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31. 发明申请

US20110124805A1 LOW VISCOSITY ALLOPHANATES CONTAINING ACTINICALLY CURABLE GROUPS 有权
标题翻译：低粘度的含有可固化组合的聚氨酯
公开(公告)号：US20110124805A1
公开(公告)日：2011-05-26
申请号：US13015118
申请日：2011-01-27
申请人： Jan Weikard , Christophe Detrembleur , Dorota Greszta-Franz , Frank Richter , Wolfgang Fischer , Jörg Schmitz , Holger Mundstock
发明人： Jan Weikard , Christophe Detrembleur , Dorota Greszta-Franz , Frank Richter , Wolfgang Fischer , Jörg Schmitz , Holger Mundstock
IPC分类号： C08L75/12 , C07D251/04
CPC分类号： C08G18/7837 , B33Y70/00 , C08G18/672 , C08G18/798 , C08G18/8166 , C09D175/14 , C09D175/16
摘要： The present invention relates to a process for preparing radiation-curing binders containing allophanate groups by reacting at temperatures of ≦130° C. A) one or more compounds containing uretdione groups with B) one or more OH-functional compounds which contain groups which react, with polymerization, with ethylenically unsaturated compounds on exposure to actinic radiation (radiation-curing groups), C) optionally NCO-reactive compounds other than B), in the presence of D) a catalyst containing at least one zinc compound, to form allophanate groups by opening the uretdione ring. The present invention also relates to the binders obtained by the process of the invention and to coating compositions containing these binders.
摘要翻译：本发明涉及通过在温度为130℃的温度下反应制备含有脲基甲酸酯基的辐射固化粘合剂的方法。A）一种或多种含有脲二酮基团的化合物与B）一种或多种含OH官能化合物，在曝光于光化辐射（辐射固化基团）时与烯属不饱和化合物反应，C）任选除B）之外的NCO-反应性化合物，在D）含有至少一种锌化合物的催化剂存在下反应形成脲基甲酸酯基通过开放脲二酮环。本发明还涉及通过本发明的方法获得的粘合剂和包含这些粘合剂的涂料组合物。

32. 发明授权

US07754827B2 Coated films 有权
标题翻译：涂膜
公开(公告)号：US07754827B2
公开(公告)日：2010-07-13
申请号：US12002909
申请日：2007-12-19
申请人： Jan Weikard , Wolfgang Fischer , Diethelm Rappen , Nicolas Stoeckel
发明人： Jan Weikard , Wolfgang Fischer , Diethelm Rappen , Nicolas Stoeckel
IPC分类号： C08G18/00 , C08F283/00
CPC分类号： C08G18/022 , C08G18/3212 , C08G18/672 , C08G18/792 , C08G18/8175 , C09D175/16 , Y10T428/31855 , C08G18/44 , C08G18/42
摘要： The invention relates to novel coated post-formable films, to surface-coating compositions for such films, to a combined method for curing the surface-coating compositions and for post-forming, as well as to molded bodies produced from the coated films.
摘要翻译：本发明涉及新颖的涂覆后可成形薄膜，用于这种薄膜的表面涂层组合物，用于固化表面涂料组合物和后成型的组合方法，以及由涂覆薄膜制成的成型体。

33. 发明申请

US20090104395A1 Disc-shaped high-density recording mediums 有权
标题翻译：碟形高密度记录介质
公开(公告)号：US20090104395A1
公开(公告)日：2009-04-23
申请号：US12288203
申请日：2008-10-17
申请人： Friedrich-Karl Bruder , Wilfried Haese , Rafael Oser , Jan Weikard , Wolfgang Fischer , Rainer Protte , Joerg Wehrle , Karlheinz Hildenbrand
发明人： Friedrich-Karl Bruder , Wilfried Haese , Rafael Oser , Jan Weikard , Wolfgang Fischer , Rainer Protte , Joerg Wehrle , Karlheinz Hildenbrand
IPC分类号： G11B3/68 , B32B27/30 , B32B27/32 , B32B27/28
CPC分类号： G11B7/2545 , G11B7/253 , G11B7/2534 , G11B7/2536 , G11B7/2538 , Y10T428/21
摘要： Optical recording mediums comprising a substrate and a recording layer and a light transmitting layer sequentially disposed on the substrate; wherein the substrate comprises one or more parts selected from the group consisting of injection molded parts, injection molded sandwich structures having a molded surface layer and a molded core layer or two injection molded parts which are UV-bonded, and combinations thereof; and wherein the substrate has a Young's modulus E of at least 2.15 GPa and a Q factor of lower than 160 measured at 25° C. at 2000 Hz in accordance to ASTM E 756-05.
摘要翻译：包括基板和记录层的光记录介质和顺序地设置在基板上的透光层; 其特征在于，所述基板包括选自注射成型部件，具有模制表面层的注射成型夹层结构和模制芯层或两个UV结合的注射成型部件的一个或多个部件及其组合; 并且其中所述基材的杨氏模量E至少为2.15GPa，Q值低于160，根据ASTM E 756-05在25℃下以2000Hz测量。

