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31. 发明授权

US06371993B1 Utilization of onium aldehydes and onium ketones for dying fibers containing keratin 有权
标题翻译：利用鎓醛和鎓酮染色含有角蛋白的纤维
公开(公告)号：US06371993B1
公开(公告)日：2002-04-16
申请号：US09529560
申请日：2000-06-19
申请人： Hinrich Moeller , Horst Hoeffkes
发明人： Hinrich Moeller , Horst Hoeffkes
IPC分类号： A61K713
CPC分类号： A61K8/4926 , A61Q5/10
摘要： The invention relates to the utilization of onium aldehydes and onium ketones of formula (1) or the derivatives thereof. In the formula, R1 represents a hydrogen atom, a (C1-C4)-alkyl group, an aryl group or a heteroaryl group. R2, R3, R4, independent of one another, each represent a hydrogen atom, a halogen atom, a (C1-C4)-alkyl group, a (C1-C4)-alkoxyl group, hydroxy-(C1-C4)-alkoxyl group, hydroxyl group, nitro group, aryl group, trifluoromethyl group, amino group or (C1-C4)-acyl group. Said amino group can be substituted by (C1-C4)-alkyl groups. Two of the residuals can be combined to form a fused benzene ring. R5 represents a (C1-C4)-alkyl group, aryl group, alkylaryl group or heteroaryl group. X designates a direct bonding or an optionally substituted vinyl group or phenyl group and Y— represents halogenide, benzenesulfonate, p-toluenesulfonate, methane sulfonate, trifluoromethane sulfonate, perchlorate, sulfate, hydrogen sulfate, tetrachlorozincate or N-oxide of the heterocyclic compound. In order to dye fibers containing keratin, onium aldehydes and onium ketones or the derivatives thereof are utilized in combination with at least one compound with a primary or secondary amino group or hydroxyl group. The compound is selected from primary or secondary aliphatic or aromatic amines, heterocyclic compounds containing nitrogen, amino acids, oligopeptides, said oligopeptides containing from 2 to 9 amino acids, as well as aromatic hydroxy compounds, and/or at least one CH-active compound.
摘要翻译：本发明涉及式（1）的鎓醛和鎓酮或其衍生物的使用。在该式中，R 1表示氢原子，（C 1 -C 4） - 烷基，芳基或杂芳基。 R2，R3，R4彼此独立地表示氢原子，卤素原子，（C1-C4） - 烷基，（C1-C4） - 烷氧基，羟基 - （C1-C4） - 烷氧基基，羟基，硝基，芳基，三氟甲基，氨基或（C1-C4） - 酰基。所述氨基可被（C 1 -C 4） - 烷基取代。两个残留物可以组合形成稠合苯环。 R5表示（C1-C4） - 烷基，芳基，烷基芳基或杂芳基。 X表示直接键合或任选取代的乙烯基或苯基，Y-表示杂环化合物的卤化物，苯磺酸盐，对甲苯磺酸盐，甲磺酸盐，三氟甲磺酸盐，高氯酸盐，硫酸盐，硫酸氢盐，四氯化锌或N-氧化物。为了染色含有角蛋白的纤维，将鎓醛和鎓酮或其衍生物与至少一种具有伯或仲氨基或羟基的化合物组合使用。该化合物选自伯或仲脂族或芳族胺，含有氮的杂环化合物，氨基酸，寡肽，所述含有2-9个氨基酸的寡肽，以及芳族羟基化合物和/或至少一种CH-活性化合物。

32. 发明授权

US5752984A Use of 1,2,3,4-tetrahydroquinoxalines as oxidation dye precursors in oxidative coloring formulations 失效
标题翻译：在氧化着色配方中使用1,2,3,4-四氢喹喔啉作为氧化染料前体
公开(公告)号：US5752984A
公开(公告)日：1998-05-19
申请号：US693078
申请日：1996-08-12
申请人： Georg Knuebel , David Rose , Horst Hoeffkes , Bernd Meinigke
发明人： Georg Knuebel , David Rose , Horst Hoeffkes , Bernd Meinigke
IPC分类号： A61K8/49 , A61Q5/10 , C07D241/42 , D06P1/32 , D06P3/08 , D06P3/14 , D06P3/30 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/494
摘要： An oxidative coloring composition for coloring human hair cointaining an oxidation dye precursor in a water-containing carrier, wherein the dye precursor comprises 1,2,3,4-tetrahydroquinoxalines corresponding to formula (I): ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 independently of one another represent hydrogen, C.sub.1-4 alkyl groups, benzyl groups, 2-phenylethyl groups or C.sub.2-4 hydroxyalkyl groups and X, Y and Z represent hydrogen, fluorine, chlorine, bromine or iodine atoms or C.sub.1-4 alkyl groups, and wherein at least one of the groups X, Y and Z is hydrogen.
摘要翻译： PCT No.PCT / EP95 / 00404 Sec。 371日期：1996年8月12日 102（e）日期1996年8月12日PCT提交1995年2月4日PCT公布。出版物WO95 / 21604 日期1995年8月17日一种氧化着色组合物，用于在含水载体中着丝粒氧化染料前体着色，其中染料前体包含对应于式（I）的1,2,3,4-四氢喹喔啉： I）其中R 1，R 2和R 3彼此独立地表示氢，C 1-4烷基，苄基，2-苯基乙基或C 2-4羟烷基，X，Y和Z表示氢，氟，氯，溴或碘原子或C 1-4烷基，并且其中基团X，Y和Z中的至少一个是氢。

