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31. 发明授权

US5466523A Hydrophilic chemically adsorbed film 失效
标题翻译：亲水化学吸附膜
公开(公告)号：US5466523A
公开(公告)日：1995-11-14
申请号：US250943
申请日：1994-05-31
申请人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
发明人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
IPC分类号： B05D1/18 , B29D11/00 , G02B1/10 , B32B7/04
CPC分类号： B82Y30/00 , B05D1/185 , B29D11/00865 , B82Y40/00 , G02B1/10 , Y10T428/261 , Y10T428/31663 , Y10T428/31667
摘要： A chemically adsorbed film containing hydrophilic groups is formed on a substrate such that it is chemically bonded by Si covalent bonds to the substrate. The adsorbed film has an improved hydrophilic property. In addition, the film provides an excellently durable and transparent fog-proof substrate. According to the method of the invention, a substrate containing hydrophilic groups is contacted with a non-aqueous solution containing a surface active material having straight chain molecules each having at one end a chlorosilyl group and at the other end at least one functional group selected from the group consisting of a bromo group, iodo group, cyano group, thiocyano group, chlorosilyl group etc. to cause a dehydrochlorination reaction between hydrophilic groups on the substrate surface and chlorosilyl groups of the surface active material, thereby forming a chemically adsorbed film on the substrate surface. The functional group at the other end of the surface active material is converted into at least one hydrophilic group selected from the group consisting of --OH, --COOH, --NH.sub.2, .dbd.NH, --N.sup.+ R.sub.3 X.sup.- (X representing a halogen atom, R represents a lower alkyl group), --NO.sub.2, --SH, and --S).sub.3 H groups.
摘要翻译：在基板上形成含有亲水基团的化学吸附膜，使其通过Si共价键与基材进行化学键合。吸附的膜具有改善的亲水性。此外，该膜还提供了耐用和透明的防雾基材。根据本发明的方法，将含有亲水基团的基材与含有直链分子的表面活性物质的非水溶液接触，所述表面活性物质的一端各自具有氯甲硅烷基，另一端与至少一个选自由溴基，碘基，氰基，硫氰基，氯代甲硅烷基等组成的基团，从而在基材表面的亲水基团与表面活性物质的氯甲硅烷基之间产生脱氯化氢反应，从而在基材表面。将表面活性物质的另一端的官能团转化为至少一种选自-OH，-COOH，-NH 2，= NH，-N + R 3 X - （X表示卤素原子， R表示低级烷基），-NO 2，-SH和-S）3 H基。

32. 发明授权

US5443511A Medical member and method of manufacturing the same 失效
标题翻译：医疗会员及其制造方法
公开(公告)号：US5443511A
公开(公告)日：1995-08-22
申请号：US89629
申请日：1993-07-12
申请人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
发明人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
IPC分类号： A61L33/00 , B05D1/18 , C09D4/00 , A61F2/28 , A61K6/08
CPC分类号： B82Y30/00 , A61L33/0088 , B05D1/185 , B82Y40/00 , B82Y5/00 , C09D4/00 , Y10S623/923
摘要： A medical member having active hydrogen groups such as hydroxyl, amino or imino groups at its surface, is dipped, either directly or after formation of an inner layer on its surface, into a solution. The solution is prepared by dissolving a surface active material, e.g., CF.sub.b 3 (CF.sub.2).sub.7 (CH.sub.2).sub.2 SiCl.sub.3 in a non-aqueous solvent. A dehydrochlorination reaction is brought about between active hydrogen groups at the surface of the member and SiCl groups of the surface active material, thus producing bonds ofCF.sub.3 (CF.sub.2).sub.7 (CH.sub.2).sub.2 Si(O--).sub.3over the entire surface. A fluorine-containing monomolecular film is formed, which is chemically (or covalently) bonded to the member surface and has a thickness at the nanometer level. Since the chemically adsorbed film is covalently bonded to the member or inner layer, it is chemically stable and difficult to separate. Excellent medical members can be obtained when the invention is applied to an artificial tooth, a joint, a bone, a blood bag, a catheter, a blood transportation tool, a dialysis equipment part, an operation thread, a medical implant and an operation tool.
摘要翻译：在其表面具有羟基，氨基或亚氨基的活性氢基团的医学成分在其表面上直接或内层形成后溶解成溶液。通过将表面活性物质例如CFb 3（CF 2）7（CH 2）2 ClCl 3溶解在非水溶剂中来制备溶液。在构件表面的活性氢基团和表面活性物质的SiCl基团之间产生脱氯化氢反应，从而在整个表面上产生CF 3（CF 2）7（CH 2）2 Si（O - ）3的键。形成化学（或共价）结合到构件表面并具有纳米级厚度的含氟单分子膜。由于化学吸附的膜共价结合到构件或内层，因此化学稳定且难以分离。将本发明应用于人造牙，关节，骨，血袋，导管，血液输送工具，透析设备部件，手术线，医疗植入物和操作工具时，可以获得优异的医疗部件。

