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31. 发明申请

US20060052571A1 Method for the production of radiation-curable urethane (meth) acrylates 审中-公开
标题翻译：用于生产可辐射固化的聚氨酯（甲基）丙烯酸酯的方法
公开(公告)号：US20060052571A1
公开(公告)日：2006-03-09
申请号：US10539830
申请日：2003-12-16
申请人： Yvonne Heischkel , Wolfgang Paulus , Reinhold Schwalm , Peter Enenkel
发明人： Yvonne Heischkel , Wolfgang Paulus , Reinhold Schwalm , Peter Enenkel
IPC分类号： C08G18/00
CPC分类号： C09D175/16 , C08G18/6795 , C08G18/8175
摘要： A radiation-curable urethane(meth)acrylate, a process for preparing a radiation-curable urethane(meth)acrylate, and a coating composition comprising a radiation-curable urethane(meth)acrylate, in which the radiation-curable urethane(meth)acrylate is tough and resilient and useful in coating systems for a variety of substrates.
摘要翻译：可辐射固化的聚氨酯（甲基）丙烯酸酯，可辐射固化的聚氨酯（甲基）丙烯酸酯的制备方法和包含可辐射固化的聚氨酯（甲基）丙烯酸酯的涂料组合物，其中可辐射固化的聚氨酯（甲基）丙烯酸酯在各种基材的涂布体系中是韧性和弹性的。

32. 发明授权

US08044197B2 Radiation curable 1,3,5-triazine carbamates and 1,3,5-triazine ureas containing vinyl groups, methacryloyl groups, or acryloyl groups 有权
标题翻译：可辐射固化的1,3,5-三嗪氨基甲酸酯和含乙烯基的1,3,5-三嗪脲，甲基丙烯酰基或丙烯酰基
公开(公告)号：US08044197B2
公开(公告)日：2011-10-25
申请号：US10593316
申请日：2005-04-08
申请人： Yvonne Heischkel , Joerg Schneider , Reinhold Schwalm , Guenter Scherr
发明人： Yvonne Heischkel , Joerg Schneider , Reinhold Schwalm , Guenter Scherr
IPC分类号： C07D251/70 , C08F2/00 , C08G18/02 , C08G18/68
CPC分类号： C07D251/70
摘要： Radiation-curable 1,3,5-triazine carbamates and 1,3,5-triazine ureas, processes for preparing them and their use.
摘要翻译：可辐射固化的1,3,5-三嗪氨基甲酸酯和1,3,5-三嗪脲，其制备方法及其应用。

33. 发明授权

US07737236B2 Polymers based on fluoranthene and their use 有权
标题翻译：基于荧蒽的聚合物及其用途
公开(公告)号：US07737236B2
公开(公告)日：2010-06-15
申请号：US11077199
申请日：2005-03-11
申请人： Reinhold Schwalm , Yvonne Heischkel , Horst Weiss
发明人： Reinhold Schwalm , Yvonne Heischkel , Horst Weiss
IPC分类号： C08F10/00 , C08F290/14 , C07J53/00 , C07D231/00
CPC分类号： C09K11/06 , C07F5/025 , C08G61/02 , C09K2211/14 , C09K2211/1408 , C09K2211/1416 , C09K2211/1433 , H01L51/0035 , H01L51/0052 , H01L51/5012
摘要： Polymers comprising repeating units of the formula I where the variables are defined as follows: a is an integer from 0 to 3, R1, R2, R3 are identical or different and are selected independently from among hydrogen, C1-C20-alkyl, C1-C20-alkyl containing one or more Si, N, P, O or S atoms, C6-C30-aryl, preferably C6-C14-aryl, C4-C14-heteroaryl, —N(C6-C14-aryl)2, and Y1, where Y1 may be identical or different and are selected from among —CH═CH2, trans- or cis-CH═CH—C6H5, acryloyl, methacryloyl, methylstyryl, O—CH═CH2 and glycidyl, where Y2 is selected from among —CH═CH2, trans- or cis-CH═CH—C6H5, acryloyl, methacryloyl, methylstyryl, —O—CH═CH2 and glycidyl, and one or more groups Y1 or Y2 may be crosslinked to one another.
摘要翻译：包含式I重复单元的聚合物，其中变量定义如下：a是0-3的整数，R1，R2，R3相同或不同，独立地选自氢，C1-C20烷基，C1- 含有一个或多个Si，N，P，O或S原子的C 20 - 烷基，C 6 -C 30 - 芳基，优选C 6 -C 14 - 芳基，C 4 -C 14 - 杂芳基，-N（C 6 -C 14 - 芳基）2和Y 1 其中Y 1可以相同或不同，并且选自-CH 2 CH 2，反式或顺式-CH = CH-C 6 H 5，丙烯酰基，甲基丙烯酰基，甲基苯乙烯基，O-CH = CH 2和缩水甘油基，其中Y 2选自 - CH 2 CH 2，反式或顺式-CH = CH-C 6 H 5，丙烯酰基，甲基丙烯酰基，甲基苯乙烯基，-O-CH = CH 2和缩水甘油基，以及一个或多个Y 1或Y 2基团可彼此交联。

