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31. 发明申请

US20120077776A1 HYDROLYSIS RESISTANT ORGANOMODIFIED TRISILOXANE SURFACTANTS 审中-公开
公开(公告)号：US20120077776A1
公开(公告)日：2012-03-29
申请号：US13314821
申请日：2011-12-08
申请人： George A. Policello , Mark D. Leatherman , Wenqing Peng , Suresh K. Rajaraman , Sophia Xia
发明人： George A. Policello , Mark D. Leatherman , Wenqing Peng , Suresh K. Rajaraman , Sophia Xia
IPC分类号： A61K31/695
CPC分类号： A01N25/30
摘要： Three types of trisiloxane surfactants having the basic formula: MDM′ are described wherein the substituents on the differing M and M′ groups, in conjunction with pendant polyalkylene oxide substituents on the D group render the surfactant resistant to hydrolysis under either basic or acidic conditions outside the pH range of 6.0 to 7.5. The compositions are useful in agricultural, household and cosmetic applications.

32. 发明申请

US20120064052A1 Hydrolysis Resistant Organomodified Trisiloxane Surfactants 审中-公开
标题翻译：耐水解有机改性的三硅氧烷表面活性剂
公开(公告)号：US20120064052A1
公开(公告)日：2012-03-15
申请号：US13166092
申请日：2011-06-22
申请人： George A. Policello , Mark D. Leatherman , Wenqing Peng , Suresh K. Rajaraman , Sophia Xia
发明人： George A. Policello , Mark D. Leatherman , Wenqing Peng , Suresh K. Rajaraman , Sophia Xia
IPC分类号： A01N63/00 , A01N55/10 , A01N43/653 , A01N43/50 , A01P13/00 , A01N59/16 , A01N59/20 , A01P7/04 , A01P11/00 , A01P3/00 , A01N43/84 , A01N43/52
CPC分类号： A01N25/30
摘要： Three types of trisiloxane surfactants having the basic formula: MDM′ are described wherein the substituents on the differing M and M′ groups, in conjunction with pendant polyalkylene oxide substituents on the D group render the surfactant resistant to hydrolysis under either basic or acidic conditions outside the pH range of 6.0 to 7.5. The compositions are useful in agricultural, household and cosmetic applications.
摘要翻译：描述了三种具有以下基础式的三硅氧烷表面活性剂：MDM'，其中不同的M和M'基团上的取代基与D基团上的聚环氧烷代表取代基结合使得表面活性剂在外部碱性或酸性条件下耐水解 pH范围为6.0〜7.5。该组合物可用于农业，家用和化妆品应用。

33. 发明申请

US20110184074A1 HYDROLYSIS RESISTANT ORGANOMODIFIED TRISILOXANE SURFACTANTS 审中-公开
标题翻译：水解抗性有机物三氧化硅表面活性剂
公开(公告)号：US20110184074A1
公开(公告)日：2011-07-28
申请号：US13080795
申请日：2011-04-06
申请人： George A. Policello , Mark D. Leatherman , Wenqing Peng , Suresh K. Rajaraman , Zijun Xia
发明人： George A. Policello , Mark D. Leatherman , Wenqing Peng , Suresh K. Rajaraman , Zijun Xia
IPC分类号： B01F3/08 , C07F7/08
CPC分类号： A61K8/894 , A61Q19/00 , C07F7/0838
摘要： Three types of trisiloxane surfactants having the basic formula: MDM′ are described wherein the substituents on the differing M and M′ groups in conjunction with a pendant polyalkylene oxide substituents on the D group to render the surfactant resistant to hydrolysis under either basic or acidic conditions.
摘要翻译：描述了三种具有以下基础式的三硅氧烷表面活性剂：MDM'，其中不同的M和M'基团上的取代基与D基团上的侧链聚环氧烷取代基结合，使表面活性剂在碱性或酸性条件下具有抗水解作用。

