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31. 发明授权

US07223357B2 Composition containing a polymer or copolymer of a 3,4-dialkoxythiophene and non-aqueous solvent 有权
标题翻译：含有3,4-二烷氧基噻吩和非水溶剂的聚合物或共聚物的组合物
公开(公告)号：US07223357B2
公开(公告)日：2007-05-29
申请号：US11180051
申请日：2005-07-12
申请人： Jean-Pierre Tahon , Roger Van den Bogaert , Bert Groenendaal , Frank Louwet
发明人： Jean-Pierre Tahon , Roger Van den Bogaert , Bert Groenendaal , Frank Louwet
IPC分类号： H01B1/12
CPC分类号： H01B1/128 , C08J3/09 , C08J2365/00 , C08L65/00 , C09D5/24 , C09D11/033 , C09D11/36 , C09D11/52 , C09D165/00 , Y10T428/2809
摘要： A method for preparing a composition containing between 0.08 and 3.0% by weight of polymer or copolymer of a 3,4-dialkoxythiophene in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, a polyanion and at least one non-aqueous solvent from a dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion in water which is prepared in the substantial absence of oxygen, comprising in the following order the steps of: i) mixing at least one of the non-aqueous solvents with the aqueous dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion; and ii) evaporating water from the mixture prepared in step i) until the content of water therein is reduced by at least 65% by weight; a printing ink, printing paste or coating composition, capable of yielding layers with enhanced conductivity at a given transparency, prepared according to the above-described method; a coating process with the coating composition thereby producing a layer with enhanced conductivity at a given transparency; and a printing process with the printing ink or paste thereby producing a layer with enhanced conductivity at a given transparency.
摘要翻译：一种制备含有0.08至3.0重量％的3,4-二烷氧基噻吩的聚合物或共聚物的组合物的方法，其中两个烷氧基可以相同或不同，或一起代表任选取代的氧 - 亚烷基 - 氧桥，聚阴离子和至少一种非水溶剂，其由（3,4-二烷氧基噻吩）的聚合物或共聚物和聚阴离子在水中的分散体组成，其在基本上不存在氧的情况下制备，包括以下步骤： i）将至少一种非水溶剂与（3,4-二烷氧基噻吩）和聚阴离子的聚合物或共聚物的水分散体混合; 和ii）从步骤i）中制备的混合物蒸发水，直到其中的水含量降低至少65重量％; 印刷油墨，印刷浆料或涂料组合物，其能够产生根据上述方法制备的在给定透明度下具有增强的导电性的层; 所述涂料组合物由此在给定的透明度下产生具有增强的导电性的层; 以及具有印刷油墨或糊料的印刷方法，从而在给定的透明度下产生具有增强的导电性的层。