34. 发明申请

US20070208101A1 Radiation Curable 1,3,5-Triazine Carbamates and 1,3,5-Triazine Ureas Containing Vinyl Groups, Methacryloyl Groups, or Acryloyl Groups 有权
标题翻译：含有乙烯基，甲基丙烯酰基或丙烯酰基的辐射固化性1,3,5-三嗪氨基甲酸酯和1,3,5-三嗪脲
公开(公告)号：US20070208101A1
公开(公告)日：2007-09-06
申请号：US10593316
申请日：2005-04-08
申请人： Yvonne Heischkel , Jorg Schneider , Reinhold Schwalm , Gunter Scherr
发明人： Yvonne Heischkel , Jorg Schneider , Reinhold Schwalm , Gunter Scherr
IPC分类号： C07D251/54 , C08G18/67
CPC分类号： C07D251/70
摘要： Radiation-curable 1,3,5-triazine carbamates and 1,3,5-triazine ureas, processes for preparing them and their use.
摘要翻译：可辐射固化的1,3,5-三嗪氨基甲酸酯和1,3,5-三嗪脲，其制备方法及其应用。

35. 发明申请

US20050159582A1 Polymers based on fluoranthene and their use 有权
标题翻译：基于荧蒽的聚合物及其用途
公开(公告)号：US20050159582A1
公开(公告)日：2005-07-21
申请号：US11077199
申请日：2005-03-11
申请人： Reinhold Schwalm , Yvonne Heischkel , Horst Weiss
发明人： Reinhold Schwalm , Yvonne Heischkel , Horst Weiss
IPC分类号： C07F5/02 , C08G61/02 , C09K11/06 , H01L51/30 , H01L51/50 , C08G61/00
CPC分类号： C09K11/06 , C07F5/025 , C08G61/02 , C09K2211/14 , C09K2211/1408 , C09K2211/1416 , C09K2211/1433 , H01L51/0035 , H01L51/0052 , H01L51/5012
摘要： Polymers comprising repeating units of the formula I where the variables are defined as follows: a is an integer from 0 to 3, R1, R2, R3 are identical or different and are selected independently from among hydrogen, C1-C20-alkyl, C1-C20-alkyl containing one or more Si, N, P, O or S atoms, C6-C30-aryl, preferably C6-C14-aryl, C4-C14-heteroaryl, —N(C6-C14-aryl)2, and Y1, where Y1 may be identical or different and are selected from among —CH═CH2, trans- or cis-CH═CH—C6H5, acryloyl, methacryloyl, methylstyryl, O—CH═CH2 and glycidyl, where Y2 is selected from among —CH═CH2, trans- or cis-CH═CH—C6H5, acryloyl, methacryloyl, methylstyryl, —O—CH═CH2 and glycidyl, and one or more groups Y1 or Y2 may be crosslinked to one another.
摘要翻译：包含式I重复单元的聚合物，其中变量定义如下：a是0-3的整数，R 1，R 2，R 3，独立地选自氢，C 1 -C 20 - C 20 - 烷基，C 1 -C 3 - 烷基，含有一个或多个Si，N，P，O或S原子的C 20 -C 20烷基，C 6 -C 30 - 芳基，优选C _{或 Y 2可以彼此交联。}

