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31. 发明授权

US5869888A Semiconductor device with lead structure on principal surface of chip 失效
标题翻译：芯片主表面具有导线结构的半导体器件
公开(公告)号：US5869888A
公开(公告)日：1999-02-09
申请号：US721339
申请日：1996-09-26
申请人： Kunihiro Tsubosaki , Michio Tanimoto , Kunihiko Nishi , Masahiro Ichitani , Shunji Koike , Kazunari Suzuki , Ryosuke Kimoto , Ichiro Anjoh , Taisei Jin , Akihiko Iwaya , Gen Murakami , Masamichi Ishihara , Junichi Arita
发明人： Kunihiro Tsubosaki , Michio Tanimoto , Kunihiko Nishi , Masahiro Ichitani , Shunji Koike , Kazunari Suzuki , Ryosuke Kimoto , Ichiro Anjoh , Taisei Jin , Akihiko Iwaya , Gen Murakami , Masamichi Ishihara , Junichi Arita
IPC分类号： H01L23/31 , H01L23/495 , H01L25/10 , H01L23/48
CPC分类号： H01L24/06 , H01L23/3107 , H01L23/3121 , H01L23/4951 , H01L24/05 , H01L24/49 , H01L25/105 , H01L2224/0401 , H01L2224/04042 , H01L2224/05554 , H01L2224/05624 , H01L2224/06136 , H01L2224/32245 , H01L2224/45015 , H01L2224/45124 , H01L2224/45144 , H01L2224/48091 , H01L2224/48247 , H01L2224/48253 , H01L2224/4826 , H01L2224/48465 , H01L2224/48624 , H01L2224/48724 , H01L2224/49113 , H01L2224/49171 , H01L2224/73215 , H01L2224/85424 , H01L2225/1029 , H01L24/45 , H01L24/48 , H01L2924/01005 , H01L2924/01006 , H01L2924/01013 , H01L2924/01014 , H01L2924/01022 , H01L2924/01023 , H01L2924/01028 , H01L2924/01029 , H01L2924/01033 , H01L2924/01039 , H01L2924/01047 , H01L2924/0105 , H01L2924/01074 , H01L2924/01078 , H01L2924/01079 , H01L2924/01082 , H01L2924/014 , H01L2924/07802 , H01L2924/1305 , H01L2924/181 , H01L2924/351 , Y10T29/49121
摘要： A semiconductor device having inner leads secured via insulating adhesive films to the principal surface of a semiconductor chip and electrically connected to the respective external terminals of the semiconductor chip. The semiconductor device that can be about the size of the chip is so configured that an outer lead is continuously extended from each inner lead up to the rear surface opposite to the principal surface of the semiconductor chip in order to hold the leads and an external device in conduction.
摘要翻译：一种半导体器件，其具有通过绝缘粘合剂膜固定到半导体芯片的主表面并与半导体芯片的各个外部端子电连接的内部引线。可以关于芯片尺寸的半导体器件被配置为使得外引线从每个内引线连续地延伸到与半导体芯片的主表面相对的后表面，以便保持引线和外部器件导通。

32. 发明授权

US3973713A Wire bonding system 失效
标题翻译：导线接合系统
公开(公告)号：US3973713A
公开(公告)日：1976-08-10
申请号：US523800
申请日：1974-11-14
申请人： Teruo Furuya , Jun Suzuki , Michio Tanimoto
发明人： Teruo Furuya , Jun Suzuki , Michio Tanimoto
IPC分类号： H01L21/60 , H01L21/00 , H01L21/92
CPC分类号： H01L24/78 , H01L21/67138 , H01L24/85 , H01L2224/05554 , H01L2224/78801 , H01L2224/85 , H01L2924/00014 , H01L2924/01005 , H01L2924/01006 , H01L2924/01019 , H01L2924/01027 , H01L2924/01033 , H01L2924/01039 , H01L2924/01047 , H01L2924/01082 , H01L2924/14
摘要： A wire bonding system connects wires between electrode pads on a semiconductor pellet fixed on a lead frame to the corresponding lead parts on the lead frame. The lead frame with the pellet fixed thereon is first set in a position beneath a projector, to obtain a magnified image of the pellet, from which the position of the pellet is measured. On the basis of the measured value, a computer calculates positions for bonding the wires. The lead frame with the pellet therein is then set on the wire bonding machine and the positions of the bonding head are controlled using the result of said calculation to carry out wire bonding. The position measuring means is separate from the bonding machine, with an on-line or off-line connection therebetween.
摘要翻译：引线接合系统将固定在引线框架上的半导体芯片上的电极焊盘之间的导线连接到引线框架上的相应引线部分。将其上固定有颗粒的引线框架首先设置在投影仪下方的位置，以获得颗粒的放大图像，从该颗粒的位置测量颗粒的位置。基于测量值，计算机计算用于接合线的位置。然后将其中具有颗粒的引线框架设置在引线接合机上，并且使用所述计算的结果来控制接合头的位置以进行引线接合。位置测量装置与粘合机分离，其间具有在线或离线连接。

