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31. 发明授权

US08048339B2 Porous anode active material, method of preparing the same, and anode and lithium battery employing the same 有权
标题翻译：多孔阳极活性材料及其制备方法以及使用其的阳极和锂电池
公开(公告)号：US08048339B2
公开(公告)日：2011-11-01
申请号：US11829787
申请日：2007-07-27
申请人： Sang-kook Mah , Han-su Kim , Dong-min Im
发明人： Sang-kook Mah , Han-su Kim , Dong-min Im
IPC分类号： H01B1/06 , H01B1/24 , H01M4/13
CPC分类号： H01M4/134 , H01M4/133 , H01M4/1393 , H01M4/364 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/42 , H01M4/466 , H01M4/587 , H01M4/625 , H01M10/052 , H01M2004/021
摘要： Provided are a porous anode active material, a method of preparing the same, and an anode and a lithium battery employing the same. The porous anode active material includes fine particles of metallic substance capable of forming a lithium alloy; a crystalline carboneous substance; and a porous carboneous material coating and attaching to the fine particles of metallic substance and the crystalline carboneous substance, the porous anode active material having pores exhibiting a bimodal size distribution with two pore diameter peaks as measured by a Barrett-Joyner-Halenda (BJH) pore size distribution from a nitrogen adsorption. The porous anode active material has the pores having a bimodal size distribution, and thus may efficiently remove a stress occurring due to a difference of expansion between a carboneous material and a metallic active material during charging and discharging. Further, the anode electrode and the lithium battery comprising the anode active material have excellent charge/discharge characteristics.
摘要翻译：提供一种多孔阳极活性材料，其制备方法，以及使用其的阳极和锂电池。多孔负极活性物质包括能够形成锂合金的金属物质微粒; 结晶碳物质; 和多孔碳质材料涂覆并附着到金属物质和结晶碳质物质的细颗粒上，多孔负极活性物质具有双孔尺寸分布，具有两孔径峰，由Barrett-Joyner-Halenda（BJH）测量，孔径分布从氮吸附。多孔负极活性物质具有双峰尺寸分布的孔，因此可以有效地消除由于填充和排出期间碳质材料和金属活性物质之间的膨胀差而产生的应力。此外，阳极电极和包含阳极活性材料的锂电池具有优异的充电/放电特性。

32. 发明授权

US07678505B2 Organic electrolytic solution and lithium battery employing the same 有权
标题翻译：有机电解液和采用其的锂电池
公开(公告)号：US07678505B2
公开(公告)日：2010-03-16
申请号：US11453641
申请日：2006-06-14
申请人： Seok-soo Lee , Young-gyoon Ryu , Han-su Kim
发明人： Seok-soo Lee , Young-gyoon Ryu , Han-su Kim
IPC分类号： H01M10/40
CPC分类号： H01M10/0567 , H01M10/052 , H01M10/0569 , H01M10/4235 , H01M2300/0025
摘要： An organic electrolytic solution and a lithium battery employing the same are provided. The organic electrolytic solution includes: a lithium salt; an organic solvent containing a high dielectric constant solvent and a low boiling point solvent; and an additive comprising a crotonate derivative including a substituted silyl group. The organic electrolytic solution and the lithium battery employing such an electrolytic solution suppress a reduction decomposition of a polar solvent and decrease irreversible capacity in the first cycle. Thus, the charge/discharge efficiency, lifespan, and reliability of the battery can be improved.
摘要翻译：提供有机电解液和使用其的锂电池。有机电解液包括：锂盐; 含有高介电常数溶剂和低沸点溶剂的有机溶剂; 和含有取代甲硅烷基的巴豆酸酯衍生物的添加剂。使用这种电解液的有机电解液和锂电池抑制极性溶剂的还原分解，并且在第一循环中降低不可逆容量。因此，可以提高电池的充电/放电效率，寿命和可靠性。