36. 发明申请

US20100317887A1 PROCESS FOR PREPARING (METH)ACRYLATES OF C10-ALCOHOL MIXTURES 有权
标题翻译：制备C10-醇混合物（甲基）丙烯酸酯的方法
公开(公告)号：US20100317887A1
公开(公告)日：2010-12-16
申请号：US12867511
申请日：2009-02-26
申请人： Uwe Meisenburg , Frank Hoefer , Reinhold Schwalm , Nick Gruber , Lothar Karrer
发明人： Uwe Meisenburg , Frank Hoefer , Reinhold Schwalm , Nick Gruber , Lothar Karrer
IPC分类号： C07C67/62
CPC分类号： C07C67/08 , C07C67/54 , C07C69/54
摘要： Process for preparing (meth)acrylates of C10-alcohol mixtures, by reacting (meth)acrylic acid with an isomer mixture of C10-alcohols composed of 2-propylheptanol as the main isomer and at least one of the C10-alcohols 2-propyl-4-methylhexanol, 2-propyl-5-methylhexanol, 2-isopropylheptanol, 2-isopropyl-4-methylhexanol, 2-isopropyl-5-methylhexanol and/or 2-propyl-4,4-dimethylpentanol, in the presence of at least one acidic catalyst and of at least one polymerization inhibitor and in the presence of a solvent which forms an azeotrope with water, the azeotrope is distilled off and condensed, and the condensate splits into an aqueous phase and an organic phase, wherein a) the esterification is performed in a reactor with a circulation evaporator and b) in the presence of a solvent, and c) the crude product is purified by subsequent purifying distillation.
摘要翻译：通过使（甲基）丙烯酸与由2-丙基庚醇组成的C 10醇的异构体混合物作为主要异构体和至少一种C10-醇2-丙基 - 丙烯酸的至少一种来制备C10-醇混合物的（甲基）丙烯酸酯的方法， 4-甲基己醇，2-丙基-5-甲基己醇，2-异丙基庚醇，2-异丙基-4-甲基己醇，2-异丙基-5-甲基己醇和/或2-丙基-4,4-二甲基戊醇，在至少一种酸性催化剂和至少一种聚合抑制剂，并且在与水形成共沸物的溶剂的存在下，蒸馏出共沸物并冷凝，并且冷凝物分解成水相和有机相，其中a）酯化在具有循环蒸发器的反应器中进行，和b）在溶剂存在下进行，和c）通过随后的纯化蒸馏纯化粗产物。

37. 发明申请

US20100010113A1 RADIATION-CURABLE COMPOUNDS 审中-公开
标题翻译：辐射可固化化合物
公开(公告)号：US20100010113A1
公开(公告)日：2010-01-14
申请号：US12444849
申请日：2007-10-08
申请人： Reinhold Schwalm , Frank Voellinger , Nick Gruber , Klaus Menzel , Susanne Neumann
发明人： Reinhold Schwalm , Frank Voellinger , Nick Gruber , Klaus Menzel , Susanne Neumann
IPC分类号： C08F2/46 , C08L75/04 , C08L83/04
CPC分类号： C08G18/0823 , C08G18/289 , C08G18/3212 , C08G18/4854 , C08G18/61 , C08G18/672 , C08G18/7837 , C09D175/16
摘要： The invention relates to radiation-curable compounds, to processes for preparing them, to their use, and to coating compositions comprising them and featuring high scratch resistance.
摘要翻译：本发明涉及可辐射固化的化合物，其制备方法，使用方法以及包含它们的组合物并具有高耐擦伤性的组合物。

38. 发明授权

US08318970B2 Process for preparing (meth)acrylates of C10-alcohol mixtures 有权
标题翻译：制备C10-醇混合物的（甲基）丙烯酸酯的方法
公开(公告)号：US08318970B2
公开(公告)日：2012-11-27
申请号：US12867511
申请日：2009-02-26
申请人： Uwe Meisenburg , Frank Hoefer , Reinhold Schwalm , Nick Gruber , Lothar Karrer
发明人： Uwe Meisenburg , Frank Hoefer , Reinhold Schwalm , Nick Gruber , Lothar Karrer
IPC分类号： C07C69/52
CPC分类号： C07C67/08 , C07C67/54 , C07C69/54
摘要： Process for preparing (meth)acrylates of C10-alcohol mixtures, by reacting (meth)acrylic acid with an isomer mixture of C10-alcohols composed of 2-propylheptanol as the main isomer and at least one of the C10-alcohols 2-propyl-4-methylhexanol, 2-propyl-5-methylhexanol, 2-isopropylheptanol, 2-isopropyl-4-methylhexanol, 2-isopropyl-5-methylhexanol and/or 2-propyl-4,4-dimethylpentanol, in the presence of at least one acidic catalyst and of at least one polymerization inhibitor and in the presence of a solvent which forms an azeotrope with water, the azeotrope is distilled off and condensed, and the condensate splits into an aqueous phase and an organic phase, wherein a) the esterification is performed in a reactor with a circulation evaporator and b) in the presence of a solvent, and c) the crude product is purified by subsequent purifying distillation.
摘要翻译：通过使（甲基）丙烯酸与由2-丙基庚醇组成的C 10醇的异构体混合物作为主要异构体和至少一种C10-醇2-丙基 - 丙烯酸的至少一种来制备C10-醇混合物的（甲基）丙烯酸酯的方法， 4-甲基己醇，2-丙基-5-甲基己醇，2-异丙基庚醇，2-异丙基-4-甲基己醇，2-异丙基-5-甲基己醇和/或2-丙基-4,4-二甲基戊醇，在至少一种酸性催化剂和至少一种聚合抑制剂，并且在与水形成共沸物的溶剂的存在下，蒸馏出共沸物并冷凝，并且冷凝物分解成水相和有机相，其中a）酯化在具有循环蒸发器的反应器中进行，和b）在溶剂存在下进行，和c）通过随后的纯化蒸馏纯化粗产物。

