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31. 发明授权

US4368115A Catalysts comprising layered chalcogenides of group IVb-group VIIb prepared by a low temperature nonaqueous precipitate technique 失效
标题翻译：包含通过低温非水沉淀技术制备的IVb族VIIb族的层状硫族化物的催化剂
公开(公告)号：US4368115A
公开(公告)日：1983-01-11
申请号：US242640
申请日：1981-03-11
申请人： Russell R. Chianelli , Theresa A. Pecoraro , Martin B. Dines
发明人： Russell R. Chianelli , Theresa A. Pecoraro , Martin B. Dines
IPC分类号： B01J27/02 , B01J27/04 , B01J27/057 , C01B19/00 , C01G1/12 , C01G47/00 , C10G45/04 , C10G49/02 , C10G45/08
CPC分类号： C10G49/02 , B01J27/02 , B01J27/04 , B01J27/0573 , C01B19/007 , C01G1/12 , C01G47/00 , C10G45/04 , C01P2002/02 , C01P2002/60 , C01P2006/12 , C01P2006/60 , C01P2006/80
摘要： In processes for the catalytic treatment of hydrocarbon feedstream containing organic sulfur comprising contacting said feedstream with a catalyst for a time at a temperature and pressure sufficient to effect the desired catalytic change on the feedstream, the improvement comprising using as the catalyst a layered composition of the formula MX.sub.y wherein M is a transition metal selected from the group consisting of Group IVb, Vb, VIb, VIIb and uranium, X is a chalcogen selected from the group consisting of sulfur, selenium, tellurium, and mixtures thereof, y is a number ranging from about 1.5 to about 3. The catalyst is prepared by reacting neat or in the presence of a nonaqueous solvent a Group IVb to VIIb or uranium metal salt, and a source of sulfide, selenide or telluride ions, and mixing the reactants at temperatures below 400.degree. C. and at atmospheric pressures. The catalyst may be isolated by filtration and washing with excess solvent (when one is used) or by vacuum pumping any volatile coproduced anion salt. Preferably the chalcogenide is sulfur and y is about 1.5 to about 2.The catalytic processes which are benefited by the use therein of the above-described compositions are hydrodesulfurization, hydrodenitrogenation, hydroconversion and hydrogenation run in the presence of hydrogen or a hydrogen donor solvent.
摘要翻译：在含有有机硫的烃进料流的催化处理方法中，包括使所述原料流与催化剂在足以在进料流上实现所需催化变化的温度和压力下接触一段时间，所述改进包括使用作为催化剂的分层组合物式MXy其中M是选自IVb，Vb，VIb，VIIb和铀的过渡金属，X是选自硫，硒，碲及其混合物的硫族元素，y是一个范围约1.5至约3.催化剂通过纯的或在非水溶剂（IVb至VIIb族或铀金属盐）和硫化物，硒化物或碲化物离子源的存在下反应制备，并将反应物在低于 400℃，在大气压下。催化剂可以通过过滤和用过量溶剂（当使用一种溶剂）洗涤时或通过真空泵送任何挥发性共生的阴离子盐来分离。硫属化物优选为硫，y为约1.5至约2.通过在上述组合物中使用而受益的催化方法是在氢或氢供体溶剂的存在下进行加氢脱硫，加氢脱氮，加氢转化和氢化。

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