33. 发明申请

US20110178334A1 FIXED-BED REACTOR AND PROCESS FOR PRODUCING ACRYLIC ACID USING THE REACTOR 有权
标题翻译：固定床反应器和使用反应器生产丙烯酸的方法
公开(公告)号：US20110178334A1
公开(公告)日：2011-07-21
申请号：US13056416
申请日：2009-09-09
申请人： Michio Tanimoto , Nobuyuki Hakozaki
发明人： Michio Tanimoto , Nobuyuki Hakozaki
IPC分类号： C07C57/18 , B01J8/00 , C22C38/00
CPC分类号： C07C45/35 , B01J8/0292 , B01J8/04 , B01J8/0453 , B01J19/30 , B01J23/002 , B01J23/30 , B01J23/881 , B01J23/8885 , B01J35/023 , B01J35/026 , B01J37/0009 , B01J37/031 , B01J2208/00522 , B01J2219/00247 , B01J2219/30215 , B01J2219/30223 , B01J2219/30265 , B01J2219/30408 , B01J2219/30416 , B01J2219/312 , B01J2523/00 , C07C51/235 , C07C47/22 , C07C57/04 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , B01J2523/17 , B01J2523/53 , B01J2523/55 , B01J2523/847
摘要： The fixed-bed reactor of the present invention which solves the above problems is a fixed-bed reactor comprising: a first catalyst layer filled with a first catalyst for producing acrolein from propylene; a second catalyst layer filled with a second catalyst for producing acrylic acid from acrolein; and an inert substance layer provided between the first catalyst layer and the second catalyst layer, and filled with an inert substance of a cylindrical shape having a surrounding wall in which an opening is formed. The process for producing acrylic acid of the present invention is a process for producing acrylic acid comprising the step of producing acrylic acid from propylene by using the fixed-bed reactor of the present invention. According to the present invention, since the inert substance of a cylindrical shape having a surrounding wall in which an opening is formed is used as an inert substance, increase of a pressure loss can be drastically suppressed, degradation of the catalyst due to by-produced high-boiling substances and the like can be suppressed, and further the yield of acrylic acid can be enhanced, as compared with the case of using conventional inert substances. Accordingly, it is possible to produce acrylic acid at a high yield stably for a long period.
摘要翻译：解决上述问题的本发明的固定床反应器是一种固定床反应器，包括：填充有由丙烯制备丙烯醛的第一催化剂的第一催化剂层; 填充有由丙烯醛制备丙烯酸的第二催化剂的第二催化剂层; 以及设置在第一催化剂层和第二催化剂层之间的惰性物质层，并且填充有具有形成有开口的周围壁的圆筒形状的惰性物质。本发明的丙烯酸的制造方法是使用本发明的固定床反应器，由丙烯制造丙烯酸的工序，是丙烯酸的制造方法。根据本发明，由于使用形成有开口的周围壁的圆筒状的惰性物质作为惰性物质，因此可以显着地抑制压力损失的增加，由于副产物引起的催化剂的劣化可以抑制高沸点物质等，与使用常规惰性物质的情况相比，可以提高丙烯酸的收率。因此，可以长期稳定地高产率制备丙烯酸。

34. 发明授权

US07884235B2 Method for gas-phase catalytic oxidation using a fixed bed reactor 有权
标题翻译：使用固定床反应器进行气相催化氧化的方法
公开(公告)号：US07884235B2
公开(公告)日：2011-02-08
申请号：US11826629
申请日：2007-07-17
申请人： Michio Tanimoto , Shin-yuki Masaki
发明人： Michio Tanimoto , Shin-yuki Masaki
IPC分类号： C07C53/00
CPC分类号： B01J8/06 , B01J8/02 , B01J2208/025 , C07C51/235 , C07C51/252 , C07C57/04
摘要： The invention provides a method of gas-phase catalytic oxidation, in particular, a production method of (meth)acrylic acid, which enables stable continuous operation of gas-phase catalytic oxidation over a long term, maintaining high yield and suppressing increase in pressure loss. In the method a fixed bed reactor is used, in which a treating agent for removing organic substance and/or carbides, preferably a treating agent having an adsorption capacity of at least 0.05% by mass, as measured by crotonaldehyde as an indicator of organic substance, is disposed on the upstream side of the gas-phase oxidation catalyst layer in respect of the direction of the gas flow. It is desirable that at least a part of the treating agent is exchanged at a frequency of at least once a year.
摘要翻译：本发明提供了一种气相催化氧化方法，特别是（甲基）丙烯酸的制备方法，其能够长期保持气相催化氧化的稳定连续运行，保持高产率并抑制压力损失增加。在该方法中，使用固定床反应器，其中除去有机物和/或碳化物的处理剂，优选具有至少0.05质量％的吸附能力的处理剂，通过巴豆醛作为有机物质的指示剂相对于气流方向配置在气相氧化催化剂层的上游侧。理想的是，至少一部分处理剂以每年至少一次的频率进行交换。