33. 发明申请

US20090155687A1 COMPOSITE ANODE ACTIVE MATERIAL, METHOD OF PREPARING THE SAME, ANODE CONTAINING THE COMPOSITE ANODE ACTIVE MATERIAL, AND LITHIUM BATTERY CONTAINING THE COMPOSITE ANODE ACTIVE MATERIAL 有权
标题翻译：复合阳极活性材料，其制备方法，包含复合阳极活性材料的阳极和含有复合阳极活性材料的锂电池
公开(公告)号：US20090155687A1
公开(公告)日：2009-06-18
申请号：US12127278
申请日：2008-05-27
申请人： Dong-min IM , Seok-gwang Doo , Han-su Kim , Jin-hwan Park
发明人： Dong-min IM , Seok-gwang Doo , Han-su Kim , Jin-hwan Park
IPC分类号： H01M4/38 , H01M4/40 , H01M4/52 , H01M4/04
CPC分类号： H01M10/052 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/40 , H01M4/48
摘要： A composite anode active material including: a metal capable of alloy formation with lithium; an intermetallic compound; and a solid solution, in which the solid solution is an alloy of the metal capable of alloy formation with lithium and the intermetallic compound, and the solid solution and the intermetallic compound have a same crystal structure.
摘要翻译：一种复合阳极活性材料，包括：能与锂形成合金的金属; 金属间化合物; 以及其中固溶体是与锂形成合金的金属和金属间化合物的合金的固溶体，固溶体和金属间化合物具有相同的晶体结构。

34. 发明授权

US07410731B2 Organic electrolytic solution and lithium battery employing the same 有权
标题翻译：有机电解液和采用其的锂电池
公开(公告)号：US07410731B2
公开(公告)日：2008-08-12
申请号：US11345844
申请日：2006-02-01
申请人： Jae-gu Yoon , Han-su Kim , Dong-min Im , Galina Myachina , Boris A. Trofimov , Doo-yeon Lee , Myung-dong Cho
发明人： Jae-gu Yoon , Han-su Kim , Dong-min Im , Galina Myachina , Boris A. Trofimov , Doo-yeon Lee , Myung-dong Cho
IPC分类号： H01M10/40
CPC分类号： H01M10/0569 , H01M4/1393 , H01M10/052 , H01M10/0567 , H01M2300/004
摘要： An organic electrolytic solution and a lithium battery employing the same are provided. The organic electrolytic solution includes: a lithium salt; an organic solvent containing a high dielectric constant solvent and a low boiling point solvent; and a dicarboxylic acid derivative having at least one substituted silyl group. The organic electrolytic solution and the lithium battery employing the same have improved reductive decomposition stability, thereby decreasing an irreversible capacity after a first cycle and improving the charge/discharge efficiency and lifespan of the battery. The lithium battery has non-varying chemical properties at room temperature and a uniform thickness after standard charging, and thus has high reliability.
摘要翻译：提供有机电解液和使用其的锂电池。有机电解液包括：锂盐; 含有高介电常数溶剂和低沸点溶剂的有机溶剂; 和具有至少一个取代甲硅烷基的二羧酸衍生物。有机电解液和使用该有机电解液的锂电池具有改善的还原分解稳定性，从而在第一次循环之后降低不可逆容量并提高电池的充放电效率和寿命。锂电池在室温下具有不变化的化学性质，并且在标准充电之后具有均匀的厚度，因此具有高可靠性。

35. 发明申请

US20080150551A1 Capacitance measurement circuit and capacitance measurement method thereof 审中-公开
标题翻译：电容测量电路及其电容测量方法
公开(公告)号：US20080150551A1
公开(公告)日：2008-06-26
申请号：US12002419
申请日：2007-12-17
申请人： Han-su Kim
发明人： Han-su Kim
IPC分类号： G01R27/26
CPC分类号： G01R27/2605
摘要： A capacitance measurement circuit includes a capacitor circuit unit having a first capacitor block and a second capacitor block, the first capacitor block having first and second variable capacitors connected in series and dividing an input voltage so as to supply a measurement storage voltage, and the second capacitor block having third and fourth variable capacitors connected in series and dividing the input voltage so as to supply a reference storage voltage. A voltage sensing unit senses the measurement storage voltage so as to supply the sensed measurement storage voltage as a measurement voltage and senses the reference storage voltage so as to supply the sensed reference storage voltage as a reference voltage.
摘要翻译：电容测量电路包括具有第一电容器块和第二电容器块的电容器电路单元，所述第一电容器块具有串联连接的第一和第二可变电容器，并且分压输入电压以提供测量存储电压，电容器块具有串联连接的第三和第四可变电容器，并且分压输入电压以提供参考存储电压。电压感测单元感测测量存储电压，以将感测的测量存储电压提供为测量电压，并感测参考存储电压，以便将感测的参考存储电压作为参考电压。

