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    • 31. 发明授权
    • Coated metal element used for producing glass
    • 用于生产玻璃的涂覆金属元素
    • US07338714B2
    • 2008-03-04
    • US10432745
    • 2001-11-29
    • Franz OttDirk GohlkeJoerg Witte
    • Franz OttDirk GohlkeJoerg Witte
    • B32B15/00B32B15/04
    • C03B5/1675C03B5/1672C03B17/04C03B40/00C03C3/06C03C3/083C03C3/085C03C3/087C03C3/091C03C3/093C03C3/097C03C3/105C03C3/108C03C3/112C23C30/00Y02P40/52
    • The regionally coated noble metal element for use in glass production has an uncoated region for contacting a glass melt and a side opposite from the uncoated region is provided with an H2-impervious layer or an H2-impervious and O2-impervious layer. The H2-impervious layer or H2-impervious and O2-impervious layer has a thickness greater than or equal to 1 mm, is heat-resistant, liquid, or solid. This layer is made from at least one partly or completely crystallized glass or a glass mixture or a ceramic material. Processes for coating the noble metal element are also described. The coated metal elements can be an electrode in a distributor, a channel or melting tank, a pipe for conducting and conditioning glass melts, a shaping tool for producing pipes and rods or a jacketed platinum tube for direct heating of bottom outlets, transport equipment or charging organs, an agitator, a pipe-drawing head, a feeder head, a plunger in gob feeders, drawing tanks and drawing lips for flat glass production and fining chambers.
    • 用于玻璃制造的区域涂覆的贵金属元件具有用于使玻璃熔体接触的未涂覆区域和与未涂覆区域相对的一侧设有H 2 O 3不透水层或H 2 2 - 不透明和O 2 - 不可见层。 H 2 - 不可透过层或H 2 O 2 - 不透水和O 2 - 不可渗透层具有大于或等于1mm的厚度,是 耐热,液体或固体。 该层由至少一种部分或完全结晶的玻璃或玻璃混合物或陶瓷材料制成。 还描述了用于涂覆贵金属元素的方法。 涂覆的金属元件可以是分配器,通道或熔池中的电极,用于导电和调节玻璃熔体的管,用于生产管和棒的成型工具或用于直接加热底部出口,运输设备或 充气器,搅拌器,拔管头,给料头,料滴给料器中的柱塞,用于平板玻璃生产和澄清室的拉丝槽和拉丝嘴。
    • 35. 发明授权
    • Borosilicate glass of high chemical resistance and low viscosity which
contains zirconium oxide and lithium oxide
    • 含有氧化锆和氧化锂的高耐化学性和低粘度的硼硅酸盐玻璃
    • US5736476A
    • 1998-04-07
    • US722668
    • 1996-09-30
    • Eckhart WatzkeAndrea KampferPeter BrixFranz Ott
    • Eckhart WatzkeAndrea KampferPeter BrixFranz Ott
    • A61J1/06B01L3/14C03C3/093C03C3/112C03C4/20
    • B01L3/5082C03C3/093A61J1/06
    • The invention relates to a borosilicate glass of high chemical resistance and low viscosity which contains zirconium oxide and lithium oxide. The borosilicate glass has hydrolytic resistance (in accordance with DIN ISO 719), class 1 acid resistance (in accordance with DIN 12116), and class 1 alkali resistance (in accordance with DIN ISO 659), and with a low operating temperature V.sub.A of between 1180.degree. C. to 1230.degree. C. and a coefficient of thermal expansion .alpha..sub.20/300 of 4.9.times.10.sup.-6 K.sup.-1. The borosilicate glass has the composition (in % by weight, based on oxide): SiO.sub.2 73-75; B.sub.2 0.sub.3 7-10; Al.sub.2 0.sub.3 5-7; ZrO.sub.2 1-3; Li.sub.2 0 0.5-1.5; Na.sub.2 0 0-10; K.sub.2 0 0-10; MgO 0-3; CaO 0-3; BaO 0-3; SrO 0-3; ZnO 0-3; ratio of SiO.sub.2 /B.sub.2 0.sub.3 .gtoreq.7.5; .SIGMA. SiO.sub.2 +Al.sub.2 0.sub.3 +ZrO.sub.2 80-83 and .SIGMA. MgO+CaO+BaO+SrO+ZnO.ltoreq.3, and fluorides 0-3. The glass is particularly suitable for use as a versatile primary packaging material for pharmaceuticals, for example as ampule glass.
    • 本发明涉及含有氧化锆和氧化锂的高耐化学性和低粘度的硼硅酸盐玻璃。 硼硅酸盐玻璃具有耐水解性(符合DIN ISO 719),1级耐酸性(符合DIN 12116)和1级耐碱性(符合DIN ISO 659标准),并具有低的工作温度VA 1180℃至1230℃,热膨胀系数α20/300为4.9×10 -6 K -1。 硼硅酸盐玻璃的组成(以重量%计,基于氧化物):SiO 2 73-75; B203 7-10; Al203 5-7; ZrO2 1-3; Li20 0.5-1.5; Na20 0-10; K20 0-10; MgO 0-3; CaO 0-3; BaO 0-3; SrO 0-3; ZnO 0-3; SiO 2 / B 2 O 3的比例> = 7.5; SIGMA SiO 2 + Al 2 O 3 + ZrO 2 80-83和SIGMA MgO + CaO + BaO + SrO + ZnO 3,氟化物0-3。 该玻璃特别适合用作药物的通用初级包装材料,例如作为安瓿玻璃。