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31. 发明授权

US07915454B2 Method for producing ethylenediamine 有权
标题翻译：乙二胺的制备方法
公开(公告)号：US07915454B2
公开(公告)日：2011-03-29
申请号：US12529107
申请日：2008-02-28
申请人： Alfred Oftring , Kirsten Dahmen , Randolf Hugo , Thilo Hahn , Katrin Baumann , Johann-Peter Melder
发明人： Alfred Oftring , Kirsten Dahmen , Randolf Hugo , Thilo Hahn , Katrin Baumann , Johann-Peter Melder
IPC分类号： C07C209/48
CPC分类号： C07C209/48 , C07C211/10
摘要： The invention relates to a process for preparing ethylenediamine by hydrogenation of aminoacetonitrile over a catalyst, wherein the hydrogenation is carried out in a solution comprising aminoacetonitrile, water in a proportion of from 0 to 60% by weight and a solvent and the aminoacetonitrile comprised in the solution is fed into the reaction vessel at a rate which is not greater than the rate at which the aminoacetonitrile reacts with hydrogen in the hydrogenation.
摘要翻译：本发明涉及一种通过氨基乙腈在催化剂上氢化制备乙二胺的方法，其中氢化是在包含氨基乙腈的溶液中，以0至60重量％的比例的水和溶剂和包含在其中的氨基乙腈溶液以不大于氨基乙腈在氢化中与氢反应的速率进料到反应容器中。

32. 发明申请

US20100274055A1 METHOD FOR PRODUCING AN AMINE 有权
标题翻译：生产氨的方法
公开(公告)号：US20100274055A1
公开(公告)日：2010-10-28
申请号：US12809649
申请日：2008-12-10
申请人： Petr Kubanek , Wolfgang Mägerlein , Ekkehard Schwab , Johann-Peter Melder , Manfred Julius
发明人： Petr Kubanek , Wolfgang Mägerlein , Ekkehard Schwab , Johann-Peter Melder , Manfred Julius
IPC分类号： C07C209/44 , B01J27/185 , B01J23/883 , B01J23/755 , B01J23/835 , B01J23/745
CPC分类号： B01J23/883 , B01J23/002 , B01J23/76 , B01J23/835 , B01J23/8435 , B01J23/8437 , B01J37/03 , B01J37/18 , B01J2523/00 , C07C209/16 , C07C213/02 , C07D295/023 , Y02P20/582 , B01J2523/44 , B01J2523/48 , B01J2523/842 , B01J2523/847 , B01J2523/68 , B01J2523/51 , B01J2523/43 , B01J2523/53 , B01J2523/54
摘要： Processes for preparing an amine, which processes comprise: reacting a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones, and mixtures thereof, with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a zirconium dioxide- and nickel-containing catalyst; wherein the catalyst comprises a catalytically active composition which comprises, before reduction with hydrogen, oxygen compounds of zirconium, nickel, and iron, and 0.2 to 5.5% by weight of at least one oxygen compound of tin, lead, bismuth, molybdenum, antimony or phosphorus, calculated as SnO, PbO, Bi2O3, MoO3, Sb2O3 and H3PO4 respectively; and wherein the catalytically active composition of the catalyst does not comprise any copper.
摘要翻译：用于制备胺的方法，该方法包括：将选自伯醇，仲醇，醛，酮及其混合物的反应物与氢和选自以下的氮化合物反应：氨，伯胺，仲胺及其混合物，在二氧化锆和含镍催化剂存在下; 其中所述催化剂包含催化活性组合物，其在用氢还原之前包括锆，镍和铁的氧化合物和0.2至5.5重量％的至少一种氧化合物的锡，铅，铋，钼，锑或磷，分别计算为SnO，PbO，Bi2O3，MoO3，Sb2O3和H3PO4; 并且其中催化剂的催化活性组合物不包含任何铜。