36. 发明申请

US20070264574A1 NEGATIVE ACTIVE MATERIAL INCLUDING METAL NANOCRYSTAL COMPOSITE, METHOD OF PREPARING THE SAME, AND ANODE AND LITHIUM BATTERY INCLUDING THE NEGATIVE ACTIVE MATERIAL 审中-公开
标题翻译：负极活性材料，包括金属纳米复合材料，其制备方法，阳极和锂电池，包括负极活性材料
公开(公告)号：US20070264574A1
公开(公告)日：2007-11-15
申请号：US11736549
申请日：2007-04-17
申请人： Han-su Kim , Jin-hwan Park , Seok-gwang Doo , Jae-phil Cho , Hyo-jin Lee , Yoo-jung Kwon
发明人： Han-su Kim , Jin-hwan Park , Seok-gwang Doo , Jae-phil Cho , Hyo-jin Lee , Yoo-jung Kwon
IPC分类号： H01M4/62 , H01M4/58 , B05D5/12 , B32B5/16 , B05D7/00
CPC分类号： H01M4/38 , B82Y30/00 , H01M4/134 , H01M4/364 , H01M4/366 , H01M4/386 , H01M4/387 , H01M4/587 , H01M4/625 , H01M10/0525 , H01M2004/021 , H01M2004/027 , Y10T428/2991
摘要： Negative active materials including metal nanocrystal composites comprising metal nanocrystals having an average particle diameter of about 20 nm or less and a carbon coating layer are provided. The negative active material includes metal nanocrystals coated by a carbon layer, which decreases the absolute value of the change in volume during charge/discharge and decreases the formation of cracks in the negative active material resulting from a difference in the volume change rate during charge/discharge between metal and carbon. Therefore, high charge/discharge capacities and improved capacity retention capabilities can be obtained.
摘要翻译：提供包括平均粒径为约20nm以下的金属纳米晶体的金属纳米晶体复合体和碳涂层的负极活性物质。负极活性材料包括由碳层涂覆的金属纳米晶体，其降低充电/放电期间体积变化的绝对值，并减少由于充电/放电期间体积变化率的差异导致的负极活性材料中的裂纹的形成，金属和碳之间的放电。因此，可以获得高充电/放电容量和改进的容量保持能力。

37. 发明授权

US07244531B2 Non-aqueous electrolyte and lithium battery using the same 有权
标题翻译：非水电解质和锂电池使用相同
公开(公告)号：US07244531B2
公开(公告)日：2007-07-17
申请号：US10631761
申请日：2003-08-01
申请人： Han-su Kim , Ju-yup Kim , Seok-soo Lee
发明人： Han-su Kim , Ju-yup Kim , Seok-soo Lee
IPC分类号： H01M10/08
CPC分类号： H01M10/0568 , H01M2/1653 , H01M4/136 , H01M4/5815 , H01M6/166 , H01M10/0525
摘要： A non-aqueous electrolyte for stabilizing the active surface of a lithium anode and a lithium battery using the non-aqueous electrolyte are provided. The non-aqueous electrolyte contains an organic solvent and a halogenated organic metal salt of formula (1) below: where M is one of Si, Sn, Pb, and Ge; R1 is one of F, Cl, Br, and I; R2 is a substituted or unsubstituted C1-C20 alkyl group or a substituted or unsubstituted phenyl group; and R3 and R4 are independently selected from the group consisting of F, Cl, Br, I, a substituted or unsubstituted C1-C20 alkyl group, and a substituted or unsubstituted phenyl group.
摘要翻译：提供了一种用于稳定锂阳极的活性表面和使用非水电解质的锂电池的非水电解质。非水电解质含有下述式（1）的有机溶剂和卤化有机金属盐：其中M是Si，Sn，Pb和Ge中的一种; R 1是F，Cl，Br和I中的一个; R 2是取代或未取代的C 1 -C 20烷基或取代或未取代的苯基; R 3和R 4独立地选自F，Cl，Br，I，取代或未取代的C 1〜 C 20烷基和取代或未取代的苯基。