32. 发明授权

US07147936B2 Layer configuration with improved stability to sunlight exposure 有权
标题翻译：层状结构具有改善的阳光照射的稳定性
公开(公告)号：US07147936B2
公开(公告)日：2006-12-12
申请号：US10642933
申请日：2003-08-18
申请人： Frank Louwet , Geert Van Dyck , Johan Loccufier , Bert Groenendaal , Hieronymus Andriessen
发明人： Frank Louwet , Geert Van Dyck , Johan Loccufier , Bert Groenendaal , Hieronymus Andriessen
IPC分类号： C07D211/021 , H01L51/50
CPC分类号： C08G61/126 , C08L25/08 , C08L2666/06 , C09J165/00 , H01G11/48 , H01G11/56 , Y02E60/13 , Y10S428/917
摘要： A layer configuration on a support, the layer configuration comprising a layer containing a polymer containing optionally substituted 3,4-alkylenedioxythiophene structural units, in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, and a compound selected from the group consisting of polyphosphoric acids, polyphosphoric acid salts, thia-alkanedicarboxylic acids, cyclohexadiene compounds and polyhydroxy-compounds selected from the group consisting of tetronic acid derivatives; ortho-dihydroxybenzene compounds with at least one sulpho group, compounds according to formula (I): HO—CH2—CH(OH)—(CH2)m—S—CH2—C(R1)(R2)—CH2—S—(CH2)n—CH(OH)—CH2—OH (I) wherein R1 and R2 are independently H, —OH or alkyl, and n and m are independently 1, 2 or 3; compounds according to formula (II): HO—(CH2)p—S—CH2—S—(CH2)q—OH (II) wherein p and q are independently 2, 3 or 4; compounds hydrolyzable to tetronic acid derivatives; compounds hydrolyzable to compounds according to formula (I); and sulpho-substituted 2-thia-alkyl-benzimidazole compounds.
摘要翻译：在支撑体上的层构型，该层构型包括含有含有任选取代的3,4-亚烷基二氧噻吩结构单元的聚合物的层，其中两个烷氧基可以相同或不同，或一起代表任选取代的氧基 - 桥，以及选自多磷酸，多磷酸盐，硫杂烷二羧酸，环己二烯化合物和选自由以下组成的组的多羟基化合物的化合物：四氢酸衍生物; 具有至少一个磺酸基的邻二羟基苯化合物，根据式（I）的化合物：<？in-line-formula description =“In-line formula”end =“lead”？> HO-CH 2 -CH（OH） - （CH 2 CH 2）m -S- CH 2 -C（R 1）（R 2） - CH 2 -S-（CH 2）n - （CH 2）n - （CH 2） -CH 2 -O-OH（I）<β在线公式描述=“在线式”末端=“尾”→其中R 1和R 2， SUP> 2独立地是H，-OH或烷基，n和m独立地是1,2或3; 根据式（II）的化合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> HO-（CH 2） > -S-CH 2 -S-（CH 2）2 -O-OH（II）<β在线配方说明书=“ 其中p和q独立地为2,3或4; 可水解成四氢酸衍生物的化合物; 可水解成根据式（I）的化合物的化合物的化合物; 和磺基取代的2-硫代 - 烷基 - 苯并咪唑化合物。

33. 发明申请

US20060100102A1 Toning agents for use in thermographic recording materials 审中-公开
标题翻译：用于热敏记录材料的调色剂
公开(公告)号：US20060100102A1
公开(公告)日：2006-05-11
申请号：US11257440
申请日：2005-10-24
申请人： Carlo Uyttendaele , Frank Louwet , Johan Loccufier
发明人： Carlo Uyttendaele , Frank Louwet , Johan Loccufier
IPC分类号： B41M5/24
CPC分类号： G03C1/4989 , C07C309/88 , C07C311/47 , C07C311/49 , G03C1/49845
摘要： A compound represented by formula (I): wherein X is a carbonyl or sulfonyl group; R2 is an alkyl, alkaryl or aryl group; and R1 is an amino group or an N-alkyl-amino group if Y is a halogen atom, an alkyl group or a hydroxy group; and R1 is a halogen atom, an alkyl group or a hydroxy group if Y is an amino group or an N-alkyl-amino group; and a thermographic recording material comprising a support and a thermosensitive element, the thermosensitive element comprising at least one substantially light-insensitive organic silver salt, at least one organic reducing agent therefor in thermal working relationship therewith, at least one binder and at least one compound represented by formula (I).
摘要翻译：由式（I）表示的化合物：其中X是羰基或磺酰基; R 2是烷基，烷芳基或芳基; 如果Y是卤素原子，烷基或羟基，则R 1是氨基或N-烷基 - 氨基; 如果Y是氨基或N-烷基 - 氨基，则R 1是卤素原子，烷基或羟基; 以及包括支持体和热敏元件的热敏记录材料，所述热敏元件包含至少一种基本上不光敏的有机银盐，至少一种与其热加工关系的有机还原剂，至少一种粘合剂和至少一种化合物由式（I）表示。