33. 发明申请

US20100105952A1 PROCESS FOR THE SYNTHESIS OF DMAPA 有权
标题翻译：合成DMAPA的方法
公开(公告)号：US20100105952A1
公开(公告)日：2010-04-29
申请号：US12683015
申请日：2010-01-06
申请人： Martin Ernst , Steffen Oehlenschläger , Frank Kuhnke , Karl-Heinz Roß , Roland Deeg , Johann-Peter Melder
发明人： Martin Ernst , Steffen Oehlenschläger , Frank Kuhnke , Karl-Heinz Roß , Roland Deeg , Johann-Peter Melder
IPC分类号： C07C209/02 , B01J19/00
CPC分类号： C07C209/48 , B01J2219/00006 , C07C253/30 , C07C211/11 , C07C255/24
摘要： The present invention relates to a process for the industrial preparation of a diamine starting from a corresponding alkenyl nitrile comprising at least one C—C double bond, which comprises the steps (a) reaction of the alkenyl nitrile with a corresponding monoamine in a first reactor so that the monoamine adds exothermically onto the at least one double bond to form an aminoalkyl nitrile, with the monoamine and water being charged initially and the alkenyl nitrile being fed in; (b) evaporation of unreacted alkenyl nitrile and monoamine to increase the concentration of the aminoalkyl nitrile product in the bottoms of the first reactor; (c) transfer of the aminoalkyl nitrile bottom product from step (b) to a second reactor; (d) batchwise catalytic hydrogenation of the aminoalkyl nitrile transferred in step (c) to the diamine in the second reactor, with each batch being obtained by initially charging a catalyst suitable for the hydrogenation of nitriles to amines and also water, the desired diamine and a base, introducing hydrogen into the second reactor and feeding in the aminoalkyl nitrile transferred in step (c); and (e) isolation of the diamine and, if appropriate, repetition of the steps (a) to (e). The invention further relates to an apparatus for preparing these diamines and the use of the apparatuses. A preferred diamine is 3-dimethylaminopropylamine (DMAPA).
摘要翻译：本发明涉及从包含至少一个C-C双键的相应链烯基腈开始工业制备二胺的方法，其包括步骤（a）在第一反应器中烯基腈与相应的单胺反应使得单胺在至少一个双键上放热添加以形成氨基烷基腈，最初加入单胺和水，并加入链烯基腈; （b）蒸发未反应的烯基腈和单胺以增加第一反应器底部氨基烷基腈产物的浓度; （c）将氨基烷基腈底部产物从步骤（b）转移至第二反应器; （d）将步骤（c）中转移的氨基烷基腈分批催化氢化为第二反应器中的二胺，每个批次通过首先将适合于将腈氢化成的催化剂加入到胺中而得到，并且还需要水，所需的二胺和碱，将氢气引入第二反应器并进料步骤（c）中转移的氨基烷基腈; 和（e）分离二胺，如果合适，重复步骤（a）至（e）。本发明还涉及一种用于制备这些二胺的装置和该装置的用途。优选的二胺是3-二甲基氨基丙胺（DMAPA）。

34. 发明申请

US20100099872A1 PRODUCTION METHOD FOR ETHYLENEAMINE MIXTURES 有权
标题翻译：乙烯胺混合物的生产方法
公开(公告)号：US20100099872A1
公开(公告)日：2010-04-22
申请号：US12529087
申请日：2008-02-27
申请人： Kirsten Dahmen , Alfred Oftring , Katrin Baumann , Randolf Hugo , Thilo Hahn , Johann-Peter Melder
发明人： Kirsten Dahmen , Alfred Oftring , Katrin Baumann , Randolf Hugo , Thilo Hahn , Johann-Peter Melder
IPC分类号： C07D241/04 , C07C209/00
CPC分类号： C07C209/48 , C07C211/10 , C07C211/13 , C07C211/14 , C07C253/30 , C07C255/25
摘要： The invention relates to a process for preparing an ethylene amine mixture, which comprises hydrogenating an amino nitrile mixture comprising at least two α-amino nitriles in an amount of at least 5% by weight in each case in the presence of a catalyst and, if appropriate, a solvent.
摘要翻译：本发明涉及一种制备乙烯胺混合物的方法，该方法包括在催化剂存在下，将包含至少两种α-氨基腈的氨基腈混合物氢化为至少5重量％，如果适当的溶剂。

35. 发明授权

US07674929B2 Method for the production of β-aminopropionic acid derivatives 有权
标题翻译：生产氨基丙酸衍生物的方法
公开(公告)号：US07674929B2
公开(公告)日：2010-03-09
申请号：US12066681
申请日：2006-09-13
申请人： Holger Evers , Johann-Peter Melder , Thomas Preiss , Harald Meissner
发明人： Holger Evers , Johann-Peter Melder , Thomas Preiss , Harald Meissner
IPC分类号： C07C255/00
CPC分类号： C07C253/30 , C07B43/04 , C07C227/06 , C07C2601/14 , C07C255/24
摘要： The invention relates to a process for preparing β-aminopropionic acid derivatives by reacting a primary or secondary amine with an acrylic acid derivative, wherein comprises (i) a first primary or secondary amine is provided as an amine of value and reacted with the acrylic acid derivative, to obtain a reaction mixture comprising a first β-aminopropionic acid derivative as a product of value and additionally unconverted acrylic acid derivative, (ii) the unconverted acrylic acid derivative present in the reaction mixture is reacted with a second secondary amine as a scavenger amine virtually fully to give a second β-aminopropionic acid derivative to obtain a reaction mixture comprising the first β-aminopropionic acid derivative as a product of value, the second β-aminopropionic acid derivative and unconverted secondary amine.
摘要翻译：本发明涉及一种通过使伯胺或仲胺与丙烯酸衍生物反应来制备β-氨基丙酸衍生物的方法，其中包括（i）第一伯胺或仲胺作为有价值的胺并与丙烯酸反应酸衍生物，得到包含第一和次氨基丙酸衍生物作为值的产物和另外未转化的丙烯酸衍生物的反应混合物，（ii）将存在于反应混合物中的未转化的丙烯酸衍生物与第二仲胺反应，一种清除剂胺实际上完全可以得到第二种 - 氨基丙酸衍生物，以获得包含第一种和第二种 - 氨基丙酸衍生物和未转化的仲胺的第一种 - 氨基丙酸衍生物的反应混合物。