34. 发明授权

US07381785B2 Preparation of new radiation-curing binders 有权
标题翻译：新型辐射固化胶粘剂的制备
公开(公告)号：US07381785B2
公开(公告)日：2008-06-03
申请号：US11080176
申请日：2005-03-14
申请人： Christophe Dètrembleur , Jan Weikard , Dorota Greszta-Franz , Wolfgang Fischer , Jörg Schmitz , Holger Mundstock
发明人： Christophe Dètrembleur , Jan Weikard , Dorota Greszta-Franz , Wolfgang Fischer , Jörg Schmitz , Holger Mundstock
IPC分类号： C08G18/78 , C08G18/67 , C08G18/16 , C09D175/16
CPC分类号： C08G18/7837 , B33Y70/00 , C08G18/166 , C08G18/672 , C09D175/16 , C08G18/3206
摘要： Process for preparing binders including reacting A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds containing groups capable of participating in polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation, and contain isocyanate-reactive groups, followed by C) reaction with one or more hydroxyl-containing compounds other than B), wherein at least one of these compounds has an OH functionality of≧2, D) in the presence of one or more compounds containing phenoxide groups, as catalysts, and E) optionally auxiliaries and additives, where the reaction with compounds of component C) proceeds at least proportionally with the formation of allophanate groups and where and including binders containing allophanate groups and groups capable of participating in a polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation, and optionally also contain NCO-reactive groups. The binders are used in coating compositions used to coat substrates.
摘要翻译：制备粘合剂的方法包括使A）一种或多种含有脲二酮基团的NCO-官能化合物与B）一种或多种含有能够在曝光于光化辐射下参与与烯属不饱和化合物聚合反应的基团的化合物，并含有异氰酸酯反应性基团，随后C）与除B）之外的一种或多种含羟基化合物反应，其中这些化合物中的至少一种具有> = 2的OH官能度，D）在一种或多种含有酚盐的化合物的存在下，作为催化剂和E）任选的助剂和添加剂，其中与组分C）的化合物的反应至少与形成脲基甲酸酯基团成比例地进行，并且其中和包括含有脲基甲酸酯基团和能够与烯属不饱和化合物进行聚合反应的基团的粘合剂暴露于光化辐射，并且任选地还含有NCO-反应性基团。粘合剂用于涂覆基材的涂料组合物中。

35. 发明授权

US07144955B2 Acrylate-functional blocked polyisocyanate resin for UV/thermally curable coatings 有权
标题翻译：用于UV /热固化涂料的丙烯酸酯官能封端多异氰酸酯树脂
公开(公告)号：US07144955B2
公开(公告)日：2006-12-05
申请号：US10694107
申请日：2003-10-27
申请人： Scott A. Grace , Michael J. Dvorchak , Richard R. Roesler , Dinesh Pethiyagoda , Michael K. Jeffries , Jan Weikard
发明人： Scott A. Grace , Michael J. Dvorchak , Richard R. Roesler , Dinesh Pethiyagoda , Michael K. Jeffries , Jan Weikard
IPC分类号： C08L75/12 , C08G18/73 , C08G18/75
CPC分类号： C08G18/792 , C08G18/4208 , C08G18/4238 , C08G18/672 , C08G18/807 , C08G18/8175 , C09D175/16 , C08G18/42
摘要： Solvent-based, dual cure coatings incorporating thermally curable blocked polyisocyanates, which also contain unsaturated linkages, and a method for preparing these coatings. The unsaturated linkages, such as acrylate groups, can be crosslinked by free-radical mechanisms such as UV curing.
摘要翻译：含有可热固化的封端多异氰酸酯（也含有不饱和键的溶剂型双重固化涂层）和制备这些涂层的方法。不饱和键如丙烯酸酯基团可以通过自由基机制如UV固化而交联。