34. 发明授权

US07964032B2 Fluorine-free trisiloxane surfactant compositions for use in coatings and printing ink compositions 有权
标题翻译：用于涂料和印刷油墨组合物的无氟三硅氧烷表面活性剂组合物
公开(公告)号：US07964032B2
公开(公告)日：2011-06-21
申请号：US11582575
申请日：2006-10-17
申请人： Suresh K. Rajaraman , Alain Lejeune , Alexander Borovik , George A. Policello , Mark D. Leatherman , Wenqing Peng , Zijun Xia
发明人： Suresh K. Rajaraman , Alain Lejeune , Alexander Borovik , George A. Policello , Mark D. Leatherman , Wenqing Peng , Zijun Xia
IPC分类号： C09D11/00
CPC分类号： C09D183/12 , C08G77/46 , C09D11/03 , C08L2666/14 , C08L2666/02 , C08L2666/04
摘要： The present invention relates to coating and printing ink compositions possessing silicone surfactants compositions comprising fluorine-free organomodified trisiloxanes which are resistant to hydrolysis between a pH of about 3 to a pH of about 12. The coatings and printing ink composition of the present invention exhibit enhanced wetting, flow and leveling properties.
摘要翻译：本发明涉及具有包含无氟有机改性的三硅氧烷的硅氧烷表面活性剂组合物的涂料和印刷油墨组合物，其在约3至约pH约12之间的水解条件下具有抗水解性。本发明的涂料和印刷油墨组合物显示出增强的润湿，流动和流平性能。

35. 发明申请

US20080090963A1 Fluorine-free trisiloxane surfactant compositions for use in coatings and printing ink compositions 有权
标题翻译：用于涂料和印刷油墨组合物的无氟三硅氧烷表面活性剂组合物
公开(公告)号：US20080090963A1
公开(公告)日：2008-04-17
申请号：US11582575
申请日：2006-10-17
申请人： Suresh K. Rajaraman , Alain Lejeune , Alexander Borovik , George A. Policello , Mark D. Leatherman , Wenqing Peng , Zijun Xia
发明人： Suresh K. Rajaraman , Alain Lejeune , Alexander Borovik , George A. Policello , Mark D. Leatherman , Wenqing Peng , Zijun Xia
IPC分类号： C08F8/00
CPC分类号： C09D183/12 , C08G77/46 , C09D11/03 , C08L2666/14 , C08L2666/02 , C08L2666/04
摘要： The present invention relates to coating and printing ink compositions possessing silicone surfactants compositions comprising fluorine-free organomodified trisiloxanes which are resistant to hydrolysis between a pH of about 3 to a pH of about 12. The coatings and printing ink composition of the present invention exhibit enhanced wetting, flow and leveling properties.
摘要翻译：本发明涉及具有包含无氟有机改性的三硅氧烷的硅氧烷表面活性剂组合物的涂料和印刷油墨组合物，其在约3至约pH约12之间的水解条件下具有抗水解性。本发明的涂料和印刷油墨组合物显示出增强的润湿，流动和流平性能。

36. 发明申请

US20070184005A1 Hydrolysis resistant organomodified trisiloxane surfactants 有权
标题翻译：耐水解的有机改性的三硅氧烷表面活性剂
公开(公告)号：US20070184005A1
公开(公告)日：2007-08-09
申请号：US11350426
申请日：2006-02-09
申请人： George A. Policello , Mark D. Leatherman , Wenqing Peng , Suresh K. Rajaraman , Zijun Xia
发明人： George A. Policello , Mark D. Leatherman , Wenqing Peng , Suresh K. Rajaraman , Zijun Xia
IPC分类号： A61K8/89
CPC分类号： A61K8/894 , A61Q19/00 , C07F7/0838
摘要： Three types of trisiloxane surfactants having the basic formula: MDM′ are described wherein the substituents on the differing M and M′ groups in conjunction with a pendant polyalkylene oxide substituents on the D group to render the surfactant resistant to hydrolysis under either basic or acidic conditions.
摘要翻译：三种类型的具有以下基本式的三硅氧烷表面活性剂：<？in-line-formula description =“In-line formula”end =“lead”？> MDM'<？in-line-formula description =“In-line Formula”end 描述了其中不同的M和M'基团上的取代基与D基团上的侧链聚环氧烷取代基取代基，使表面活性剂在碱性或酸性条件下耐水解。

