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31. 发明授权

US07235624B2 Charge dissipation modifiers for olefinic interpolymer compositions 有权
标题翻译：烯烃互聚物组合物的电荷耗散改性剂
公开(公告)号：US07235624B2
公开(公告)日：2007-06-26
申请号：US11508710
申请日：2006-08-23
申请人： Carlos Gilberto Ortiz , Peter Anthony Fox , Raymond L. Laakso, Jr. , Gary R. Marchand , Steven R. Oriani , Walter Werner Schmiegel , Michael K. Laughner , Deepak R. Parikh
发明人： Carlos Gilberto Ortiz , Peter Anthony Fox , Raymond L. Laakso, Jr. , Gary R. Marchand , Steven R. Oriani , Walter Werner Schmiegel , Michael K. Laughner , Deepak R. Parikh
IPC分类号： C08F6/00 , C08K5/17 , H01B7/00
CPC分类号： C08F297/02 , C08F210/18 , C08F297/08 , C08K3/32 , C08K5/17 , C08K5/18 , C08K5/3432 , C08K5/52 , C08K5/55 , C08K2003/329 , C08F210/06 , C08F232/00 , C08F2500/25 , C08F2500/17
摘要： Olefinic interpolymer compositions comprising the olefinic interpolymer, residuals from a transition metal catalyst and boron containing activator package, and a charge dissipation modifier and methods for making them. The compositions have dissipation factors that are at least 50% less than the corresponding olefinic interpolymer compositions which have not been treated with charge dissipation modifiers. The compositions are useful in wire and cable applications.
摘要翻译：包含烯烃互聚物的烯烃互聚物组合物，过渡金属催化剂的残余物和含硼活化剂包，以及电荷耗散改性剂及其制备方法。该组合物的损耗因子比未用电荷耗散改性剂处理的相应的烯烃互聚物组合物少至少50％。组合物可用于电线和电缆应用。

32. 发明申请

US20160215129A1 OPTICAL FIBER CABLE COMPONENTS 有权
标题翻译：光纤电缆组件
公开(公告)号：US20160215129A1
公开(公告)日：2016-07-28
申请号：US14915354
申请日：2013-10-18
申请人： Mohamed ESSEGHIR , Gangwei SUN , Bharat I. CHAUDHARY , Chester J. KMIEC , Gary R. MARCHAND , Yushan HU , DOW GLOBAL TECHNOLOGIES LLC
发明人： Mohamed Esseghir , Gangwei Sun , Bharat I. Chaudhary , Chester J. Kmiec , Gary R. Marchand , Yushan Hu
IPC分类号： C08L23/12 , G02B6/44 , C08L53/00
CPC分类号： C08L23/12 , C08L53/00 , C08L2201/08 , C08L2203/12 , C08L2205/06 , C08L2205/24 , G02B6/4407 , G02B6/4429 , G02B6/443 , G02B6/4479 , C08L23/0815
摘要： Optical cable components fabricated from an extrudable polymeric blend of crystalline polypropylene modified with one or more impact-modifying polymers. The impact-modifying polymers are selected from an olefin multi-block interpolymer, an olefin block composite, and combinations thereof. Optionally, the polymeric blend can further comprise an elastomer other than the impact-modifying polymer. The polymeric blend may also contain one or more additives. The optical fiber cable components can be selected from buffer tubes, core tubes, and slotted core tubes.
摘要翻译：由用一种或多种冲击改性聚合物改性的结晶聚丙烯的可挤出聚合物共混物制成的光缆部件。冲击改性聚合物选自烯烃多嵌段互聚物，烯烃嵌段复合材料及其组合。任选地，聚合共混物还可以包含不同于冲击改性聚合物的弹性体。聚合物共混物还可以含有一种或多种添加剂。光纤电缆组件可以从缓冲管，芯管和开槽芯管中选择。

