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    • 31. 发明授权
    • Air-drying acrylate lacquer binders
    • 空气干燥丙烯酸酯漆粘合剂
    • US4129537A
    • 1978-12-12
    • US842042
    • 1977-10-14
    • Rolf DheinLothar Fleiter
    • Rolf DheinLothar Fleiter
    • C09D163/00C09D125/14C09D3/58C09D3/74
    • C09D125/14C08K5/10
    • An air-drying lacquer binder comprising a copolymer of copolymerized units of20 to 55% by weight of styrene,5 to 30% by weight of glycidyl(meth)acrylate, and0 to 50% by weight of at least one (meth)acrylic acid ester with 1 to 10 carbon atoms in the alcohol component,Which has been esterified with0 to 15% by weight of at least one natural, drying fatty acid, and10 to 50% by weight of isomerized drying fatty acids(the sum of the percentage contents amounting to 22 - 50 percent by weight) based on the copolymer and drying fatty acids and dicarboxylic acid anhydride subsequently used, up to an acid number of
    • 一种空气干燥漆粘合剂,其包含共聚单元的共聚单位为20至55%,苯乙烯重量百分比为5至30%,丙烯酸(甲基)酯为重量百分比,和至少一个(甲基)丙烯酸重量的0至50% 在酒精组分中含有1至10个碳原子的酸性酯,其已经以至少一种天然的重量为基准,0至15%的脂肪酸​​,以及等于脂肪酸的脂肪酸的重量为10至50%(“ 基于共聚物和干燥脂肪酸和二羧酸类抗坏血酸的百分比含量(以重量计)为22-50重量%,最多为<10,30至75%。 含有相同双重债券的异构干燥脂肪酸,以及所形成的羟基组合,其后按照重量的0.5%至3%反应,基于BINDER,四氢醋酸酐和/或至少的总成分 其中一个异星系 漆粘合剂具有非常好的颜料吸收和润湿性能,非常好的漆级可加工性,甚至在恒定干燥条件下加入防结皮剂恒定干燥时间后,
    • 38. 发明授权
    • Pure, in particular catalyst-free polyurethanes
    • 纯的,特别是无催化剂的聚氨酯
    • US5374704A
    • 1994-12-20
    • US166760
    • 1993-12-14
    • Hanns-Peter MullerRolf DheinHerbert HuglHeinz Pudleiner
    • Hanns-Peter MullerRolf DheinHerbert HuglHeinz Pudleiner
    • A61L24/00A61L27/00A61L27/18A61L29/00A61L29/06A61L31/06B65D65/38C08G18/08C08G18/10C08G18/44C08G18/73C08G18/75C08G18/77C08J5/18
    • C08G18/773A61L27/18A61L29/06A61L31/06C08G18/10C08G18/44C08G18/75
    • The present invention is directed to pure polyurethanes which are biocompatible. These pure polyurethanes comprise the reaction product of:a) a pre-adduct containing NCO groups and comprising the reaction product ofi) a diisocyanate selected from the group consisting of aliphatic diisocyanates, cycloaliphatic diisocyanates, and mixtures thereof, withii) a macrodiol having a molecular weight of from 500 to 10,000 wherein said components i) and ii) reacted at temperatures of from 90.degree.-150.degree. C.; withb) a chain extender having a molecular weight of from 62 to 400 and being selected from the group consisting of aliphatic diols, cycloaliphatic diols, and mixtures thereof, and optionally,c) additional diisocyanate selected from the group consisting of aliphatic diisocyanates, cycloaliphatic diisocyanates, and mixtures thereof,wherein said component c), when added, is added either simultaneously with component b) or separately from component b), the quantities of components a)i), a)ii), and c) being such that the molar ratio of diisocyanate to macrodiol is from 1.5:1 to 22:1, and the reaction of components a) and b) and optionally component c) is conducted at temperatures of from 90.degree. to 230.degree. C., with the proviso that the reaction conditions are maintained until said polyurethane has a melt viscosity of at least 2500 mPa.s at 120.degree. C.
    • 本发明涉及生物相容的纯聚氨酯。 这些纯聚氨酯包括以下物质的反应产物:a)含有NCO基团的预加合物,其包含i)选自脂族二异氰酸酯,脂环族二异氰酸酯及其混合物的二异氰酸酯的反应产物,ii)具有 分子量为500至10,000,其中所述组分i)和ii)在90-150℃的温度下反应; 其中b)分子量为62至400的扩链剂,并且选自脂族二醇,脂环族二醇及其混合物,以及任选地,c)另外的二异氰酸酯,其选自脂族二异氰酸酯,脂环族脂族 二异氰酸酯及其混合物,其中所述组分c)在加入时与组分b)同时加入或与组分b)分开加入,组分a)i),a)ii)和c)的数量使得 二异氰酸酯与大分子二醇的摩尔比为1.5:1至22:1,组分a)和b)和任选组分c)的反应在90℃至230℃的温度下进行,条件是 维持反应条件,直到所述聚氨酯在120℃下的熔体粘度为至少2500mPa.s。
    • 40. 发明授权
    • Process for coating heat resistant substrates with two component stoving
compositions
    • 用双组分烘干组合物涂覆耐热基材的方法
    • US5304400A
    • 1994-04-19
    • US821093
    • 1992-01-15
    • Rolf DheinKnud ReuterBurkhard KohlerRainer RettigLothar Backer
    • Rolf DheinKnud ReuterBurkhard KohlerRainer RettigLothar Backer
    • B05D3/02B05D5/00B05D7/02B05D7/06B05D7/14B05D7/24C08G18/08C08G18/62C08K5/29C09D5/02C09D133/02C09D133/04C09D133/06C09D175/04
    • C08G18/6254C08G18/0819C08K5/29
    • The present invention relates to a process for preparing a coated, heat resistant substrate byI) coating the substrate with a coating composition containinga) a solution or dispersion containinga1) 100 parts by weight of at least one hydroxyl-functional polyacrylate resin in dissolved or dispersed form, wherein the resin has a hydroxyl value of 15 to 200 mg KOH/G solid resin, an acid value of 5 to 250 mg KOH/G solid resin and a total content of chemically incorporated carboxylate and/or sulfonate groups of 8 to 450 milliequivalents per 100 g of solids,a2) 25 to 395 parts by weight of water anda3) 5 to 125 parts by weight of at least one organic solvent having a boiling point or boiling range at 1013 mbar of 100 to 300.degree. C. andb) at least one organic polyisocyanate in a quantity corresponding to an equivalent ratio of isocyanate groups of component b) to isocyanate-reactive groups of component a1) of 0.7:1 to 3:1, andII) curing the coating composition at a temperature of 40 toThe present invention is also directed to the coated substrates obtained by this process.
    • 本发明涉及一种制备涂层耐热基材的方法,其方法是用涂料组合物涂覆基材,所述涂料组合物含有:a)含有a1)100重量份的至少一种羟基官能的聚丙烯酸酯树脂溶解的溶液或分散体 或分散形式,其中所述树脂的羟值为15-200mg KOH / G固体树脂,酸值为5至250mg KOH / G固体树脂,并且化学掺入的羧酸盐和/或磺酸盐基团的总含量为8 每100g固体为450毫当量,a2)25至395重量份的水和a3)5至125重量份的至少一种沸点或沸点范围为1013毫巴的有机溶剂为100至300摄氏度 和b)至少一种有机多异氰酸酯,其量对应于组分b)的异氰酸酯基团与组分a1)的异氰酸酯反应性基团的当量比为0.7:1至3:1,和II)使涂料组合物固化 温度为40℃ 本发明还涉及通过该方法获得的涂布基材。