35. 发明申请

US20100249455A1 Process for producing acrolein and acrylic acid 失效
标题翻译：制备丙烯醛和丙烯酸的方法
公开(公告)号：US20100249455A1
公开(公告)日：2010-09-30
申请号：US12662123
申请日：2010-03-31
申请人： Michio Tanimoto , Hideo Onodera
发明人： Michio Tanimoto , Hideo Onodera
IPC分类号： C07C51/25 , C07C45/35
CPC分类号： C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04
摘要： The invention offers an improvement in a process for start-up in the occasion of producing acrolein and acrylic acid by catalytically oxidizing propylene at vapor phase under high load conditions, the start-up meaning the step of increasing the propylene supply rate (loading) from the non-reacting condition to the prescribed reaction conditions. This process is characterized in that the propylene supply rate is increased in the start-up stage of the reaction until the prescribed composition of starting reactant gas and the flow rate of the starting reactant gas are obtained, while adjusting at least one of the reaction temperature, the composition of the starting reactant gas and flow rate of the starting reactant gas, so as to maintain the propylene conversion at not lower than 90 mol %, the maximum peak temperature of the catalyst layer in each reaction zone at no higher than 450° C., and the sum of each ΔT (maximum peak temperature of a catalyst layer—reaction temperature) at the catalyst layer in each of the reaction zones to be no more than 180° C., respectively. According to this process, the reaction speedily reaches the steady state (standard operating conditions) and a high acrolein and acrylic acid yield is stably achieved from the start of the reaction.
摘要翻译：本发明提供了在高负载条件下通过在气相下催化氧化丙烯来生产丙烯醛和丙烯酸的情况下的启动方法的改进，启动意味着将丙烯供应速率（负载）从对规定的反应条件的非反应条件。该方法的特征在于，在反应的启动阶段，丙烯供给速率增加，直到获得规定的起始反应气体组成和起始反应气体的流量，同时调节至少一个反应温度，起始反应物气体的组成和起始反应气体的流速，以保持丙烯转化率不低于90mol％，各反应区中催化剂层的最高峰值温度不高于450° C，以及每个反应区域中的催化剂层的每个＆Dgr; T（催化剂层 - 反应温度的最大峰值温度）的总和分别不超过180℃。根据该方法，反应快速达到稳定状态（标准操作条件），从反应开始就可以稳定地获得高丙烯醛和丙烯酸的收率。

36. 发明申请

US20100249454A1 Process for producing acrylic acid 有权
标题翻译：丙烯酸生产工艺
公开(公告)号：US20100249454A1
公开(公告)日：2010-09-30
申请号：US12659994
申请日：2010-03-26
申请人： Michio Tanimoto , Hideo Onodera
发明人： Michio Tanimoto , Hideo Onodera
IPC分类号： C07C51/235
CPC分类号： C07C51/252 , C07C57/04
摘要： The invention offers an improvement in a process for start-up in the occasion of producing acrylic acid by catalytically oxidizing acrolein at vapor phase under high load conditions, the start-up meaning the step of increasing the acrolein supply rate (loading) from the non-reacting condition to the prescribed reaction conditions. This process is characterized in that the acrolein supply rate is increased in the start-up stage of the reaction until the prescribed composition of starting reactant gas and the flow rate of the starting reactant gas are obtained, while adjusting at least one of the reaction temperature, the composition of the starting reactant gas and the flow rate of the starting reactant gas, so as to maintain the acrolein conversion at not lower than 90 mol %, the maximum peak temperature of the catalyst layer in each reaction zone at no higher than 400° C., and the sum of each ΔT (maximum peak temperature of a catalyst layer-reaction temperature) at the catalyst layer in each of the reaction zones to be no more than 150° C., respectively. According to this process, the reaction speedily reaches the steady state (standard operating conditions) and a high acrylic acid yield is stably achieved from the start of the reaction.
摘要翻译：本发明提供了在高负载条件下通过在气相下催化氧化丙烯醛来生产丙烯酸的情况下的启动方法的改进，启动意味着提高丙烯醛供应速率（负载）反应条件达到规定的反应条件。该方法的特征在于，在反应开始阶段丙烯醛供应速率增加，直到获得规定的起始反应气体组成和起始反应气体的流量，同时调节至少一个反应温度，起始反应气体的组成和起始反应气体的流量，以使丙烯醛的转化率保持在不低于90mol％，催化剂层在每个反应区中的最大峰值温度不高于400℃ ℃，以及每个反应区域中的催化剂层的每个＆Dgr; T（催化剂层 - 反应温度的最大峰值温度）的总和分别不超过150℃。根据该方法，反应快速达到稳定状态（标准操作条件），从反应开始就稳定地得到高丙烯酸收率。

