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31. 发明授权

US06787581B2 Radio hardenable powder paints 失效
标题翻译：无线硬化粉末涂料
公开(公告)号：US06787581B2
公开(公告)日：2004-09-07
申请号：US10181134
申请日：2002-10-22
申请人： Rainer Blum , Horst Hintze-Bruening , Uwe Meisenburg
发明人： Rainer Blum , Horst Hintze-Bruening , Uwe Meisenburg
IPC分类号： B05D136
CPC分类号： C09D167/07
摘要： The invention relates to powder coating material curable with high-energy radiation, comprising an unsaturated polyester resin (A) and a polymeric crosslinker (B) containing, based on the polymer main chain, terminal and/or pendant propenyl, butenyl and/or isoprenyl groups. The unsaturated polyester resin (A) and/or the polymeric crosslinker (B) comprise structural units of the general formula I and/or II. These novel powder coating materials are curable with high-energy radiation, preferably UV light, and are notable in particular for a very good viscosity stability during the preparation, in the melt, of the resins and the compounding of the coating materials, for outstanding coating properties, and for a low oxygen sensitivity on curing. The films resulting after the cure, moreover, exhibit outstanding elasticity.
摘要翻译：本发明涉及可用高能量辐射固化的粉末涂料，其包含不饱和聚酯树脂（A）和聚合物交联剂（B），所述聚合物交联剂（B）含有基于聚合物主链的末端和/或侧链丙烯基，丁烯基和/或异戊二烯基团体不饱和聚酯树脂（A）和/或聚合物交联剂（B）包含通式I和/或II的结构单元。这些新型粉末涂料可用高能量辐射，优选紫外光固化，特别是在制备过程中，在熔体中，树脂的混合和涂层材料的混合中具有非常好的粘度稳定性，用于优异的涂层性能以及固化时的低氧敏感性。此外，治愈后产生的膜具有出色的弹性。

32. 发明授权

US06632561B1 Composites bodies used as separators in electrochemical cells 失效
标题翻译：复合体用作电化学电池中的分离器
公开(公告)号：US06632561B1
公开(公告)日：2003-10-14
申请号：US09830265
申请日：2001-04-25
申请人： Stephan Bauer , Bernd Bronstert , Helmut Möhwald , Rainer Blum , Gerhard Dötter
发明人： Stephan Bauer , Bernd Bronstert , Helmut Möhwald , Rainer Blum , Gerhard Dötter
IPC分类号： H01M216
CPC分类号： H01M4/621 , H01M2/1673 , H01M10/052 , H01M10/0525 , Y10T428/249953 , Y10T428/249994 , Y10T428/249998 , Y10T428/254 , Y10T428/31504 , Y10T428/31565 , Y10T428/3158 , Y10T428/31583 , Y10T428/31587 , Y10T428/31721 , Y10T428/31725
摘要： A composite comprises at least one layer which includes a composite comprising (a) from 1 to 99% by weight of a solid (I) with a primary particle size of from 5 nm to 100 &mgr;m or a mixture made from at least two solids, (b) from 99 to 1% by weight of a polymeric binder (II) which includes: (IIa) from 1 to 100% by weight of a polymer or copolymer (IIa) which has, along the chain, terminally and/or laterally, reactive groups (RG) which are capable of crosslinking reactions when exposed to heat and/or UV radiation, and (IIb) from 0 to 99% by weight of at least one polymer or copolymer (IIb) which is free from reactive groups RG, where the at least one layer has been applied to at least one second layer comprising at least one conventional separator.
摘要翻译：复合材料包括至少一层，其包括复合材料，所述复合材料包含（a）1至99重量％的初级粒度为5nm至100μm的固体（I）或由至少两个固体，（b）99至1重量％的聚合物粘合剂（II），其包含：1至100重量％的聚合物或共聚物（IIa）（IIa）其具有沿链条的末端和/或侧向反应性基团（RG），其在暴露于热和/或UV辐射时能够交联反应，并且其中0至99重量％至少一种不含活性基团RG的聚合物或共聚物（IIb），其中至少一层已施加至至少一层包含至少一种常规分离剂的第二层。