37. 发明申请

US20110251067A1 Hydrolysis Resistant Organomodified Trisiloxane Surfactants 审中-公开
标题翻译：耐水解有机改性的三硅氧烷表面活性剂
公开(公告)号：US20110251067A1
公开(公告)日：2011-10-13
申请号：US13166116
申请日：2011-06-22
申请人： George A. Policello , Mark D. Leathermani , Wenqing Peng , Suresh K. Rajaraman , Sophia Xia
发明人： George A. Policello , Mark D. Leathermani , Wenqing Peng , Suresh K. Rajaraman , Sophia Xia
IPC分类号： A01N57/20 , A01N59/26 , A01N59/16 , A01N59/06 , A01N59/14 , A01N59/20 , A01N59/08 , A01N43/50 , A01N43/54 , A01N43/38 , A01N63/00 , A01N43/22 , A01N65/12 , A01N47/10 , A01P7/04 , A01P3/00 , A01P11/00 , A01N39/02 , A01N43/40 , A01P13/00 , A01N55/10
CPC分类号： A01N25/30
摘要： Three types of trisiloxane surfactants having the basic formula: MDM′ are described wherein the substituents on the differing M and M′ groups, in conjunction with pendant polyalkylene oxide substituents on the D group render the surfactant resistant to hydrolysis under either basic or acidic conditions outside the pH range of 6.0 to 7.5. The compositions are useful in agricultural, household and cosmetic applications.
摘要翻译：描述了三种具有以下基础式的三硅氧烷表面活性剂：MDM'，其中不同的M和M'基团上的取代基与D基团上的聚环氧烷代表取代基结合使得表面活性剂在外部碱性或酸性条件下耐水解 pH范围为6.0〜7.5。该组合物可用于农业，家用和化妆品应用。