33. 发明授权

US09309396B2 Thermoplastic vulcanizate composition, method of producing the same, and articles made therefrom 有权
标题翻译：热塑性硫化橡胶组合物，其制造方法和由其制成的制品
公开(公告)号：US09309396B2
公开(公告)日：2016-04-12
申请号：US13991531
申请日：2010-12-30
申请人： Yabin Sun , Morgan M. Hughes , Xiangyang Tai , Arnis U. Paeglis , Gary R. Marchand
发明人： Yabin Sun , Morgan M. Hughes , Xiangyang Tai , Arnis U. Paeglis , Gary R. Marchand
IPC分类号： C08L23/16 , C08L23/26 , C08K5/00
CPC分类号： C08L23/26 , C08K5/0025 , C08L23/16 , C08L2205/02 , C08L2205/03 , C08L2205/22 , C08L2312/00 , C08L23/142 , C08L23/12
摘要： A thermoplastic vulcanizate composition comprising from 5 wt % to 95 wt %, based on the total weight of the thermoplastic vulcanizate composition, of a first component comprising a first propylene-based polymer selected from the group consisting of (i) propylene/α-olefin copolymers comprising from 1 to 20 wt % α-olefin and characterized by a g′ ratio of less than 1, measured at interpolymer number average molecular weight (Mn), an MFR (2.16 kg @ 230° C.) greater than or equal to 0.01, a density greater than or equal to 0.850 g/cc, and a molecular weight distribution, Mw/Mn, less than or equal to 3.5, and (ii) combinations thereof; and from 5 wt % to 95 wt %, based on the total weight of the thermoplastic vulcanizate composition, of a second component selected from the group consisting of curable or vulcanizable rubbers, having a density from 0.85 to 0.88 g/cc, I2 from 0.001 to 5 g/10 min, and a Mooney viscosity from 5 to 400, and combinations thereof; wherein at least one of the rubbers is vulcanizable; wherein the thermoplastic vulcanizate composition has a tensile strength at break of greater than or equal to 8 MPa and tear strength at 23° C. of at least 190 lb-f/in. is provided. Methods of making the composition and articles made from the composition are also provided.
摘要翻译：一种热塑性硫化胶组合物，其包含基于热塑性硫化橡胶组合物总重量的5重量％至95重量％的第一组分，其包含第一丙烯类聚合物，其选自（i）丙烯/α-烯烃共聚物，其包含1至20重量％的α-烯烃，并且以共聚体数均分子量（Mn），MFR（2.16kg @ 230℃）测量的Ag'比小于1，大于或等于0.01 ，密度大于或等于0.850g / cc，分子量分布Mw / Mn小于或等于3.5，和（ii）它们的组合; 和5重量％至95重量％，基于热塑性硫化橡胶组合物的总重量，选自可固化或可硫化橡胶的第二组分，其密度为0.85至0.88g / cc，I2为0.001 至5g / 10min，门尼粘度为5至400，及其组合; 其中所述橡胶中的至少一种是可硫化的; 其中所述热塑性硫化橡胶组合物的断裂拉伸强度大于或等于8MPa，并且在23℃下的撕裂强度为至少190lb-f / in。被提供。还提供了由组合物制备组合物和制品的方法。