33. 发明授权

US5425989A Self-lubricating device 失效
标题翻译：自润滑装置
公开(公告)号：US5425989A
公开(公告)日：1995-06-20
申请号：US145669
申请日：1993-11-04
申请人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
发明人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
IPC分类号： B05D1/18 , B05D5/08 , C09D4/00 , B32B7/04
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , C09D4/00 , B05D5/08 , Y10T428/261 , Y10T428/266 , Y10T428/268 , Y10T428/31536 , Y10T428/31663
摘要： A chemically adsorbed film having a surface layer containing fluorine groups and a stem layer chemically bonded by siloxane bonds to a substrate is formed on the surface of a frictional portion of a machine part such as a gear or a bearing or on the surface of a game ball. An excellently self-lubricating low frictional resistance machine part or game ball thus can be obtained. A frictional portion of a gear or the like, made of SiO.sub.2 or like ceramic material, is dipped and held in a solution containing a surface active material, e.g., CF.sub.3 (CF.sub.2).sub.7 (CH.sub.2).sub.2 SiCl.sub.3 dissolved in a non-aqueous solvent. A hydrochloric acid removal reaction is brought about between SiCl groups of the material, which contains a fluorocarbon and a chlorosilane group, and hydroxyl groups numerously present on the SiO2 surface, thus forming bonds ofCF.sub.3 (CF.sub.2).sub.7 (CH.sub.2).sub.2 Si(O--).sub.3over the entire frictional portion surface. A fluorine-containing monomolecular film thus is formed, which is chemically bonded to the substrate and has a thickness of about 1.5 nm.
摘要翻译：在机械部件例如齿轮或轴承的摩擦部分的表面上或游戏表面上形成具有含氟基团的表面层和通过硅氧烷键合到基材上的茎层的化学吸附膜球。因此可以获得优异的自润滑低摩擦阻力机器部件或游戏球。将由SiO 2或类似陶瓷材料制成的齿轮等的摩擦部分浸渍并保持在含有溶解在非水溶剂中的表面活性物质例如CF 3（CF 2）7（CH 2）2 ClCl 3）的溶液中。在含有碳氟化合物和氯硅烷的材料的SiCl基团和SiO 2表面上大量存在的羟基之间产生盐酸去除反应，从而形成CF 3（CF 2）7（CH 2）2 Si（O- ）3在整个摩擦部分表面上。因此，形成与基板化学键合并且具有约1.5nm的厚度的含氟单分子膜。

34. 发明授权

US5407709A Anti-contaminating adsorbed film and method of manufacturing the same 失效
标题翻译：抗污染吸附膜及其制造方法
公开(公告)号：US5407709A
公开(公告)日：1995-04-18
申请号：US148499
申请日：1993-11-08
申请人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
发明人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
IPC分类号： B05D1/18 , C03C17/42 , C08J7/04 , C09D4/00 , C09D183/02 , C09D183/08 , B05D3/06
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , B82Y5/00 , C03C17/42 , C08J7/047 , C09D183/02 , C09D183/08 , C09D4/00 , C08J2483/00 , Y10T428/261 , Y10T428/31612 , Y10T428/31663
摘要： This invention provides for an anti-contaminating film which is adsorbed to a substrate surface. The film contains a --Si-- group and fluorocarbon group. The --Si-- group is covalently bonded to the substrate surface. It also provides a forming method of an anti-contaminating film on a hydrogen active substrate surface by contacting the substrate surface with a non-aqueous solution, containing a surface active material having fluorocarbon groups and chlorosilane groups, the substrate surface having active hydrogen groups, removing unreacted surface active material remaining on the substrate by washing the substrate with a non-aqueous organic solution for making a monomolecular precursor film, reacting chlorosilane groups unreacted in the adsorbed monomolecular a precursor film with water after the removing step, and drying the adsorbed monomolecular film.
摘要翻译：本发明提供一种吸附在基材表面上的防污膜。该片含有-Si-基和氟碳基。 -Si-基团共价结合到基材表面。还通过使基板表面与含有具有氟代烃基的表面活性物质和氯代硅烷基的非水溶液接触，具有活性氢基团的基材表面，在氢活性基材表面上提供抗污染膜的形成方法，通过用用于制备单分子前体膜的非水有机溶液洗涤基底来除去残留在基底上的未反应的表面活性物质，在除去步骤后将吸附的单分子前体膜中的未反应的氯硅烷与水反应，并将吸附的单分子电影。