36. 发明申请

US20100029976A1 METHOD FOR PRODUCING TETRAETHYLENEPENTAMINE 有权
标题翻译：生产四氯乙烯胺的方法
公开(公告)号：US20100029976A1
公开(公告)日：2010-02-04
申请号：US12529047
申请日：2008-02-27
申请人： Kirsten Dahmen , Alfred Oftring , Randolf Hugo , Thilo Hahn , Katrin Baumann , Johann-Peter Melder
发明人： Kirsten Dahmen , Alfred Oftring , Randolf Hugo , Thilo Hahn , Katrin Baumann , Johann-Peter Melder
IPC分类号： C07C209/44 , C07C255/25 , C07C253/00
CPC分类号： C07C209/48 , C07C255/25 , C07C211/14
摘要： The invention relates to a process for preparing tetraethylenepentamine (TEPA) by hydrogenation of diethylenetriaminediacetonitrile (DETDN) over a catalyst. If appropriate, DETDN can also be present as a constituent of an amino nitrile mixture which additionally comprises diethylenetriaminemonoacetonitrile (DETMN).
摘要翻译：本发明涉及通过在催化剂上氢化二亚乙基三胺二乙酸（DETDN）制备四亚乙基五胺（TEPA）的方法。如果合适，DETDN也可以作为另外包含二亚乙基三氨基乙腈（DETMN）的氨基腈混合物的组分存在。

37. 发明申请

US20090275781A1 METHOD FOR PRODUCING AN AMINE 失效
标题翻译：生产氨的方法
公开(公告)号：US20090275781A1
公开(公告)日：2009-11-05
申请号：US12373793
申请日：2007-07-04
申请人： Petr Kubanek , Bram Willem Hoffer , Ekkehard Schwab , Johann-Peter Melder , Holger Evers , Till Gerlach
发明人： Petr Kubanek , Bram Willem Hoffer , Ekkehard Schwab , Johann-Peter Melder , Holger Evers , Till Gerlach
IPC分类号： C07C209/68 , B01J23/28
CPC分类号： C07C213/02 , B01J23/002 , B01J23/885 , B01J37/0009 , B01J37/0045 , B01J37/03 , B01J37/18 , B01J2523/00 , C07C209/16 , C07C209/26 , C07D295/023 , C07C211/10 , C07C215/08 , C07C217/08
摘要： Processes comprising: (i) providing a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones and mixtures thereof, and (ii) reacting the reactant with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a catalyst comprising a zirconium dioxide- and nickel-containing catalytically active composition, to form an amine; wherein the catalytically active composition, prior to reduction with hydrogen, comprises oxygen compounds of zirconium, copper, nickel and cobalt, and one or more oxygen compounds of molybdenum in an amount of 5.5 to 12% by weight, calculated as MoO3.
摘要翻译：方法包括：（i）提供选自伯醇，仲醇，醛，酮及其混合物的反应物，和（ii）使反应物与氢和氮化合物反应，所述氮和化合物选自氨，伯胺，仲胺及其混合物，在含有二氧化锆和镍的催化活性组合物的催化剂存在下，形成胺; 其中所述催化活性组合物在用氢还原之前包括锆，铜，镍和钴的氧化合物，以及以MoO 3计算的一种或多种重量百分比为5.5至12％的钼的氧化合物。

38. 发明授权

US07501047B2 Method for purifying caprolactam 失效
标题翻译：己内酰胺纯化方法
公开(公告)号：US07501047B2
公开(公告)日：2009-03-10
申请号：US10534822
申请日：2003-11-11
申请人： Hermann Luyken , Andreas Ansmann , Christoph Benisch , Peter Baβler , Rolf-Hartmuth Fischer , Stefan Maixner , Johann-Peter Melder
发明人： Hermann Luyken , Andreas Ansmann , Christoph Benisch , Peter Baβler , Rolf-Hartmuth Fischer , Stefan Maixner , Johann-Peter Melder
IPC分类号： B01D3/14 , B01D3/34 , C07D201/08 , C07D201/16
CPC分类号： C07D201/16
摘要： The disclosure relates to a process for purifying crude caprolactam. The process involves converting a first mixture of 6-amino capronitrile and water to a second mixture of caprolactam ammonia, water, high boilers and low boilers using a catalyst. The ammonia is removed from the second mixture to obtain a third mixture. Water is removed from the third mixture to give crude caprolactam, high boiler and low boilers. Purified caprolactam is then obtained by a series of distillation steps.
摘要翻译：本公开涉及纯化己内酰胺的方法。该方法包括使用催化剂将6-氨基己腈和水的第一混合物转化成己内酰胺氨，水，高锅炉和低锅炉的第二混合物。从第二混合物中除去氨以获得第三混合物。从第三混合物中除去水，得到粗己内酰胺，高锅炉和低锅炉。然后通过一系列蒸馏步骤获得纯化的己内酰胺。