34. 发明申请

US20130324658A1 Thermoplastic Vulcanizate Composition, Method of Producing the Same, and Articles Made Therefrom 有权
标题翻译：热塑性硫化橡胶组合物，其制造方法及其制品
公开(公告)号：US20130324658A1
公开(公告)日：2013-12-05
申请号：US13991531
申请日：2010-12-30
申请人： Yabin Sun , Morgan M. Hughes , Xiangyang Tai , Arnis U. Paeglis , Gary R. Marchand
发明人： Yabin Sun , Morgan M. Hughes , Xiangyang Tai , Arnis U. Paeglis , Gary R. Marchand
IPC分类号： C08L23/26
CPC分类号： C08L23/26 , C08K5/0025 , C08L23/16 , C08L2205/02 , C08L2205/03 , C08L2205/22 , C08L2312/00 , C08L23/142 , C08L23/12
摘要： A thermoplastic vulcanizate composition comprising from 5 wt % to 95 wt %, based on the total weight of the thermoplastic vulcanizate composition, of a first component comprising a first propylene-based polymer selected from the group consisting of (i) propylene/α-olefin copolymers comprising from 1 to 20 wt % α-olefin and characterized by a g′ ratio of less than 1, measured at interpolymer number average molecular weight (Mn), an MFR (2.16 kg @ 230° C.) greater than or equal to 0.01, a density greater than or equal to 0.850 g/cc, and a molecular weight distribution, Mw/Mn, less than or equal to 3.5, and (ii) combinations thereof; and from 5 wt % to 95 wt %, based on the total weight of the thermoplastic vulcanizate composition, of a second component selected from the group consisting of curable or vulcanizable rubbers, having a density from 0.85 to 0.88 g/cc, I2 from 0.001 to 5 g/10 min, and a Mooney viscosity from 5 to 400, and combinations thereof; wherein at least one of the rubbers is vulcanizable; wherein the thermoplastic vulcanizate composition has a tensile strength at break of greater than or equal to 8 MPa and tear strength at 23° C. of at least 190 lb-f/in. is provided. Methods of making the composition and articles made from the composition are also provided.
摘要翻译：一种热塑性硫化橡胶组合物，其包含基于热塑性硫化橡胶组合物总重量的5重量％至95重量％的第一组分，其包含第一丙烯类聚合物，其选自（i）丙烯/α-烯烃共聚物，其包含1至20重量％的α-烯烃，并且以共聚体数均分子量（Mn），MFR（2.16kg @ 230℃）测量的Ag'比小于1，大于或等于0.01 ，密度大于或等于0.850g / cc，分子量分布Mw / Mn小于或等于3.5，和（ii）它们的组合; 和5重量％至95重量％，基于热塑性硫化橡胶组合物的总重量，选自可固化或可硫化橡胶的第二组分，其密度为0.85至0.88g / cc，I2为0.001 至5g / 10min，门尼粘度为5至400，及其组合; 其中所述橡胶中的至少一种是可硫化的; 其中所述热塑性硫化橡胶组合物的断裂拉伸强度大于或等于8MPa，并且在23℃下的撕裂强度为至少190lb-f / in。被提供。还提供了由组合物制备组合物和制品的方法。

35. 发明授权

US08273826B2 Impact modification of thermoplastics with ethylene/α-olefin interpolymers 有权
标题翻译：热塑性塑料与乙烯/α-烯烃互聚物的冲击改性
公开(公告)号：US08273826B2
公开(公告)日：2012-09-25
申请号：US12732950
申请日：2010-03-26
申请人： Kim L. Walton , Gary R. Marchand , Shrikant Dhodapkar , Mridula Kapur , Shaofu Wu
发明人： Kim L. Walton , Gary R. Marchand , Shrikant Dhodapkar , Mridula Kapur , Shaofu Wu
IPC分类号： C08L53/00 , C08L83/00 , C08L23/00 , C08L23/04 , C08F8/00
CPC分类号： C08L67/00 , C08L23/06 , C08L23/0815 , C08L23/10 , C08L51/06 , C08L69/00 , C08L101/00 , C08L2314/06 , C08L2666/06
摘要： Impact modified compositions having good impact performance can be made from a thermoplastic (e.g., a polyolefin such as polypropylene or HDPE) and a multi-block ethylene/α-olefin interpolymer. The compositions are easily molded and often have particular utility in making, for example, automotive facia, parts and other household articles.
摘要翻译：具有良好冲击性能的冲击改性组合物可以由热塑性塑料（例如，聚烯烃如聚丙烯或HDPE）和多嵌段乙烯/α-烯烃互聚物制成。组合物易于模塑，并且通常在制备例如汽车面漆，部件和其它家用制品中具有特别的用途。