33. 发明授权

US06632481B1 Binders curable thermally and/or by high-energy radiation 失效
标题翻译：热固化和/或通过高能辐射固化的粘合剂
公开(公告)号：US06632481B1
公开(公告)日：2003-10-14
申请号：US09762486
申请日：2001-02-07
申请人： Rainer Blum , Rodriguez Jorge Prieto , Wolfgang Reich
发明人： Rainer Blum , Rodriguez Jorge Prieto , Wolfgang Reich
IPC分类号： C08L7514
CPC分类号： C08G63/47 , C08G18/683 , C08G63/553 , C09D163/10 , C09D167/07 , C09D175/16
摘要： The invention relates to a binder, preferably for coating materials, which is curable thermally and/or by high-energy radiation and comprises a mixture of substances comprising (a) as one component, monomers or polymers which have a least one vinyl ether, vinyl ester, (meth)acrylic and/or allyl group and (b) as a further component, saturated polymers and/or unsaturated polymers different from component (a), with the proviso that at least one of components (a) and (b) has structural units of the formulae (I) and/or (II) the other component (b) has structural units of the formulae (I) and/or (II) at least when it contains saturated polymers. The invention also relates to a process for preparing the binder and to a formulation which comprises the binder of the invention. This formulation is in the form of a pigmented or unpigmented coating material or powder coating material. In addition, the invention relates to a procedure for preparing coatings, which following application are cured thermally and/or by irradiation with UV light or electron beams.
摘要翻译：本发明涉及一种粘合剂，优选用于涂覆材料，其可热和/或通过高能量辐射固化，并且包含作为一种组分的物质的混合物，所述物质具有至少一种乙烯基醚，乙烯基酯，（甲基）丙烯酸和/或烯丙基和作为其它组分的（b）作为另外的组分，不同于组分（a）的饱和聚合物和/或不饱和聚合物，条件是组分（a）和（b）中的至少一种具有式（I）和/或（II）的结构单元，另一组分（b）至少具有式（I）和/或（II）的结构单元）当其含有饱和聚合物时。本发明还涉及制备粘合剂的方法和包含本发明粘合剂的制剂。该制剂是着色或未着色的涂料或粉末涂料的形式。此外，本发明涉及一种制备涂料的方法，其后续应用是热和/或通过用UV光照射或/ 电子束

34. 发明授权

US06475663B1 Compositions suitable for electrochemical cells 失效
标题翻译：适用于电化学电池的组合物
公开(公告)号：US06475663B1
公开(公告)日：2002-11-05
申请号：US09762076
申请日：2001-02-01
申请人： Helmut Möhwald , Gerhard Dötter , Rainer Blum , Peter Keller , Stephan Bauer , Bernd Bronstert
发明人： Helmut Möhwald , Gerhard Dötter , Rainer Blum , Peter Keller , Stephan Bauer , Bernd Bronstert
IPC分类号： H01M464
CPC分类号： H01G9/025 , G01N27/4073 , H01M2/164 , H01M2/1653 , H01M4/13 , H01M4/621 , H01M4/622 , H01M10/052 , H01M10/0565 , H01M2300/0082
摘要： A composition comprising: (a) from 0 to less than 1% by weight of a pigment (I) having a primary particle size of from 5 nm to 100 &mgr;m which is a solid Ia or a compound Ib which acts as cathode material in electrochemical cells or a compound Ic which acts as anode material in electrochemical cells or a mixture of the solid Ia with the compound Ib or the compound Ic, (b) more than 99 to 100% by weight of a polymeric material (II) which comprises: (IIa)from 1 to 100% by weight of a polymer or copolymer (IIa) containing reactive groups (RG) on the chain in terminal and/or lateral positions which are capable of crosslinking reactions in the presence of heat and/or with UV radiation, and (IIb) from 0 to 99% by weight of at least one polymer or copolymer (IIb) which contains no reactive groups (RG).
摘要翻译：一种组合物，其包含：（a）0至小于1重量％的一次粒径为5nm至100μm的颜料（I），其为固体Ia或用作电化学阴极材料的化合物Ib 电池或化合物Ic，其在电化学电池中充当阳极材料或固体Ia与化合物Ib或化合物Ic的混合物，（b）大于99至100重量％的聚合物材料（II），其包含：（IIa）1至100重量％的在末端和/或侧向位置上含有反应性基团（RG）的聚合物或共聚物（IIa），其能够在热和/或UV存在下交联反应辐射和（IIb）0至99重量％的至少一种不含反应性基团（RG）的聚合物或共聚物（IIb）。

