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31. 发明专利

DOP2010000044A DERIVADO DE OXOPIRAZINA Y HERBICIDA 未知
公开(公告)号：DOP2010000044A
公开(公告)日：2010-03-31
申请号：DO2010000044
申请日：2010-01-29
申请人： KUMIAI CHEMICAL INDUSTRY CO , IHARA CHEMICAL IND CO
发明人： TAMAI RYUJI , ITO MINORU , KOBAYASHI MASAMI , MITSUNARI TAKASHI , NAKANO YUKI
IPC分类号： C07D241/44 , C07D471/04

32. 发明专利

CA2494130A1 PYRAZOLE DERIVATIVES AND PROCESS FOR THE PRODUCTION THEREOF 未知
公开(公告)号：CA2494130A1
公开(公告)日：2004-02-12
申请号：CA2494130
申请日：2003-07-31
申请人： IHARA CHEMICAL IND CO , KUMIAI CHEMICAL INDUSTRY CO
发明人： NAKATANI MASAO , MIYAZAKI MASAHIRO , ITO MINORU
IPC分类号： C07D231/20 , C07D231/22
摘要： The invention relates to pyrazole derivatives useful as intermediates in the production of isoxazoline derivatives having excellent herbicidal activity a nd crops-weeds selectivity and a process for the production thereof. Pyrazole derivatives represented by the general formula [I] or pharmacologically acceptable salts thereof: [I] wherein R1 is C1-6 alkyl; R2 is C1-3 haloalkyl ; R3 is hydrogen, C1-3 alkyl which may have one or more substituents selected from group .alpha. of substituents, or formyl; and R4 is hydrogen or C1-3 haloalkyl (with the proviso that when R3 is hydrogen or formyl, R4 is C1-3 haloalkyl, while when R3 is C1-3 alkyl which may have one or more substituen ts selected from group .alpha. of substituents, R4 is hydrogen or C1-3 haloalky l).

33. 发明公开

EP2792667A4 DIPHENYLAMINE COMPOUND AND METHOD FOR PRODUCING SAME 有权转让
标题翻译： VERFAHREN ZU IHRER HERSTELLUNG的DIPHENYLAMINVERBINDUNG
公开(公告)号：EP2792667A4
公开(公告)日：2015-07-15
申请号：EP12857717
申请日：2012-12-05
申请人： IHARA CHEMICAL IND CO , KUMIAI CHEMICAL INDUSTRY CO
发明人： ITO MINORU , IKUMI AKIKO
IPC分类号： C07C209/10 , C07C211/56 , C07C213/02 , C07C217/92
CPC分类号： C07C209/10 , C07C211/56 , C07C213/02 , C07C217/92
摘要： [Problem] The purpose of the present invention is to provide an inexpensive and convenient production method of diphenylamine compounds that can solve problems in the conventional technology such as decrease in reactivity, restriction of substituents, high temperature, high pressure, by-products or the like. Further, diphenylamine compounds useful as intermediates of medicine and agricultural chemicals are provided. [Solution] A method for producing diphenylamine compounds represented by general formula (3): which is characterized by reacting aniline compounds represented by general formula (2): under the presence of base and ethers solvent, with 2,6-dichloronitrobenzene compound represented by general formula (1): and a diphenylamine compound represented by general formula (3) .
摘要翻译：本发明的目的是提供一种廉价且方便的二苯胺化合物的制造方法，其能够解决现有技术中的问题，例如反应性的降低，取代基的限制，高温，高压，副产物或喜欢。此外，提供了可用作药物和农药的中间体的二苯胺化合物。 [溶液]通式（3）表示的二苯胺化合物的制造方法，其特征在于，使通式（2）表示的苯胺化合物与碱和醚类溶剂的存在下，与2,6-二氯硝基苯化合物通式（1）：和通式（3）表示的二苯胺化合物。