36. 发明申请

US20110060103A1 BUTENE/A-OLEFIN BLOCK INTERPOLYMERS 有权
标题翻译： BUTENE / A-OLEFIN BLOCK INTERPOLYMERS
公开(公告)号：US20110060103A1
公开(公告)日：2011-03-10
申请号：US12864433
申请日：2009-01-30
申请人： Gary R. Marchand , Yunwa W. Cheung , Benjamin C. Poon , Jeffrey D. Weinhold , Kim L. Walton , Pankaj Gupta , Colin Lipishan , Phillip D. Hustad , Roger L. Kuhlman , Edmund M. Carnahan , Eddy I. Garcia-Meitin , Patricia L. Roberts
发明人： Gary R. Marchand , Yunwa W. Cheung , Benjamin C. Poon , Jeffrey D. Weinhold , Kim L. Walton , Pankaj Gupta , Colin Lipishan , Phillip D. Hustad , Roger L. Kuhlman , Edmund M. Carnahan , Eddy I. Garcia-Meitin , Patricia L. Roberts
IPC分类号： C08F2/38 , C08L53/00 , C08F293/00
CPC分类号： C08F297/08
摘要： Embodiments of the invention provide a class of mesophase separated butene/α-olefin block interpolymers with controlled block sequences. The butene/α-olefin interpolymers are characterized by an average block index, ABI, which is greater than zero and up to about 1.0 and a molecular weight distribution, Mw/Mn, greater than about 1.4. Preferably, the block index is from about 0.2 to about 1. In addition or alternatively, the block butene/α-olefin interpolymer is characterized by having at least one fraction obtained by Temperature Rising Elution Fractionation (TREF'), wherein the fraction has a block index greater than about 0.3 and up to about 1.0 and the butene/α-olefin interpolymer has a molecular weight distribution, Mw/Mn, greater than about 1.4.
摘要翻译：本发明的实施方案提供了一类具有受控块序列的中间相分离的丁烯/α-烯烃嵌段互聚物。丁烯/α-烯烃互聚物的特征在于平均嵌段指数ABI，其大于零且高达约1.0，分子量分布Mw / Mn大于约1.4。优选地，嵌段指数为约0.2至约1.另外或替代地，嵌段丁烯/α-烯烃互聚物的特征在于具有通过升温洗脱分级（TREF'）获得的至少一个级分，其中所述级分具有嵌段指数大于约0.3且至多约1.0，并且丁烯/α-烯烃互聚物的分子量分布Mw / Mn大于约1.4。

37. 发明申请

US20110054121A1 BUTENE/ALPHA-OLEFIN BLOCK INTERPOLYMERS 有权
标题翻译： BUTENE / ALPHA-OLEFIN BLOCK INTERPOLYMERS
公开(公告)号：US20110054121A1
公开(公告)日：2011-03-03
申请号：US12864427
申请日：2009-01-30
申请人： Gary R. Marchand , Yunwa W. Cheung , Benjamin C. Poon , Jeffrey D. Weinhold , Kim L. Walton , Pankaj Gupta , Colin Lipishan , Philip D. Hustad , Roger L. Kuhlman , Edmund M. Carnahan , Eddy I. Garcia-Metin , Patricia L. Robert
发明人： Gary R. Marchand , Yunwa W. Cheung , Benjamin C. Poon , Jeffrey D. Weinhold , Kim L. Walton , Pankaj Gupta , Colin Lipishan , Philip D. Hustad , Roger L. Kuhlman , Edmund M. Carnahan , Eddy I. Garcia-Metin , Patricia L. Robert
IPC分类号： C08L53/00 , C08F293/00
CPC分类号： C08F297/08
摘要： Embodiments of the invention provide a class of butene/α-olefin block interpolymers. The butene/α-olefin inter-polymers are characterized by an average block index, ABI, which is greater than zero and up to about 1.0 and a molecular weight distribution, Mw/Mn, greater than about 1.3. Preferably, the block index is from about 0.2 to about 1. In addition or alternatively, the block butene/α-olefin interpolymer is characterized by having at least one fraction obtained by Temperature Rising Elution Fractionation (‘TREF’), wherein the fraction has a block index greater than about 0.3 and up to about 1.0 and the butene/α-olefin interpolymer has a molecular weight distribution, Mw/Mn, greater than about 1.4.
摘要翻译：本发明的实施方案提供了一类丁烯/α-烯烃嵌段互聚物。丁烯/α-烯烃聚合物的特征在于平均嵌段指数ABI，其大于零且高达约1.0，分子量分布Mw / Mn大于约1.3。优选地，嵌段指数为约0.2至约1.另外或替代地，嵌段丁烯/α-烯烃互聚物的特征在于具有通过升温洗脱分级（'TREF'）获得的至少一个级分，其中级分具有大于约0.3且高达约1.0的嵌段指数，丁烯/α-烯烃互聚物的分子量分布Mw / Mn大于约1.4。