35. 发明授权

US5187639A Capacitor and method of manufacturing the same 失效
标题翻译：电容器及其制造方法
公开(公告)号：US5187639A
公开(公告)日：1993-02-16
申请号：US897291
申请日：1992-06-11
申请人： Kazufumi Ogawa , Mamoru Soga , Norihisa Mino
发明人： Kazufumi Ogawa , Mamoru Soga , Norihisa Mino
IPC分类号： B32B7/10 , H01G4/14 , H01G4/18 , H01G4/20 , H01G4/33
CPC分类号： B82Y30/00 , B82Y10/00 , H01G4/206 , Y10T29/435
摘要： A monomolecularfilm which can be used as a dielectric film is obtained on a substrate surface. For example, an aluminum foil electrode substrate having a natural oxide film is obtained by chemically adsorbing a chlorosilane-based surface active material comprising a fluorocarbon chain to the substrate. It is possible in this invention to have a pre-treatment as follows in lieu of using the natural oxide layer: forming an electrolytic oxidated layer by electrolytic oxidation of the metallic film, or bonding a thin oxide layer such as SiO.sub.2, Al.sub.2 O.sub.3 being several hundred nanometers in thickness to the surface metallic film by spatter deposition, thus obtaining an excellent capacitor. A capacitor can be obtained by deposition of the aluminum layer on the surface bilayer laminated film. A thin film capacitor which has a high volume can be obtained comprising a thin (nanometer level), substantially pinhole-free dielectric film by using a siloxane-based monomolecular film having a fluorocarbon chain as the dielectric film.

36. 发明授权

US5143750A Method of manufacturing chemically adsorbed film 失效
标题翻译：制备化学吸附膜的方法
公开(公告)号：US5143750A
公开(公告)日：1992-09-01
申请号：US810114
申请日：1991-12-19
申请人： Yoshikazu Yamagata , Norihisa Mino , Kazufumi Ogawa , Mamoru Soga
发明人： Yoshikazu Yamagata , Norihisa Mino , Kazufumi Ogawa , Mamoru Soga
IPC分类号： B05D1/18 , C03C17/30 , C04B41/45 , C04B41/49 , C04B41/81 , C04B41/84 , C09D4/00 , H01L21/312
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , C03C17/30 , C04B41/009 , C04B41/4505 , C04B41/4922 , C04B41/81 , C04B41/84 , C09D4/00 , H01L21/3121
摘要： According to the invention, a chemically adsorbing material is reacted with a substrate surface having active hydrogen groups by dipping the substrate into a solution of the chemically adsorbing material simultaneous and applying ultrasonic waves to the solution. In this way, a high concentration monomolecular and/or polymer film substantially free from pin holes can be formed in a short period of time. That is, while the ultrasonic waves are applied, a chemical adsorbing material having an end functional chlorosilyl group is adsorbed onto the substrate surface, thereby forming a chemically adsorbed monomolecular and/or polymer film. The frequency of the ultrasonic waves are suitably in a range of 25 to 50 kHz. In addition, after formation of the adsorbed film, the substrate is washed for making monomolecular film by dipping it in a washing solution while applying ultrasonic waves. In this way, non-reacted chemical adsorbing material remaining on the substrate can be efficiently washed away.