34. 发明授权

US06890584B2 Flexographic ink containing a polymer or copolymer of a 3,4-dialkoxythiophene 失效
标题翻译：柔性油墨含有3,4-二烷氧基噻吩的聚合物或共聚物
公开(公告)号：US06890584B2
公开(公告)日：2005-05-10
申请号：US10175948
申请日：2002-06-20
申请人： Luc Leenders , Eddie Daems , Frank Louwet , Rafaël Samijn , Jean-Pierre Tahon , Roger Van den Bogaert
发明人： Luc Leenders , Eddie Daems , Frank Louwet , Rafaël Samijn , Jean-Pierre Tahon , Roger Van den Bogaert
IPC分类号： C08G61/12 , C09D11/00 , C09D11/10 , C09D165/00 , C09K11/06 , H01B1/12 , H01L51/30 , H01L51/52 , B41M1/04
CPC分类号： H01B1/128 , C08G61/126 , C09D11/10 , C09D11/106 , C09D11/30 , C09D11/52 , C09D165/00 , C09K11/06 , H01L51/0022 , H01L51/0037 , H01L51/5206 , H01L51/5221
摘要： A non-dye containing flexographic ink containing a polymer or copolymer of a 3,4-dialkoxythiophene in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, a polyanion and a latex binder in a solvent or aqueous medium, characterized in that the polymer or copolymer of a 3,4-dialkoxythiophene is present in a concentration of at least 0.1% by weight in the ink and that the ink is capable of producing a colorimetrically additive transparent print; a method of preparing the flexographic ink; and a flexographic printing process therewith.
摘要翻译：包含3,4-二烷氧基噻吩的聚合物或共聚物的非染料含柔性油墨，其中两个烷氧基可以相同或不同，或一起代表任选取代的氧 - 亚烷基 - 氧桥，聚阴离子和胶乳粘合剂在溶剂或水性介质中，其特征在于3,4-二烷氧基噻吩的聚合物或共聚物在油墨中以至少0.1重量％的浓度存在，并且油墨能够产生比色添加剂透明印刷品; 柔性油墨的制备方法; 和柔性版印刷工艺。

35. 发明申请

US20050009986A1 New 3,4-alkylenedioxy-thiophene copolymers 有权
标题翻译：新的3,4-亚烷基二氧基 - 噻吩共聚物
公开(公告)号：US20050009986A1
公开(公告)日：2005-01-13
申请号：US10844551
申请日：2004-05-12
申请人： Bert Groenendaal , Frank Louwet
发明人： Bert Groenendaal , Frank Louwet
IPC分类号： C08G61/12 , C09D165/00 , C08F20/58
CPC分类号： C08G61/126 , C09D165/00 , H01G11/48 , H01G11/56 , Y02E60/13
摘要： An aqueous dispersion of a copolymer of at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of less than 2.2 g/L with at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of at least 2.2 g/L and a polyanion; a preparation process therefor; its use for coating; a printing ink containing the aqueous dispersion; an electro-conductive layer containing a copolymer of at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of less than 2.2 g/L with at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of at least 2.2 g/L and a polyanion derived from an aqueous dispersion thereof; and an antistatic layer containing a copolymer of at least one 3,4-alkylenedioxy-thiophene compound with a solubility in water at 25° C. of less than 2.2 g/L with at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of at least 2.2 g/L and a polyanion derived from an aqueous dispersion thereof.
摘要翻译：至少一种3,4-二亚烷基二氧噻吩化合物在25℃下在水中的溶解度小于2.2g / L的共聚物的水分散体与至少一种在水中溶解度为25的3,4-亚烷基二氧噻吩化合物至少2.2g / L的聚阴离子; 其准备过程; 其用于涂料; 含有水分散体的印刷油墨; 含有至少一种在25℃下在水中的溶解度低于2.2g / L的3,4-亚烷基二氧噻吩化合物与至少一种在水中溶解度的3,4-亚烷基二氧噻吩化合物的共聚物的导电层在25℃下为至少2.2g / L，衍生自其水分散体的聚阴离子; 以及含有至少一种在25℃下在水中溶解度小于2.2g / L的3,4-亚烷基二氧基 - 噻吩化合物与至少一种具有溶解度的3,4-亚烷基二氧噻吩化合物的共聚物的抗静电层 25℃下的水至少为2.2g / L，衍生自其水分散体的聚阴离子。