37. 发明授权

US07429678B2 Composite-oxide catalyst and process for production of acrylic acid using said catalyst 失效
标题翻译：复合氧化物催化剂和使用所述催化剂生产丙烯酸的方法
公开(公告)号：US07429678B2
公开(公告)日：2008-09-30
申请号：US10764852
申请日：2004-01-26
申请人： Michio Tanimoto , Harunori Hirao
发明人： Michio Tanimoto , Harunori Hirao
IPC分类号： C07C51/16 , C07C51/235
CPC分类号： C07C45/35 , B01J23/002 , B01J23/8885 , B01J35/0006 , B01J2523/00 , C07C51/252 , C07C47/22 , C07C57/04 , B01J2523/54 , B01J2523/68 , B01J2523/17 , B01J2523/53 , B01J2523/55 , B01J2523/69 , B01J2523/842
摘要： There are disclosed a catalyst and a process for production of acrylic acid using this catalyst, wherein, even under conditions where hot spots are formed, the catalyst is excellent in activity, selectivity, and catalyst life time and displays stable performances for a long time. The catalyst is shown by the following formula (1): MoaVbWcCudAeBfCgOx (1) (wherein: A is at least one species selected from among cobalt, nickel, iron, lead, and bismuth; B is at least one species selected from among antimony, niobium, and tin; and C is at least one species selected from among silicon, aluminum, titanium, and zirconium; and further, a, b, c, d, e, f, g, and x are atomic ratios of Mo, V, W, Cu, A, B, C, and O respectively; and, in the case of a=12, the following inequalities are satisfied: 2≦b≦15; 0
摘要翻译：公开了使用该催化剂的催化剂和丙烯酸的制造方法，其中即使在形成热点的条件下，催化剂的活性，选择性和催化剂寿命也优异，长时间显示出稳定的性能。催化剂由下式（1）表示：<？in-line-formula description =“In-line Formulas”end =“lead”？> Mo a >>>>> e e O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O （1）<？in-line-formula description =“In-line Formulas”end =“tail”？>（其中：A是选自钴，镍，铁，铅中的至少一种和铋; B是选自锑，铌和锡中的至少一种; C是选自硅，铝，钛和锆中的至少一种;此外，a，b，c，d， e，f，g和x分别是Mo，V，W，Cu，A，B，C和O的原子比;并且在a = 12的情况下，满足以下不等式：2 <= b <= 15; 0

38. 发明申请

US20060245992A1 Fixed-bed shell-and-tube reactor and its usage 有权
公开(公告)号：US20060245992A1
公开(公告)日：2006-11-02
申请号：US11409588
申请日：2006-04-23
申请人： Michio Tanimoto , Hideto Hashiba
发明人： Michio Tanimoto , Hideto Hashiba
IPC分类号： B01J19/32
CPC分类号： C07C51/313 , B01J8/0015 , B01J8/06 , B01J23/002 , B01J23/28 , B01J23/50 , B01J23/8876 , B01J27/19 , B01J27/198 , B01J2208/00752 , B01J2208/00805 , B01J2523/00 , C07C5/48 , C07C45/35 , C07C51/215 , C07C51/252 , C07C51/265 , C07C2523/28 , C07D301/08 , Y02P20/52 , C07C11/06 , C07C47/22 , C07C57/04 , C07C63/26 , B01J2523/51 , B01J2523/55 , B01J2523/13 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/845 , B01J2523/847 , B01J2523/15
摘要： The present invention provides: a fixed-bed shell-and-tube reactor, which can stably produce an aimed product for a long period when a solid particulate material such as a catalyst is packed and used for each substance; and its usage. The fixed-bed shell-and-tube reactor comprises a plurality of reaction tubes that are packed with a solid particulate material and arranged in parallel, wherein the solid particulate material is weighed so as to be uniform volume, and is packed in each reaction tube in a packing time of not shorter than 30 seconds per liter.