37. 发明授权

US5443901A Magnetic recording medium having an adsorbed film of molecules comprising two species of straight carbon chain molecules 失效
标题翻译：具有包含两种直链碳链分子的分子的吸附膜的磁记录介质
公开(公告)号：US5443901A
公开(公告)日：1995-08-22
申请号：US155244
申请日：1993-11-22
申请人： Norihisa Mino , Mamoru Soga , Ogawa Kazufumi
发明人： Norihisa Mino , Mamoru Soga , Ogawa Kazufumi
IPC分类号： G11B5/72 , G11B5/725 , G11B5/735 , G11B5/738 , G11B5/00
CPC分类号： B82Y30/00 , B82Y10/00 , G11B5/72 , G11B5/725 , G11B5/735 , G11B5/738 , Y10S428/90 , Y10T428/265 , Y10T428/31663
摘要： A magnetic recording film, which has excellent slip durability, is run-proof and wear-proof as well as self-lubricating, is obtained by forming a chemically adsorbed film composed of straight carbon chain surface active materials having different carbon numbers, the chemically adsorbed film being chemically bonded via siloxane covalently bonds.In the method of manufacture, a magnetic recording medium, e.g., a hard disk, is contacted with a solution which is made by dissolving a straight carbon chain surface active material having a chlorosilyl group at one end and a fluorocarbon or hydrocarbon group at the other end in a non-aqueous solvent, thereby chemically bonding the chlorosilane-based straight chain surface active material to the surface of the magnetic recording medium via siloxane covalently bonds.
摘要翻译：通过形成由具有不同碳数的直链碳链表面活性材料构成的化学吸附膜，具有防滑，耐磨和自润滑的优异的耐滑性的磁记录膜，化学吸附通过硅氧烷化学键合的膜共价键合。在制造方法中，将磁记录介质（例如硬盘）与通过将一端具有氯甲硅烷基的直链碳链表面活性材料和另一端的碳氟化合物或烃基溶解而制成的溶液在非水溶剂中结束，从而通过硅氧烷将基于氯硅烷的直链表面活性材料化学键合到磁记录介质的表面进行共价键合。

38. 发明授权

US07560731B2 Organic electronic device and method for manufacturing the same 失效
标题翻译：有机电子器件及其制造方法
公开(公告)号：US07560731B2
公开(公告)日：2009-07-14
申请号：US11633924
申请日：2006-12-05
申请人： Shinichi Yamamoto , Norihisa Mino , Kazufumi Ogawa
发明人： Shinichi Yamamoto , Norihisa Mino , Kazufumi Ogawa
IPC分类号： H01L35/24
CPC分类号： G02F1/13439 , C08G61/122 , G02F1/1343 , G02F2001/136295 , G02F2202/022 , H01L51/0021 , H01L51/0035
摘要： An organic electronic device of the present invention includes a substrate, at least two electrodes formed on the substrate, a conductive organic thin film that is formed on the substrate and electrically connects the electrodes, and a coating film for coating at least a portion of the electrodes. The conductive organic thin film is a polymer of organic molecules containing a conjugated-bondable group, and one end of each of the organic molecules is chemically bonded to the surface of the substrate and the conjugated-bondable groups in the organic molecules are polymerized with other conjugated-bondable groups to form a conjugated bond chain. The coating film electrically connects the electrodes to the conductive organic thin film and achieves a smaller connection resistance than that in the case where the electrodes and the conductive organic thin film are connected directly. As the coating film, a film made of metal selected from gold, platinum, and silver, a conductive polymeric film, or a monomolecular film that is chemically bonded to the electrodes can be used.
摘要翻译：本发明的有机电子器件包括基板，形成在基板上的至少两个电极，形成在基板上并电连接电极的导电有机薄膜，以及用于涂覆至少一部分电极。导电有机薄膜是含有共轭键合基团的有机分子的聚合物，并且每个有机分子的一端化学键合到基底表面，并且有机分子中的共轭键基团与其它分子聚合共轭键合基团以形成共轭键链。涂膜将电极与导电性有机薄膜电连接，与直接连接电极和导电性有机薄膜的情况相比，能够实现较小的连接电阻。作为涂膜，可以使用由金，铂，银等金属制成的膜，导电性聚合物膜，或与电极化学键合的单分子膜。