36. 发明授权

US06632472B2 Redispersable latex comprising a polythiophene 有权
标题翻译：包含聚噻吩的可再分散胶乳
公开(公告)号：US06632472B2
公开(公告)日：2003-10-14
申请号：US09892011
申请日：2001-06-26
申请人： Frank Louwet , Raf Samijn
发明人： Frank Louwet , Raf Samijn
IPC分类号： C09D1102
CPC分类号： C09D11/52 , C08G61/126 , C09D11/106 , C09D165/00
摘要： A redispersible or soluble product, optionally having a solids content higher than 10% by weight, obtainable by freeze drying an aqueous dispersion of a latex comprising a polyanion and a polymer or copolymer of a substituted or unsubstituted thiophene; a printing ink comprising the above product; a coating dispersion or solution comprising the above product; and a method for making an antistatic or electroconductive layer comprising the steps of redispersing or diluting the above product by adding water or an organic solvent so as to obtain a dispersion or solution, optionally adding other ingredients to the coating solution or dispersion and applying the dispersion or solution to an object.
摘要翻译：通过将包含聚阴离子和取代或未取代的噻吩的聚合物或共聚物的胶乳的水分散体冷冻干燥，可再分散或可溶性产品，任选地具有高于10重量％的固体含量; 包含上述产品的印刷油墨; 包含上述产品的涂料分散体或溶液; 以及制造抗静电或导电层的方法，包括以下步骤：通过加入水或有机溶剂对上述产物进行再分散或稀释，以获得分散体或溶液，任选地向涂布溶液或分散体中加入其它成分并施加该分散体或解决方案。

37. 发明授权

US06427595B1 Heat-sensitive imaging element for making lithographic printing plates comprising polymer particles with a specific particle size 失效
标题翻译：用于制造平版印刷版的热敏成像元件，其包含特定粒度的聚合物颗粒
公开(公告)号：US06427595B1
公开(公告)日：2002-08-06
申请号：US08989469
申请日：1997-12-12
申请人： Marc Van Damme , Joan Vermeersch , Frank Louwet , Raf Samijn
发明人： Marc Van Damme , Joan Vermeersch , Frank Louwet , Raf Samijn
IPC分类号： B41N114
CPC分类号： B41C1/1025 , B41C2201/04 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/24 , B41C2210/262
摘要： According to the present invention there is provided a heat-sensitive imaging element for making lithographic printing plates. The heat-sensitive imaging element comprises an image-forming layer comprising hydrophobic thermoplastic polymer particles having a specific particle size and polydispersity for obtaining printing plates with an improved sensitivity, excellent developability, high throughput and less scumming.
摘要翻译：根据本发明，提供了一种用于制造平版印刷版的热敏成像元件。热敏成像元件包括图像形成层，其包含具有特定粒度和多分散性的疏水性热塑性聚合物颗粒，用于获得具有改进的灵敏度，优异的显影性，高通量和较少浮渣的印刷版。

38. 发明授权

US5917003A Process for producing polymers of .alpha.,.omega.-unsaturated conjugated compounds, and high molecular weight conjugated polymers thus obtainable 失效
标题翻译：制备α，ω-不饱和共轭化合物的聚合物的方法和由此获得的高分子量共轭聚合物
公开(公告)号：US5917003A
公开(公告)日：1999-06-29
申请号：US304134
申请日：1994-09-12
申请人： Joanes Gelan , Dirk Vanderzande , Frank Louwet
发明人： Joanes Gelan , Dirk Vanderzande , Frank Louwet
IPC分类号： H05B33/20 , C08G61/00 , C08G61/02 , C09K11/06 , H01L51/50 , H05B33/12 , C08G69/08
CPC分类号： C08G61/02
摘要： A process for producing polymers of .alpha., .omega.-unsaturated conjugated compounds, which includes reacting a compound of the formula (I),B--A--C (I)whereinB denotes a sp.sup.3 -hybridized carbon atom carrying at least one hydrogen atom,A denotes a conjugated-.pi.-system or a --CH.dbd.CH--group, andC denotes a carbon atom carrying at least one leaving group,with a base in a solvent. On reaction of the base with the compound of the formula (I) a polymer is formed as a by-product essentially soluble in the solvent and a solid is formed as a by-product which is essentially insoluble in the solvent. According to the process, chemically and thermally stable, high molecular weight polymers of high purity and high regularity are obtained in good yield. If the products of the process carry groups that undergo elimination, forming double bonds, high quality electroluminescent materials can be prepared.
摘要翻译：一种制备α，ω-不饱和共轭化合物的聚合物的方法，其包括使式（I）的化合物，BAC（I），其中B表示携带至少一个氢原子的sp3-杂化的碳原子，A表示共轭 - π系或-CH = CH-基，C表示携带至少一个离去基团的碳原子，在溶剂中含有碱。在碱与式（I）化合物的反应中，形成聚合物作为基本上可溶于溶剂的副产物，并且固体形成为基本上不溶于溶剂的副产物。根据该方法，获得了高纯度和高规则性的化学和热稳定的高分子量聚合物。如果该方法的产物携带消除的组，形成双键，则可以制备高品质的电致发光材料。