39. 发明申请

US20080255360A1 Process for Producing Ethyleneamines 有权
标题翻译：生产乙烯胺的方法
公开(公告)号：US20080255360A1
公开(公告)日：2008-10-16
申请号：US12088715
申请日：2006-09-25
申请人： Gunther van Cauwenberge , Johann-Peter Melder , Holger Evers , Till Gerlach , Frank Kiesslich , Ekkehard Schwab , Bram Willem Hoffer
发明人： Gunther van Cauwenberge , Johann-Peter Melder , Holger Evers , Till Gerlach , Frank Kiesslich , Ekkehard Schwab , Bram Willem Hoffer
IPC分类号： C07C209/14 , C07D295/023 , C07D241/04
CPC分类号： C07C209/16 , B01J21/04 , B01J23/755 , B01J35/023 , B01J37/0201 , B01J37/18 , C07D295/02 , C07D295/13 , C07C211/10 , C07C211/14
摘要： Processes comprising: providing a starting material comprising monoethanolamine; and reacting the starting material with ammonia in the presence of a heterogeneous transition metal catalyst to form a reaction product comprising one or more ethylene amines; wherein the catalyst comprises a catalytically active composition, which prior to treatment with hydrogen, comprises a mixture of oxygen-containing compounds of aluminum, copper, nickel and cobalt; and wherein the catalyst is present as one or more shaped catalyst particles selected from spheres, extrudates, pellets and other geometries, wherein the sphere or extrudate has a diameter of
摘要翻译：方法包括：提供包含单乙醇胺的原料; 并在非均相过渡金属催化剂的存在下使原料与氨反应形成包含一种或多种亚乙基胺的反应产物; 其中所述催化剂包含催化活性组合物，其在用氢处理之前包括铝，铜，镍和钴的含氧化合物的混合物; 并且其中所述催化剂作为选自球体，挤出物，丸粒和其它几何形状的一种或多种成型催化剂颗粒存在，其中所述球体或挤出物的直径<3mm，所述颗粒具有<3mm的高度，而另一种几何形状具有等效直径L = 1 / a'<0.70mm，其中a'是每单位体积的外表面积（mm×s×2 / 由 ${定义的}^{3 MI> a =A/ MSUB>Vp其中A < SUB>是催化剂颗粒的外表面积（mm 2），V p是催化剂颗粒的体积（mm 3） 3＆lt; 3＆gt; 3＆lt; 3＆gt;）。}$

40. 发明授权

US07435855B2 Process for the continuous synthesis of methylamines 有权
标题翻译：连续合成甲胺的方法
公开(公告)号：US07435855B2
公开(公告)日：2008-10-14
申请号：US11629801
申请日：2005-06-16
申请人： Marco Bosch , Jan Kurt Eberhardt , Roderich Röttger , Thomas Krug , Johann-Peter Melder
发明人： Marco Bosch , Jan Kurt Eberhardt , Roderich Röttger , Thomas Krug , Johann-Peter Melder
IPC分类号： C07C209/14
CPC分类号： C07C209/16 , C07C211/04
摘要： Process for the continuous synthesis of methylamines by reaction of methanol and/or dimethyl ether with ammonia in the presence of a heterogeneous catalyst, wherein the catalyst used is a shaped body which comprises a microporous material and at least one organosilicon compound as binder and can be produced by a process comprising the steps (I) preparation of a mixture comprising the microporous material, the binder, a pasting agent and a solvent, (II) mixing and densification of the mixture, (III) shaping of the densified mixture to give a shaped body, (IV) drying of the shaped body and (V) calcination of the dried shaped body.
摘要翻译：在多相催化剂存在下，通过甲醇和/或二甲醚与氨的反应连续合成甲胺的方法，其中使用的催化剂是成形体，其包含微孔材料和至少一种有机硅化合物作为粘合剂，并且可以是通过包括步骤（I）制备包含微孔材料，粘合剂，粘贴剂和溶剂的混合物的方法制备的方法制备，（II）混合和混合物的致密化，（III）使致密混合物成形，得到（IV）成型体的干燥和（V）干燥成型体的煅烧。

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