39. 发明申请

US20070085076A1 Organic electronic device and method for manufacturing the same 失效
公开(公告)号：US20070085076A1
公开(公告)日：2007-04-19
申请号：US11633924
申请日：2006-12-05
申请人： Shinichi Yamamoto , Norihisa Mino , Kazufumi Ogawa
发明人： Shinichi Yamamoto , Norihisa Mino , Kazufumi Ogawa
IPC分类号： H01L29/08
CPC分类号： G02F1/13439 , C08G61/122 , G02F1/1343 , G02F2001/136295 , G02F2202/022 , H01L51/0021 , H01L51/0035
摘要： An organic electronic device of the present invention includes a substrate, at least two electrodes formed on the substrate, a conductive organic thin film that is formed on the substrate and electrically connects the electrodes, and a coating film for coating at least a portion of the electrodes. The conductive organic thin film is a polymer of organic molecules containing a conjugated-bondable group, and one end of each of the organic molecules is chemically bonded to the surface of the substrate and the conjugated-bondable groups in the organic molecules are polymerized with other conjugated-bondable groups to form a conjugated bond chain. The coating film electrically connects the electrodes to the conductive organic thin film and achieves a smaller connection resistance than that in the case where the electrodes and the conductive organic thin film are connected directly. As the coating film, a film made of metal selected from gold, platinum, and silver, a conductive polymeric film, or a monomolecular film that is chemically bonded to the electrodes can be used.

40. 发明申请

US20060257588A1 Conductive organic thin film, method for manufacturing the same, and electronic device, electric cable, electrode, pyrrolyl compound, and thienyl compound using the same 有权
标题翻译：导电性有机薄膜及其制造方法以及电子器件，电缆，电极，吡咯基化合物及使用其的噻吩基化合物
公开(公告)号：US20060257588A1
公开(公告)日：2006-11-16
申请号：US11488994
申请日：2006-07-19
申请人： Kazufumi Ogawa , Norihisa Mino , Shinichi Yamamoto
发明人： Kazufumi Ogawa , Norihisa Mino , Shinichi Yamamoto
IPC分类号： C09K19/00
CPC分类号： H01L51/0545 , B82Y10/00 , G02F1/133711 , G02F1/133719 , G02F1/13378 , G02F1/133784 , G02F1/133788 , G02F2001/133796 , G02F2202/027 , H01B1/12 , H01B1/125 , H01B1/127 , H01L51/0012 , H01L51/0075 , H01L51/0508 , H01L51/0595 , H01L51/42 , H01L51/428 , Y02E10/549 , Y02P70/521 , Y10S428/91 , Y10T428/10 , Y10T428/1005 , Y10T428/1014 , Y10T428/31663
摘要： It is an object to provide a conductive organic thin film having organic molecules that include at one end a terminal bonding group that is covalently bonded to a substrate surface, a conjugate bonding group that is located at any portion of the organic molecules and that is polymerized with other molecules, and a polar functional group that does not include active hydrogen and that is located at any portion between the terminal bonding group and the conjugate bonding group, wherein the organic molecules are oriented and their conjugate bonding groups are polymerized, forming a conduction network. The conductivity (ρ) of the conductive organic thin film at room temperature (25° C.) is at least 5.5×105 S/cm, and preferably at least 1×107 S/cm, without dopants, having significantly higher conductivity than metals such as gold and silver. In particular, a film of polypyrrole or polythienylene conjugate bonds that is polymerized through polymerization through electrolytic oxidation has high conductivity.
摘要翻译：本发明的目的是提供一种具有有机分子的导电有机薄膜，该有机分子的一端包含共价结合到基材表面的端键合基团，位于有机分子的任何部分并且被聚合的共轭键合基团与其它分子，以及不包括活性氢并且位于末端键合基团和共轭键合基团之间的任何部分的极性官能团，其中有机分子取向并且它们的共轭键合基团聚合，形成导电网络。导电有机薄膜在室温（25℃）下的电导率（rho）至少为5.5×10 -5 S / cm，优选至少为1×10 7 / S / cm，没有掺杂剂，具有比诸如金和银的金属显着更高的导电率。特别地，通过电解氧化聚合而聚合的聚吡咯或聚噻吩键共轭键具有高导电性。

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