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    • 32. 发明授权
    • Unsaturated polyesters
    • 不饱和聚酯
    • US5407772A
    • 1995-04-18
    • US159176
    • 1993-11-30
    • Robert D. BayleyCarol A. FoxThomas R. HoffendHadi K. MahabadiEnno E. AgurGuerino SacripanteMichael S. Hawkins
    • Robert D. BayleyCarol A. FoxThomas R. HoffendHadi K. MahabadiEnno E. AgurGuerino SacripanteMichael S. Hawkins
    • C08G63/547G03G9/087G03G9/00
    • C08G63/547G03G9/08755G03G9/08791G03G9/08793G03G9/08797
    • Unsaturated linear polymers have repeating units of a reaction product of a first monomer, a second monomer, a third monomer and optionally a fourth monomer. The linear polymers have a glass transition temperature ranging from about 52.degree. C. to about 61.degree. C. The first monomer should have a weight average molecular weight less than 200. The second monomer may be a dicarboxylic acid or diester which is different than the third monomer. A concentration of second residues of the polymer, derived from the second monomer, ranges from about 3 wt. % to about 15 wt. %, based on the total weight of the polymer. The third monomer is an aromatic dicarboxylic acid or an ester thereof. In the polymer, a concentration of third residues, derived from the third monomer, ranges from about 40 wt. % to about 55 wt. %, based on the total weight of the polymer. The fourth monomer is a diol having a higher molecular weight than the first monomer. In a process for preparing the inventive polymer, the first, second, third monomer (and optionally a fourth monomer) and/or a catalyst undergo transesterification to form the unsaturated, linear polymer.
    • 不饱和线性聚合物具有第一单体,第二单体,第三单体和任选的第四单体的反应产物的重复单元。 线性聚合物的玻璃化转变温度为约52℃至约61℃。第一单体应具有小于200的重均分子量。第二单体可以是二羧酸或二酯,其不同于 第三单体。 衍生自第二单体的聚合物的第二残余物的浓度范围为约3wt。 %至约15wt。 %,基于聚合物的总重量。 第三单体是芳族二羧酸或其酯。 在聚合物中,衍生自第三单体的第三残基的浓度范围为约40wt。 %至约55wt。 %,基于聚合物的总重量。 第四单体是分子量高于第一单体的二醇。 在制备本发明聚合物的方法中,第一,第二,第三单体(和任选的第四单体)和/或催化剂进行酯交换以形成不饱和的线性聚合物。