33. 发明授权

US5651793A Hydrogen peroxide preparations containing foam regulators 失效
标题翻译：含泡沫调节剂的过氧化氢制剂
公开(公告)号：US5651793A
公开(公告)日：1997-07-29
申请号：US619679
申请日：1996-03-28
申请人： Horst Hoeffkes , Winifried Neuhaus , Karin Nelles
发明人： Horst Hoeffkes , Winifried Neuhaus , Karin Nelles
IPC分类号： A45D19/00 , B01D19/04 , C08L33/02 , C08L83/04 , D06L3/02 , D06P1/32 , D06P3/08 , A61K7/13
CPC分类号： A61Q5/08 , A61K8/062 , A61K8/22 , A61K8/8152 , A61K8/891 , A61K8/922 , A61Q5/10 , B01D19/0409
摘要： A water-containing hydrogen peroxide composition having a pH of 2 to 6 for the oxidative dyeing and bleaching of hair. The composition contains an anionic surfactant, hydrogen peroxide, a water-soluble or water-dispersible, thickening polymer or copolymer containing carboxyl or carboxylate groups, and optionally a C.sub.12 -C.sub.18 fatty alcohol ethoxylated with up to 50 moles of ethylene oxide or a hydrogenated castor oil ethoxylated with up to 50 moles of ethylene oxide, and 0.001% to 0.05% by weight of a foam regulator component consisting of polysiloxane containing fine-particle hydrophobicized silica, wherein the content of fine-particle hydrophobicized silica is from 0.5% to 20% by weight, based on the weight of the foam regulator component.
摘要翻译： PCT No.PCT / EP94 / 03118 Sec。 371日期：1996年3月28日 102（e）1996年3月28日PCT 1994年9月19日PCT PCT。公开号WO95 / 08978 日期1995年4月6日一种含氧过氧化氢组合物，其用于氧化染色和脱毛的pH为2〜6。该组合物含有阴离子表面活性剂，过氧化氢，含有羧基或羧酸盐基团的水溶性或水分散性增稠聚合物或共聚物，以及任选的具有至多50摩尔环氧乙烷乙氧基化的C12-C18脂肪醇或氢化蓖麻用高达50摩尔环氧乙烷乙氧基化的油以及由含有细颗粒疏水化二氧化硅的聚硅氧烷组成的泡沫调节剂组分的0.001％至0.05％，其中细颗粒疏水化二氧化硅的含量为0.5％至20％，基于泡沫调节剂组分的重量。