34. 发明公开

EP1405853A4 ISOXAZOLINE DERIVATIVES AND HERBICIDES 有权
标题翻译：异恶唑啉衍生物和除草剂
公开(公告)号：EP1405853A4
公开(公告)日：2004-07-21
申请号：EP02743670
申请日：2002-06-20
申请人： KUMIAI CHEMICAL INDUSTRY CO , IHARA CHEMICAL IND CO
发明人： NAKATANI MASAO , ITO MINORU , KIMIJIMA KYOKO , MIYAZAKI MASAHIRO , FUJINAMI MAKOTO , UENO RYOHEI , TAKAHASHI SATORU
IPC分类号： A01N43/80 , A01N43/82 , A01N43/90 , C07D413/12
CPC分类号： C07D413/12 , A01N43/80 , A01N43/82 , A01N43/90
摘要： The invention aims at providing isoxazoline derivatives having excellent herbicidal effect and selectivity between crops and weeds. Isoxazoline derivatives represented by the following general formula or pharmacologically acceptable salts thereof: wherein R1 is haloalkyl; R2 is hydrogen, alkyl, or the like; R3, R4, R5, and R6 are each hydrogen or the like; Y is pyrrolyl, pyrazolyl, isothiazolyl, oxazolyl, imidazolyl, pyridazinyl, pyrimidinyl, pyrazinyl, triazinyl, triazolyl, oxadiazolyl, or the like; and n is an integer of 0 to 2.

35. 发明专利

JP2000026421A DIARYL SULFIDE DERIVATIVE AND PEST CONTROLLING AGENT 失效
公开(公告)号：JP2000026421A
公开(公告)日：2000-01-25
申请号：JP1941899
申请日：1999-01-28
申请人： KUMIAI CHEMICAL INDUSTRY CO , IHARA CHEMICAL IND CO
发明人： TOYABE KEIJI , ITO MINORU , NISHIYAMA KIYOTOSHI , ASAHIDA MITSUHARU , WADA NOBUHIDE , YANO YUKO , KOMATSU MASAAKI , FUJISAWA TOYOICHI , SHIMAZU HOTOKU
IPC分类号： C07D275/02 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/54 , A01N43/653 , A01N43/76 , A01N43/78 , A01N43/80 , C07D213/70 , C07D213/71 , C07D213/85 , C07D213/89 , C07D249/12 , C07D261/10 , C07D263/46 , C07D275/03 , C07D277/36 , C07D277/40 , C07D277/48 , C07D277/56 , C07D277/64 , C07D307/68 , C07D333/34 , C07D333/36 , C07D333/38 , C07D409/04
摘要： PROBLEM TO BE SOLVED: To produce a new compound useful as an insecticide capable manifesting remarkable effects especially on Plutella xylostella, Chilo suppressalis, etc., which are agricultural and horticultural pests, having high efficacies even in a small dose and excellent in safety. SOLUTION: This compound is represented by formula I [Q denotes N or the like; X1 denotes H or the like; X2 denotes H or the like; the heteroaryl denotes a group represented by formula II or the like; R1 and R2 denote each H or the like; however, at least one thereof denotes SOnR4; R4 denotes a 1-4C alkyl or the like; (n) denote 0-2, with the proviso that X1 and X2 are not simultaneously H or the like], e.g. 2-(2,6-dichloro-4-trifluoromethylphenyl)-5- isopropylthiazole. The compound represented by formula I is produced by reacting, e.g. a compound represented by formula II (a group represented by formula IV is the above heteroaryl) [e.g. 2-(2,6-dichloro-4- trifluoromethylphenyl)-5-mercaptothiazole] with a compound represented by the formula; R4L1 (L1 is a halogen or the like) (e.g. isopropyl iodide) in the presence of a base such as potassium carbonate in a solvent.

36. 发明专利

JPH09301973A CHROMENE DERIVATIVE AND HERBICIDE CONTAINING THE SAME AS ACTIVE INGREDIENT 失效
公开(公告)号：JPH09301973A
公开(公告)日：1997-11-25
申请号：JP13946896
申请日：1996-05-09
申请人： KUMIAI CHEMICAL INDUSTRY CO , IHARA CHEMICAL IND CO
发明人： ITO MINORU , MIYAZAKI MASAHIRO , TAKEUCHI AKIRA , TAMARU MASATOSHI , YAMAJI MITSUHIRO , HANAI RYO , UOZU SOTA , SADOHARA HIDEO
IPC分类号： C07D487/04 , A01N43/38 , A01N43/54 , A01N43/90 , C07D405/04 , C07D513/04
摘要： PROBLEM TO BE SOLVED: To obtain a new 2H-chromene derivative having excellent weeding effect on various kinds of weeds, excellent in selectivity between weeds and crops and useful as an active ingredient of a herbicide for removing weeds in uplands, paddy fields, etc. SOLUTION: This compound is represented by formula I or formula III [X is H or a halogen; Y is X or cyano; R to R are each H, an alkyl, a cycloalkyl, a haloalkyl, etc., and R and R together may form a (substituted) 3-8C spiro ring; Q is 1-methyl-6-trifluoromethylurasil-3-yl, a group of formula II (Z is O or S), etc.], e.g. 3-(8-chloro-6-fluoro-2H-chromen-5-yl)-1-methyl-6- trifluoromethylurasil. The compound of formula I is obtained by condensing a compound of formula IV with a propargyl halide in the presence of a base to afford a compound of formula V and cyclizing the compound of formula V.

