本质上是弹性体，并且交联的烯属弹性体，（C）高分子量交联二烯属弹性体由衍生自选自1,3-丁二烯和异戊二烯的共轭二烯单体的重复单元组成，其中高分子量二烯弹性体的重均分子量为至少约20万，（D）一种油

35. 发明授权

US06255379B1 Rubber containing short fiber reinforcement with anchoring agent and articles, including tires, having a component thereof 有权
标题翻译：含有锚固剂的短纤维增强橡胶和包含轮胎的制品，其具有其组分
公开(公告)号：US06255379B1
公开(公告)日：2001-07-03
申请号：US09397751
申请日：1999-09-16
申请人： Bruce Raymond Hahn , Thierry Florent Edme Materne
发明人： Bruce Raymond Hahn , Thierry Florent Edme Materne
IPC分类号： C08K300
CPC分类号： C08K5/548 , B60C1/00 , B60C1/0016 , B60C1/0025 , C08K7/02 , C08L21/00 , C08L2666/08
摘要： The invention relates to composites of rubber compositions reinforced with short, discontinuous fibers together with an anchoring agent. Preferably, the rubber composition is exclusive of amorphous silica. The invention also relates to articles, including industrial products and tires, which have at least one component thereof. The invention particularly relates to industrial rubber belts having at least one component of such rubber composite and to tires with at least one component of such rubber composite.
摘要翻译：本发明涉及用短的不连续纤维与锚固剂一起增强的橡胶组合物的复合材料。优选地，橡胶组合物不包括无定形二氧化硅。本发明还涉及具有至少一种组分的制品，包括工业产品和轮胎。本发明特别涉及具有这种橡胶复合材料的至少一种组分的工业橡胶带和具有这种橡胶复合材料的至少一种组分的轮胎。

36. 发明授权

US07825194B2 Hairy polymeric nanoparticles 有权
标题翻译：毛状聚合物纳米粒子
公开(公告)号：US07825194B2
公开(公告)日：2010-11-02
申请号：US12287426
申请日：2008-10-10
申请人： Lei Zheng , Eric Sean Castner , Thierry Florent Edme Materne
发明人： Lei Zheng , Eric Sean Castner , Thierry Florent Edme Materne
IPC分类号： C08F8/42 , C08F36/04 , C08F36/08 , C08F36/06
CPC分类号： C08F257/02 , C08C1/15 , C08F6/22 , C08F236/06 , C08L51/00
摘要： This invention discloses a process for synthesizing a hairy polymer particle which comprises the steps of (1) polymerizing a vinyl aromatic monomer by emulsion polymerization in an aqueous medium to produce core particles, (2) recovering the core particles from the aqueous medium, (3) dispersing the core particles in an organic solvent, (4) adding an organo-lithium compound to the dried core particles in the organic solvent to produce the hairless core initiator, and (5) utilizing the hairless core initiator to initiate the anionic polymerization of a conjugated diolefin monomer in an organic solvent to produce a solution of the hairy polymer particles. The hairy polymer nanoparticles can then be recovered from the organic solvent. These hairy polymer particles are comprised of (1) a core which is comprised of a polymer of a vinyl aromatic monomer and (2) hairs which are polymer chains of a conjugated diolefin monomer, wherein the hairs are covalently bonded to the core. The core is typically spherical in shape, has a diameter of less than 1000 nm, and is comprised of a crosslinked polymer of a vinyl aromatic monomer. The hairy polymer particles of this invention are useful as fillers in rubber compositions used in making articles of manufacture, such as tires, hoses, power transmission belts, windshield wiper blades, and the like.
摘要翻译：本发明公开了一种合成毛状聚合物颗粒的方法，其包括以下步骤：（1）通过乳液聚合在水性介质中聚合乙烯基芳族单体以产生核心颗粒，（2）从水介质中回收芯颗粒，（3 ）将核心颗粒分散在有机溶剂中，（4）将有机锂化合物加入到有机溶剂中的干燥芯颗粒中以制备无毛芯引发剂，和（5）利用无毛芯引发剂引发阴离子聚合共轭二烯单体在有机溶剂中以产生毛状聚合物颗粒的溶液。然后可以从有机溶剂中回收毛状聚合物纳米颗粒。这些毛发聚合物颗粒包括（1）由乙烯基芳族单体的聚合物组成的芯和（2）作为共轭二烯烃单体的聚合物链的毛发，其中毛发共价键合到芯上。芯通常为球形，直径小于1000nm，并且由乙烯基芳族单体的交联聚合物组成。本发明的毛发聚合物颗粒可用作用于制造制品的橡胶组合物中的填料，例如轮胎，软管，动力传动带，挡风玻璃刮水器等。