39. 发明申请

US20080050534A1 UV-PHOTOPOLYMERIZABLE COMPOSITION FOR PRODUCING ORGANIC CONDUCTIVE LAYERS, PATTERNS OR PRINTS 有权
标题翻译：用于生产有机导电层，图案或印刷品的紫外光可聚合组合物
公开(公告)号：US20080050534A1
公开(公告)日：2008-02-28
申请号：US11836581
申请日：2007-08-09
申请人： Frank Louwet , Louis Bollens
发明人： Frank Louwet , Louis Bollens
IPC分类号： B05D3/06 , C08J3/28 , C09D11/10
CPC分类号： C09D165/00 , C09D5/24 , C09D11/101 , G03F7/027 , G03F7/093 , G03F7/16 , H01B1/127 , H01L51/0022 , H01L51/0036 , H01L51/0037 , H05K3/105
摘要： A composition comprising a polyanion and a polymer or copolymer of a substituted or unsubstituted thiophene as a solution or as a dispersion in a liquid medium and at least one compound with at least two vinyl groups, wherein said liquid medium comprises at least one non-aqueous solvent and has less than 30% by weight of water; and said composition comprises more than 0.1% by weight of the polymer or copolymer of a substituted or unsubstituted thiophene and is capable of UV-photopolymerization due to said composition comprising at least one vinyl-compound capable of initiating UV-photopolymerization and/or at least one UV-photoinitiator; an ink with the composition of the composition; and a process for producing a layer or pattern on an object with the composition.
摘要翻译：一种组合物，其包含聚阴离子和取代或未取代的噻吩作为溶液或作为液体介质中的分散体的聚合物或共聚物和至少一种具有至少两个乙烯基的化合物，其中所述液体介质包含至少一种非水性并且具有小于30重量％的水; 并且所述组合物包含大于0.1重量％的取代或未取代的噻吩的聚合物或共聚物，并且由于所述组合物包含至少一种能够引发UV-光聚合的乙烯基化合物和/或至少一种UV-光引发剂; 具有组合物组成的油墨; 以及用于在具有该组成的物体上产生层或图案的工艺。

40. 发明授权

US07122130B2 Composition containing a polymer or copolymer of a 3,4-dialkoxythiophene and non-aqueous solvent 有权
公开(公告)号：US07122130B2
公开(公告)日：2006-10-17
申请号：US10894441
申请日：2004-07-19
申请人： Jean-Piere Tahon , Roger Van den Bogaert , Bert Groenendaal , Frank Louwet
发明人： Jean-Piere Tahon , Roger Van den Bogaert , Bert Groenendaal , Frank Louwet
IPC分类号： H01B1/12
CPC分类号： H01B1/128 , C08J3/09 , C08J2365/00 , C08L65/00 , C09D5/24 , C09D11/033 , C09D11/36 , C09D11/52 , C09D165/00 , Y10T428/2809
摘要： A method for preparing a composition containing between 0.08 and 3.0% by weight of polymer or copolymer of a 3,4-dialkoxythiophene in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, a polyanion and at least one non-aqueous solvent from a dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion in water which is prepared in the substantial absence of oxygen, comprising in the following order the steps of: i) mixing at least one of the non-aqueous solvents with the aqueous dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion; and ii) evaporating water from the mixture prepared in step i) until the content of water therein is reduced by at least 65% by weight; a printing ink, printing paste or coating composition, capable of yielding layers with enhanced conductivity at a given transparency, prepared according to the above-described method; a coating process with the coating composition thereby producing a layer with enhanced conductivity at a given transparency; and a printing process with the printing ink or paste thereby producing a layer with enhanced conductivity at a given transparency.

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