36. 发明申请

US20060116502A1 Blocked polyisocyanates and their use in dual-cure coating compositions 审中-公开
标题翻译：封闭的多异氰酸酯及其在双重固化涂料组合物中的用途
公开(公告)号：US20060116502A1
公开(公告)日：2006-06-01
申请号：US11287752
申请日：2005-11-28
申请人： Christoph Gurtler , Markus Mechtel , Jan Weikard , Nusret Yuva
发明人： Christoph Gurtler , Markus Mechtel , Jan Weikard , Nusret Yuva
IPC分类号： C08G18/00
CPC分类号： C09D175/16 , C08G18/673 , C08G18/807
摘要： The present invention relates to blocked polyisocyanates containing at least one radiation-curable groups and at least one structural unit of the formula (II) wherein R1, R2 and R3 independently of one another are hydrogen or a C1-C4 alkyl radical or a cycloalkyl radical, R4 is a C1-C4 alkyl, C6-C10 cycloalkyl or C7-C14 aralkyl radical and x is an integer from 1 to 5. The present invention also relates to a process for preparing these blocked polyisocyanates and to dual-cure coating, adhesive or sealant compositions containing these polyisocyanates.
摘要翻译：本发明涉及含有至少一个可辐射固化基团和至少一个式（II）的结构单元的封端多异氰酸酯，其中R 1，R 2和R 2，彼此独立地是氢或C 1 -C 4烷基或环烷基，R 4，是C 1 -C 4烷基，C 6 -C 10环烷基或C 7 - 其中x是1至5的整数。本发明还涉及一种制备这些封端多异氰酸酯的方法和双重固化涂料，粘合剂或密封剂组合物，其包含这些多异氰酸酯。

37. 发明申请

US20060094819A1 Low-viscosity, radiation-curable urethane binder dispersions with high solids contents 审中-公开
标题翻译：低粘度，可辐射固化的聚氨酯粘合剂分散体，固体含量高
公开(公告)号：US20060094819A1
公开(公告)日：2006-05-04
申请号：US11264078
申请日：2005-11-01
申请人： Manfred Muller , Richard Kopp , Wolfgang Fischer , Jan Weikard
发明人： Manfred Muller , Richard Kopp , Wolfgang Fischer , Jan Weikard
IPC分类号： C08G18/08
CPC分类号： C09D167/07 , C08G18/672 , C08G18/673 , C08G63/676 , C08K5/13 , C08L67/07 , C08L75/16 , C08L2201/50 , C09D175/16 , C08L2666/20 , C08L2666/18
摘要： The present invention relates to water-free and cosolvent-free binder compositions A) containing of a mixture of A1) at least one emulsifier-free, hydrophobic binder containing groups which can be polymerized by high-energy radiation and A2) at least one hydrophilic unsaturated polyester resin containing the reaction product of a) at least one unsaturated dicarboxylic acid and/or an anhydride thereof, b) at least one polyalkylene oxide compound having a number average molecular weight of 106 to 2000, at least 2 hydroxyl end groups and at least 2 oxyalkylene units, wherein at least 50% of the oxyalkylene units are oxyethylene units, and c) at least one hydroxy-functional compound containing at least one polymerizable unsaturated group per molecule selected from vinyl, allyl, methacrylic and acrylic groups. The present invention also relates to aqueous dispersions containing the binder compositions A), to a process for preparing an aqueous dispersion containing the binder dispersion, to a process for diluting the binder composition with tap water, to producing coatings from the aqueous dispersions and to the use of the binder compositions for preparing coating, adhesive or sealant compositions.
摘要翻译：本发明涉及无水和无溶剂的粘合剂组合物A），其包含A1）至少一种不含乳化剂的疏水性粘合剂，其含有能够通过高能量辐射聚合的基团和A2）至少一种亲水性含有a）至少一种不饱和二羧酸和/或其酸酐的反应产物的不饱和聚酯树脂，b）至少一种数均分子量为106至2000的聚环氧烷化合物，至少2个羟基端基和至少2个氧化烯单元，其中至少50％的氧化烯单元是氧化乙烯单元，和c）至少一种含有至少一个选自乙烯基，烯丙基，甲基丙烯酸和丙烯酸基团的每个分子的可聚合不饱和基团的羟基官能化合物。本发明还涉及含有粘合剂组合物A）的水分散体，制备含有粘合剂分散体的水性分散体的方法，用于用自来水稀释粘合剂组合物的方法，从水性分散体生产涂料，使用粘合剂组合物来制备涂料，粘合剂或密封剂组合物。

38. 发明申请

US20060052573A1 Blocked polyisocyanates curing free from elimination products for dualcure systems 有权
公开(公告)号：US20060052573A1
公开(公告)日：2006-03-09
申请号：US11219395
申请日：2005-09-02
申请人： Thomas Facke , Jan Weikard , Wolfgang Fischer
发明人： Thomas Facke , Jan Weikard , Wolfgang Fischer
IPC分类号： C08G18/00
CPC分类号： C08G18/8175 , C09D175/16
摘要： The invention provides innovative blocked polyisocyanates whose crosslinking is initiated thermally and photochemically. The polyisocyanates comprise at least one thermally reversibly blocked NCO group whose blocking agent contains at least one group which on exposure to actinic radiation reacts, with polymerization, with ethylenically unsaturated compounds. A process for preparing the polyisocyanates, and their use in binders, is also provided.