39. 发明申请

US20090000519A1 Coatings Reparable by Energy Discharge 审中-公开
标题翻译：能量放电可分离的涂料
公开(公告)号：US20090000519A1
公开(公告)日：2009-01-01
申请号：US12162129
申请日：2007-01-23
申请人： Reinhold Schwalm , Nick Gruber , Lydie Tuchbreiter , Gabriele Dlugosch , Frank Vollinger
发明人： Reinhold Schwalm , Nick Gruber , Lydie Tuchbreiter , Gabriele Dlugosch , Frank Vollinger
IPC分类号： C04B16/00 , C08L79/00 , C07F7/18 , C07F7/02 , C08G77/14 , C08G77/06 , C08L75/04
CPC分类号： C09D175/16 , C08G18/672 , C08G18/7837 , C08G18/809 , C08G18/61
摘要： Coating compositions repairable by introduction of energy and comprising defined siloxanes, coatings obtained therewith and repairable by introduction of energy, methods of producing them, and their use.
摘要翻译：涂料组合物可通过引入能量并且包含限定的硅氧烷，由其获得的涂层和通过引入能量进行修复，可以制造它们的方法及其用途来修复。

40. 发明授权

US09090736B2 Rheological agent for radiation-curable coating compositions 有权
标题翻译：辐射固化涂料组合物的流变剂
公开(公告)号：US09090736B2
公开(公告)日：2015-07-28
申请号：US13399006
申请日：2012-02-17
申请人： Reinhold Schwalm , Erich Beck
发明人： Reinhold Schwalm , Erich Beck
IPC分类号： C08G18/78 , C08G18/67 , C08G18/81 , C08F283/00 , C08K5/21 , C09D175/14 , C09D175/16 , C07C275/04 , C07C275/26 , C07C275/60
CPC分类号： C08G18/8116 , C07C275/04 , C07C275/26 , C07C275/60 , C08F283/008 , C08G18/6705 , C08G18/671 , C08G18/672 , C08G18/673 , C08G18/675 , C08G18/7837 , C08G18/8125 , C08K5/21 , C09D175/14 , C09D175/16
摘要： A radiation-curable rheological assistant which comprises a compound comprising at least one (meth)acrylate group and at least one urea group of the formula —NH—(CO)—NR1R2 connected thereto wherein R1 and R2 each independently of one another are hydrogen, alkyl, aryl, cycloalkyl or aralkyl, with the proviso that at least one of the radicals is other than hydrogen, a process for preparing the rheological assistant by reacting at least one compound which has at least one isocyanate-reactive group and at least one (meth)acrylate group with at least one di- or polyisocyanate, use of the rheological assistant in radiation-curable coating compositions, such radiation-curable coating compositions, and the use of such radiation-curable coating compositions.
摘要翻译：一种可辐射固化的流变助剂，其包含与至少一种（甲基）丙烯酸酯基团和至少一个与其连接的式-NH-（CO）-NR1R2的脲基团的化合物，其中R 1和R 2各自独立地为氢，烷基，芳基，环烷基或芳烷基，条件是至少一个基团不是氢;一种通过使至少一种具有至少一个异氰酸酯反应性基团的化合物和至少一种甲基）丙烯酸酯基团与至少一种二异氰酸酯或多异氰酸酯，在辐射固化涂料组合物中使用流变助剂，这种可辐射固化涂料组合物，以及使用这种可辐射固化涂料组合物。

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