37. 发明专利

JP2000198768A 3-ARYLPHENYL SULFIDE DERIVATIVE AND INSECTICIDE/MITICIDE 失效
公开(公告)号：JP2000198768A
公开(公告)日：2000-07-18
申请号：JP10890399
申请日：1999-04-16
申请人： KUMIAI CHEMICAL INDUSTRY CO , IHARA CHEMICAL IND CO
发明人： TOYABE KEIJI , TAKETO NOBUO , ITO MINORU , HIRAIDE TETSUYA , NISHIYAMA KIYOTOSHI , ASAHIDA MITSUHARU , MAEDA YASUNOBU , WADA NOBUHIDE , FUJISAWA TOYOICHI , YANO YUKO , KOMATSU MASAAKI , TADA OSAMU
IPC分类号： C07D249/08 , A01N41/10 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/54 , A01N43/56 , A01N43/653 , A01N43/76 , A01N43/78 , C07C317/14 , C07C317/22 , C07C317/44 , C07C321/28 , C07C323/09 , C07C323/18 , C07C323/22 , C07C323/35 , C07C323/41 , C07C323/43 , C07C323/62 , C07D213/57 , C07D231/12 , C07D239/36 , C07D333/20 , C07D333/28
摘要： PROBLEM TO BE SOLVED: To obtain the subject new compound as a specific arylphenyl sulfide derivative, having high efficacy even at low doses, useful as an insecticide of high safety, exhibiting excellent controlling effect on insect pests including hemipteron pests, and capable of controlling resistant insect pests as well. SOLUTION: This new compound is a compound of formula I R is a 2-6C alkyl, alkenyl, or the like; (n) is 0-2; Ar is a group of formula II [Q1 to Q5 are each N, C-A1 (A1 is H, a halogen, or the like) or the like]; B0 to B3 are each H, a halogen, or the like}, e.g. 2-(2-propenylthio)-4-(4-trifluoromethylphenyl) benzonitrile. The compound of formula I is obtained by reaction of an arylphenylthiol derivative with a compound of RL1 (L1 is a halogen or the like) in the molar ratio of the latter to the former of 1-5 in 0.5-10 l of a solvent (e.g. diethyl ether) in the presence of 1-5 molar times of a base or radical initiator pref. at 0-150 deg.C for 10 min to 20 h.

38. 发明专利

JPH101478A INDAZOLESULFONYLUREA DERIVATIVE AND HERBICIDE 失效
公开(公告)号：JPH101478A
公开(公告)日：1998-01-06
申请号：JP17182896
申请日：1996-06-11
申请人： KUMIAI CHEMICAL INDUSTRY CO , IHARA CHEMICAL IND CO
发明人： ITO MINORU , SUZUKI CHIHARU , TAMARU MASATOSHI , HANAI RYO , UOZU SOTA , YAMAJI MITSUHIRO , SADOHARA HIDEO
IPC分类号： C07D401/14 , A01N47/36 , C07D403/12 , C07D409/14
摘要： PROBLEM TO BE SOLVED: To obtain a new compound exhibiting specifically high safety to useful crops, especially beet and having excellent herbicidal activity. SOLUTION: This compound is expressed by formula I (R is a haloalkylsulfonyl, an alkenylsulfonyl, a phenylcarbonyl, etc.; R and R are each H, halogen, an alkyl, an alkoxycarbonyl, etc.; A and B are each an alkoxy or an alkyl; X is O or S; Y is H, an alkyl, etc.; Z is N or methine), e.g. methyl 1-chloromethanesulfonyl-1-3 [(4,6-dimethoxy-2-pyrimidinyl) aminocarbonyl]aminosulfonyl}-1H-indazole-4-carboxylate. The compound of the formula I can be produced by reacting a compound of the formula II with a compound of the formula R -L in a solvent or in the absence of solvent optionally in the presence of a base. The compound exhibits excellent herbicidal activity against broad-leaved weeds such as polygonum, redroot pigweed, smooth pigweed and Indian mallow, cyperaceous weeds, true grass weeds, etc., over a wide growth range from the preemergency state to the growing stage.