39. 发明申请

US20060051591A1 Radiation-curing binders and a process for their preparation 有权
标题翻译：辐射固化粘合剂及其制备方法
公开(公告)号：US20060051591A1
公开(公告)日：2006-03-09
申请号：US11217728
申请日：2005-09-01
申请人： Jan Weikard , Christoph Gurtler , Wolfgang Fischer , Jorg Schmitz , Holger Mundstock
发明人： Jan Weikard , Christoph Gurtler , Wolfgang Fischer , Jorg Schmitz , Holger Mundstock
IPC分类号： B32B27/00 , C08G18/00 , B29D11/00
CPC分类号： C08G18/8175 , B33Y70/00 , C09D175/14 , Y10T428/31551
摘要： The invention relates to a process for preparing binders which contain 1) allophanate groups, 2) groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups) and 3) optionally NCO-reactive groups, by reacting at temperatures ≦130° C. A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds that contain isocyanate-reactive groups and groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups), and then C) with one or more saturated, hydroxyl-containing compounds other than B), at least one of these compounds having an OH functionality of ≧2, in the presence of D) a catalyst containing one or more ammonium salts or phosphonium salts of aliphatic or cycloaliphatic carboxylic acids, the reaction with compounds C) taking place at least proportionally with the formation of allophanate groups. The present invention also relates to the binders obtained by the process of the invention.
摘要翻译：本发明涉及一种制备粘合剂的方法，其包含1）脲基甲酸酯基团，2）与烯键式不饱和化合物反应的基团与暴露于光化辐射（辐射固化基团）和3）任选的NCO-反应性基团反应的基团， A）一种或多种含有脲二酮基团的NCO-官能化合物，B）一种或多种含有异氰酸酯反应性基团的化合物和与烯键式不饱和化合物反应的基团，其在暴露于光化辐射下聚合（辐射 - 固化基团），然后C）与除了B）之外的一种或多种饱和的含羟基化合物，在D存在下，具有OH官能度> = 2的这些化合物中的至少一种，含有一种或多种脂肪族或脂环族羧酸的铵盐或鏻盐，与化合物C）的反应至少与脲基甲酸酯基团的形成成比例地发生。本发明还涉及通过本发明的方法获得的粘合剂。

40. 发明申请

US20050209361A1 Preparation of new radiation-curing binders 有权
标题翻译：新型辐射固化胶粘剂的制备
公开(公告)号：US20050209361A1
公开(公告)日：2005-09-22
申请号：US11080176
申请日：2005-03-14
申请人： Christophe Detrembleur , Jan Weikard , Dorota Greszta-Franz , Wolfgang Fischer , Jorg Schmitz , Holger Mundstock
发明人： Christophe Detrembleur , Jan Weikard , Dorota Greszta-Franz , Wolfgang Fischer , Jorg Schmitz , Holger Mundstock
IPC分类号： C08G18/16 , C08G18/67 , C08G18/78 , C09D175/16 , C08G2/00
CPC分类号： C08G18/7837 , B33Y70/00 , C08G18/166 , C08G18/672 , C09D175/16 , C08G18/3206
摘要： Process for preparing binders including reacting A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds containing groups capable of participating in polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation, and contain isocyanate-reactive groups, followed by C) reaction with one or more hydroxyl-containing compounds other than B), wherein at least one of these compounds has an OH functionality of ≧2, D) in the presence of one or more compounds containing phenoxide groups, as catalysts, and E) optionally auxiliaries and additives, where the reaction with compounds of component C) proceeds at least proportionally with the formation of allophanate groups and where and including binders containing allophanate groups and groups capable of participating in a polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation, and optionally also contain NCO-reactive groups. The binders are used in coating compositions used to coat substrates.
摘要翻译：制备粘合剂的方法包括使A）一种或多种含有脲二酮基团的NCO-官能化合物与B）一种或多种含有能够在曝光于光化辐射下参与与烯属不饱和化合物聚合反应的基团的化合物，并含有异氰酸酯反应性基团，随后C）与除B）之外的一种或多种含羟基化合物反应，其中这些化合物中的至少一种具有> = 2的OH官能度，D）在一种或多种含有酚盐的化合物的存在下，作为催化剂和E）任选的助剂和添加剂，其中与组分C）的化合物的反应至少与形成脲基甲酸酯基团成比例地进行，并且其中和包括含有脲基甲酸酯基团和能够与烯属不饱和化合物进行聚合反应的基团的粘合剂暴露于光化辐射，并且任选地还含有NCO-反应性基团。粘合剂用于涂覆基材的涂料组合物中。

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