35. 发明授权

US06200645B1 Polyester resin impregnating and coating solutions and their use 有权
标题翻译：聚酯树脂浸渍和涂层溶液及其用途
公开(公告)号：US06200645B1
公开(公告)日：2001-03-13
申请号：US09367931
申请日：1999-10-27
申请人： Rainer Blum , Klaus-Wilhelm Lienert , Manfred Eichhorst
发明人： Rainer Blum , Klaus-Wilhelm Lienert , Manfred Eichhorst
IPC分类号： B05D302
CPC分类号： C08G63/553 , C08L67/06 , C09D167/06
摘要： The polyester resin impregnating and coating solution comprises polyesters having structures of the formula (I) where n is from 0 to 10 and where the solution is essentially free from monomers containing acrylic, vinylic or allylic unsaturation and where the solvent employed preferably comprises aliphatic saturated C2-6 alcohols, C3-6 ketones or C3-6 carboxylic esters or mixtures thereof, the proportion of the solvent being from 5 to 60% by weight of the overall polyester resin impregnating and coating solution.
摘要翻译：聚酯树脂浸渍和涂布溶液包括具有式（I）结构的聚酯，其中n为0至10，并且其中溶液基本上不含含有丙烯酸，乙烯基或烯丙基不饱和基团的单体，并且其中所用的溶剂优选包含脂族饱和C2- 6个醇，C3-6酮或C3-6羧酸酯或其混合物，溶剂的比例为总聚酯树脂浸渍和涂布溶液的5至60重量％。

36. 发明授权

US6165557A Solvent-free coating compositions which can be cured with low emissions 失效
标题翻译：无溶剂的涂料组合物可以以低排放固化
公开(公告)号：US6165557A
公开(公告)日：2000-12-26
申请号：US101224
申请日：1998-08-20
申请人： Rainer Blum , Uwe Meisenburg , Dietmar Chmielewski , Thomas Loerzer
发明人： Rainer Blum , Uwe Meisenburg , Dietmar Chmielewski , Thomas Loerzer
IPC分类号： C09D11/104 , C09D167/06 , C09D167/07 , C09D179/08 , B05D3/02 , B05D7/16
CPC分类号： C09D11/104 , C09D167/06 , C09D167/07 , C09D179/08
摘要： The invention relates to solvent-free coating compositions which can be cured with low emissions and comprise, as binders, saturated and/or unsaturated polyesters whose structural units include dihydrodicyclopentadiene units of the formula (I): ##STR1## and/or oligodihydrodicyclopentadiene units of the formula (II): ##STR2## where n=1 to 10, to processes for the production of coatings using the novel coating compositions, and to the use of the coating compositions for coating metal containers, especially cans.
摘要翻译： PCT No.PCT / DE96 / 02406 Sec。 371日期：1998年8月20日 102（e）1998年8月20日PCT PCT 1996年12月13日PCT公布。公开号WO97 / 25386 PCT 日期1997年7月17日本发明涉及可以以低排放固化的无溶剂涂料组合物，并且包含作为粘合剂的饱和和/或不饱和聚酯，其结构单元包括式（I）的二氢二环戊二烯单元：和/或二聚二环戊二烯式（II）的单元：其中n = 1至10，用于使用新型涂料组合物生产涂料的方法，以及用于涂覆金属容器，特别是罐的涂料组合物的用途。

37. 发明授权

US6103451A Multilayer element for producing printing or relief plates 失效
标题翻译：用于生产印刷或浮雕板的多层元件
公开(公告)号：US6103451A
公开(公告)日：2000-08-15
申请号：US157599
申请日：1998-09-21
申请人： Rainer Blum , Sabine Philipp , Alfred Leinenbach
发明人： Rainer Blum , Sabine Philipp , Alfred Leinenbach
IPC分类号： B32B27/30 , G03F7/00 , G03F7/11
CPC分类号： G03F7/11
摘要： A multilayer element comprising a substrate, an intermediate layer and a photopolymerizable or photocrosslinkable layer in the stated order is used for producing printing or relief plates. The intermediate layer contains a copolymer of a monomer (A) of the formula (I) or (II) and a copolymerizable monomer (B) ##STR1## where R.sup.1 is vinyl, propen-2-yl, 1-buten-2-yl or styryl or a radical R.sup.2 --O--CO--CH.dbd.CH--, R.sup.2 is an alkyl, aryl, aralkyl or cycloalkyl radical of up to 10 carbon atoms, R.sup.3 is H, methyl or ethyl and n is from zero to 5. The intermediate layer in the multilayer element has improved adhesion in the laminate. It is initially nontacky and does not become tacky until after the application of the photopolymerizable layer, as a result of the interaction with said layer. The improved adhesion in the laminate is retained even after storage and repeated use of the finished printing plates.
摘要翻译：使用包括基板，中间层和可光聚合或可光致交联层的多层元件按照所述的顺序制造印刷版或浮雕版。中间层包含式（I）或（II）的单体（A）和可共聚单体（B）的共聚物，其中R 1是乙烯基，丙烯-2-基，1-丁烯-2-基或苯乙烯基或基团R2-O-CO-CH = CH-，R2是至多10个碳原子的烷基，芳基，芳烷基或环烷基，R3是H，甲基或乙基，n是0-5。多层元件具有改进的层压体粘附性。由于与所述层的相互作用，它最初是不粘的，并且直到施加可光聚合层之后才变粘。即使在保存并重复使用成品印刷版之后，也保留了层压体中改善的粘合性。