39. 发明专利

JPH06157515A 1-CARBAMOYL-1,2,4-TRIAZOLE DERIVATIVE AND HERBICIDE 失效
公开(公告)号：JPH06157515A
公开(公告)日：1994-06-03
申请号：JP34155792
申请日：1992-11-27
申请人： KUMIAI CHEMICAL INDUSTRY CO , IHARA CHEMICAL IND CO
发明人： YAMAGUCHI MIKIO , ITO MINORU , TAKEUCHI AKIRA , TACHIKAWA SHIGEHIKO , YANAGISAWA KATSUTADA , WASHINO MASAMI , MIYAZAWA TAKESHIGE
IPC分类号： A01N43/653 , A01N47/38 , C07D403/12 , C07D413/12
摘要： PURPOSE:To obtain a 1-carbamoyl-1,2,4-triazole derivative useful as a herbicide capable of withering only weeds without exerting an undesirable influence by its action, remaining only slight residue to environment because of sufficient effects with a small amount. CONSTITUTION:A compound of formula I {X is O or NR [R is H, alkyl, formula VIII (R is halogen, alkyl, alkoxy or haloalkyl; (i) is 0-2; (j) is 0 or 1)]; R and R are each alkyl, halogen or alkoxy; R and R are H, alkyl, alkenyl, alkynyl or phenyl, or ones mutually bonding to form a ring; (n) is 1 or 2} such as 1-(N,N-diethylcarbamoyl)-3-(3,5-dimethylisooxazol-4-ylsulfonyl)-1 H-1,2,4-triazole. This compound is obtained by reacting a compound of formula II with 2-mercapto-1,2,4-triazole to give a compound of formula III, reacting the compound of formula III with a compound of formula IV, treating the prepared compound of formula V with an oxidizing agent to give a compound of formula VI and then reacting the resultant compound with a compound of formula VII.

40. 发明专利

CO6160266A2 DERIVADO DE OXOPIRAZINA Y HERBICIDA 未知
公开(公告)号：CO6160266A2
公开(公告)日：2010-05-20
申请号：CO10010108
申请日：2010-02-01
申请人： KUMIAI CHEMICAL INDUSTRY CO
发明人： TAMAI RYUJI , ITO MINORU , NAKANO YUKI , MITSUNARI TAKASHI , KOBAYASHI MASAMI
IPC分类号： A01N43/66 , A01N43/80 , A01N43/84 , A01N43/90 , A01N47/02 , C07D241/44 , C07D471/04
摘要： Se describe un derivado de oxopirazina que tiene excelente actividad herbicida, exhibiendo al mismo tiempo alta seguridad para cosechas útiles, o una sal del mismo. También se describe un herbicida que contiene dicho derivado de oxipirazina o una sal del mismo. Se describe de manera específica un derivado de oxipirazina representado por la fórmula general [I] que se encuentra más adelante o una sal del mismo. También se describe en forma específica un herbicida que contiene cualesquiera de los compuestos. (En la fórmula X1 representa un átomo de oxígeno e un átomo de azufre; X2 representa CH o N(O)m; en donde m representa un entero de 0 ó 1; R1 representa un átomo de hidrógeno; un grupo C1-C12 alquilo o similar; R2 es un átomo de halógeno, un grupo ciano o similar; R3 representa un grupo hidroxilo; un átomo de halógeno o similar; A1 representa C(R4R5); A2 representa C(R6R7) o C=O; A3 representa (CR8R9); y R4-R9 cada uno representan un átomo de hidrógeno o un grupo alquilo).1.- Un derivado de oxopirazina representado por la fórmula [I], o una sal agroquímicamente aceptable del mismo:en donde X1 representa un átomo de oxigeno o un átomo de azufre; X2 representa CH (el átomo de carbono puede ser substituido con R2), esto es, CH el cual puede ser substituido con un substituyente R2, o N(O)m; m representa un entero de 0 ó 1; R1 representa un átomo de hidrógeno; un grupo C1-C12 alquilo; un grupo C2-C6 alquenilo; un grupo C2-C6 alquinilo; un grupo C3-C8 cicloalquilo; un grupo C3-C8 cicloalquil-C1-C6 alquilo; un grupo C1-C6 haloalquilo; un grupo C3-C6 haloalquenilo; un grupo C2-C6 haloalquinilo; un grupo C3-C8 halocicloalquilo; un grupo C3-C8 halocicloalquil-C1-C6 alquilo; un grupo amino-C1-C6 alquilo; un grupo nitro-C1-C6 alquilo; un grupo mono(C1-C6 alquil)amino-C1-C6 alquilo; un grupo di (Ci-Cs alquiaminoCi-Cs alquilo; ...

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