37. 发明申请

US20090042719A1 Hairy polymeric nanoparticles 有权
标题翻译：毛状聚合物纳米粒子
公开(公告)号：US20090042719A1
公开(公告)日：2009-02-12
申请号：US12287426
申请日：2008-10-10
申请人： Lei Zheng , Eric Sean Castner , Thierry Florent Edme Materne
发明人： Lei Zheng , Eric Sean Castner , Thierry Florent Edme Materne
IPC分类号： B01J31/12
CPC分类号： C08F257/02 , C08C1/15 , C08F6/22 , C08F236/06 , C08L51/00
摘要： This invention discloses a process for synthesizing a hairy polymer particle which comprises the steps of (1) polymerizing a vinyl aromatic monomer by emulsion polymerization in an aqueous medium to produce core particles, (2) recovering the core particles from the aqueous medium, (3) dispersing the core particles in an organic solvent, (4) adding an organo-lithium compound to the dried core particles in the organic solvent to produce the hairless core initiator, and (5) utilizing the hairless core initiator to initiate the anionic polymerization of a conjugated diolefin monomer in an organic solvent to produce a solution of the hairy polymer particles. The hairy polymer nanoparticles can then be recovered from the organic solvent. These hairy polymer particles are comprised of (1) a core which is comprised of a polymer of a vinyl aromatic monomer and (2) hairs which are polymer chains of a conjugated diolefin monomer, wherein the hairs are covalently bonded to the core. The core is typically spherical in shape, has a diameter of less than 1000 nm, and is comprised of a crosslinked polymer of a vinyl aromatic monomer. The hairy polymer particles of this invention are useful as fillers in rubber compositions used in making articles of manufacture, such as tires, hoses, power transmission belts, windshield wiper blades, and the like.
摘要翻译：本发明公开了一种合成毛状聚合物颗粒的方法，其包括以下步骤：（1）通过乳液聚合在水性介质中聚合乙烯基芳族单体以产生核心颗粒，（2）从水介质中回收芯颗粒，（3 ）将核心颗粒分散在有机溶剂中，（4）将有机锂化合物加入到有机溶剂中的干燥芯颗粒中以制备无毛芯引发剂，和（5）利用无毛芯引发剂引发阴离子聚合共轭二烯单体在有机溶剂中以产生毛状聚合物颗粒的溶液。然后可以从有机溶剂中回收毛状聚合物纳米颗粒。这些毛发聚合物颗粒包括（1）由乙烯基芳族单体的聚合物组成的芯和（2）作为共轭二烯烃单体的聚合物链的毛发，其中毛发共价键合到芯上。芯通常为球形，直径小于1000nm，并且由乙烯基芳族单体的交联聚合物组成。本发明的毛发聚合物颗粒可用作用于制造制品的橡胶组合物中的填料，例如轮胎，软管，动力传动带，挡风玻璃刮水器等。