38. 发明授权

US5302458A Adhesion promoter 失效
标题翻译：粘合促进剂
公开(公告)号：US5302458A
公开(公告)日：1994-04-12
申请号：US86314
申请日：1993-07-06
申请人： Rainer Blum , Hans J. Heller , Hans-Joachim Haehnle , Klaus Lienert
发明人： Rainer Blum , Hans J. Heller , Hans-Joachim Haehnle , Klaus Lienert
IPC分类号： C03C17/34 , C03C25/40 , C09D4/00 , B32B27/04
CPC分类号： C03C25/40 , C03C17/3405 , C09D4/00 , Y10T428/31612 , Y10T428/31663 , Y10T428/31721
摘要： Use of a mixture of from 5 to 95% by weight of an azidosilane of the formulaN.sub.3 --R.sup.3 --Si--R.sup.1.sub.n (OR.sup.2).sub.3-n Iwhere R.sup.1 is C.sub.1 -C.sub.3 -alkyl, phenyl, benzyl or tolyl, R.sup.2 is C.sub.1 -C.sub.4 -alkyl, C.sub.2 -C.sub.4 -alkoxyalkyl, phenyl or benzyl, R.sup.3 is C.sub.1 -C.sub.8 -alkylene, which may be interrupted by oxygen, sulfur or --(N--R.sup.4)-- in which R.sup.4 is hydrogen, methyl, ethyl or phenyl, and n is 0, 1 or 2, and from 5 to 95% by weight of an aminoalkoxysilane of the formulaH.sub.2 N--R.sup.5 --Si--R.sup.6.sub.m (OR.sup.7).sub.3-m (II)where R.sup.5 is C.sub.1 -C.sub.6 -alkylene, C.sub.5 -C.sub.6 -cycloalkylene or C.sub.5 -C.sub.6 -arylene, each of which may be additionally substituted by one or two C.sub.1 -C.sub.3 -alkyl groups, and R.sup.6 and R.sup.7, independently of one another, are C.sub.1 -C.sub.6 -alkyl or C.sub.5 -C.sub.6 -cycloalkyl, each of which may likewise be additionally substituted by one or two C.sub.1 -C.sub.3 -alkyl groups, and m may be 0, 1 or 2, as an adhesion promoter between polycondensates containing, as structural units, heterocyclic ring systems containing nitrogen atoms, or precursors of these polycondensates, and inorganic substrates.
摘要翻译：使用5至95重量％的式N3-R3-Si-R1n（OR2）3-nI的叠氮硅烷的混合物，其中R1是C1-C3-烷基，苯基，苄基或甲苯基，R2是C1- C4-烷基，C2-C4-烷氧基烷基，苯基或苄基，R3是C1-C8-亚烷基，其可以被氧，硫或 - （N-R4） - 被中断，其中R4是氢，甲基，乙基或苯基，和n为0,1或2，和5至95重量％的式H2N-R5-Si-R6m（OR7）3-m（Ⅱ）的氨基烷氧基硅烷，其中R5为C1-C6-亚烷基，C5-C6 亚环烷基或C 5 -C 6亚芳基，其各自可以另外被一个或两个C 1 -C 3 - 烷基取代，R 6和R 7彼此独立地是C 1 -C 6烷基或C 5 -C 6环烷基，其中每一个也可以另外被一个或两个C 1 -C 3烷基取代，并且m可以是0,1或2，作为含有作为结构单元的含氮原子或前体的杂环体系的缩聚物之间的粘合促进剂的这些缩聚物和无机基材。

