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    • 31. 发明专利
    • DE69429198T2
    • 2002-08-14
    • DE69429198
    • 1994-08-12
    • MITSUI CHEMICALS INC
    • SHINOZAKI TETSUNORIKIOKA MAMORU
    • C08F4/02C08F4/649C08F4/651C08F4/654C08F4/658C08F10/06C08F110/06C08F210/06C08F297/08
    • The present invention provides olefin polymerization catalysts and processes for preparing a polypropylene and a propylene block copolymer using said olefin polymerization catalysts. The olefin polymerization catalyst (I) of the invention is formed from: ÄI-1Ü a contact product obtained by contacting: (A) a solid titanium catalyst component, (B) an organometallic compound catalyst component, and (C) a specific organosilicon compound; ÄII-1Ü (D) a specific polyether compound; and optionally, ÄIIIÜ an organometallic compound catalyst component. The olefin polymerization catalyst (2) of the invention is formed from: Ä1-2Ü a contact product obtained by contacting: (A) a solid titanium catalyst component, (B) an organometallic compound catalyst component, and (D) a specific polyether compound; ÄII-2Ü (C) a specific organosilicon compound; and optionally, ÄIIIÜ an organometallic compound catalyst component. The contact product ÄI-1Ü or ÄI-2Ü may be replaced by one which is obtained by prepolymerizing an olefin of 2 or more carbon atoms in the presence of the catalyst components for the contact product ÄI-1Ü or ÄI-2Ü in such a way that the amount of the prepolymer formed is 0.01 to 2,000 g based on 1 g of the solid titanium catalyst component (A). In the processes for preparing a polypropylene according to the invention, propylene is polymerized in the presence of the above-mentioned olefin polymerization catalysts. According to the invention, highly isotactic polypropylene can be prepared. The processes for preparing a propylene block copolymer according to the invention comprises the steps of polymerizing propylene to form a polypropylene component and copolymerizing ethylene and an alpha -olefin of 3 to 20 carbon atoms to form an ethylene/ alpha -olefin copolymer component, in an optional order, in the presence of the specific polymerization catalysts. In the propylene block copolymer obtained by the invention, the polypropylene component is highly isotactic and the rubber component has a high intrinsic viscosity Ä eta Ü.
    • 36. 发明专利
    • Film and release film
    • 电影和电影片
    • JP2014058697A
    • 2014-04-03
    • JP2014002371
    • 2014-01-09
    • Mitsui Chemicals Inc三井化学株式会社
    • MATSUMOTO TETSUHIROTSUTSUI TOSHIYUKIRO KISHUKUROIWA YOSHINORINAGATA TAKUJISHIBAHARA ATSUSHINAKAMURA TATSUYATANAKA TORUSHINOZAKI TETSUNORI
    • C08F210/14C08J5/18
    • C08F10/00C08F210/14C08F2500/26C08J5/18C08J2323/20C08F4/651C08F2500/15
    • PROBLEM TO BE SOLVED: To produce a 4-methyl-1-pentene polymer excellent in stereoregularity, transparency and heat resistance, and a film excellent in transparency, heat resistance, releasability and suitable as a release film, which is obtained from the 4-methyl-1-pentene polymer.SOLUTION: The 4-methyl-1-pentene copolymer includes a structural unit derived from 4-methyl-1-pentene by 80 to 99.9 mass% and a structural unit derived from at least one α-olefin having 3 to 11 carbon atoms, excluding 4-methyl-1-pentene, by 0.1 to 20 mass%, in which a ratio (a/b) of the content amass% of structural units derived from the α-olefin having 3 to 11 carbon atoms excluding 4-methyl-1-pentene in a n-decane soluble component to the content bmass% of structural units derived from the at least one α-olefin having 3 to 11 carbon atoms excluding 4-methyl-1-pentene in the copolymer ranges from 2.0 to 4.0. A film is produced from the 4-methyl-1-pentene polymer.
    • 要解决的问题:为了制备立构规整性,透明性和耐热性优异的4-甲基-1-戊烯聚合物,以及透明性,耐热性,脱模性优异且适合作为脱模膜的膜,其由4- 甲基-1-戊烯聚合物。溶液:4-甲基-1-戊烯共聚物包括衍生自80-99.9质量%的4-甲基-1-戊烯的结构单元和衍生自至少一种α-烯烃的结构单元,其具有 3〜11个碳原子(不包括4-甲基-1-戊烯)0.1〜20质量%,其中来自具有3〜11个碳原子的α-烯烃的结构单元的含量的氨基酸的比例(a / b) 在正癸烷可溶成分中除去4-甲基-1-戊烯以外的原子的至少1种以上的除了4-甲基-1-戊烯以外的含有3〜11个碳原子的α-烯烃的结构单元的含量bmass% 范围从2.0到4.0。 由4-甲基-1-戊烯聚合物制备薄膜。
    • 40. 发明专利
    • Polypropylene resin composition and application thereof
    • 聚丙烯树脂组合物及其应用
    • JP2003041072A
    • 2003-02-13
    • JP2002149152
    • 2002-05-23
    • Mitsui Chemicals Inc三井化学株式会社
    • YAMADA MASAYACHOKAI MICHIOFUTAMI YASUOSHINOZAKI TETSUNORIKIOKA MAMORU
    • B65D65/40B32B27/32C08J5/18C08L23/10
    • PROBLEM TO BE SOLVED: To provide a polypropylene resin composition capable of providing a sheet excellent in a steam barrier property, rigidity and transparency, and a press-through pack packaging polypropylene sheet and a press-through pack packaging polypropylene multilayer sheet.
      SOLUTION: This polypropylene resin composition comprises (A) 70-95 wt.% propylene polymer having such properties that a melt flow rate of the polymer is in the range of 0.1 to 500 g/10 min, a pentad isotacticity [M5] of a boiled heptane-insoluble component is in the range of 0.970 to 0.995, a pentad isotacticity [M3] of a boiled heptane-insoluble component is in the range of 0.0020 to 0.0050, and a crystallinity of a boiled heptane-insoluble component is ≥60% and (D) 30-5 wt.% hydrogenated petroleum resin.
      COPYRIGHT: (C)2003,JPO
    • 要解决的问题:提供一种能够提供蒸气阻隔性,刚性和透明度优异的片材的聚丙烯树脂组合物,以及压入包装包装聚丙烯片材和压入包装包装聚丙烯多层片材。 解决方案:该聚丙烯树脂组合物包含(A)70-95重量%的丙烯聚合物,其具有使聚合物的熔体流动速率在0.1-500g / 10min的范围内,丙烯聚合物的五元等规度[M5] 沸腾庚烷不溶性成分在0.970〜0.995的范围内,沸腾庚烷不溶成分的五价全同立构规整度[M3]在0.0020〜0.0050的范围内,沸腾庚烷不溶成分的结晶度> 60 %和(D)30-5重量%氢化石油树脂。