38. 发明授权

US07365131B2 Thermoplastic vulcanizate composition 失效
标题翻译：热塑性硫化胶组合物
公开(公告)号：US07365131B2
公开(公告)日：2008-04-29
申请号：US11106977
申请日：2005-04-15
申请人： Manoj Ajbani , Christopher Kiehl , Thierry Florent Edme Materne
发明人： Manoj Ajbani , Christopher Kiehl , Thierry Florent Edme Materne
IPC分类号： C08F8/00 , C08L33/04 , C08L9/00 , C08L23/00 , C08L23/04 , C08G18/42
CPC分类号： C08L53/025 , C08L21/00 , C08L23/06 , C08L23/12 , C08L25/06 , C08L35/06 , C08L53/00 , C08L53/02 , C08L71/12 , C08L91/00 , C08L2666/02 , C08L2666/24 , C08L2666/04 , C08L2666/14 , C08L2666/20
摘要： A thermoplastic vulcanizate composition comprised of (a) thermoplastic resin selected from the group consisting of polyphenylene ether, polypropylene, polyethylene, and polystyrene, (b) at least one elastomer selected from the group consisting of butadiene-isoprene copolymer rubbers, copolymers of a conjugated diolefin monomer and an acrylate monomer, copolymers of a conjugated diolefin monomer and an methacrylate monomer, copolymers of a conjugated diolefin monomer and a vinyl aromatic monomer, copolymers of a conjugated diolefin monomer and an acrylonitrile monomer, blends of polyisoprene rubber with styrene-butadiene rubber, wherein the elastomer is at least partially crosslinked, wherein the repeat units in the elastomer are distributed throughout the elastomer in an essentially random manner, and (c) oil.
摘要翻译：一种热塑性硫化胶组合物，其包含（a）选自聚苯醚，聚丙烯，聚乙烯和聚苯乙烯的热塑性树脂，（b）至少一种选自丁二烯 - 异戊二烯共聚物橡胶的共聚物，共轭二烯烃单体和丙烯酸酯单体，共轭二烯烃单体和甲基丙烯酸酯单体的共聚物，共轭二烯烃单体和乙烯基芳族单体的共聚物，共轭二烯烃单体和丙烯腈单体的共聚物，聚异戊二烯橡胶与苯乙烯 - 丁二烯橡胶的共混物，其中弹性体至少部分交联，其中弹性体中的重复单元以基本上随机的方式分布在整个弹性体中，和（c）油。

39. 发明授权

US07264868B2 Overmolded grip 失效
标题翻译：包覆成型的抓地力
公开(公告)号：US07264868B2
公开(公告)日：2007-09-04
申请号：US10672675
申请日：2003-09-26
申请人： Manoj Ajbani , Christopher Kiehl , Thierry Florent Edme Materne
发明人： Manoj Ajbani , Christopher Kiehl , Thierry Florent Edme Materne
IPC分类号： B32B15/06 , B32B25/08
CPC分类号： C08L51/006 , B32B25/04 , C08C19/02 , C08K5/01 , C08L15/00 , C08L21/00 , C08L53/025 , C08L71/12 , C08L101/00 , Y10T428/24983 , Y10T428/31692 , Y10T428/31696 , Y10T428/31699 , Y10T428/31931 , Y10T428/31935 , C08L2666/02 , C08L2666/04
摘要： The present invention discloses an article of manufacture comprising a soft thermoplastic elastomer composition overmolded onto a hard substrate, wherein the soft thermoplastic composition includes (a) 5 to 60 parts by weight of a thermoplastic resin, (b) 5 to 70 parts of a rubbery elastomer comprised of repeat units that are derived from a conjugated diene monomer, wherein the rubbery elastomer is optionally at least partially crosslinked, and wherein the rubbery polymer is a solution polymer, (c) 5 to 90 parts of a highly saturated elastomer selected from the group consisting of styrene-ethylene butylene-styrene polymers, styrene-ethylene propylene-styrene polymers, hydrogenated polybatadiene, hydrogenated polyisoprene, hydrogenated styrene-isoprene random copolymers, hydrogenated styrene-butadiene random copolymers, and (d) 15 to 200 parts by weight of an oil.
摘要翻译：本发明公开了一种包含模塑在硬质基材上的软质热塑性弹性体组合物的制品，其中软质热塑性组合物包含（a）5-60重量份的热塑性树脂，（b）5-70重量份的橡胶状弹性体由衍生自共轭二烯单体的重复单元构成，其中橡胶状弹性体任选地至少部分交联，其中橡胶状聚合物为溶液聚合物，（c）5-90份高度饱和的弹性体，其选自由苯乙烯 - 乙烯 - 丁烯 - 苯乙烯聚合物组成的组，苯乙烯 - 乙烯丙烯 - 苯乙烯聚合物，氢化聚二
烯二烯，氢化聚异戊二烯，氢化苯乙烯 - 异戊二烯无规共聚物，氢化苯乙烯 - 丁二烯无规共聚物，和（d）15-200重量份一种油