39. 发明授权

US5159011A Aqueous formulations of copolymer latices and polyisocyanate dispersions 失效
标题翻译：共聚物和聚异氰酸酯分散体的水性配方
公开(公告)号：US5159011A
公开(公告)日：1992-10-27
申请号：US730468
申请日：1991-07-16
申请人： Maria G. Rau , Rainer Blum , Gerd Louis
发明人： Maria G. Rau , Rainer Blum , Gerd Louis
IPC分类号： C08G18/62 , C08G18/70 , C08G18/80 , D06M11/45 , D06M11/46 , D06M11/56 , D06M15/564 , D06M15/693 , D06M23/04 , D06N3/04 , D06N3/14
CPC分类号： D06N3/144 , C08G18/6216 , C08G18/705 , C08G18/80 , D06M11/45 , D06M11/46 , D06M11/56 , D06M15/564 , D06M15/693 , D06M23/04 , D06N3/04 , D06M2101/06 , D06M2101/18 , D06M2101/32
摘要： Aqueous formulations of copolymer latices and polyisocyanate dispersions, containingA) from 5 to 40% by weight of one or more synthetic resins of(a) from 0.1 to 20 parts by weight of one or more monoolefinically unsaturated monomers which carry one or more groups which are reactive with isocyanates and(b) from 80 to 99.9 parts by weight of one or more mono- or diolefinically unsaturated monomers which are copolymerizable with (a) and have no acidic hydrogen atoms,B) from 0.5 to 5% by weight of one or more finely divided, stabilized polyisocyanates,C) effective amounts of dispersants andD) from 5 to 40% by weight of one or more finely divided fillers,are used as coating materials for woven and nonwoven substrates.
摘要翻译：共聚物胶乳和多异氰酸酯分散体的水性配方，含有A）5-40重量％的一种或多种合成树脂（a）0.1-20重量份一种或多种携带一个或多个基团的单烯属不饱和单体，与异氰酸酯反应，和（b）80-99.9重量份可与（a）可共聚并且不具有酸性氢原子的一种或多种单或二烯属不饱和单体，B）0.5至5重量％或更细的分散稳定的多异氰酸酯，C）有效量的分散剂和D）5至40重量％的一种或多种细碎填料用作织造和非织造基材的涂料。

40. 发明授权

US4888124A Preparation of stable dispersions of finely divided polyisocyanates and preparation of heat-crosslinkable isocyanate systems 失效
标题翻译：精细分散的多异氰酸酯的稳定分散体的制备和热交联的异氰酸酯体系的制备
公开(公告)号：US4888124A
公开(公告)日：1989-12-19
申请号：US112049
申请日：1987-10-23
申请人： Rainer Blum , Horst Belde , Rolf Osterloh , Guenter Uhl
发明人： Rainer Blum , Horst Belde , Rolf Osterloh , Guenter Uhl
IPC分类号： C08G18/00 , C07C265/12 , C07C265/14 , C08G18/70 , C08G18/72 , C08G18/80 , C09D175/00
CPC分类号： C08G18/798 , C07C265/12 , C08G18/603 , C08G18/70 , C08G18/707
摘要： A process for the preparation of stable dispersions of finely divided polyisocyanates, and the preparation of heat-crosslinkable isocyanate systems.Stable dispersions of finely divided polyisocyanates in a liquid which may or may not contain surfactants, protective colloids and other assistants are obtained by a method in which polyisocyanates are treated with a stabilizer in the presence of absence of the liquid, and the dispersions prepared from these are finely dispersed and/or milled under the action of high shear forces, if necessary with the addition of further stabilizer.These dispersions are useful as crosslinking agents, particularly for the preparation of heat-cross-linkable isocyanate systems.
摘要翻译：制备细分散的多异氰酸酯的稳定分散体的方法，以及制备热交联的异氰酸酯体系。可以或不含有表面活性剂，保护胶体和其它辅助剂的液体中细分散的多异氰酸酯的稳定分散体是通过在不存在液体的情况下用稳定剂处理多异氰酸酯的方法获得的，并且由这些制备的分散体在高剪切力的作用下被细分散和/或研磨，如果需要，加入另外的稳定剂。这些分散体可用作交联剂，特别是用于制备可热交联的异氰酸酯体系。

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