34. 发明授权

US5616150A Isatin-containing formulations for coloring keratin-containing fibers 失效
标题翻译：含有角蛋白的纤维的含靛红的制剂
公开(公告)号：US5616150A
公开(公告)日：1997-04-01
申请号：US535261
申请日：1995-10-30
申请人： Hinrich Moeller , Horst Hoeffkes
发明人： Hinrich Moeller , Horst Hoeffkes
IPC分类号： A61K8/00 , A61K8/31 , A61K8/33 , A61K8/36 , A61K8/365 , A61K8/368 , A61K8/41 , A61K8/46 , A61K8/49 , A61K8/60 , A61Q5/10 , C07D209/38 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/492
摘要： A composition for coloring keratin-containing fibers containing:(a) at least one isatin derivative corresponding to formula I: ##STR1## wherein R.sup.1 can represent hydrogen, a C.sub.1-4 alkyl group, a C.sub.2-4 hydroxyalkyl group, a C.sub.2-20 acyl group, a phenyl group, and a benzoyl group, and R.sup.2, R.sup.3, R.sup.4 and R.sup.5 independently of one another can represent hydrogen, hydroxy, halogen, nitro groups, sulfo groups, carboxyl groups, C.sub.1-4 alkyl groups, C.sub.1-4 alkoxy groups or NR.sup.6 R.sup.7 groups and where R.sup.6 and R.sup.7 independently of one another represent hydrogen, C.sub.1-4 alkyl groups or C.sub.2-4 hydroxyalkyl groups, and wherein two adjacent groups R.sup.3, R.sup.4 and R.sup.5 may also represent an alkylenedioxy group containing 1 to 4 carbon atoms,(b) at least one compound selected from the group consisting of: (i) primary aliphatic amines; (ii) heterocyclic or isocyclic aromatic compounds without a primary amino group; (iii) aromatic carboxylic and sulfonic acids with a primary amino group; (iv) aniline derivatives; (v) dianiline derivatives; (vi) non-aromatic unsubstituted or amino-(C.sub.1-4)-alkyl-, hydroxy-(C.sub.1-4)-alkyl-carboxyl-substituted hetero-cycles; and (vii)amino sugars; and(c) a water-containing carrier.
摘要翻译： PCT No.PCT / EP94 / 01246 Sec。 371 1995年10月30日第 102（e）1995年10月30日日期PCT 1994年4月21日PCT PCT。第WO94 / 24988号公报日本1994年11月10日一种用于着色含角蛋白纤维的组合物，其含有：（a）至少一种对应于式I的靛红衍生物：其中R 1可以表示氢，C 1-4烷基， 4个羟烷基，C2-20酰基，苯基和苯甲酰基，R2，R3，R4和R5彼此独立地表示氢，羟基，卤素，硝基，磺基，羧基，C1 -4-烷基，C 1-4烷氧基或NR 6 R 7基团，其中R 6和R 7彼此独立地表示氢，C 1-4烷基或C 2-4羟基烷基，并且其中两个相邻基团R 3，R 4和R 5也可以表示含有1至4个碳原子的亚烷基二氧基，（b）至少一种选自以下的化合物：（i）伯脂肪族胺; （ii）不含伯氨基的杂环或环状芳族化合物; （iii）具有伯氨基的芳族羧酸和磺酸; （iv）苯胺衍生物; （v）二苯胺衍生物; （vi）非芳族未取代或氨基 - （C 1-4） - 烷基 - ，羟基 - （C 1-4） - 烷基 - 羧基取代的杂环; 和（vii）氨基糖; （c）含水载体。

35. 发明授权

US5104412A Hair dyeing compositions 失效
标题翻译：头发染色组合物
公开(公告)号：US5104412A
公开(公告)日：1992-04-14
申请号：US635160
申请日：1991-02-20
申请人： David Rose , Horst Hoeffkes , Edgar Lieske
发明人： David Rose , Horst Hoeffkes , Edgar Lieske
IPC分类号： A61K8/00 , A61K8/41 , A61K8/92 , A61Q5/10
CPC分类号： A61K8/415 , A61Q5/10
摘要： Hair dyeing compositions contain N-cycloalkyl-3-aminophenols corresponding to the following formula ##STR1## in which n is an integer of 4 to 8 and R.sup.1, R.sup.2, and R.sup.3 independently of one another represent hydrogen, methyl groups or chlorine,or salts thereof as oxidation dye intermediates of the coupler type in addition to typical primary intermediates in a carrier. In conjunction with typical primary intermediates, for example of the p-phenylenediamine derivative type, the new coupler compounds produce shades of brown of high fastness.
摘要翻译： PCT No.PCT / EP89 / 00707 Sec。 371日期1991年2月20日 102（e）日期1991年2月20日PCT提交1989年6月23日PCT公布。 WO90 / 00046 PCT出版物日本1990年1月11日。毛发染色组合物含有对应于下列式（IMAGE）的N-环烷基-3-氨基苯酚，其中n为4-8的整数，并且R 1，R 2和R 3彼此独立地表示氢，甲基或氯或其盐作为偶联剂型的氧化染料中间体，以及载体中典型的主要中间体。结合典型的主要中间体，例如对苯二胺衍生物类型，新的成色剂化合物产生高牢度的棕色色调。