40. 发明授权

US07087660B2 Preparation of components and articles with directed high frequency energy heated silica-rich rubber components containing high softening point polymer and sulfur curative 失效
标题翻译：制备具有定向高频能量的部件和制品加热含有高软化点聚合物和硫固化剂的富二氧化硅橡胶组分
公开(公告)号：US07087660B2
公开(公告)日：2006-08-08
申请号：US10629421
申请日：2003-07-29
申请人： Thomas Robert Maier , Bruce Raymond Hahn , Brian John Doucet , Thierry Florent Edme Materne
发明人： Thomas Robert Maier , Bruce Raymond Hahn , Brian John Doucet , Thierry Florent Edme Materne
IPC分类号： C08F2/46 , C08L23/26
CPC分类号： B60C1/00 , B29B13/023 , B29C2035/0855 , B29C2035/0861 , B29K2009/00 , B29K2021/00 , B29L2030/00 , B60C1/0016 , B60C17/0009 , Y10S522/911 , Y10T152/10846
摘要： This invention relates to a process of preparation of components and articles of manufacture containing at least one of such components, such as tires, and the resulting prepared components and fabricated articles, by use of directed high frequency energy internally heated silica-rich rubber compositions which contain sulfur curative and a significant content of high softening point polymer, namely a polymer and/or elastomer having a melting point (Tm) and/or high glass transition temperature (Tg) above 0° C., and particularly above 30° C., and which contains a minimal, if any, carbon black reinforcement. Such directed high frequency energy heating is provided, individually, by directed radio frequency (electromagnetic) radiation and/or by directed microwave radiation. Representative examples of such polymers may be, for example, trans 1,4-polybutadiene, 3,4-polyisoprene, natural cis 1,4-polyisoprene rubber, isoprene/butadiene copolymer having a high trans 1,4-polybutadiene component, polystyrene, styrene/butadiene rubber having a high trans 1,4-polybudadiene component and styrene/butadiene rubber having a high styrene content.
摘要翻译：本发明涉及通过使用定向高频能内部加热的富含二氧化硅的橡胶组合物制备包含至少一种诸如轮胎的组分和所得制备的组分和制造的制品的组分和制品的方法，含有硫化固化剂和显着含量的高软化点聚合物，即具有高于0℃，特别是高于30℃的熔点（Tm）和/或高玻璃化转变温度（Tg）的聚合物和/或弹性体。，并且其包含最小的（如果有的话）炭黑增强物。通过定向射频（电磁）辐射和/或通过定向微波辐射单独提供这种定向高频能量加热。这种聚合物的代表性实例可以是例如反式1,4-聚丁二烯，3,4-聚异戊二烯，天然顺式1,4-聚异戊二烯橡胶，具有高反式1,4-聚丁二烯组分的异戊二烯/丁二烯共聚物，聚苯乙烯，具有高反式1,4-聚丁二烯组分的苯乙烯/丁二烯橡胶和苯乙烯含量高的苯乙烯/丁二烯橡胶。

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