39. 发明授权

US06583316B1 Catalysts for production of unsaturated aldehyde and unsaturated carboxylic acid and a process for producing unsaturated aldehyde and unsaturated carboxylic acid using the catalysts 有权
标题翻译：用于生产不饱和醛和不饱和羧酸的催化剂和使用该催化剂生产不饱和醛和不饱和羧酸的方法
公开(公告)号：US06583316B1
公开(公告)日：2003-06-24
申请号：US09568975
申请日：2000-05-11
申请人： Hideo Onodera , Michio Tanimoto
发明人： Hideo Onodera , Michio Tanimoto
IPC分类号： C07C5116
CPC分类号： C07C51/25 , B01J21/06 , B01J23/002 , B01J23/10 , B01J23/8871 , B01J23/8876 , B01J35/0006 , B01J2523/00 , C07C51/252 , C07C57/04 , B01J2523/13 , B01J2523/3712 , B01J2523/41 , B01J2523/48 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , B01J2523/15 , B01J2523/36 , B01J2523/847
摘要： Improved catalysts for use in vapor phase oxidation of at least one compound selected from the group consisting of propylene, isobutylene, t-butanol and methyl-t-butyl ether with molecular oxygen or a molecular oxygen-containing gas to produce the corresponding unsaturated aldehyde and unsaturated carboxylic acid are provided. The improved catalysts are compositions comprising (A) a complex oxide containing as essential components molybdenum, bismuth and iron, which is known per se as a catalyst for said reaction and (B) a complex oxide containing cerium and zirconium as the essential components. When the improved catalysts are used, the production operation of unsaturated aldehyde and unsaturated carboxylic acid can be continued stably for over prolonged period.
摘要翻译：改进的催化剂用于至少一种选自丙烯，异丁烯，叔丁醇和甲基叔丁基醚与分子氧或含分子氧气体的化合物的气相氧化，以产生相应的不饱和醛和不饱和羧酸。改进的催化剂是包含（A）包含作为主要组分钼，铋和铁的复合氧化物的组合物，其本身已知作为所述反应的催化剂，（B）以铈和锆为主要成分的复合氧化物。当使用改进的催化剂时，不饱和醛和不饱和羧酸的生产操作可以长时间持续稳定。

40. 发明授权

US06509508B2 Process for producing (meth)acrolein and (meth)acrylic acid 有权
标题翻译：制备（甲基）丙烯醛和（甲基）丙烯酸的方法
公开(公告)号：US06509508B2
公开(公告)日：2003-01-21
申请号：US10074035
申请日：2002-02-14
申请人： Naomasa Kimura , Michio Tanimoto , Hideo Onodera
发明人： Naomasa Kimura , Michio Tanimoto , Hideo Onodera
IPC分类号： C07C4535
CPC分类号： C07C51/235 , B01J23/002 , B01J23/31 , B01J23/8876 , B01J23/8885 , B01J2523/00 , C07C45/32 , C07C45/35 , C07C45/37 , C07C51/252 , C07C47/22 , C07C57/04 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , B01J2523/15 , B01J2523/3712 , B01J2523/847
摘要： A reaction for producing (metho)acrolein and (meth)acrylic acid by vaporn-phase oxidation of at least a compound selected from propyl-ene, isobytylene, t-bytanol and methyl-t-butyl ether. For the process Complex oxide catalysts represented by the formula, MoaWbBicFedAeBfCgDhEiOx (in which A is Ni or Co; B is Na, K, Rb, Cs or Tl; C is an alkaline earth metal; D is P, Te, Sb, Sn, Ce, Pb, Nb, Mn, As, B or Zn; E is Si, Al, Ti or Zr; and where a is 12, 0≦b≦10, 0
摘要翻译：通过至少选自丙基，异丁烯，叔丁醇和甲基叔丁基醚的化合物的蒸发相氧化制备（甲基）丙烯醛和（甲基）丙烯酸的反应。对于该方法，由式（其中A是Ni或Co; B是Na，K，Rb，Cs或Tl; C是碱土金属），D是P，Te，Sb，Sn，Ce ，Pb，Nb，Mn，As，B或Zn; E为Si，Al，Ti或Zr;其中a为12,0 <= b <= 10,0

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