38. 发明授权

US08491876B2 Cosmetic compositions comprising hydrolysis resistant organomodified disiloxane surfactants 有权
标题翻译：包含耐水解的有机改性的二硅氧烷表面活性剂的化妆品组合物
公开(公告)号：US08491876B2
公开(公告)日：2013-07-23
申请号：US12621726
申请日：2009-11-19
申请人： Mark D. Leatherman , George A. Policello , Suresh K. Rajaramaran
发明人： Mark D. Leatherman , George A. Policello , Suresh K. Rajaramaran
IPC分类号： A61Q5/12
CPC分类号： A61Q19/00 , A61K8/585 , C09D163/00 , C08L2666/44
摘要： Compositions comprising disiloxane surfactant compositions comprising a silicone composition comprising a silicone having the formula: MM′ where M=R1R2R3SiO1/2; M′=R4R5R6SiO1/2; with R1 selected from the group consisting of branched monovalent hydrocarbon radical of from 3 to 6 carbon atoms and R7, where R7 has the formula: R8R9R10SiR12 with R8, R9, and R10 each independently selected from the group of monovalent hydrocarbon radicals having from 1 to 6 carbon atoms and monovalent aryl or alkaryl hydrocarbon radicals having from 6 to 13 carbon atoms and R12 is a divalent hydrocarbon radical having from 1 to 3 carbon atoms, R2 and R3 are each independently selected from the group of from 1 to 6 carbon atom monovalent hydrocarbon radicals or R1, with R4 an alkylpolyalkyleneoxide of the general formula: R13(C2H4O)a(C3H6O)b(C4H8O)cR14 where R13 is a divalent linear or branched hydrocarbon radical having the structure: —CH2—CH(R15)(R16)dO— where R15 is H or methyl; R16 is a divalent alkyl radical of 1 to 6 carbons where the subscript d may be 0 or 1; R14 is selected from the group consisting of H, monovalent hydrocarbon radicals of from 1 to 6 carbon atoms and acetyl where the subscripts a, b and c are zero or positive and satisfy the following relationships: 2≦a+b+c≦20 with a≧2, and R5 and R6 are each independently selected from the group of monovalent hydrocarbon radicals having from 1 to 6 carbon atoms or R4 that exhibit resistance to hydrolysis over a wide pH range.
摘要翻译：包含二硅氧烷表面活性剂组合物的组合物，其包含硅氧烷组合物，其包含具有式MM的其中M = R 1 R 2 R 3 SiO 1/2的硅氧烷; M'= R4R5R6SiO1 / 2; 其中R 1选自3至6个碳原子的支化一价烃基和R 7，其中R 7具有下式：R 8 R 9 R 10 SiR 12，其中R 8，R 9和R 10各自独立地选自具有1至 6个碳原子和具有6至13个碳原子的单价芳基或烷芳基烃基，R 12是具有1至3个碳原子的二价烃基，R 2和R 3各自独立地选自1至6个碳原子的单价烃基或R 1，其中R 4是具有通式R 13（C 2 H 4 O）a（C 3 H 6 O）b（C 4 H 8 O）c R 14的烷基聚环氧烷，其中R 13是具有以下结构的二价直链或支链烃基：-CH 2 -CH（R 15））dO-，其中R 15是H或甲基; R16是1至6个碳的二价烷基，其中下标d可以是0或1; R 14选自H，1至6个碳原子的一价烃基和乙酰基，其中下标a，b和c为零或正，并且满足以下关系：2 @ a + b + c @ 20与 a> = 2，R 5和R 6各自独立地选自具有1至6个碳原子的一价烃基或在宽pH范围内表现出抗水解性的R4。

39. 发明申请

US20100069279A1 HOME CARE COMPOSITIONS COMPRISING HYDROLYSIS RESISTANT ORGANOMODIFIED DISILOXANE SURFACTANTS 有权
标题翻译：包含抗水性抗坏血酸甲醛表面活性剂的家庭护理组合物
公开(公告)号：US20100069279A1
公开(公告)日：2010-03-18
申请号：US12621774
申请日：2009-11-19
申请人： Mark D. Leatherman , George A. Policello , Suresh K. Rajaramaran
发明人： Mark D. Leatherman , George A. Policello , Suresh K. Rajaramaran
IPC分类号： C11D1/66 , C09G1/02 , C09K3/18
CPC分类号： A61Q19/00 , A61K8/585 , C09D163/00 , C08L2666/44
摘要： Compositions comprising disiloxane surfactant compositions comprising a silicone composition comprising a silicone having the formula: MM′ where M=R1R2R3SiO1/2; M′=R4R5R6SiO1/2; with R1 selected from the group consisting of branched monovalent hydrocarbon radical of from 3 to 6 carbon atoms and R7, where R7 has the formula: R8R9R10SiR12 with R8, R9, and R10 each independently selected from the group of monovalent hydrocarbon radicals having from 1 to 6 carbon atoms and monovalent aryl or alkaryl hydrocarbon radicals having from 6 to 13 carbon atoms and R12 is a divalent hydrocarbon radical having from 1 to 3 carbon atoms, R2 and R3 are each independently selected from the group of from 1 to 6 carbon atom monovalent hydrocarbon radicals or R1, with R4 an alkylpolyalkyleneoxide of the general formula: R13(C2H4O)a(C3H6O)b(C4H8O)cR14 where R13 is a divalent linear or branched hydrocarbon radical having the structure: —CH2—CH(R15)(R16)dO— where R15 is H or methyl; R16 is a divalent alkyl radical of 1 to 6 carbons where the subscript d may be 0 or 1; R14 is selected from the group consisting of H, monovalent hydrocarbon radicals of from 1 to 6 carbon atoms and acetyl where the subscripts a, b and c are zero or positive and satisfy the following relationships: 2≦a+b+c≦20 with a≧2, and R5 and R6 are each independently selected from the group of monovalent hydrocarbon radicals having from 1 to 6 carbon atoms or R4 that exhibit resistance to hydrolysis over a wide pH range.
摘要翻译：包含二硅氧烷表面活性剂组合物的组合物，其包含硅氧烷组合物，其包含具有式MM的其中M = R 1 R 2 R 3 SiO 1/2的硅氧烷; M'= R4R5R6SiO1 / 2; 其中R 1选自3至6个碳原子的支化一价烃基和R 7，其中R 7具有下式：R 8 R 9 R 10 SiR 12，其中R 8，R 9和R 10各自独立地选自具有1至 6个碳原子和具有6至13个碳原子的单价芳基或烷芳基烃基，R 12是具有1至3个碳原子的二价烃基，R 2和R 3各自独立地选自1至6个碳原子的单价烃基或R 1，其中R 4是具有通式R 13（C 2 H 4 O）a（C 3 H 6 O）b（C 4 H 8 O）c R 14的烷基聚环氧烷，其中R 13是具有以下结构的二价直链或支链烃基：-CH 2 -CH（R 15））dO-，其中R 15是H或甲基; R16是1至6个碳的二价烷基，其中下标d可以是0或1; R 14选自H，1至6个碳原子的一价烃基和乙酰基，其中下标a，b和c为零或正，并且满足以下关系：2＆nlE; a + b + c＆nlE; 20与 a≥2，R5和R6各自独立地选自具有1至6个碳原子的一价烃基或在宽pH范围内表现出抗水解性的R4。