38. 发明授权

US07745543B2 Cure system composition and a method for curing chlorinated elastomer compositions 有权
标题翻译：固化体系组成和固化氯化弹性体组合物的方法
公开(公告)号：US07745543B2
公开(公告)日：2010-06-29
申请号：US11359307
申请日：2006-02-22
申请人： Raymond L. Laakso, Jr. , Gary R. Marchand
发明人： Raymond L. Laakso, Jr. , Gary R. Marchand
IPC分类号： C08C19/20 , C08C19/22 , C08F8/30 , C08F8/34 , C08K5/47 , C08K5/19 , C08J3/24
CPC分类号： C08K5/0025 , C08K3/011 , C08K5/19 , C08K5/3415 , C08L11/00 , C08L23/286
摘要： The instant invention is an improved cure system composition and a method for curing chlorinated elastomer compositions. The cure system composition includes a polymercapto crosslinking agent; an inorganic base; and an onium salt. The onium salt has a formula selected from the group consisting of wherein Z is a nitrogen or phosphorous atom, R1 to R4 are independently alkyl or aryl groups containing between 2 and 8 carbon atoms, and the total number of carbon atoms on R1-R4 is between 10 and 14; wherein R5 and R6 are alkyl groups containing between 1 and 8 carbon atoms, and the total number of carbon atoms on R5-R6 being between 5 and 9; and wherein X is an anion. The method for curing a chlorinated elastomer composition according to instant invention includes the following steps: (1) providing a chlorinated elastomer composition; (2) providing a cure system composition as described above; (3) contacting said chlorinated elastomer composition with said cure system composition; and (4) thereby curing said chlorinated elastomer composition.
摘要翻译：本发明是改进的固化体系组合物和用于固化氯化弹性体组合物的方法。固化体系组成包括聚合物巯基交联剂; 无机碱; 和盐盐。鎓盐具有选自其中Z为氮或磷原子的式，R 1至R 4独立地为含有2至8个碳原子的烷基或芳基，R1-R4上的总碳原子数为 10至14岁; 其中R5和R6是含有1至8个碳原子的烷基，R5-R6上的总碳原子数在5和9之间; 并且其中X是阴离子。固化本发明的氯化弹性体组合物的方法包括以下步骤：（1）提供氯化弹性体组合物; （2）提供如上所述的固化体系组合物; （3）使所述氯化弹性体组合物与所述固化体系组合物接触; 和（4）由此固化所述氯化弹性体组合物。