36. 发明授权

US4948528A Free-flowing pearlescent concentrate 失效
标题翻译：自由流动的珠光浓缩液
公开(公告)号：US4948528A
公开(公告)日：1990-08-14
申请号：US303373
申请日：1989-01-27
申请人： Horst Hoeffkes , Anke Kaczich
发明人： Horst Hoeffkes , Anke Kaczich
IPC分类号： A61K8/00 , A61Q5/02 , A61Q5/12 , B01F17/16 , B01F17/34 , B01F17/42 , B01F17/44 , B01F17/56 , B01J13/00 , C09D5/36 , C09K3/00 , C11D1/74 , C11D1/835 , C11D3/20 , C11D3/40
CPC分类号： C11D3/0089 , A61K8/39 , A61K8/4973 , A61K8/4993 , A61K8/604 , A61Q5/02 , Y10S514/937 , Y10S516/01 , Y10S516/07
摘要： A pearlescent concentrate in the form of a free-flowing dispersion containing from 5 to 15% by weight of one or more ester corresponding to the following formulaR.sup.1 -(OC.sub.n H.sub.2n).sub.x -OR.sup.2and from 1 to 6% by weight of one or more fatty acid mono- ethanolamide may be prepared using from 2 to 8% by weight of one or more compound selected from the group alkyl (oligo) glucoside, sorbitan fatty acid ester, fatty amine ethoxylate, ether carboxylic acid, or fatty acid monoester or diester of glycerol ethoxylate as an emulsifier.

37. 发明授权

US4824594A Free-flowing pearlescent concentrate 失效
标题翻译：自由流动的珠光浓缩液
公开(公告)号：US4824594A
公开(公告)日：1989-04-25
申请号：US125506
申请日：1987-11-25
申请人： Horst Hoeffkes , Anke Kaczich
发明人： Horst Hoeffkes , Anke Kaczich
IPC分类号： A61K8/00 , A61Q5/02 , A61Q5/12 , B01F17/16 , B01F17/34 , B01F17/42 , B01F17/44 , B01F17/56 , B01J13/00 , C09D5/36 , C09K3/00 , C11D1/74 , C11D1/835 , C11D3/20 , C11D3/40
CPC分类号： C11D3/0089 , A61K8/39 , A61K8/4973 , A61K8/4993 , A61K8/604 , A61Q5/02 , Y10S514/937 , Y10S516/01 , Y10S516/07
摘要： A pearlescent concentrate in the form of a free-flowing dispersion containing from 5 to 15% by weight of one or more ester corresponding to the following formulaR.sup.1 --(OC.sub.n H.sub.2n).sub.x --OR.sup.2and from 1 to 6% by weight of one or more fatty acid monoethanolamide may be prepared using from 2 to 8% by weight of one or more compound selected from the group alkyl (oligo) glucoside, sorbitan fatty acid ester, fatty amine ethoxylate, ether carboxylic acid, or fatty acid monoester or diester of glycerol ethoxylate as an emulsifier.
摘要翻译：一种自由流动分散体形式的珠光浓缩物，其含有5至15重量％的一种或多种对应于下式R1-（OCnH2n）x-OR2的酯和1至6重量％的一种或多种脂肪酸单乙醇酰胺可以使用2至8重量％的一种或多种选自烷基（寡）葡萄糖苷，脱水山梨醇脂肪酸酯，脂肪胺乙氧基化物，醚羧酸或脂肪酸单酯或甘油二酯的化合物乙氧基化物作为乳化剂。

38. 发明授权

US4795632A Preparations for washing and rinsing hair 失效
标题翻译：清洗和漂洗头发的准备
公开(公告)号：US4795632A
公开(公告)日：1989-01-03
申请号：US874874
申请日：1986-06-16
申请人： Karl Giede , Horst Hoeffkes
发明人： Karl Giede , Horst Hoeffkes
IPC分类号： A61K8/00 , A61K20060101 , A61K8/40 , A61K8/41 , A61K8/46 , A61K8/81 , A61Q5/00 , A61Q5/02 , A61Q5/12 , C08F16/34 , C11D3/20 , C11D3/37 , A61K7/06 , A61K7/08
CPC分类号： A61Q5/02 , A61K8/8147 , A61Q5/12 , Y10S424/04 , Y10S514/852 , Y10S514/864
摘要： Preparations for washing or rinsing hair contain polyaldehydocarboxylic acids having an average molecular weight of from 600 to 10,000, a carboxyl group content of from 5 to 9 and preferably from 7 to 9 and an aldehyde group content of from 1 to 5 and preferably from 1 to 3 per 10 monomer units, or water-soluble salts thereof. These additives reduce the smoothness of dry hair and improve body and stylability after washing. The polyaldehydocarboxylic acids are preferably used in conjunction with hair-conditioning linear alkyl and/or alkylether phosphate salts, alkyl, hydroxyalkyl and/or aminoalkyl phosphonate salts. Preferred embodiments are hair shampoos containing from about 1 to about 10% by weight of the polyaldehydocarboxylic acids and from about 5 to about 50% by weight of anionic surfactants of the alkyl sulfate and/or alkylether sulfate type and hair rinses containing from about 1 to about 10% by weight of hair-conditioning alkyl and/or alkylether phosphate salts and/or alkane phosphonate salts.
摘要翻译：用于洗涤或漂洗头发的制剂含有平均分子量为600至10,000，羧基含量为5至9，优选为7至9，醛基含量为1至5，优选1至5的聚醛羧酸每10个单体单元3个，或其水溶性盐。这些添加剂降低了干性头发的平滑度，并且改善了洗涤后的身体和造型。聚醛羧酸优选与头发调理线性烷基和/或烷基醚磷酸盐，烷基，羟烷基和/或氨基烷基膦酸盐一起使用。优选的实施方案是含有约1至约10重量％的聚醛羧酸的洗发剂和约5至约50重量％的烷基硫酸盐和/或烷基醚硫酸盐型的阴离子表面活性剂和含有约1至约10重量％的调理烷基和/或烷基醚磷酸盐和/或烷烃膦酸盐。