40. 发明授权

US08569385B2 Hydrolysis resistant organomodified silylated ionic surfactants 失效
标题翻译：耐水解的有机改性的硅烷化离子表面活性剂
公开(公告)号：US08569385B2
公开(公告)日：2013-10-29
申请号：US12955276
申请日：2010-11-29
申请人： Mark D. Leatherman , George A. Policello , Wenqing N. Peng , Liping Zeng , Ronald Wagner , Suresh K. Rajamaran , Zijun Xia
发明人： Mark D. Leatherman , George A. Policello , Wenqing N. Peng , Liping Zeng , Ronald Wagner , Suresh K. Rajamaran , Zijun Xia
IPC分类号： A61K47/24 , A61K31/695 , C09D7/12 , C11D1/82 , C09K3/00 , A61Q90/00
CPC分类号： A61Q19/00 , A01N25/30 , A61K8/585 , C07F7/081 , C10G33/04 , C11D3/162 , D21C3/28 , D21H17/59 , D21H19/32 , D21H21/12
摘要： The present invention provides for a composition comprising a silane having the formula: (R1)(R2)(R3)Si—R4—Si(R5)(R6)(R7) wherein R1, R2, R3, R5, and R6 are each independently selected from the group consisting of 1 to 6 monovalent hydrocarbon radicals, aryl, and a hydrocarbon group of 7 to 10 carbons containing an aryl group; R4 is a hydrocarbon group of 1 to 3 carbons; R7 comprises an anionic, cationic or zwitterionic substituent. The silanes of the present invention exhibit resistance to hydrolysis over a wide pH range.
摘要翻译：本发明提供一种组合物，其包含具有下式的（R 1）（R 2）（R 3）Si-R 4 -Si（R 5）（R 6）（R 7）的硅烷，其中R 1，R 2，R 3，R 5和R 6各自为独立地选自1至6个一价烃基，芳基和含有芳基的7至10个碳的烃基; R4是1〜3个碳原子的烃基; R7包含阴离子，阳离子或两性离子取代基。本发明的硅烷在宽的pH范围内表现出抗水解性。

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