38. 发明申请

US20070020519A1 Anode active material, manufacturing method thereof and lithium battery using the anode active material 审中-公开
标题翻译：阳极活性物质及其制造方法以及使用该负极活性物质的锂电池
公开(公告)号：US20070020519A1
公开(公告)日：2007-01-25
申请号：US11481657
申请日：2006-07-05
申请人： Han-su Kim , Seok-gwang Doo , Jae-phil Cho
发明人： Han-su Kim , Seok-gwang Doo , Jae-phil Cho
IPC分类号： H01M4/60 , H01M4/38
CPC分类号： H01M4/40 , H01M4/366 , H01M4/38 , H01M4/382 , H01M4/387 , H01M4/405 , H01M4/60 , H01M10/052
摘要： Provided are an anode active material for a lithium secondary battery, a manufacturing method of the anode active material, and a lithium secondary battery using the anode active material. More particularly, an anode active material for a lithium secondary battery having a high capacity and an excellent cycle lifetime, a manufacturing method of the anode active material, and a lithium secondary battery using the anode active material are provided. In the anode active material, monomers are coated on a tin nanopowder. The anode active material has a higher capacity and a higher cycle lifetime than a conventional anode active material.
摘要翻译：提供一种锂二次电池用负极活性物质，负极活性物质的制造方法以及使用该负极活性物质的锂二次电池。更具体地，提供了具有高容量和优异的循环寿命的用于锂二次电池的负极活性材料，阳极活性材料的制造方法和使用阳极活性材料的锂二次电池。在阳极活性材料中，单体涂覆在锡纳米粉末上。阳极活性材料具有比常规阳极活性材料更高的容量和更高的循环寿命。

39. 发明授权

US08968920B2 Organic electrolyte solution including silane compound and lithium battery employing the same 有权
标题翻译：含有硅烷化合物的有机电解质溶液和使用其的锂电池
公开(公告)号：US08968920B2
公开(公告)日：2015-03-03
申请号：US11848919
申请日：2007-08-31
申请人： Seok-soo Lee , Young-gyoon Ryu , Han-su Kim , Nina K. Gusarova
发明人： Seok-soo Lee , Young-gyoon Ryu , Han-su Kim , Nina K. Gusarova
IPC分类号： H01M6/16 , H01M10/0567 , C07F7/04 , H01M10/0525
CPC分类号： H01M10/0567 , H01M6/168 , H01M10/0525 , H01M2220/30 , Y02E60/122
摘要： Organic electrolyte solutions and lithium batteries employing the same are provided. In one embodiment, an organic electrolyte solution includes a silane compound. The inventive organic electrolyte solutions prevent crack formation caused by volumetric changes in the anode active material during charging/discharging of the battery. This improves charge/discharge characteristics, resulting in improved battery stability, reliability, and charge/discharge efficiency, which is a dramatic improvement over conventional organic electrolyte solutions, which have higher irreversible capacities due to the decomposition of polar solvents.
摘要翻译：提供有机电解质溶液和使用其的锂电池。在一个实施方案中，有机电解质溶液包括硅烷化合物。本发明的有机电解质溶液防止在电池充电/放电期间负极活性材料的体积变化引起的裂纹形成。这提高了充电/放电特性，从而提高了电池稳定性，可靠性和充电/放电效率，这是由于极性溶剂的分解而具有更高不可逆容量的常规有机电解质溶液的显着改进。

40. 发明授权

US08906557B2 Anode active material and method of preparing the same 有权
标题翻译：阳极活性物质及其制备方法
公开(公告)号：US08906557B2
公开(公告)日：2014-12-09
申请号：US11689941
申请日：2007-03-22
申请人： Gue-sung Kim , Yong-nam Ham , Han-su Kim , Dong-min Im
发明人： Gue-sung Kim , Yong-nam Ham , Han-su Kim , Dong-min Im
IPC分类号： H01B1/02 , H01M4/38 , H01M4/134 , H01M4/04 , H01M4/36 , H01M10/052 , H01M4/133 , H01M4/62 , H01M4/02
CPC分类号： H01M10/052 , H01M4/0471 , H01M4/133 , H01M4/134 , H01M4/364 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/625 , H01M4/626 , H01M2004/021 , Y02E60/122
摘要： Anode active materials and methods of preparing the same are provided. One anode active material includes a carbonaceous material capable of improving battery cycle characteristics. The carbonaceous material bonds to and coats metal active material particles and fibrous metallic particles to suppress volumetric changes.
摘要翻译：提供阳极活性物质及其制备方法。一种负极活性材料包括能够改善电池循环特性的碳质材料。碳质材料粘合并涂覆金属活性材料颗粒和纤维状金属颗粒以抑制体积变化。

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