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    • 32. 发明授权
    • Cyclosiloxanes containing mesogenic side groups
    • 含有MESOGENIC侧组的环硅氧烷
    • US5221759A
    • 1993-06-22
    • US728479
    • 1991-07-11
    • Norman HaeberleWolfgang HaasFranz-Heinrich Kreuzer
    • Norman HaeberleWolfgang HaasFranz-Heinrich Kreuzer
    • C07F7/21C09K19/40G02F1/13
    • C09K19/408C07F7/21
    • The present invention relates to cyclic siloxanes which have at least one group of formula (1) bonded to a silicon atom--(CH.sub.2).sub.x --R"--[--L--A--].sub.y --(L).sub.z --T (1),in which x is an integer having a value of at least 2, preferably having a value of from 2 to 10, R" is a chemical bond or a divalent radical of the formula --COO--, --OOC--, --CH.sub.2 --CH.sub.2 --, --CH.dbd.CH--, --C.tbd.C--, --N.dbd.N--, --N.dbd.N(O)--, --CH.dbd.N--, --N.dbd.CH--, --N.dbd.N--, --N.dbd.N(O)--, --N.dbd.CH--, --CH.dbd.N--, or --Si(R).sub.2 --, where the radical R is identical or different and is an optionally substituted hydrocarbon radical having from 1 to 18 carbon atoms, L which is the same or different represents the 1,4-phenylene or 1,4-cyclohexylene radicals which are optionally 2-, 3-, 5- and/or 6-substituted by at least one radical Q, Q is the same or different radical selected from hydrogen, fluorine or chlorine atoms or cyano, methyl or trifluoromethyl groups, A is the same or different and represents divalent radicals R" is a chemical bond or a divalent radical of the formula --CH.sub.2 --O--, or --O--CH.sub.2 --, y is an integer having a value of from 0 to 10, preferably from 0 to 2, z is an integer having a value of from 0 to 10, preferably from 0 to 2, with the proviso that the sum y+z is at least 1, and T is a cholesteryl radical or a substituted or unsubstituted hydrocarbon radical having from 1 to 18 carbon atoms, in which the substituents are preferably selected from the group consisting of halogen atoms, cyano groups, nitro groups, hydrocarbonoxy groups having from 1 to 10 carbon atoms and mixtures thereof.
    • 本发明涉及具有至少一个键合到硅原子 - (CH 2)x -R“ - [ - LA-] y-(L)zT(1)的式(1)的基团的环状硅氧烷,其中 x是值至少为2,优选为2至10的整数,R“为化学键或式-COO - , - OOC - , - CH 2 -CH 2 - , - -CH = CH - , - C 3BOND C - , - N = N - , - N = N(O) - , - CH = N - , - N = CH-,-N = O) - , - N = CH-,-CH = N-或-Si(R)2 - ,其中基团R相同或不同,为具有1至18个碳原子的任选取代的烃基,L 相同或不同,代表通过至少一个基团Q任选2-,3-,5-和/或6-取代的1,4-亚苯基或1,4-亚环己基,Q是相同或不同的基团 选自氢,氟或氯原子或氰基,甲基或三氟甲基,A相同或不同,表示二价基团R“为化学键或式-CH 2 -O-的二价基团, 或-O-CH 2 - ,y为0至10,优选0至2的整数,z为0至10,优选0至2的整数,条件是 和y + z至少为1,T为胆固醇基或具有1至18个碳原子的取代或未取代的烃基,其中取代基优选选自卤素原子,氰基,硝基 具有1至10个碳原子的烃氧基及其混合物。
    • 34. 发明授权
    • Silylated benzoic acid derivatives II
    • 苯乙烯酸衍生物II
    • US5158702A
    • 1992-10-27
    • US542130
    • 1990-06-22
    • Wolfgang HaasNorman HaberleRainer WinklerFranz-Heinrich Kreuzer
    • Wolfgang HaasNorman HaberleRainer WinklerFranz-Heinrich Kreuzer
    • G02F1/13B01J31/22B01J31/30C07B61/00C07F7/08C09K19/40
    • C07F7/0818C07F7/0852C07F7/0896C09K19/406
    • The present invention relates to compounds of the formula ##STR1## in which Z is a radical bonded to the benzene ring in the 2-, 3-, 5- or 6-position, namely a halogen atom, a cyano group or a hydroxyl group,n is 0, 1 or 2,R" is a radical of the formulaR'''--[Si(R*).sub.2 ](CH.sub.2).sub.y R""-- (9), in whichY is an integer from 4 to 18,R''' is as defined in the description,R* is identical or different, optionally substituted C.sub.1 - to C.sub.18 -hydrocarbon or hydrocarbonoxy radicals,R"" is a radical of the formula --(E).sub.z -- which is optionally bonded to the carboxy group via a phenylene or biphenylene radical, whereE is a divalent radical of the formula --O-- or --Si(R*).sub.2 --, andZ is the number 0 or 1, and the radicalR' is a halogen atom, a cyano radical, a cholesteryl radical, a radical as defined for R* or of the formula --C.sub.6 H.sub.4 --R**, andR** may have any meaning of R*, with the exception of an n-octyloxy or an n-decyloxy radical,and the preparation and use thereof.
    • 本发明涉及式(VIII)的化合物,其中Z是在2-,3-,5-或6-位上与苯环键合的基团,即卤素原子,氰基或 羟基,n为0,1或2,R“为式R”' - [Si(R *)2](CH 2)y R“' - (9)的基团,其中Y 是4至18的整数,R“如说明书中所定义,R *相同或不同,任选取代的C 1至C 18烃或烃氧基,R”'是下式的基团 - (E)z-,其任选地通过亚苯基或亚联苯基与羧基键合,其中E是式-O-或-Si(R *)2 - 的二价基团,Z是数字0或1 ,并且基团R'是卤素原子,氰基,胆甾醇基,如R *或式-C 6 H 4 -R **所定义的基团,R **可具有任何R *的含义,与 正辛氧基或正癸氧基除外,其制备和用途。