39. 发明申请

US20090326143A1 CURE SYSTEM FOR HALOGENATED ELASTOMER COMPOSITIONS, A CURABLE HALOGENATED ELASTOMER COMPOSITION, AND A METHOD FOR CURING HALOGENATED ELASTOMER COMPOSITIONS 有权
标题翻译：固化的弹性体组合物的固化体系，可固化的氢化弹性体组合物和用于固化氢化的弹性体组合物的方法
公开(公告)号：US20090326143A1
公开(公告)日：2009-12-31
申请号：US12438981
申请日：2007-08-21
申请人： Raymond L. Laakso, JR. , Gary R. Marchand
发明人： Raymond L. Laakso, JR. , Gary R. Marchand
IPC分类号： C08L27/22 , C08F114/02 , C09K3/00
CPC分类号： C08K5/0025 , C08K5/098 , C08K5/47 , C08L23/286 , C08L81/00 , C08L2312/00 , C08L11/00 , C08L2666/22
摘要： The instant invention is a cure system for halogenated elastomer compositions, a curable halogenated elastomer composition, and a method for curing a halogenated elastomer composition. The cure system for halogenated elastomer compositions includes a polymercapto crosslinking agent, an inorganic base, and a hydrated salt selected from the group consisting of lithium citrate, trilithium citrate pentahydrate, trilithium citrate tetrahydrate, and monolithium dihydrogen citrate monohydrate. The curable halogenated elastomer composition includes a chlorinated elastomer, and a cure system including a polymercapto crosslinking agent, an inorganic base, and a hydrated salt selected from the group consisting of lithium citrate, trilithium citrate pentahydrate, trilithium citrate tetrahydrate, and monolithium dihydrogen citrate monohydrate. Furthermore, the method for curing a halogenated elastomer composition includes the following steps: (1) providing a chlorinated elastomer composition; (2) providing a cure system composition including a polymercapto crosslinking agent, an inorganic base, and a hydrated salt selected from the group consisting of lithium citrate, trilithium citrate pentahydrate, trilithium citrate tetrahydrate, and monolithium dihydrogen citrate monohydrate; (3) uniformly blending the cure system into the chlorinated elastomer composition; (4) thereby forming a curable chlorinated elastomer composition; (5) subjecting the curable chlorinated elastomer composition to heat or heat and pressure; and (6) thereby curing the curable chlorinated elastomer composition.
摘要翻译：本发明是用于卤化弹性体组合物，可固化的卤化弹性体组合物和用于固化卤化弹性体组合物的方法的固化体系。卤化弹性体组合物的固化体系包括聚合物巯基交联剂，无机碱和选自柠檬酸锂，柠檬酸三柠檬酸五水合物，柠檬酸三柠檬酸四水合物和单二水合柠檬酸二氢柠檬酸一水合物的水合盐。可固化卤化弹性体组合物包括氯化弹性体，以及包含聚合物巯基交联剂，无机碱和选自柠檬酸锂，柠檬酸三柠檬酸五水合物，柠檬酸三柠檬酸四水合物和柠檬酸二氢柠檬酸锂一水合物的水合盐的固化体系。此外，卤化弹性体组合物的固化方法包括以下步骤：（1）提供氯化弹性体组合物; （2）提供包含聚合物巯基交联剂，无机碱和选自柠檬酸锂，柠檬酸三柠檬酸五水合物，柠檬酸三柠檬酸四水合物和柠檬酸二氢锂一水合物的水合盐的固化体系组合物; （3）将固化体系均匀混合到氯化弹性体组合物中; （4），从而形成可固化的氯化弹性体组合物; （5）对可固化的氯化弹性体组合物进行加热或加热和加压; 和（6）从而固化可固化的氯化弹性体组合物。

40. 发明申请

US20090076225A1 VULCANIZABLE HALOGENATED ELASTOMER COMPOSITIONS 有权
标题翻译：可再生的氢化弹性体组合物
公开(公告)号：US20090076225A1
公开(公告)日：2009-03-19
申请号：US11719222
申请日：2005-12-21
申请人： Raymond L. Laakso, JR. , Gary R. Marchand , Sandra Watson
发明人： Raymond L. Laakso, JR. , Gary R. Marchand , Sandra Watson
IPC分类号： C08F214/22 , C08F136/18 , C08F24/00 , C08F214/28 , C08F28/02
CPC分类号： C08K5/0091 , C08K5/0025 , C08K5/17 , C08L11/00 , C08L27/12
摘要： The invention provides compositions comprising nitrogen containing chelating agents, which can be used to reduce the effects of zinc contamination on the vulcanization rates of polymercapto based cure systems for halogenated elastomers. Such chelating agents are effective at eliminating vulcanization rate inconsistencies due to zinc contamination, without inducing negative changes to the vulcanization reaction or the subsequent physical properties of the halogenated elastomer vulcanizate. The invention also provides methods of curing a halogenated elastomer using the inventive compositions, and for articles prepared from the same.
摘要翻译：本发明提供了包含含氮螯合剂的组合物，其可用于降低锌污染对基于聚合物巯基的卤化弹性体固化体系的硫化速率的影响。这种螯合剂对于消除由于锌污染引起的硫化速率不一致而不会引起硫化反应的负面变化或卤化弹性体硫化橡胶的后续物理性能是有效的。本发明还提供了使用本发明组合物固化卤化弹性体的方法以及由其制备的制品。

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