39. 发明授权

US4761249A Soil-collecting cleaning enhancers in aqueous surfactant laundering and cleaning solutions 失效
标题翻译：水性表面活性剂洗涤和清洁溶液中的土壤收集清洁增强剂
公开(公告)号：US4761249A
公开(公告)日：1988-08-02
申请号：US945610
申请日：1986-12-23
申请人： Karl Giede , Brigitte Giesen , Horst Hoeffkes , Alfred Meffert , Andreas Syldatk , Johann F. Fues
发明人： Karl Giede , Brigitte Giesen , Horst Hoeffkes , Alfred Meffert , Andreas Syldatk , Johann F. Fues
IPC分类号： C11D3/12 , C11D3/00 , C11D3/22 , C11D3/37 , C11D17/00 , C11D17/04 , D06L1/12 , C11D3/26 , C11D17/06
CPC分类号： C11D17/0034 , C11D3/0036 , C11D3/37 , C11D3/3703 , C11D3/3769
摘要： Soil-collecting detergency enhancers for detergent solutions comprising a substantially water-insoluble polyfunctional quaternary ammonium compound or a water-soluble polyfunctional quaternary ammonium compound fixed to a water-insoluble solid carrier. The detergency enhancers may be used in the cleaning of soiled articles, particularly those soiled with pigments, in aqueous detergent solutions such as for washing fabrics.
摘要翻译：用于洗涤剂溶液的土壤收集洗涤增强剂，其包含基本上不溶于水的多官能季铵化合物或固定在水不溶性固体载体上的水溶性多官能季铵化合物。洗涤增强剂可用于清洁污染的制品，特别是用颜料污染的物品，在洗涤剂等洗涤剂溶液中。

40. 发明授权

US07225920B2 Mixing device 失效
标题翻译：混合装置
公开(公告)号：US07225920B2
公开(公告)日：2007-06-05
申请号：US11222564
申请日：2005-09-09
申请人： Horst Hoeffkes , Ullrich Bernecker , Martina Seiler
发明人： Horst Hoeffkes , Ullrich Bernecker , Martina Seiler
IPC分类号： B01F3/12 , B01F13/00 , B01F15/02 , B65D65/46
CPC分类号： A61K8/02 , A45D2019/0066 , A61K2800/242 , A61K2800/88 , A61Q5/065 , A61Q5/08 , A61Q5/10 , B01F13/002 , B01F13/0022 , B01F15/00506 , B01F15/00512 , B01F15/0205 , B01F15/0207 , B01F15/0224 , B01F2215/0031 , B65D47/10 , B65D65/46 , B65D81/3233
摘要： The invention relates to a mixing device for mixing a pulverulent product, which is contained in a film sachet that is soluble in liquid, with said liquid and optionally at least one additional component. The aim of the invention is to accelerate the mixing of pulverulent products, which are packed in film sachets that are soluble in liquid, with a liquid, without the risk of creating dust. This is achieved by a sealable mixing container (2) comprising a receiving chamber (7) for the pulverulent product (9) contained in the film sachet (8), the liquid and the optional additional component. The receiving chamber (7) is equipped with fitted components (6, 6′), which act mechanically on the film sachet (8).
摘要翻译：本发明涉及一种用于将包含在可溶于液体的薄膜小袋中的粉状产品与所述液体和任选的至少一种附加组分混合的混合装置。本发明的目的是加速将可溶于液体的薄膜袋中的粉状产物与液体混合，而不会产生灰尘的风险。这通过可密封的混合容器（2）来实现，该容器包括用于包含在薄膜小包装（8）中的粉状产品（9）的接收室（7），液体和任选的附加组件。接收室（7）配有装配的部件（6,6'），其在薄膜小袋（8）上机械地作用。

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